US20060144855A1 - Distributor for pasty to flowable materials - Google Patents

Distributor for pasty to flowable materials Download PDF

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Publication number
US20060144855A1
US20060144855A1 US10/523,580 US52358005A US2006144855A1 US 20060144855 A1 US20060144855 A1 US 20060144855A1 US 52358005 A US52358005 A US 52358005A US 2006144855 A1 US2006144855 A1 US 2006144855A1
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US
United States
Prior art keywords
bag
container
mouthpiece
dispenser
pump
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/523,580
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English (en)
Inventor
Alfred Von Schuckmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of US20060144855A1 publication Critical patent/US20060144855A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/02—Membranes or pistons acting on the contents inside the container, e.g. follower pistons
    • B05B11/026—Membranes separating the content remaining in the container from the atmospheric air to compensate underpressure inside the container

Definitions

  • the invention relates to a dispenser for pasty to flowable substances, the filling volume of which is held by a dimensionally stable container, at least half of which comprises a bag which, when emptied from the mouthpiece, collapses into one container half.
  • a dispenser of this type is known from EP 0 505 611 A2.
  • the delivery of the pasty substance takes place by means of positive emptying pressure. It is produced by means of a dimensionally stable, squeezable container.
  • the pressure. build-up is obtained under valve control, acting from the bottom of the dispenser.
  • Such a device is located in the head of the dispenser.
  • the bag enclosed by the container comprises in part a bottom half which can be made to collapse and the other half of which is stiffened from the inside by a hard part.
  • U.S. Pat. No. 2,471,852 provides the proposal of producing the positive emptying pressure by means of a compression spring mounted at the bottom of the dimensionally stable container.
  • the collapsing bag provided over it in that case comprises part of a cartridge, the upper container half of which is formed as a dome-shaped hard part, in the zenith of which there is an outlet valve, which is actuated by means of a dispenser mechanism similar to a pushbutton.
  • the spring has over it a cup-shaped body, which is shaped to follow the tapering collapsing contour.
  • a dispenser of the generic type of a simpler, functionally more advantageous design is achieved: there is no longer any need for the deforming squeezing actuation of the container, which if overdone or underdone could lead to malfunctions and, moreover, also takes quite some getting use to. Rather, the dispenser head actuation of the accustomed form of handling is used.
  • the replenishing of the apportioned portion dispensed takes place by suction via the filling level column of the pasty to flowable substance. The bag follows on automatically in the dispensing direction.
  • a grid is disposed in front of the passage region between container shell half and emptying mouthpiece pump, to support the collapsed bag. This prevents the delivery access path from being clogged with pasty substance.
  • the shell half equipped with the emptying mouthpiece pump has on its inner surface supporting ribs for the bag, preferably reaching as far as the passage region.
  • Such a system of struts, similar to buildings, can be provided already in the injection-molding process. Path-blocking arrangements such as loops are avoided. It is also advantageous that the bag has an easily stabilized base area.
  • the inlet opening, adjoining the passage region, of the emptying mouthpiece pump is formed as a web-interrupted annular opening, running concentrically and coaxially in relation to the bag. The substance present is sucked over a wide front to replenish the supply. No partial pockets can form in the bag.
  • an annular opening may also be formed by a ring of holes.
  • the further measure that the annular opening is disposed in the base of a collecting funnel diverging counter to the direction of delivery of the substances proves to be advantageous.
  • Said collecting funnel acts as an aligned feeding collector.
  • the diameter of the annular opening substantially corresponds to the diameter of the passage region or grid.
  • FIG. 1 shows the dispenser realised as a standing unit, in side view, closed by a protective cap, slightly enlarged,
  • FIG. 2 shows the plan view of this
  • FIG. 3 shows the dispenser in an exploded representation
  • FIG. 4 shows an inner view of the shell half of the container carrying the emptying mouthpiece pump, showing supporting ribs for the bag,
  • FIG. 5 shows a vertical section through the container of the dispenser, with flanges still unconnected
  • FIG. 6 shows a enlargement VI from FIG. 5 .
  • FIG. 7 shows a cross-section in the region of a supporting rib
  • FIG. 8 shows a vertical section through the emptying mouthpiece pump, greatly enlarged.
  • the dispenser Sp represented is realised as a standing unit. It serves for dispensing pasty to flowable substances M, the filling volume of which is held by a dimensionally stable container 1 .
  • the container 1 is of an elongate form, flat and of unround cross-section, preferably elliptical (see FIG. 2 ).
  • the container 1 is divided in half with regard to its longitudinal center axis x-x in terms of assembly.
  • the shell halves 2 , 3 are identical in terms of their cavity, apart from further molded formations still to be explained below.
  • the open ends, directed toward each other, are angled away outward at the periphery.
  • the upper shell half 2 provides a flange 4 and the lower shell half 3 provides a flange 5 (cf. also FIG. 6 ).
  • the flange 4 of the upper shell half 2 is folded vertically in the direction of a standing surface 6 , as seen in the longitudinal direction of the container 1 .
  • the corresponding angle leg 7 engages over the outwardly directed end edge 8 of the flange 5 of the lower shell half 3 .
  • the relevant edge contour consequently forms a channel 9 (cf. FIG. 3 ) for the snug fit of the flange 5 of the lower shell half 3 .
  • This peripheral edge connection creates a good basis for the mounting of an internal element of the container 1 , to be precise in the form of a bag 10 .
  • Said bag is foldable, preferably capable of turning inside out, and has for this purpose the required elasticity or also flexibility.
  • the bag 10 is made to match the inner lining both of the lower shell half 3 and of the upper shell half 2 that can be reached when it collapses. It comes to lie in close contact with the respective inside wall of the container shell halves 2 , 3 . Above, pasty substance M lies in between.
  • the bag 10 Facing the plane E-E, the bag 10 is held on the container side by means of an edge 11 .
  • the faces directed toward one another of the flanges 4 and 5 serve in this case as a connecting join similar to clamping jaws.
  • the correspondingly outwardly projecting edge 11 of the bag 10 is in this case captured in the region of an, as it were, equatorial connecting join.
  • Its elastic material serves in this case at the same time as a seal.
  • the connecting join has the reference numeral 12 . It may have parallel walls, as clearly shown by FIG. 6 , or else thicken wedgingly continuously toward the outer edge, so that undercut areas are created which, in addition to the mere nonpositive connecting engagement, also permit a positive engagement as a reinforced capturing means.
  • the entries to the connecting join have a convex transverse rounding. This avoids a cutting action at the “collapse hinge”.
  • the bending of the angle leg 7 may take place thermally.
  • an adhesive connection, a latching connection or even a screw connection is also conceivable if the shell halves 2 , 3 are rotationally symmetrical, at least in the region of the join.
  • the shell halves 2 , 3 go over into narrowed cross-sectional zones.
  • the upper tapering zone in this case ends in a passage region 13 of the container 1 for the delivery of the pasty substance M.
  • Said passage region is circular and of relatively large diameter, using virtually the entire flattening width of the container 1 .
  • the end of the lower shell half 3 directed toward the standing surface 6 likewise goes over into a narrowed cross-sectional zone.
  • This tapering zone has a standing edge 14 .
  • Said standing edge is of such a vertical height that it leaves a clearance with respect to said standing surface 6 under the base 15 of the container 1 formed there.
  • the base 15 has in the center an air-equalizing opening 16 . Said opening compensates in terms of volume for the region underneath the bag 10 as the latter moves upward.
  • connection piece 17 receives an annular collar 18 adapted to it by being reduced in diameter. Both formations are basically cylindrical.
  • the relevant head region of the dispenser Sp serves for receiving a manually actuable emptying mouthpiece pump P.
  • the emptying mouthpiece pump P actually seated in the apex region of the upper shell half 2 forms with its upper structure an actuating button 19 oriented vertically in terms of movement. Away from its recessed actuating surface, there is a laterally directed, upwardly sloping mouthpiece 20 .
  • Said mouthpiece is of a tubular form, at least in the end region, and is consequently suitable for the delivery of an amount of pasty or flowable substance M formed into a strand.
  • a negative pressure is exerted by means of the mouthpiece pump P, obtaining the effect of powerful, complete emptying of the bag 10 , which initially hangs down then increasingly collapses in the dispensing direction, to be precise perceptibly in the direction of a clearance facing the mouthpiece pump P of the upper shell half 2 of a size corresponding to the bag 10 .
  • the direction of delivery is identified by arrow y. It coincides with the longitudinal center axis x-x and goes over into a slightly rising lateral direction within the actuating button 19 .
  • the actuating button 19 carrying the mouthpiece 20 , can be turned, about said longitudinal centre axis x-x. This permits individually operatingly-convenient dispensing, whether over the longer axis of the elliptical outline of the container 1 or over the shorter axis or over steplessly achievable intermediate regions.
  • the delivery does not leave any residue, since a grid 21 is disposed in front of the passage region 13 of the container 1 , between the inside wall of the upper container shell half 2 and the emptying mouthpiece pump P. Said grid fills the passage region 13 and is convexly curved slightly into the region of the filling volume, counter to the direction of delivery arrow y. It is stiffened in this way.
  • the grid 21 may be a separate component.
  • this basket-like formation already already to be molded onto the upper shell half 2 .
  • the assembly comprises an outer ring 22 and an inner ring 23 joined by radial webs 24 (reference is made to FIG. 4 ). There are six radial webs 24 , to be precise spaced at equal angles from one another.
  • a further means for dispensing the pasty substance M with virtually no residue is that the shell half 2 equipped with the emptying mouthpiece pump P on the inside is provided with supporting ribs 25 for the bag 10 . Said bag cannot then get in the way, even partially. Rather, the flow supply paths W are kept free by the exposed system of struts of such supporting ribs 25 (compare FIG. 7 ).
  • the bag 10 or its wall can move in an orderly fashion toward the passage region 13 in the direction of delivery arrow y.
  • the outer ring 22 rests on heads 25 ′ of the supporting ribs 25 protruding into the passage region 13 . Said outer ring is mounted in a clamping manner on them.
  • ribs 25 distributed at equal angles are provided. They can already be moulded-in.
  • the rib height increases continuously in the direction of the passage region 13 and tapers in the opposite direction on the inner face of the shell surface 2 .
  • the base area 26 of the bag 10 is formed with a thicker wall than the wall of the bag 10 adjoining in the manner of a cup.
  • the thickness is chosen such that the overall collapsability is not impaired, that is to say that the collapsing behavior is retained.
  • Said thickening acts like a slightly stiffened follow-up base.
  • the thickening may extend over the entire base area 26 or, however, as represented, be formed merely as an annular path.
  • the head of the dispenser Sp has a protective cap 27 over it. This at the same time avoids unwanted discharge of the content, for example when the container 1 is carried along with other utensils in a bag or the like.
  • the relative position of the protective cap 27 is defined, for example by use of the stepped transition between the connection piece 17 and the annular collar 18 , forming a shoulder 28 .
  • the cap-shaped body may be frictionally mounted; however, a screw connection may also be used, as preferred here (compare FIG. 8 ).
  • the annular collar 18 received in the connecting piece 17 is part of an insert 29 received in the dispenser head. Said annular collar is terminated on the substance side by a base 30 .
  • Extending from the base 30 is part of the cylinder 31 forming the aforementioned emptying mouthpiece pump P.
  • Running in the cylinder 31 is a piston 32 , which can be displaced against spring loading by the actuating button 19 .
  • Said piston forms the upper limitation of a pump chamber 33 , the lower termination of which is provided by the base 30 .
  • inlet valve VI In the base 30 there is an inlet valve VI. It is a non-return valve, which controls in terms of flow an annular opening 34 incorporated in the base 30 and consists of elastomeric material.
  • the outlet valve V 2 keeps passage openings 36 closed.
  • the central channel 38 itself is then in connection with the mouthpiece 20 .
  • the shaft 39 of the piston 32 attached to the rear of the piston head 35 is of a hollow form. As can be seen from the drawing, the functional parts are accommodated in it appropriately for operation.
  • a connecting part 40 contributes to this. So too does the cup-shaped form.
  • the cup opening points in the direction of the container 1 . Its top is firmly connected to the actuating button 19 .
  • the cup-shaped connecting part 40 is provided with an annular stop projection 41 .
  • Said stop projection interacts with an axial channel 42 , providing counter stops, on the inner side of the annular collar 18 .
  • the annular width determines the excursion and establishes the portion-forming clearance of the pump chamber 33 .
  • the cup-shaped connecting part 40 like the annular wall of the cylinder 31 open in the opposite direction, contributes to the creation of a spring chamber 43 .
  • Said spring chamber receives a compression spring 44 .
  • the latter loads the actuating button 19 in the direction of the basic position, as revealed by FIG. 8 .
  • the spring action at the upper end is directed against the top of the cup-shaped connecting part 40 and the spring action at the end facing the supply of substance is directed against the base 30 , which consequently forms the fixed abutment.
  • Special supporting elements such as webs, beads etc. are used.
  • the compression spring 44 has a slight bias.
  • the annular opening 34 formed in the base 30 is interspersed, between the central region of the base and the base region concentrically adjoining radially beyond the annular opening, by webs 45 .
  • Such webs 45 disposed in the manner of spokes, preferably extend such that they are spaced at equal angles from one another.
  • the web-interrupted system explained and also the ring of holes system can optionally also be used with respect to the passage opening 36 in the region of the outlet valve V 2 .
  • Both the annular opening 34 according to the described basic configuration and the passage opening 36 continue in the direction of delivery arrow y into funnel-shaped widened portions in the manner of countersunk holes for screws. This assists the raising of the valves V 1 , V 2 to open them during the discharging pumping process.
  • annular opening having a catching funnel 46 on the side facing the substance M.
  • Said catching funnel is already moulded into the base 30 and has a wall diverging in a rotationally symmetrical manner counter to the dispensing direction arrow y.
  • the diameter of the annular opening 34 substantially corresponds to the diameter of the passage region 13 or of the grid 21 .
  • the emptying mouthpiece pump P can be positioned in relation to the neck, that is the connecting piece 17 , of the container 1 by way of the screw connection.
  • the thread is designated by 47 .
  • a screw limitation 48 At the height of the inlet valve V 1 there is a screw limitation 48 . Directed inward into the housing, said screw limitation continues into a shoulder wall, which in the way described above carries the grid 21 . Between the grid 21 and the base 30 there remains a dispensing antechamber, which cannot be clogged by the bag wall.
  • the delivery takes place as follows: downward movement of the actuating button 19 causes the volume of the pump chamber 33 to be reduced. Substance M located in it cannot escape in the direction of the supply on account of the closing action of the inlet valve V 1 .
  • the enclosed substance, passing the passage opening 36 is delivered via the intermediate chamber 37 to the central channel 38 , to emerge from there via mouthpiece 20 .
  • This path is released by the opening action of the outlet valve V 2 .
  • the actuating button 19 is let go after delivery, a return displacement of the piston 32 takes place in the direction of the basic position represented. This leads to a negative pressure in the pump chamber 33 .
  • substance M is replenished from the supply.
  • the inlet valve V 1 opens. Extraneous air cannot enter as a result of the closing action of the outlet valve V 2 .
  • the return displacement takes place because of the force of the compression spring 44 .

Landscapes

  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Coating Apparatus (AREA)
  • Control And Other Processes For Unpacking Of Materials (AREA)
  • Bag Frames (AREA)
US10/523,580 2002-07-29 2003-07-07 Distributor for pasty to flowable materials Abandoned US20060144855A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10234417.5 2002-07-29
DE10234417A DE10234417A1 (de) 2002-07-29 2002-07-29 Spender für pastöse bis fließfähige Massen
PCT/EP2003/007245 WO2004013016A1 (de) 2002-07-29 2003-07-07 Spender für pastöse bis fliessfähige massen

Publications (1)

Publication Number Publication Date
US20060144855A1 true US20060144855A1 (en) 2006-07-06

Family

ID=30128468

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/523,580 Abandoned US20060144855A1 (en) 2002-07-29 2003-07-07 Distributor for pasty to flowable materials

Country Status (13)

Country Link
US (1) US20060144855A1 (ru)
EP (1) EP1527005B1 (ru)
JP (1) JP2006500288A (ru)
CN (1) CN1671605A (ru)
AT (1) ATE355235T1 (ru)
AU (1) AU2003253032A1 (ru)
CA (1) CA2493256A1 (ru)
DE (2) DE10234417A1 (ru)
PL (1) PL202337B1 (ru)
RU (1) RU2326036C2 (ru)
TW (1) TWI290120B (ru)
UA (1) UA84847C2 (ru)
WO (1) WO2004013016A1 (ru)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060255072A1 (en) * 2005-04-21 2006-11-16 Hagin Susanne E Metering pump arrangement and method for the production of a filled metering pump arrangement
US20100327015A1 (en) * 2009-06-25 2010-12-30 Nihon Kim Co., Ltd. Storage container
KR101120873B1 (ko) * 2007-02-21 2012-02-27 콸콤 인코포레이티드 무선 노드 검색 프로시저
US20120175382A1 (en) * 2011-01-11 2012-07-12 Mcauley-Davis Talisha N Liquid Container
US20130098944A1 (en) * 2011-10-24 2013-04-25 Myrtle Broadney Container Assembly With Dual Means of Dispensing Fluids
US20140027470A1 (en) * 2012-07-25 2014-01-30 Keith A. Pelfrey Collapsible container and dispenser employing a collapsible container
US20140103034A1 (en) * 2012-10-12 2014-04-17 Grayling Industries, Inc. Flexible container liner
US9907420B2 (en) * 2014-01-20 2018-03-06 Jennifer Fellin Food pouch container
USD822500S1 (en) 2017-01-24 2018-07-10 Gesenia Vargas-Folch Lotion bottle
USD977985S1 (en) * 2019-08-29 2023-02-14 J. Choo Limited Fragrance bottle
USD1009510S1 (en) 2020-01-21 2024-01-02 Conopco, Inc. Cartridge
USD1011888S1 (en) * 2020-01-21 2024-01-23 Conopco, Inc. Bottle

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004103855A1 (en) * 2003-05-20 2004-12-02 Erik Langelund Container for a liquid or semi-liquid material, method for manufacturing the container and use thereof
DE102005049531B4 (de) * 2005-04-25 2021-10-28 Rpc Bramlage Gmbh Spender für flüssige oder pastöse Massen
IT1393823B1 (it) * 2009-04-20 2012-05-11 Lumson Spa Dispositivo per contenere a tenuta d'aria e per erogare sostanze fluide
KR101606385B1 (ko) * 2014-12-04 2016-03-25 (주)서일홀딩스 액상 용기
KR101530907B1 (ko) * 2014-12-26 2015-06-23 이충호 액상 용기
FR3063661B1 (fr) * 2017-03-07 2021-05-21 Promens Sa Dispositif de distribution d'un produit avec amorcage ameliore
KR102264427B1 (ko) * 2018-06-26 2021-06-11 벨몬트 & 컴퍼니 인코포레이티드 내부 액세스를 가지는 분배 용기

Citations (7)

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US2471852A (en) * 1947-07-19 1949-05-31 Bau Robert Gordon Dispenser with flow restricting valve
US3288334A (en) * 1965-05-28 1966-11-29 Calmar Inc Disppenser with collapsible container and pump
US5100027A (en) * 1989-07-25 1992-03-31 L'oreal Dispensing unit for at least one product, a cosmetic product in particular, in cream, liquid or powder form
US5630531A (en) * 1994-08-08 1997-05-20 Societe D'innovation Recherche Plastique Device for packaging a product with a manual pump for dispensing individual metered amounts
US6070763A (en) * 1997-07-02 2000-06-06 L'oreal Dispenser pump for a liquid or pasty product
US6073805A (en) * 1998-03-27 2000-06-13 L'oreal Assembly for packaging and dispensing a liquid product
US6648244B2 (en) * 2001-12-18 2003-11-18 Lung-You Yu Atomizer with a bellows-shaped container body

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FR2081244A1 (ru) * 1970-03-23 1971-12-03 Bouet Bernard
FR2251195A5 (en) * 1973-11-09 1975-06-06 Gillespie Gordon Dispensing container for face cream, etc. - has eccentric stiffening disc on varied thickness base of discharge membrane
DE9013168U1 (de) * 1990-09-17 1992-01-16 Wella Ag, 6100 Darmstadt Behälter
DE4121179A1 (de) * 1991-06-27 1993-03-11 Kautex Werke Gmbh Quetschflasche mit innenbehaelter

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2471852A (en) * 1947-07-19 1949-05-31 Bau Robert Gordon Dispenser with flow restricting valve
US3288334A (en) * 1965-05-28 1966-11-29 Calmar Inc Disppenser with collapsible container and pump
US5100027A (en) * 1989-07-25 1992-03-31 L'oreal Dispensing unit for at least one product, a cosmetic product in particular, in cream, liquid or powder form
US5630531A (en) * 1994-08-08 1997-05-20 Societe D'innovation Recherche Plastique Device for packaging a product with a manual pump for dispensing individual metered amounts
US6070763A (en) * 1997-07-02 2000-06-06 L'oreal Dispenser pump for a liquid or pasty product
US6073805A (en) * 1998-03-27 2000-06-13 L'oreal Assembly for packaging and dispensing a liquid product
US6648244B2 (en) * 2001-12-18 2003-11-18 Lung-You Yu Atomizer with a bellows-shaped container body

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060255072A1 (en) * 2005-04-21 2006-11-16 Hagin Susanne E Metering pump arrangement and method for the production of a filled metering pump arrangement
KR101120873B1 (ko) * 2007-02-21 2012-02-27 콸콤 인코포레이티드 무선 노드 검색 프로시저
US20100327015A1 (en) * 2009-06-25 2010-12-30 Nihon Kim Co., Ltd. Storage container
US20120175382A1 (en) * 2011-01-11 2012-07-12 Mcauley-Davis Talisha N Liquid Container
US20130098944A1 (en) * 2011-10-24 2013-04-25 Myrtle Broadney Container Assembly With Dual Means of Dispensing Fluids
US9045268B2 (en) * 2012-07-25 2015-06-02 Gojo Industries, Inc. Collapsible container and dispenser employing a collapsible container
US20140027470A1 (en) * 2012-07-25 2014-01-30 Keith A. Pelfrey Collapsible container and dispenser employing a collapsible container
US20140103034A1 (en) * 2012-10-12 2014-04-17 Grayling Industries, Inc. Flexible container liner
US9907420B2 (en) * 2014-01-20 2018-03-06 Jennifer Fellin Food pouch container
USD822500S1 (en) 2017-01-24 2018-07-10 Gesenia Vargas-Folch Lotion bottle
USD977985S1 (en) * 2019-08-29 2023-02-14 J. Choo Limited Fragrance bottle
USD1009510S1 (en) 2020-01-21 2024-01-02 Conopco, Inc. Cartridge
USD1011888S1 (en) * 2020-01-21 2024-01-23 Conopco, Inc. Bottle

Also Published As

Publication number Publication date
TW200404720A (en) 2004-04-01
CA2493256A1 (en) 2004-02-12
EP1527005B1 (de) 2007-02-28
WO2004013016A1 (de) 2004-02-12
PL373736A1 (en) 2005-09-05
DE10234417A1 (de) 2004-02-12
PL202337B1 (pl) 2009-06-30
DE50306676D1 (de) 2007-04-12
ATE355235T1 (de) 2006-03-15
EP1527005A1 (de) 2005-05-04
RU2326036C2 (ru) 2008-06-10
CN1671605A (zh) 2005-09-21
JP2006500288A (ja) 2006-01-05
TWI290120B (en) 2007-11-21
RU2005105291A (ru) 2005-08-10
UA84847C2 (ru) 2008-12-10
AU2003253032A1 (en) 2004-02-23

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