US20050211949A1 - Detectable refrigerant compositions and uses thereof - Google Patents

Detectable refrigerant compositions and uses thereof Download PDF

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Publication number
US20050211949A1
US20050211949A1 US10/984,530 US98453004A US2005211949A1 US 20050211949 A1 US20050211949 A1 US 20050211949A1 US 98453004 A US98453004 A US 98453004A US 2005211949 A1 US2005211949 A1 US 2005211949A1
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United States
Prior art keywords
hfc
refrigerant
hfe
cbrf
ocf
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Abandoned
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US10/984,530
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English (en)
Inventor
Donald Bivens
Thomas Leck
Mack McFarland
Barbara Minor
John Steichen
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EIDP Inc
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Individual
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Priority to US10/984,530 priority Critical patent/US20050211949A1/en
Priority to ARP040104179A priority patent/AR048659A1/es
Priority to RU2006120449/04A priority patent/RU2006120449A/ru
Priority to CA2543979A priority patent/CA2543979C/en
Priority to KR1020067009253A priority patent/KR101227269B1/ko
Priority to AU2004291895A priority patent/AU2004291895B2/en
Priority to KR1020127001511A priority patent/KR20120025617A/ko
Priority to JP2006539959A priority patent/JP2007512396A/ja
Priority to BRPI0415805-9A priority patent/BRPI0415805A/pt
Priority to CN2004800335071A priority patent/CN1882671B/zh
Assigned to E. I. DU PONT DE NEMOURS AND COMPANY reassignment E. I. DU PONT DE NEMOURS AND COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BIVENS, DONALD BERNARD, MCFARLAND, MACK, MINOR, BARBARA HAVILAND, LECK, THOMAS J., STEICHEN, JOHN CARL
Publication of US20050211949A1 publication Critical patent/US20050211949A1/en
Priority to NO20062742A priority patent/NO20062742L/no
Priority to US12/414,022 priority patent/US7779668B2/en
Priority to US12/820,678 priority patent/US20100251803A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
    • G01M3/00—Investigating fluid-tightness of structures
    • G01M3/02—Investigating fluid-tightness of structures by using fluid or vacuum
    • G01M3/04—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point
    • G01M3/20—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point using special tracer materials, e.g. dye, fluorescent material, radioactive material
    • G01M3/22—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point using special tracer materials, e.g. dye, fluorescent material, radioactive material for pipes, cables or tubes; for pipe joints or seals; for valves; for welds; for containers, e.g. radiators
    • G01M3/226—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point using special tracer materials, e.g. dye, fluorescent material, radioactive material for pipes, cables or tubes; for pipe joints or seals; for valves; for welds; for containers, e.g. radiators for containers, e.g. radiators
    • G01M3/228—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point using special tracer materials, e.g. dye, fluorescent material, radioactive material for pipes, cables or tubes; for pipe joints or seals; for valves; for welds; for containers, e.g. radiators for containers, e.g. radiators for radiators

Definitions

  • the present invention relates to detectable refrigerant compositions having tracers that are useful in vapor compression refrigeration systems.
  • the detectable tracers permit detection of the composition upon leaking.
  • HFC-134a 1,1,1,2-tetrafluoroethane
  • CFC chlorofluorocarbon
  • Refrigeration and air conditioning industry solutions include designing essentially leak-free hydrofluorocarbon-based refrigeration systems, as well as possibly transitioning from higher GWP to lower GWP refrigerants, including certain hydrofluorocarbons (e.g., 1,1-difluoroethane (HFC-152a)) and hydrocarbons as well as compounds such as carbon dioxide, ammonia, and dimethyl ether.
  • hydrofluorocarbons e.g., 1,1-difluoroethane (HFC-152a)
  • hydrocarbons as well as compounds such as carbon dioxide, ammonia, and dimethyl ether.
  • the solution involves carbon dioxide used as a refrigerant
  • detection differentiating from background (atmospheric) carbon dioxide concentration (which may vary, e.g., in a sealed space depending on occupant respiration, efficiency of combustion and emission control apparatus, etc.), and quantifying leaking carbon dioxide refrigerant is a difficult problem to solve with current apparatus and methods.
  • background atmospheric
  • HFC-152a 1,1-difluoroethane
  • detection differentiating from background 1,1-difluoroethane concentration (which may be separately present due to usage of HFC-152a as aerosol propellant and polymer foam blowing agent), and quantifying leaking 1,1-difluoroethane refrigerant is a difficult problem to solve with currently available apparatus and methods.
  • Some current detectors are also less sensitive to hydrofluorocarbons and have more difficulty detecting HFC leaks than compounds containing chlorine.
  • compositions of the present invention meet the industry needs.
  • a detectable refrigerant composition comprising: at least one refrigerant selected from the group consisting of: hydrofluorocarbon, hydrochlorofluorocarbon, perfluorocarbon, hydrofluorocarbon ether, perfluorocarbon ether, hydrocarbon, carbon dioxide, ammonia, and dimethyl ether, and an effective amount of a tracer wherein said tracer is different from said refrigerant.
  • a further disclosure is a method for analyzing at least one gas component in the detectable refrigerant composition of claim the present invention, said method comprising: providing an array of at least two chemo/electro-active materials, each chemo/electro-active material exhibiting a different electrical response characteristic upon exposure to the individual gas component in said refrigerant than each other chemo/electro-active material; exposing said array to said refrigerant-composition; determining an electrical response of each chemo/electro-active material upon exposure of said array to said refrigerant; and analyzing the individual gas component from the electrical response values.
  • Another disclosure is a detectable refrigerant composition, wherein said refrigerant is at least one member selected from the group consisting of hydrofluorocarbon, hydrochlorofluorocarbon, perfluorocarbon, hydrofluorocarbon ether, perfluorocarbon ether, hydrocarbon, carbon dioxide, ammonia, and dimethyl ether, and an effective amount of a tracer, to produce a detectable refrigerant composition or to improve the detectability of refrigerant composition, wherein said refrigerant composition is in a vessel, exterior of said vessel having a means for detecting said tracer in said refrigerant-tracer combination.
  • the present invention relates in part to a detectable refrigerant composition
  • a detectable refrigerant composition comprising at least one refrigerant, and an effective amount of a tracer wherein said tracer is different from said refrigerant.
  • Refrigerant of the present invention is preferred to have a normal boiling point of about 80° C. or less.
  • the refrigerant of the present invention is at least one refrigerant selected from the group consisting of hydrofluorocarbon, hydrochlorofluorocarbon, perfluorocarbon, hydrofluorocarbon ether, perfluorocarbon ether, hydrocarbon, carbon dioxide, ammonia, and dimethyl ether.
  • Representative hydrofluorocarbon refrigerants include fluoromethane (HFC-41), difluoromethane (HFC-32), trifluoromethane (HFC-23), fluoroethane (HFC-161), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1,2,2-tetrafluoroethane (HFC-134) and 1,1,1,2,2-pentafluoroethane (HFC-125).
  • fluoromethane HFC-41
  • difluoromethane HFC-32
  • trifluoromethane HFC-23
  • fluoroethane HFC-161
  • 1,1-difluoroethane HFC-152a
  • 1,1,1-trifluoroethane HFC-143a
  • 1,1,1,2-tetrafluoroethanethane H
  • hydrochlorofluorocarbon refrigerants include chlorodifluoromethane (HCFC-22), 2-chloro-1,1,1-trifluoroethane (HCFC-123), 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124) and 1-chloro-1,1-difluoroethane (HCFC-142b).
  • perfluorocarbon refrigerants include tetrafluoromethane (PFC-14), hexafluoroethane (PFC-116), octafluoropropane (PFC-218) and decafluorobutane (PFC-31-10).
  • Representative hydrofluorocarbon ether refrigerants include CF 3 OCHF 2 (HFE-125), CF 3 OCH 3 (HFE-143a), CF 3 OCH 2 F (HFE-134a), CHF 2 OCHF 2 (HFC-134), cyclo-(CF 2 CF 2 CF 2 O—) (HFE-c216), CF 3 CF 2 OCH 3 (HFE-245cbEbg), CHF 2 OCHFCF 3 (HFE-236eaEbg), CHF 2 CF 2 OCH 3 (HFE-254cb2), C 4 F 9 OCH 3 (HFE-7100) and C 4 F 9 OC 2 H 5 (HFE-7200).
  • Representative perfluorocarbon ether refrigerants include CF 3 OCF 3 , CF 3 OC 2 F 5 , C 2 F 5 OC 2 F 5 and CF 3 OCF(CF 3 )CF(CF 3 )OCF 3 .
  • Representative hydrocarbon refrigerants include methane, ethane, propane, cyclopropane, propylene, n-butane, cyclobutane, 2-methylpropane, methylcyclopropane, n-pentane, cyclopentane, 2-methylbutane, methylcyclobutane, 2,2-dimethylpropane and dimethylcyclopropane isomers.
  • Another aspect of the present invention is wherein said refrigerant composition is in a vessel, exterior of said vessel having either a mobile, transportable, hand-held or stationary means for detecting said tracer in said refrigerant-tracer combination.
  • the tracer is at least one member selected from the group consisting of C 1-5 hydrofluorocarbon, C 1-2 hydrochlorofluorocarbon, C 1-4 hydrochlorocarbon, C 2-6 fluoroether, C 1-5 hydrocarbon, C 1-3 hydrocarbon alcohol, C 1-3 hydrocarbon amine, C 1-3 hydrocarbon mercaptan, C 1-4 hydrocarbon ether, C 3-4 hydrocarbon ketone, C 3-4 bromofluoroketone, C 2-4 hydrocarbon aldehyde, 1,1,1-trifluorotoluene, p-chloro-1,1,1-trifluorotoluene, sulfur dioxide, nitrogen oxide, ethanolamine, ammonia, perfluoromethyl iodide, and perfluoroethyl iodide.
  • Representative hydrofluorocarbon tracer compositions of the present invention include fluoromethane (HFC-41), difluoromethane (HFC-32), trifluoromethane (HFC-23), fluoroethane (HFC-161), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1,2,2-tetrafluoroethane (HFC-134), 1,1,1,2,2-pentafluoroethane (HFC-125), 1,1,1,3,3,3-hexafluoropropane (HFC-236fa), 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea), and 1,1,2,2,3,3,4,4,-octafluorobutane (HFC-338 pcc).
  • fluoromethane HFC-41
  • hydrochlorofluorocarbon tracer compositions of the present invention include chlorodifluoromethane (HCFC-22), 2-chloro-1,1,1-trifluoroethane (HCFC-123), 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124) and 1-chloro-1,1-difluoroethane (HCFC-142b).
  • hydrochlorocarbon tracer compositions of the present invention include methyl chloride, methylene chloride, ethyl chloride, trans-1,2-dichloroethylene, 1-propyl chloride and 2-propyl chloride.
  • Representative fluoroether tracer compositions of the present invention include CF 3 OCHF 2 (HFE-125), CF 3 OCH 3 (HFE-143a), CF 3 OCH 2 F (HFE-134a), CHF 2 OCHF 2 (HFC-134), cyclo-(CF 2 CF 2 CF 2 O—) (HFE-c216), CF 3 CF 2 OCH 3 (HFE-245cbEbg), CHF 2 OCHFCF 3 (HFE-236eaEbg); C 4 F 9 OCH 3 (HFE-7100) and C 4 F 9 OC 2 H 5 (HFE-7200).
  • Representative hydrocarbon tracer compositions of the present invention include methane, ethane, propane, cyclopropane, propylene, n-butane, cyclobutane, 2-methylpropane, methylcyclopropane, n-pentane, cyclopentane, 2-methylbutane, methylcyclobutane, 2,2-dimethylpropane and dimethylcyclopropane isomers.
  • hydrocarbon alcohol tracer compositions of the present invention methanol, ethanol, 1-propanol and 2-propanol.
  • hydrocarbon amine tracer compositions of the present invention are methyl amine or ethyl amine,
  • a representative hydrocarbon mercaptan tracer composition of the present invention is ethyl mercaptan.
  • hydrocarbon ether tracer compositions of the present invention include dimethyl ether, ethyl methyl ether and diethyl ether.
  • hydrocarbon ketone tracer compositions of the present invention include propanone and butanone,
  • bromofluoroketone tracer compositions of the present invention are selected from the group consisting of CF 3 C(O)CBrFCF 2 CF 3 ; CF 3 C(O)CF 2 CF 2 CBrF 2 ; CBrF 2 C(O)CF(CF 3 ) 2 ; CF 3 C(O)CBr(CF 3 ) 2 ; CBrF 2 CF 2 C(O)CF 2 CF 3 ; CF 3 CBrFC(O)CF 2 CF 3 ; CF 3 CBrFC(O)CF 2 CF 2 CF 3 ; CF 3 CF 2 C(O)CBrFCF 2 CF 3 ; CF 3 CF 2 C(O)CF 2 CF 2 CBrF 2 ; CF 3 C(O)CBr(CF 3 )CF 2 CF 3 ; CF 3 C(O)CBrFCF 3 ; CF 3 C(O)CBrFCF 3 ; CF 3 C(O
  • hydrocarbon aldehyde tracer compositions of the present invention are acetaldehyde or propionaldehyde.
  • Additional tracer compositions of the present invention include sulfur dioxide, and a nitrogen oxide selected from nitric oxide or nitrous oxide.
  • effective amount of tracer is meant an amount of at least one tracer component that when combined with refrigerants of the present will result in a detectable refrigerant-tracer mixture.
  • the effective amount of tracer is preferably sufficient to allow for accurate, reproducible, and optionally quantifiable detection of a refrigerant leak.
  • An effective amount of tracer is generally from about 0.001 to about 5 weight percent of tracer, and more preferably from about 0.01 to about 1 weight percent of tracer, based on the total weight of refrigerant and tracer.
  • the tracer of the present invention has a vapor pressure (neat) at 25° C. of generally from about 0.01 to about 500 times, preferably from about 1 to about 300 times, the vapor pressure at 25° C. of said refrigerant (neat).
  • Tracer is preferably selected for a given refrigerant such that it may be accurately and reproducibly detected in the presence of background gases using an appropriate means for detecting said tracer.
  • refrigerant and tracer form a low boiling (maximum pressure) azeotropic or azeotrope-like mixture.
  • a low boiling (maximum pressure) azeotropic or azeotrope-like mixture is preferred in the instance where refrigerant and an effective amount of tracer, under temperature and pressure conditions where a vessel containing said mixture is leaking, allow for accurate detection of a refrigerant leak, via detection of tracer.
  • Preferred refrigerants are the relatively low GWP compounds difluoromethane (HFC-32), 1,1-difluoroethane (HFC-152a), propane, cyclopropane, propylene, n-butane, 2-methylpropane, carbon dioxide, ammonia, and dimethyl ether.
  • the tracers include ammonia, nitric oxide, 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), 1,1,1,2-tetrafluoroethane (HFC-134a) and dimethyl ether.
  • the refrigerant is 1,1-difluoroethane (HFC-152a)
  • the tracer is preferably selected from at least one of ammonia, nitric oxide or dimethyl ether
  • the means for detecting tracer is preferably a chemo/electro-active array detector, corona discharge detector, heated electrochemical detector or heated diode detector.
  • the present invention also relates to a method of using the refrigerant composition of the present invention to detect its presence wherein said refrigerant is at least one member selected from the group consisting of hydrofluorocarbon, hydrochlorofluorocarbon, perfluorocarbon, hydrofluorocarbon ether, perfluorocarbon ether, hydrocarbon, carbon dioxide, ammonia, and dimethyl ether, said method comprising providing a detector having a means for detecting said tracer in the vicinity of said refrigerant composition.
  • the method described herein may be used to detect leaks in a vapor compression refrigeration or air conditioning system or heat pump system.
  • the detection is carried out by a means for detecting said tracer, wherein in the absence of the tracer component would not be detectable, or at best difficult to detect, or unreliably detectable.
  • the means for detecting said tracer is selected from the group consisting of a chemo/electro-active array detector, corona discharge detector, heated diode detector, heated electrochemical detector, photoionization detector, infra red detector, ultrasonic detector and an electron capture detector.
  • the present invention also relates to a method for analyzing at least one gas component in the detectable refrigerant composition of the present invention, said method comprising: providing an array of at least two chemo/electro-active materials, each chemo/electro-active material exhibiting a different electrical response characteristic upon exposure to the individual gas component in said refrigerant than each other chemo/electro-active material; exposing said array to said refrigerant-composition; determining an electrical response of each chemo/electro-active material upon exposure of said array to said refrigerant; and analyzing the individual gas component from the electrical response values.
  • the method described herein optionally may further comprise determining a value for the temperature of said refrigerant composition independently of the determination of the electrical responses of the chemo/electro-active materials; optionally, digitizing the electrical responses and the temperature value, so as to permit calculation of a value from the digitized electrical responses and temperature value, and optionally, analyzing the gas component.
  • Suitable array detectors are described in U.S. patent application Ser. No. 09/977,791, filed Oct. 15, 2001, published U.S. 2002-121,440 and U.S. patent application Ser. No. 10/1117,472, filed Apr. 5, 2002, both incorporated herein by reference.
  • Representative means for detecting tracer include a corona discharge detector as disclosed in U.S. Pat. No. 6,333,632, U.S. Pat. No. 4,609,875 and U.S. Pat. No. 4,488,118, all of which are incorporated herein by reference.
  • Representative means for detecting tracer include a heated diode detector as disclosed in U.S. Pat. No. 5,932,176, herein incorporated by reference.
  • Representative means for detecting tracer include a heated electrochemical sensor as disclosed in U.S. Pat. No. 4,400,260, herein incorporated by reference.
  • Representative means for detecting tracer include a photoionization detector as disclosed in U.S. Pat. No. 5,393,979, herein incorporated by reference.
  • Representative means for detecting tracer include an ultrasonic detector as disclosed in European patent publication EP 0 319 133 A2, herein incorporated by reference.
  • Representative means for detecting tracer include infra red detectors as disclosed in U.S. Pat. No. 5,528,792 and U.S. Pat. No. 6,373,056, both incorporated herein by reference.
  • Representative means for detecting tracer further include electron capture detectors.
  • the present invention involves a method for detecting refrigerant leaking from a vessel.
  • vessel any sealed vessel containing refrigerant, including but not limited to, lab and commercial scale cylinders, railroad and tractor-trailer tank cars, piping, and vapor compression refrigeration and air conditioning (AC) apparatus and associated piping and storage containers that may be found in stationary (e.g., home or commercial AC) or mobile (e.g., automobile, train, boat, airplane) installations.
  • stationary e.g., home or commercial AC
  • mobile e.g., automobile, train, boat, airplane
  • compositions of the present invention were prepared a suitable container. Comparative compositions that did not contain tracer compositions were also prepared. Compositions were then leaked in the vapor phase in the presence of a hand-held Ritchie Yellow Jacket® Accuprobe® heated electrochemical detector. The digital readout scale was 0 (for no detection) to 9 (for maximum detection). Results are shown below. Detector Digital Composition Reading CO 2 0 CO 2 /0.05 wt % trans- 8 1,2-dichloroethylene CO 2 /0.1 wt % HFC- 5 152a The data show that addition of tracer enables the detector to detect a CO2 leak, whereas it was unable to detect the leak without tracer present.
  • compositions of the present invention were prepared in a suitable container. Comparative compositions that did not contain tracer compositions were also prepared. Compositions were then leaked in the vapor phase in the presence of a hand-held TIF Instruments 5650 corona discharge halogen leak detector and the detector reading was recorded based on number of red lights illuminated. Results are shown below. Detector Reading Composition (number of red lights) HFC-134a 2 HFC-134a/0.1 wt % 4 trans-1,2- dichloroethylene CO2 2 CO2/0.1 wt % HFC- 5 152a The data show that addition of tracer improves the ability of the detector to detect an HFC-134a or CO 2 refrigerant leak.
  • compositions of the present were prepared in a suitable container. Comparative compositions that did not contain tracer compositions were also prepared. Compositions were then leaked in the vapor phase in the presence of a hand-held Ritchie Yellow Jacket® Accuprobe® heated electrochemical detector. The digital readout scale was 0 for no detection to 9 for maximum detection. Results are shown below. Detector Digital Composition Reading HFC-152a 1 HFC-152a/0.03 4 wt % trans-1,2- dichloroethylene HFC-152a/0.1 wt % 4 HCFC-22 The data show that addition of tracer improves the ability of the detector to detect an HFC-152a refrigerant leak.
  • compositions of the present were prepared in a suitable container. Comparative compositions that did not contain tracer compositions were also prepared. Compositions were then leaked in the vapor phase in the presence of a hand-held TIF Instruments 5650 corona discharge halogen leak detector and the detector reading was recorded based on number of red lights illuminated. Results are shown below.
  • Detector Reading Composition (number of red lights) HFC-152a 0 HFC-152a/0.03 wt % 6 trans-1,2- dichloroethylene HFC-152a/0.1% 6 HCFC-22 The data show that addition of tracer enables the detector to detect presence of an HFC-152a leak, whereas it was unable to detect the leak without tracer present.

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  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
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US10/984,530 2003-11-13 2004-11-09 Detectable refrigerant compositions and uses thereof Abandoned US20050211949A1 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
US10/984,530 US20050211949A1 (en) 2003-11-13 2004-11-09 Detectable refrigerant compositions and uses thereof
JP2006539959A JP2007512396A (ja) 2003-11-13 2004-11-12 検出可能な冷媒組成物およびその使用
BRPI0415805-9A BRPI0415805A (pt) 2003-11-13 2004-11-12 composições detectáveis refrigerantes, método de uso da composição de refrigerante e método para analisar pelo menos um componente de gás na composição detectável refrigerante
CA2543979A CA2543979C (en) 2003-11-13 2004-11-12 Detectable refrigerant compositions and uses thereof
KR1020067009253A KR101227269B1 (ko) 2003-11-13 2004-11-12 검출가능한 냉매 조성물 및 그의 용도
AU2004291895A AU2004291895B2 (en) 2003-11-13 2004-11-12 Detectable refrigerant compositions and uses thereof
KR1020127001511A KR20120025617A (ko) 2003-11-13 2004-11-12 검출가능한 냉매 조성물 및 그의 용도
ARP040104179A AR048659A1 (es) 2003-11-13 2004-11-12 Composiciones refrigerantes detectables y usos de las mismas
RU2006120449/04A RU2006120449A (ru) 2003-11-13 2004-11-12 Обнаруживаемые охлаждающие композиции и их применение
CN2004800335071A CN1882671B (zh) 2003-11-13 2004-11-12 可检测制冷剂组合物及其应用
NO20062742A NO20062742L (no) 2003-11-13 2006-06-13 Paviselige kjolemiddelsammensetninger og anvendelser derav
US12/414,022 US7779668B2 (en) 2003-11-13 2009-03-30 Detectable refrigerant compositions and uses thereof
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US8692037B2 (en) 2008-05-07 2014-04-08 E I Du Pont De Nemours And Company Compositions comprising 1,1,1,2,3-pentafluoropropane or 2,3,3,3-tetrafluoropropene
US11312890B2 (en) 2008-05-07 2022-04-26 The Chemours Company Fc, Llc Compositions comprising 2,3-dichloro-1,1,1 -trifluoropropane, 2-chloro-1,1,1 -trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene
US8333902B2 (en) 2008-05-07 2012-12-18 E I Du Pont De Nemours And Company Compositions comprising 1,1,1,2,3-pentafluoropropane or 2,3,3,3- tetrafluoropropene
US8147709B2 (en) 2008-05-07 2012-04-03 E. I. Du Pont De Nemours And Company Compositions comprising 3,3,3-trifluoropropyne
US9486657B2 (en) 2008-05-07 2016-11-08 The Chemours Company Fc, Llc Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene
US10214669B2 (en) 2008-05-07 2019-02-26 The Chemours Company Fc, Llc Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene
USRE47862E1 (en) 2008-05-07 2020-02-18 The Chemours Company Fc, Llc Compositions comprising 1,1,1,2,3-pentafluoropropane or 2,3,3,3-tetrafluoropropene
US11512239B2 (en) 2008-05-07 2022-11-29 The Chemours Company Fc, Llc Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene
US20090278075A1 (en) * 2008-05-07 2009-11-12 E. I. Du Pont De Nemours And Company Compositions comprising 1,1,1,2,3-pentafluoropropane or 2,3,3,3- tetrafluoropropene
US8877086B2 (en) 2008-05-07 2014-11-04 E I Du Pont De Nemours And Company Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene
US10584270B2 (en) 2008-05-07 2020-03-10 The Chemours Company Fc, Llc Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene
US11001738B2 (en) 2008-05-07 2021-05-11 The Chemours Company Fc, Llc Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene
US8147710B2 (en) 2008-10-10 2012-04-03 E. I. Du Pont De Nemours And Company Compositions comprising 2,3,3,3-tetrafluoropropene, 2-chloro-2,3,3,3-tetrafluoropropanol, 2-chloro-2,3,3,3-tetrafluoro-propyl acetate or zinc (2-chloro-2,3,3,3-tetrafluoropropoxy) chloride
US20100090156A1 (en) * 2008-10-10 2010-04-15 E. I. Du Pont De Nemours And Company Compositions comprising 2,3,3,3-tetrafluoropropene, 2-chloro-2,3,3,3-tetrafluoropropanol, 2-chloro-2,3,3,3-tetrafluoro-propyl acetate or zinc (2-chloro-2,3,3,3-tetrafluoropropoxy) chloride
US8518294B2 (en) 2008-10-10 2013-08-27 E I Du Pont De Nemours And Company Compositions comprising 2,3,3,3-tetrafluoropropene, 2-chloro-2,3,3,3-tetrafluoropropanol, 2-chloro-2,3,3,3-tetrafluoro-propyl acetate or zinc (2-chloro-2,3,3,3-tetrafluoropropdxy) chloride
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US9943717B2 (en) 2009-12-22 2018-04-17 The Chemours Company Fc, Llc Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane
US11596824B2 (en) 2009-12-22 2023-03-07 The Chemours Company Fc, Llc Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane
US12145015B2 (en) 2009-12-22 2024-11-19 The Chemours Company Fc, Llc Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane
US12023536B2 (en) 2009-12-22 2024-07-02 The Chemours Company Fc, Llc Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3 tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane
US11331525B2 (en) 2009-12-22 2022-05-17 The Chemours Company Fc, Llc Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane
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US9051500B2 (en) 2009-12-22 2015-06-09 E I Du Pont De Nemours And Company Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane
US10688329B2 (en) 2009-12-22 2020-06-23 The Chemours Company Fc, Llc Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane
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JP2018529936A (ja) * 2015-07-28 2018-10-11 キャリア コーポレイションＣａｒｒｉｅｒ Ｃｏｒｐｏｒａｔｉｏｎ 冷媒分析器及び冷媒分析器の使用方法
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CN1882671A (zh) 2006-12-20
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JP2007512396A (ja) 2007-05-17
AU2004291895B2 (en) 2011-05-26
AR048659A1 (es) 2006-05-17
EP1682628B1 (en) 2012-10-17
CN1882671B (zh) 2013-03-27
CA2543979C (en) 2012-10-16
KR20070012621A (ko) 2007-01-26
CA2543979A1 (en) 2005-06-02
US20100251803A1 (en) 2010-10-07
AU2004291895A1 (en) 2005-06-02
NO20062742L (no) 2006-08-09
KR101227269B1 (ko) 2013-01-28
KR20120025617A (ko) 2012-03-15
RU2006120449A (ru) 2007-12-27
PL1682628T3 (pl) 2013-03-29
US20090189077A1 (en) 2009-07-30
US7779668B2 (en) 2010-08-24
WO2005049759A1 (en) 2005-06-02

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