US20050233140A1 - Polytrimethylene terephtalate conjugate fiber and method of preparing the same - Google Patents

Polytrimethylene terephtalate conjugate fiber and method of preparing the same Download PDF

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Publication number
US20050233140A1
US20050233140A1 US10/516,235 US51623504A US2005233140A1 US 20050233140 A1 US20050233140 A1 US 20050233140A1 US 51623504 A US51623504 A US 51623504A US 2005233140 A1 US2005233140 A1 US 2005233140A1
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Prior art keywords
ptt
polytrimethylene
fiber
terephtalate
conjugate
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Abandoned
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US10/516,235
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English (en)
Inventor
Tae-Hwan OH
Jung-Hun Hyun
Byeong-Il Kim
Jin-Soo Ham
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Huvis Corp
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Huvis Corp
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Priority claimed from KR10-2002-0029202A external-priority patent/KR100481296B1/ko
Priority claimed from KR1020020064897A external-priority patent/KR20040036094A/ko
Application filed by Huvis Corp filed Critical Huvis Corp
Assigned to HUVIS CORPORATION reassignment HUVIS CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HAM, JIN-SOO, HYUN, JUNG-HUN, KIM, BYEONG-IL, OH, TAE-HWAN
Publication of US20050233140A1 publication Critical patent/US20050233140A1/en
Abandoned legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
    • D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
    • D02G1/0213—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting after drawing the yarn on the same machine
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
    • D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
    • D02G1/022—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting while simultaneously drawing the yarn
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/02—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
    • D02G1/0206—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
    • D02G1/0266—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting false-twisting machines
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]

Definitions

  • the present invention in general, relates to a polyester conjugate fibers and method of preparing such fibers.
  • the present invention relates to a polyester conjugate fiber, and a method of preparing such a fiber, comprising conjugate-spinning two types of polyesters having different intrinsic viscosities to produce a fiber having a side-by-side cross-section, and subsequently performing a heat-treating and relaxation process to develop high self-crimpability and overall quality of the fiber. More particularly, the present invention relates to a method of preparing a polyester conjugate fiber, capable of developing crimpability and supplying good spinning operability even at a smaller difference between intrinsic viscosities of two polymers than a conventional intrinsic viscosity difference.
  • Flat yarns prepared by the conventional methods have a crimping rate of about 30% (when measured by the method provided in the present invention), thus providing elasticity to manufactured textile fabrics.
  • additional fabric weave patterns should be designed to develop high elasticity, and it is especially hard to obtain satisfactory elasticity in fabric weaves having many cross-links of warp and weft.
  • Japanese Pat. Laid-open Publication No. 2000-256918 discloses a latent crimp polyester conjugate fiber, which is prepared by conjugate-spinning polyester ‘A’ containing trimethylene terephtalate at an amount of over 85 mol % of repeat units and an uncopolymerized component having three or more ester-forming functional groups, and either of polyester ‘B’ containing trimethylene terephtalate at an amount of over 85 mol % of repeat units and a component having three or more ester-forming functional groups at an amount of 0.5-0.2 mol %, and polyester ‘C’ containing trimethylene terephtalate at an amount of over 85 mol % of repeat units and an uncopolymerized component having three or more ester-forming functional groups, having an intrinsic viscosity lower than the polyester ‘A’ by 0.15-0.30, into a side-by-side or eccentric sheath-core
  • two polyester components must have a difference of over 0.15 in their intrinsic viscosities.
  • the fiber in the flat yarn form must be processed into a false twisted yarn by a false twisting treatment to obtain desired crimpability.
  • the fiber is severely curved at a lower part of a spinning nozzle, and spinning operability is very poor.
  • the difference in intrinsic viscosities of two components of a side-by-side fiber is small good spinning operability is obtainable, but it is hard to develop crimpability in a resulting fiber.
  • a conjugate fiber can be prepared by conjugate spinning two different types of trimethylene terephtalates having a difference of 0.05-0.15 in their intrinsic viscosities into a side-by-side fiber, with good spinning operabililty, and the resulting conjugate fiber exhibits high self-crimpability even in a flat yarn form, not in a false twist yarn form, in addition that, when a bicomponent conjugate fiber prepared by conjugate-spinning polymers having a small difference between their intrinsic viscosities is subjected to a false twisting treatment, difference in shrinkage of the polymers occurs owing to the difference in the intrinsic viscosities of the polymers, and latent torque is developed by false twisting at a heat treatment step, thereby giving a conjugate fiber with high crimpability as well as sufficient bulky property.
  • FIG. 1 illustrates an example of a cross-section of polytrimethylene terephtalate conjugate fibers prepared according to the present invention
  • FIG. 2 is a schematic view of a spinning machine equipped with extruders, which is used to produce the fibers of Examples of the present invention.
  • a method of preparing a polytrimethylene terephtalate conjugate fiber comprising conjugate spinning two types of polytrimethylene terephtalates having different intrinsic viscosities into a side-by-side fiber in which a difference between the intrinsic viscosities ranges from 0.05 to 0.15, under a condition, which achieves a difference between melt viscosities of the two polymers in a range of below 1000 poise.
  • the present invention provides a polytrimethylene terephtalate conjugate fiber comprising two types of polytrimethylene terephtalates having different intrinsic viscosities, where a difference between the intrinsic viscosities ranges from 0.05 to 0.15, and having a side-by-side structure.
  • the two types of polytrimethylene terephtalates conjugate-spun into a side-by-side fiber according to the present invention have different intrinsic viscosities in which the difference between the intrinsic viscosities is preferably in a range of from 0.05 to 0.15.
  • a side-by-side fiber having a structure shown as in FIG. 1 can be melt-spun without additional nozzle designs and has good spinning operability, in addition that a desired fiber having good crimpability can be obtained just by combination of two polymers having a small difference in intrinsic viscosity by suitably setting temperatures of extruders.
  • PTT-H a polytrimethylene terephtalate having a high intrinsic viscosity
  • PTT-L a polytrimethylene terephtalate having a low intrinsic viscosity
  • bis(3-hydroxypropyl)ether (DPG) and cyclic dimmer as by-products generated during polymerization may be present at amounts of less than 3.0 mol %/diol and less than 3 wt %, respectively.
  • DPG bis(3-hydroxypropyl)ether
  • cyclic dimmer as by-products generated during polymerization may be present at amounts of less than 3.0 mol %/diol and less than 3 wt %, respectively.
  • the difference between intrinsic viscosities of PTT-H and PTT-L is below 0.15, it is known that a difference between shrinkages of the two polymers is small owing to a small difference between melt viscosities between the two polymers, thereby not producing a desired fiber having a satisfactory crimping rate.
  • a polytrimethylene terephtalate conjugate fiber having a desired crimping rate is prepared even by using polymers having the same viscosity difference described above.
  • the difference between the melt viscosities of the two polymers is below 1000 poise, and more preferably less than 300 poise, a resulting fiber having a satisfactory crimping rate of over 30% even may be obtained using the polymers having the small viscosity difference of below 0.15.
  • a method of measuring the crimping rate will be described below, and the crimping rate should be over 30% to manufacture a fabric having sufficient elasticity.
  • the difference between the melt viscosities of the two polymers may be regulated by extruding the two polymers at different temperatures to generate different heat histories in melted products of the two polymers, or modifying combination ratio of a polymer having high viscosity and a polymer having low viscosity.
  • spinning temperature is preferably in a range of from 235 to 275° C.
  • PTT-H and PTT-L have different intrinsic viscosities ranging from 0.7 to 1.1, and the difference between the intrinsic viscosities of the two polymers is preferably from 0.05 to 0.15.
  • the intrinsic viscosity of each polymer is less than 0.7 or more than 1.1, spinning operability is poor.
  • PTT-L has an intrinsic viscosity of 0.8-0.95 and is 30-70% of total weight of a resulting fiber
  • PTT-H has an intrinsic viscosity of 0.85-1.1 and is 70-30% of total weight of the resulting fiber.
  • a side-by-side fiber having a crimping rate of 30% is obtained.
  • Such a fiber is usable to prepare elastic fabrics, but not suitable for preparation of high elastic fabrics that are manufactured using spandex covered yarns and require high crimping rate.
  • a crimped flat yarn is prepared and then undergoes a false twisting process, thereby producing a grey yarn usable in preparing highly elastic fabrics.
  • the spinning speed suitable in the present invention is preferably set to, but is not limited to, 1,500-4,000 m/min.
  • a false twisting-draw ratio and a false twisting temperature are important.
  • the false twisting-draw ratio is preferably from 1.0 to 1.5, and the false twisting temperature is preferably from 100 to 180° C.
  • a false twister comprising a first feed roller (first FR), a heater, a cooling plate, a friction twisting apparatus and a second feed roller (second FR), in which each component is arranged in order of steps of processing a yarn
  • drawing is performed between the first FR and the second FR at a drawing rate of 1.0-1.5.
  • the yarn is false-twisted at the upstream region of the friction twisting apparatus, and is thermal-fixed by the heater, and the shape of the yarn is fixed by the cooling plate.
  • the false twisting-draw ratio is preferably from 1.00 to 1.50, and more preferably, 1.03 to 1.20.
  • a friction twisting apparatus useful in the present invention includes inscribed or circumscribed-type friction twisting apparatuses capable of acting to twist as well as feed, and preferably, a circumscribed-type shaft twister and a belt nip twister.
  • the draw ratio is determined depending on physical properties of a polytrimethylene terephtalate undrawn yarn or false twisted yarn, wherein a residual elongation is preferably 30-65%, and more preferably, 35-50%.
  • the false twisting temperature of the yarns at an outlet of the heater during the false twist-drawing process is preferably from 100 to 180° C.
  • the false twisting temperature is below 100° C., quality of fabrics is deteriorated, as follows: false twist tension is increased, thus leading to increased generation of yarn cutting and crimps are not suitably generated during the false twisting process, dimensional stability or crimpability is reduced, and shrinkage difference is induced at a heat-treating process performed as a post-process after preparation of false twisted yarns and thus color change occurs in fabrics.
  • the flat yarns prepared by the above false twisting process have latent torque, and the latent torque is developed by a relaxation heat-treatment performed as a post-process, thereby producing a final conjugate fiber having good crimpability, bulky property and abundant crimps.
  • a polytrimethylene terephtalate conjugate fiber which comprises two types of polytrimethylene terephtalates having different intrinsic viscosities in which a difference between the intrinsic viscosities ranges from 0.05 to 0.15.
  • the resulting conjugate fiber has a side-by-side structure, a strength of 2.0-3.5 g/den, an elongation of 30-65%, a crimping rate of over 20% and an elastic recovery of over 90% at an elongation of 30%.
  • the strength is below 2.0 g/den, yarn cutting often occurs owing to the low strength, and workability in manufacturing fabrics is bad.
  • the strength is over 3.5 g/den, texture of fabrics is bad.
  • polytrimethylene terephtalate having an intrinsic viscosity (IV) of 1.0 at an amount of 50% by weight, which was used as PTT-H, and polytrimethylene terephtalate having an IV of 0.9 as PTT-L were spun at a spinning speed of 2000 m/min and at extruder temperatures of 260° C. and 265° C., respectively, using a side-by-side-type spinning nozzle, and then drawn at a draw ratio of 1.5, a draw temperature of 55° C. and a heat treatment temperature of 220° C. Cool air of 23° C.
  • Woven fabrics were prepared and stained according to the method as in Example 1 except for change of extruder temperatures of polytrimethylene terephtalate having an IV of 1.0 as PTT-H and polytrimethylene terephtalate having an IV of 0.9 as PTT-L to temperatures as listed in Table 1, below.
  • the resulting yarns were drawn with false twisting at various false twisting temperatures and various draw ratios as shown in Table 3, below, using a false twister (Murata 33H), thus producing false twist fibers.
  • a false twister Morata 33H
  • woven fabrics of weight of 200 g/m 2 were produced, and then stained at 105° C.
  • a difference between intrinsic viscosities of the two polymers was 0.1, and the ‘K’ value was 0.053.
  • Physical properties of the polymers and fibers were evaluated by the following methods.
  • Intrinsic viscosity After sufficiently dissolving each polymer in a 1% ortho-chloro phenol solution of 120° C., intrinsic viscosity was measured at a water bath of 30° C. using an Ubbelohde viscometer.
  • Crimping rate (TC, %): Under a tension of 50 mg/de, a sample of a bundle of yarns of 3000 de was obtained. The sample was heat-treated in hot water of 100° C. for 20 min under a load of 0.5 mg/de not causing tangling of yarns, whereby crimp is developed. After removing the load, the sample was cooled for 4 hrs and air-dried. 1 min after supplying a load of 2 mg/de to the air-dried sample, length L 1 of the yarns was measured. After measuring L 1 , a load of 2 mg/de+200 mg/de was applied to the sample, and, after 1 min., length L 2 of the yarns was measured. The crimping rate (TC) was calculated according to Equation 2, below, using the measured L 1 and L 2 values.
  • a polyester conjugate fiber having self-crimpability in a flat yarn form, not in a false twist fiber can be prepared.
  • a polyester conjugate fiber showing high crimpability and bulky property by induced latent torque can be prepared, supplying good spin-draw operability.
US10/516,235 2002-05-27 2003-03-11 Polytrimethylene terephtalate conjugate fiber and method of preparing the same Abandoned US20050233140A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR10-2002-0029202A KR100481296B1 (ko) 2002-05-27 2002-05-27 폴리트리메틸렌테레프탈레이트 복합섬유 및 그 제조방법
KR10-2002-0029202 2002-05-27
KR10-2002-0064897 2002-10-23
KR1020020064897A KR20040036094A (ko) 2002-10-23 2002-10-23 고권축 특성을 갖는 폴리트리메틸렌테레프탈레이트복합가연섬유 및 그 제조방법
PCT/KR2003/000470 WO2003100143A1 (en) 2002-05-27 2003-03-11 Polytrimethylene terephtalate conjugate fiber and method of preparing the same

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US (1) US20050233140A1 (ja)
EP (1) EP1518012A4 (ja)
JP (1) JP2005527715A (ja)
CN (1) CN1656261A (ja)
TW (1) TWI278542B (ja)
WO (1) WO2003100143A1 (ja)

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US20050223140A1 (en) * 2004-03-31 2005-10-06 Pak-Lung Seto Receive buffer in a data storage system
US20060095608A1 (en) * 2004-10-29 2006-05-04 Pak-Lung Seto Buffer utilization in a frame based communication system
US20060179810A1 (en) * 2005-02-11 2006-08-17 Tianyi Liao Stretch woven fabrics
US20080226908A1 (en) * 2004-03-23 2008-09-18 John Greg Hancock Bi-Component Electrically Conductive Drawn Polyester Fiber and Method For Making Same
US10271999B2 (en) 2014-11-06 2019-04-30 The Procter & Gamble Company Crimped fiber spunbond nonwoven webs/laminate
US10856144B2 (en) 2015-06-05 2020-12-01 Samsung Electronics Co., Ltd Method, server, and terminal for transmitting and receiving data
US11135103B2 (en) 2014-11-06 2021-10-05 The Procter & Gamble Company Apertured webs and methods for making the same
US11213436B2 (en) 2017-02-16 2022-01-04 The Procter & Gamble Company Substrates having repeating patterns of apertures for absorbent articles

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KR100573077B1 (ko) * 2003-12-19 2006-04-24 주식회사 효성 폴리트리메틸렌테레프탈레이트, 상기폴리트리메틸렌테레프탈레이트의 제조방법 및 상기폴리트리메틸렌테레프탈레이트로 제조한폴리트리메틸렌테레프탈레이트 섬유
CN101490318B (zh) * 2006-07-27 2012-09-05 欧瑞康纺织有限及两合公司 用于制造卷曲的合成丝线的方法

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