US20050112236A1 - Delivery system for active components as part of an edible composition having preselected tensile strength - Google Patents
Delivery system for active components as part of an edible composition having preselected tensile strength Download PDFInfo
- Publication number
- US20050112236A1 US20050112236A1 US10/719,298 US71929803A US2005112236A1 US 20050112236 A1 US20050112236 A1 US 20050112236A1 US 71929803 A US71929803 A US 71929803A US 2005112236 A1 US2005112236 A1 US 2005112236A1
- Authority
- US
- United States
- Prior art keywords
- delivery system
- tensile strength
- active component
- composition
- edible composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/02—Apparatus specially adapted for manufacture or treatment of chewing gum
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/0002—Processes of manufacture not relating to composition and compounding ingredients
- A23G3/0004—Processes specially adapted for manufacture or treatment of sweetmeats or confectionery
- A23G3/0006—Manufacture or treatment of liquids, pastes, creams, granules, shred or powder
- A23G3/0017—Transformation of a liquid, paste, cream, lump, powder, granule or shred into powder, granule or shred; Manufacture or treatment of powder
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/346—Finished or semi-finished products in the form of powders, paste or liquids
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/38—Sucrose-free products
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/10—Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/14—Chewing gum characterised by the composition containing organic or inorganic compounds containing peptides or proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/18—Chewing gum characterised by shape, structure or physical form, e.g. aerated products
- A23G4/20—Composite products, e.g. centre-filled, multi-layer, laminated
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
- A23G2200/06—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing beet sugar or cane sugar if specifically mentioned or containing other carbohydrates, e.g. starches, gums, alcohol sugar, polysaccharides, dextrin or containing high or low amount of carbohydrate
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
- A23G2200/10—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing amino-acids, proteins, e.g. gelatine, peptides, polypeptides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2220/00—Products with special structure
- A23G2220/20—Products with special structure with a composite structure, e.g. laminated products, coated products, microstructures, e.g. with encapsulated ingredients
Definitions
- the present invention is generally directed to a delivery system for edible compositions in which a desired active component is encapsulated in a manner such that the tensile strength of the delivery system is within a desirable range to provide controlled release of the active component in a consistent manner over an extended period of time.
- the delivery system may, for example, provide consistent, extended and controlled delivery of a sweetener in a chewing gum composition or confectionery composition.
- Encapsulating active components in edible compositions to prolong their release and/or to slow their degradation is known.
- Encapsulating materials used to coat such components include, for example, cellulose, cellulose derivatives, arabinogalactin, gum arabic, polyolefins, waxes, vinyl polymers, gelatin, zein and mixtures thereof.
- the encapsulating materials have been used to protect active components such as sweeteners, acids, flavorings, soluble dietary fibers, biologically active agents such as pharmaceutical compounds or medicinal drugs, breath freshening agents, and the like.
- sweeteners particularly high intensity sweeteners to prevent against premature degradation, to enhance the uniformity of release, and to prolong release in a controlled manner.
- High intensity sweeteners generally have a sweetening intensity greater than sugar (sucrose) and a caloric value lower than that of sugar at equivalent sweetness levels. It is especially desirable to control the release of high intensity sweeteners in compositions since the high sweetness levels can easily overwhelm the consumer. Moreover, the controlled release of the sweetener provides desirable masking of unpleasant tasting materials. Because each high intensity sweetener is chemically and physically distinct, each is a challenge to use in an edible composition and each exhibits one or more shortcomings, which may be moderated by encapsulation.
- high intensity sweeteners lose their sweetness intensity rapidly when used in edible compositions such as chewing gums and confections. Encapsulation can modulate arid prolong release to provide a more desirable taste profile.
- Some high intensity sweeteners such as saccharin, stevioside, acesulfame-K, glycyrrhizin, and thaumatin have an associated bitter taste or off-note.
- Certain high intensity sweeteners are also unstable in the presence of certain chemicals including aldehydes and ketones, and sensitive to exposure to environmental conditions including moisture. Solid sucralose is known to turn dark during prolong storage upon exposure to heat and ambient air. Encapsulation can be used to isolate unstable compounds to prevent degradation and prolong shelf life.
- the taste profile of a high intensity sweetener can be described as a rapid burst of sweetness.
- high intensity sweeteners reach their peak sweet taste rapidly, with the intensity of sweet taste rapidly declining soon thereafter.
- the initial rapid burst can be unpleasant to many consumers as the strong sweet taste tends to overpower the other flavors that may be present in the edible composition.
- the relatively rapid loss of sweetness can also result in a bitter aftertaste.
- the selection of a suitable encapsulating material i.e., polyvinyl acetate
- U.S. Pat. No. 4,711,784 to Yang discloses a chewing gum composition containing a high molecular weight polyvinyl acetate blended with a hydrophobic plasticizer as an encapsulating material.
- the encapsulating material is used to encapsulate an active ingredient such as aspartame.
- U.S. Pat. No. 4,816,265 to Cherukuri et al. discloses a sweetener delivery system, which uses a coating composed of an emulsifier and a polyvinyl acetate encapsulating material having a molecular weight of from about 2,000 to 14,000, optionally in the presence of a wax.
- the coating is applied to sweeteners such as aspartame to effectuate sustained release of the sweetener.
- U.S. Pat. No. 5,057,328 to Cherukuri et al. discloses a food acid delivery system for use in for example, chewing gums, having a food acid that is encapsulated in a matrix comprising an emulsifier and polyvinyl acetate in a specified molecular weight range.
- U.S. Pat. No. 5,108,763 to Chau et al. discloses a sweetening agent delivery system having prolonged sweetener release.
- the system utilizes a high intensity sweetener encapsulated in polyvinyl acetate having a molecular weight in the range of from about 2,000 to 100,000.
- the system further includes the use of a plasticizing agent, a waxy material and an emulsifying agent.
- U.S. Pat. No. 5,789,002 to Duggan et al. discloses a process for preparing sweeteners and acids as ingredients for chewing gum compositions.
- the Duggan et al. reference discloses encapsulating the sweetener or acid in a delivery system such as polyvinyl acetate.
- U.S. patent application Ser. No. 2002/0122842 filed by Seiestad et al. discloses food mixtures including chewing gums containing at least two acids encapsulated by a polyvinyl acetate matrix.
- the polyvinyl acetate has a molecular weight in the range of from about 20,000 to 120,000.
- the prior art systems identified above prepare encapsulating materials by taking into account the selection of an encapsulating material (e.g. polyvinyl acetate) and its molecular weight.
- an encapsulating material e.g. polyvinyl acetate
- the present invention provides a new approach to the controlled release of an active component in edible compositions such as, for example, chewing gum and confectionery compositions.
- the active component(s) and materials used to encapsulate the same provide a delivery system(s) that enables exceptional control of the release of the active component over a wide range of delivery systems and takes into account the use of a range of encapsulating materials and additives that may be used to formulate the delivery system.
- the delivery system is formulated based on tensile strength as the prime factor in formulating a delivery system that can deliver a designated active component at a desirable release rate.
- the encapsulated active components are preserved until release is desirable and therefore protected against moisture, reactive compounds, pH changes and the like.
- the delivery system is tailored to the sweetener to provide consistent sustained release, thus extending the time the sweetener is released to provide an edible composition which provides a long lasting desirable taste profile, increased salivation and overall enjoyment of the taste imparted therefrom without the disadvantage of prior art systems in which the sweetener may be released at less or more than a desirable rate.
- the present invention is premised chiefly on the discovery that the tensile strength of the delivery system is critical to obtaining a desired controlled, extended release of an active component.
- a delivery system can be readily and easily formulated using a broad range of materials (e.g., encapsulating agents, active components, additives) with the desired characteristics to achieve a particular desirable release rate.
- the active components and materials used to encapsulate the same provide a delivery system that provides exceptional control of the release of the active component.
- a delivery system for active components can be provided based on the tensile strength of the delivery system having a specific tensile strength when compared to a standard.
- This approach differs from those prior art systems that focus on one characteristic (molecular weight) of one of the materials (encapsulating material) used to produce the delivery system.
- a delivery system is formulated to express a desired release profile by adjusting and modifying the tensile strength through the specific selection of the active component, the encapsulating material, the additives, the amount of the active component and the like which can be compared to at least one, typically a plurality of standard delivery systems each having a known release rate.
- any delivery system which has the desired tensile strength may be used without being limited to a particular encapsulating material and its molecular weight.
- the formulation process can be extended to encapsulating materials which exhibit similar physical and chemical properties as the encapsulating material forming part of the standard delivery system.
- tensile strength means the maximum stress a material subjected to a stretching load can withstand without tearing.
- a standard method for measuring tensile strength of a given substance is defined by the American Society of Testing Materials in method number ASTM-D638.
- the selection of a desired tensile strength within a desirable range enables the production of edible compositions using a range of materials including encapsulating materials without having to focus on a particular encapsulating material and without being limited to modifying the release rate solely through the selection of a molecular weight for the encapsulating material.
- a delivery system for inclusion in an edible composition such as a chewing gum composition or confectionery composition having at least one active component encapsulated by an encapsulating material wherein the delivery system has a tensile strength of at least 6,500 psi, and typically ranging from about 6,500 psi to 200,000 psi.
- an edible composition such as a chewing gum composition or a confectionery composition
- a delivery system comprising at least one active component encapsulated within an encapsulating material, the delivery system having a tensile strength of at least 6,500 psi.
- a method of preparing a target delivery system for an edible composition comprising combining at least one active component, at least one encapsulating material, and optionally at least one additive until a preselected tensile strength of the target delivery system is obtained based on comparison with the tensile strength of at least one sample delivery system having the same or-similar active component and a known release rate of the active component.
- a method of preparing a target delivery system for an edible composition useful for delivering at least one active component at a desired release rate comprising the step of encapsulating the at least one active component in an encapsulating material in a manner that provides the target delivery system with a tensile strength of at least 6,500 psi.
- Still further there is provided a method of preparing a target delivery system for an edible composition useful for delivering at least one active component at a desired release rate comprising encapsulating the at least one active component in an encapsulating material in a manner that provides the target delivery system with a target tensile strength associated with the desired release rate, enabling the delivery system to release the at least one active component form the edible composition at the desired release rate.
- a method of preparing an edible composition containing a target delivery system useful for delivering at least one active component at a desired release rate comprising encapsulating the at least one active component in an encapsulating material in a manner that provides the target delivery system with a target tensile strength associated with the desired release rate enabling the delivery system to release the at least one active component from the edible composition at desired release rate, and adding the target delivery system to the edible composition.
- edible compositions containing the present delivery system there is also provided edible compositions containing the present delivery system.
- the preferred embodiment of the present invention relates to chewing gum compositions, confectionery compositions and beverages
- the present invention can be utilized to produce a variety of edible compositions including, but not limited to, food products, foodstuffs, nutrient-containing compositions, pharmaceuticals, nutraceuticals, vitamins and other products that may be prepared for consumption by the consumer.
- the delivery system may be readily incorporated into an edible composition, the edible compositions which may benefit from and are encompassed by the present invention are wide ranging as indicated above.
- FIG. 1 is a graph comparing perceived sweetness intensity of three samples of gum over a 30 minute period in accordance with the present invention
- FIG. 2 is a graph comparing perceived sweetness intensity of two samples of gum each containing different tensile strength delivery systems over a 30 minute period in accordance with the present invention
- FIG. 3 is a graph comparing the percentage of aspartame retained over a period of time for two samples of gum containing different tensile strength delivery systems in accordance with the present invention.
- FIG. 4 is a graph comparing perceived bitterness intensity of two gum samples each containing different tensile strength delivery systems in accordance with the present invention.
- delivery system as used herein is meant to encompass the encapsulating material and a single active component encapsulated therein as well as other additives used to form the delivery system as hereinafter described. It will be understood that the edible compositions of the present invention may contain a plurality of delivery systems with each delivery system containing a single active component.
- encapsulating material is meant to encompass any one or more edible water insoluble materials capable of forming a solid coating or film as a protective barrier around the active component.
- the present invention is directed generally to a delivery system as defined herein for use in edible compositions, which comprises an encapsulating material and an active component encapsulated by the encapsulating material.
- the delivery system of the present invention is formulated with a predetermined tensile strength sufficient to provide consistent controlled release of the active component over a preselected period of time such as an extended period of time typically up to about 25 to 30 minutes or more.
- the predetermined tensile strength is determined based, in part, on the active component and the desired release time of the same.
- the predetermined tensile strength may be selected from a standard comprised of one or more delivery systems with each standard delivery system having a known release rate of the desired active component.
- the delivery system of the present invention further provides the active component with a protective barrier against moisture and other conditions such as pH changes, reactive compounds and the like, the presence of which can undesirably degrade the active component.
- the delivery system facilitates the controlled release of the active component in a wide variety of edible compositions including chewing gum compositions, food products, confectionery compositions, pharmaceutical compositions, beverages, foodstuffs, nutrient-containing compositions, vitamins, nutraceuticals and the like.
- the delivery system is developed in accordance with the present invention to have a desirable tensile strength which may be selected, depending in part on the active component and the release rate of the active component desired, from a standard of known delivery systems containing the active component at known release rates.
- the active components which may be incorporated as part of the delivery system may be selected from sweeteners including high intensity sweeteners, acids, flavorants, pharmaceuticals, therapeutic agents, vitamins, breath fresheners, cooling agents and other materials that would benefit by coating for protection, controlled release and/or for taste masking.
- the active components include nicotine useful for the treatment of addiction to tobacco products and caffeine typically found in coffee and/or cola beverages.
- the active component is a sweetener, and more preferably a high intensity sweetener such as neotame and aspartame.
- a delivery system for delivering an active component can be formulated to ensure an effective sustained release of the active component based on the type and amount of the active component and desired release rate. For example, it may be desirable to effect the controlled release of a high intensity sweetener over a period of 25 to 30 minutes to ensure against a rapid burst of sweetness which may be offensive to some consumers. A shorter controlled release time may be desirable for other type of active components such as pharmaceuticals or therapeutic agents, which may be incorporated into the same edible composition by using separate delivery systems for each active component.
- delivery systems may be formulated with a particular tensile strength associated with a range of release rates based on a standard.
- the standard may comprise a series of known delivery systems having tensile strengths over a range extending, for example, from low to high tensile strength values.
- Each of the delivery systems of the standard will be associated with a particular release rate or ranges of release rates.
- a delivery system can be formulated with a relatively slow release rate by a fabricating a delivering system having a relatively high tensile strength.
- lower tensile strength compositions tend to exhibit relatively fast release rates.
- An important factor of the present invention is that the tensile strength of the delivery system is directly associated with the release rate of the active component without direct regard for the type or molecular weight of the encapsulating material.
- the present invention includes the incorporation of a plurality of delivery systems to deliver a plurality of separate active components including active components which may be desirably released at distinctly different release rates.
- high intensity sweeteners may desirably be released over an extended period of time (e.g. 20 to 30 minutes) while some pharmaceuticals are desirably released over a significantly shorter period of time.
- a method of selecting a target delivery system containing an active component for an edible composition generally includes preparing a targeted delivery system containing an active component, an encapsulating material and optional additives, with the targeted delivery system having a pre-selected tensile strength.
- the tensile strength of the targeted delivery system is pre-selected to provide a desirable release rate of the active component. This selection of the tensile strength is based on the tensile strengths of sample delivery systems having the same or similar active component and known release rates of the active component.
- the method comprises the steps of (a) obtaining a plurality of sample delivery systems comprising an active component, at least one encapsulating material, and optional additives, wherein each of the delivery systems has a different tensile strength; (b) testing the sample delivery systems to determine the respective release rates of the active component; and (c) formulating a target delivery system containing the same active component with a tensile strength corresponding to a desired release rate of the active component based on the obtained sample delivery systems.
- a plurality of delivery systems may be prepared in this manner each containing a different active component by utilizing a comparison with standard delivery systems containing such different active components.
- the method of selecting at least one delivery system suitable for incorporation into an edible composition preferably begins by determining a desired release rate for an active component (i.e. a first active component).
- the determination of the desired release rate may be from known literature or technical references or by in vitro or in vivo testing.
- the desired release rate is determined, it is typical to determine the desired tensile strength (i.e. first tensile strength) for a delivery system (i.e. first delivery system) that can release the first active component at the desired release.
- the delivery system is obtained which can deliver the active component as required it is then selected for eventual inclusion in an edible composition.
- the method described above may then be repeated for a second active component and for additional active components as described via the determination and selection of a suitable delivery system.
- the present method can be used in connection with formulating the target delivery system using encapsulating materials having similar physical and chemical properties including the degree of water solubility, affinity for the active component, and the like as those used in the sample delivery systems.
- the active component is released from the composition in a highly controlled and consistent manner irrespective of the particular type of encapsulating materials employed.
- the process for selecting and formulating suitable delivery systems is enhanced in a manner which effectively reduces the need for trial and error experimentation typically necessary in prior art systems.
- the present invention enables the formulation of a suitable target delivery system by focusing on a single variable (i.e., tensile strength) and therefore takes into account all components of the delivery system including encapsulating materials and any additives (e.g., fats and oils) that may be desirably added to the formulation and enables the delivery system when added to an edible composition to release the active component at a desirable release rate.
- a single variable i.e., tensile strength
- any additives e.g., fats and oils
- the desired tensile strength of the delivery system can be readily determined within a desired range. Tensile strengths of at least 6,500 psi are typical, with most applications operating within a desirable tensile strength range of 6,500 to 200,000 psi.
- the formulation of a delivery system with a desirable tensile strength can be made from a variety of encapsulating materials and additives which hereinafter are referred to as “tensile strength modifying agents or modifiers.” These additives may be used to formulate the delivery system by modifying the tensile strength of the delivery system, including tensile strength-lowering materials such as fats, emulsifiers, plasticizers (softeners), waxes, low molecular weight polymers, and the like, in addition to tensile strength increasing materials such as high molecular weight polymers.
- the tensile strength of the delivery system can also be fine tuned by combining different tensile strength modifiers to form the delivery system.
- the tensile strength of high molecular weight polymers such as polyvinyl acetate may be reduced when tensile strength lowering agents such as fats and/or oils are added.
- tensile strength modifiers or modifying agents include, but are not limited to, fats (e.g., hydrogenated or non-hydrogenated vegetable oils, animal fats), waxes (e.g., microcrystalline wax, bees wax), plasticizers/emulsifiers (e.g., mineral oil, fatty acids, mono- and diglycerides, triacetin, glycerin, acetylated monoglycerides, glycerol rosin monostearate esters), low and high molecular weight polymers (e.g., polypropylene glycol, polyethylene glycol, polyisobutylene, polyethylene, polyvinylacetate) and the like, and combinations thereof. Plasticizers may also be referred to as softeners.
- plasticizers may also be referred to as softeners.
- the overall tensile strength of the delivery system can be adjusted or altered in such a way that a preselected tensile strength is obtained for the corresponding desired release rate of the active component from an edible composition based on a comparison with a standard.
- the delivery system of the present invention is typically in the form of a powder or granules.
- the particle size is not critical to the function of the present invention however the particle size is desirably selected according to the desired rate of release and/or mouthfeel (i.e., grittiness) and the type of carrier incorporated in the edible composition.
- the particle size is preferably less than 600 microns.
- the amount of the ingredients incorporated into the compositions according to the present invention is designated as % by weight based on the total weight of the composition.
- the delivery systems of the present invention produce controlled release of the active components as desired through the use of a preselected tensile strength when matched with a desirable release rate selected according to the type of the active components to be encapsulated, the encapsulating material used, the additives incorporated, the desired rate of release of the active component, and the like.
- the materials used to encapsulate the active component are generally selected from edible water insoluble materials capable of forming a strong matrix, solid coating or film as a protective barrier around the active component.
- the encapsulating material is chosen in a manner consistent with the tensile strength of the delivery system which will typically be at least 6,500 psi, more typically in the range of from about 6,500 to 200,000 psi.
- Such encapsulating materials may be selected from polyvinyl acetate, polyethylene, crosslinked polyvinyl pyrrolidone, polymethylmethacrylate, polylactidacid, polyhydroxyalkanoates, ethylcellulose, polyvinyl acetatephthalate, polyethylene glycol esters, methacrylicacid-co-methylmethacrylate, and the like, and combinations thereof.
- the encapsulating material may be present in amounts of from about 0.2% to 10% by weight based on the total weight of the edible composition, preferably 1 % to 5% by weight.
- the amount of the encapsulating material will, of course, depend in part on the amount of the active component which must be encapsulated.
- the amount of the encapsulating material with respect to the weight of the delivery system is from about 30% to 99%, preferably from about 60% to 90% by weight.
- the tensile strength of the delivery system may be selected from relatively high tensile strengths when a relatively slow rate of release is desired and relatively lower tensile strengths when a faster rate of release is desired.
- the release rate of the active component will generally be lower than the release rate of the active component in a delivery system having a tensile strength of 10,000 psi regardless of the type of encapsulating material (e.g. polyvinyl acetate) chosen.
- the encapsulating material is polyvinyl acetate.
- a representative example of a polyvinyl acetate product suitable for use as an encapsulating material in the present invention is Vinnapas® B100 sold by Wacker Polymer Systems of Adrian, Mich.
- a delivery system utilizing polyvinyl acetate may be prepared by melting a sufficient amount of polyvinyl acetate at a temperature of about 65° to 120° C. for a short period of time, e.g., 5 minutes. The melt temperature will depend on the type and tensile strength of the polyvinyl acetate encapsulating material where higher tensile strength materials will generally melt at higher temperatures.
- a suitable amount of the active component e.g., high intensity sweetener such as aspartame
- the active component e.g., high intensity sweetener such as aspartame
- the resulting mixture is a semi-solid mass, which is then cooled (e.g., at 0° C.) to obtain a solid, and then ground to a U.S. Standard sieve size of from about 30 to 200 (600 to 75 microns).
- the tensile strength of the resulting delivery system can readily be tested according to ASTM-D638.
- a suitable encapsulating material will also depend in part on the type and amount of the active component and the presence of other additives or ingredients.
- the above mentioned additives may be added to the encapsulating material during the molten state.
- the amount of additives used in the delivery system of the present invention will of course vary according to the desired tensile strength but will typically range up to 40% by weight based on the total weight of the delivery system.
- the presence of fats and oils as an additive has been found to have two effects on the delivery system.
- the first effect is observed at lower concentrations, i.e. up to 5% by weight, wherein the fats and/or oils either maintain or increase the tensile strength of the delivery system.
- the fats and/or oils tend to reduce the tensile strength of the delivery system.
- a suitable delivery system with the desired release of the active component may be readily formulated in accordance with the present invention because the targeted delivery system is prepared based on sample delivery systems having known release rates for the active component.
- the sweeteners may be selected from solid natural or synthetic sweeteners capable of imparting high intensity sweetness.
- these sweeteners include amino acid-based sweeteners, dipeptide sweeteners, glycyrrhizin, saccharin and its salts, acesulfame salts, cyclamates, steviosides, talin, dihydrochalcone compounds, chlorinated sucrose polymers such as sucralose and combinations thereof. Included among the high intensity sweeteners are aspartame and neotame.
- the active component (e.g., sweetener), which is part of the delivery system, may be used in amounts necessary to impart the desired effect associated with use of the active component (e.g., sweetness). With respect to their presence in the delivery system, the active components may be present in amounts of from about 1% to 70% by weight based on the total weight of the delivery system, preferably from about 10% to 40% by weight based on the total weight of the delivery system.
- the sweeteners may be present in amounts of from about 0.1% to 6% by weight based on the total weight of the edible composition, and more preferably 0.5% to 3% by weight.
- the active component especially when the active component is a sweetener may also be present in the edible composition in free form depending on the release profile desired.
- edible compositions which comprise the present delivery system and a carrier in an amount appropriate to accommodate the delivery system.
- carrier refers to an orally acceptable vehicle such as the soluble and insoluble components of a chewing gum composition capable of being mixed with the delivery system, and which will not cause harm to warm-blooded animals including humans.
- the carriers further include those components of the composition that are capable of being commingled without significant interaction with the delivery system.
- the edible composition is a chewing gum composition having prolonged release (e.g., typically at least 15 minutes) of the active component.
- the chewing gum composition comprises a chewing gum base and the delivery system of the present invention that comprises an encapsulating material and at least one encapsulated active component such as, for example, a sweetener or a flavorant.
- the delivery system is present in amounts from about 0.2% to 10% by weight based on the total weight of the chewing gum composition, preferably from about 1% to 5% by weight.
- the present invention may be incorporated with a variety of processes for preparing chewing gum compositions as known in the art.
- Such chewing gum compositions may be and include a variety of different formulations that are typically used to make chewing gum products.
- a chewing gum composition contains a chewable gum base portion, which is essentially free of water and is water insoluble and a water soluble bulk portion.
- the water soluble portion is generally released from the gum base portion over a period of time during chewing.
- the gum base portion is retained in the mouth throughout the chewing.
- the water insoluble gum base generally comprises elastomers, elastomer solvents, plasticizers, waxes, emulsifiers, and inorganic fillers.
- Plastic polymers such as polyvinyl acetate, which behave somewhat as plasticizers, are also included.
- Other plastic polymers that may be used include polyvinyl laurate, crosslinked polyvinyl pyrrolidone and polyhydroxy alkanoates.
- the elastomers may constitute from about 5% to 95% by weight of the gum base, preferably 10% to 70% by weight and more preferably 15% to 45% by weight.
- elastomers include synthetic elastomers such as polyisobutylene, polybutylene, isobutylene-isoprene co-polymers, styrene-butadiene co-polymers, polyvinyl acetate and the like.
- Elastomers may also include natural elastomers such as natural rubber as well as natural gums such as jelutong, lechi caspi, perillo, massaranduba balata, chicle, gutta hang kang or combinations thereof. Other elastomers are known to those of ordinary skill in the art.
- Elastomer plasticizers modify the finished gum firmness when used in the gum base.
- Elastomer plasticizers are typically present in an amount up to 75% by weight of the gum base, preferably from about 5% to 45% by weight and more preferably from about 10% to 30% by weight.
- examples of elastomer plasticizers include natural rosin esters such as glycerol ester of partially hydrogenated rosin, glycerol ester of tall oil rosin, pentaerythritol esters of partially hydrogenated rosin, methyl and partially hydrogenated methyl esters of rosin, and the like.
- Synthetic elastomer plasticizers such as terpene resins may also be employed in gum base composition.
- Waxes include synthetic and naturally occurring waxes such as polyethylene, bees wax, carnauba and the like. Petroleum waxes such a paraffin may also be used. The waxes may be present in the amount up to 30% by weight of the gum base. Waxes aid in the curing of the finished gum and help improve the release of flavor and may further extend the shelf life of the product.
- Elastomer solvents are often resins such as terpene resins.
- Plasticizers sometimes referred to as softeners, are typically fats and oils, including tallow, hydrogenated vegetable oils, and cocoa butter.
- Gum base typically also includes a filler component.
- the filler component modifies the texture of the gum base and aid processing.
- examples of such fillers include magnesium and aluminum silicates, clay, alumina, talc, titanium oxide, cellulose polymers, and the like. Fillers are typically present in the amount of from 1% to 60% by weight.
- Emulsifiers which sometimes also have plasticizing properties, include glycerol monostearate, lecithin, and glycerol triacetate. Further, gum bases may also contain optional ingredients such as antioxidants, colors, and flavors.
- the insoluble gum base may be present in the amount of from about 5% to 95% by weight of the chewing gum. Typically, the insoluble gum base may present in the amount of from about 10% to 50% by weight of the gum base, preferably from about 20% to 40% by weight of the gum base.
- Softeners are added to the chewing gum in order to optimize the chewability and mouth feel of the gum.
- Softeners also known in the art as plasticizers or plasticizing agents, is generally present in amounts from about 0.5% to 15% by weight based on the total weight of the chewing gum composition.
- Softeners contemplated by the present invention include, for example, lecithin.
- aqueous sweetener solutions such as those containing sorbitol, hydrogenated starch hydrolysate, corn syrup, and combinations thereof may be used as softeners and binding agents in the gum.
- the chewing gum compositions of the present invention may be coated or uncoated and be in the form or slabs, sticks, pellets, balls and the like.
- the composition of the different forms of the chewing gum compositions will be similar but may vary with regard to the ratio of the ingredients.
- coated gum compositions may contain a lower percentage of softeners.
- Pellets and balls have a small chewing gum core, which is then coated with either a sugar solution or a sugarless solution to create a hard shell.
- Slabs and sticks are usually formulated to be softer in texture than the chewing gum core.
- the delivery system is added during the manufacture of the chewing gum composition.
- the delivery system is added as one of the last steps, preferably the last step in the formation of the chewing gum composition.
- this process modification incorporates the delivery system into the gum composition without materially binding the delivery system therein such as may occur if the delivery system is mixed directly with the gum base.
- the delivery system while only loosely contained within the gum composition can more effectively release the active component therefrom during a typical chewing operation.
- a material portion of the delivery system is free of the gum base and the corresponding ingredients of the chewing gum.
- Coating techniques for applying a coating for a chewing gum composition such as pan and spray coating are well known.
- Preferred in the practice of the present invention is coating with solutions adapted to build a hard candy layer. Both sugar and sugar alcohols may be used for this purpose together with high intensity sweeteners, colorants, flavorants and binders.
- moisture absorbing compounds suitable for use in the coating syrups include mannitol or dicalcium phosphate.
- useful anti-adherent compounds include talc, magnesium trisilicate and calcium carbonate. These ingredients may be employed in amounts of from about 0.5% to 5% by weight of the syrup.
- dispersing agents include titanium dioxide, talc or other anti-adherent compounds as set forth above.
- the coating syrup is usually heated and a portion thereof deposited on the cores. Usually a single deposition of the coating syrup is not sufficient to provide the desired amount or thickness of coating and it usually will be necessary to apply second, third or more coats of the coating syrup in order to build up the weight and thickness of the coating to desired levels with layers allowed to dry in-between coats.
- a method of preparing the chewing gum composition of the present invention is provided by sequentially adding the various chewing gum ingredients including the delivery system of the present invention to any commercially available mixer known in the art. After the ingredients have been thoroughly mixed, the gum base is discharged from the mixer and shaped into the desired form such as by rolling into sheets and cutting into sticks, extruding into chunks, or casing into pellets.
- the ingredients are mixed by first melting the gum base and adding it to the running mixer.
- the base may also be melted into the mixer itself.
- Colors or emulsifiers may also be added at this time.
- a softener may be added to the mixer at this time, along with syrup and a portion of the bulking agent. Further parts of the bulking agent are then added to the mixer. Flavorants are typically added with the final portion of the bulking agent.
- the delivery system exhibiting a predetermeined tensile strength is added to the resulting mixture.
- Other optional ingredients are added in the batch in a typical fashion, well known to those of ordinary skill in the art.
- the gum mass may be formed into a variety of shapes and products.
- the ingredients may be formed into pellets or balls and used as cores to make a coated chewing gum product.
- any type of chewing gum product can be utilized with the present invention.
- the coating may contain ingredients such as flavorants, artificial sweeteners, dispersing agents, coloring agents, film formers and binding agents.
- Flavorants contemplated by the present invention include those commonly known in the art such as essential oils, synthetic flavors, or mixtures thereof, including but are not limited to, oils derived from plants and fruits such as citrus oils, fruit essences, peppermint oil, spearmint oil, other mint oils, clove oil, oil of wintergreen, anise and the like.
- the flavorants may also be added to the coating syrup in an amount such that the coating may be present in amounts of from about 0.2% to 1.2% by weight flavoring agent, and more preferably from about 0.7% to 1.0% by weight flavoring agent.
- Dispersing agents are often added to syrup coatings for the purpose of whitening and tack reduction.
- Dispersing agents contemplated by the present invention to be employed in the coating syrup include titanium dioxide, talc, or any other anti-stick compound.
- the dispersing agent may be added to the coating syrup in an amount such that the coating contains from about 0.1% to 1.0%, and more preferably from about 0.3% to 0.6% by weight of the agent.
- Coloring agents may be added directly to the coating syrup in dye or lake form. Coloring agents contemplated by the present invention include food quality dyes. Film formers may be added to the coating syrup include methylcellulose, carboxymethyl cellulose, ethyl cellulose, hydroxyethyl cellulose, and the like or combinations thereof. Binding agents may be added either as an initial coating on the chewing gum center or may be added directly to the coating syrup. Binding agents contemplated by the present invention include gum arabic, gum talha, gelatin, vegetable gums, and the like. The binding agents, when added to the coating syrup, are typically added in amounts from about 0.5% to 10% by weight.
- the present invention further encompasses confectionery compositions containing the delivery system of the present invention.
- Confectionery compositions include, for example, compressed tablets such as mints, hard boiled candies, chocolates, chocolate containing products, nutrient bars, nougats, gels, centerfill confections, fondants, panning goods, consumable thin films and other compositions falling within the generally accepted definition of confectionery compositions.
- Confectionery compositions in the form of pressed tablets such as mints may generally be made by combining finely sifted sugar or sugar substitute, flavoring agent (e.g. peppermint flavor) bulking agent such as gum arabic, and an optional coloring agent.
- flavoring agent e.g. peppermint flavor
- bulking agent such as gum arabic
- coloring agent e.g. peppermint flavor
- the flavoring agent, bulking agent are combined and then gradually the sugar or sugar substitute are added along with a coloring agent if needed.
- the product is then granulated by passing through a seize of desired mesh size (e.g. 12 mesh) and then dried typically at temperatures of from about 55° C. to 60° C.
- desired mesh size e.g. 12 mesh
- the resulting powder is fed into a tableting machine fitted with a large size punch and the resulting pellets are broken into granules and then pressed.
- High boiled candies typically contain sugar or sugar substitute, glucose, water, flavoring agent and optional coloring agent.
- the sugar is dissolved in the water and glucose is then added.
- the mixture is brought to a boil.
- the resulting liquid to which may previously have been added a coloring agent is poured onto an oiled slab and cooled.
- the flavoring agent are then added and kneaded into the cooled mass.
- the resulting mixture is then fed to a drop roller assembly known in the art to form the final hard candy shape.
- a nougat composition typically includes two principal components, a high boiled candy and a frappe.
- egg albumen or substitute thereof is combined with water and whisked to form a light foam.
- Sugar and glucose are added to water and boiled typically at temperatures of from about 130° C. to 140° C. and the resulting boiled product is poured into a mixing machine and beat until creamy.
- the beaten albumen and flavoring agent are combined with the creamy product and the combination is thereafter thoroughly mixed.
- the rate of release of the active component is affected by the variation in tensile strength such that the release rate of the higher tensile strength delivery system is generally slower than the release rate of lower tensile strength formulations.
- the tensile strength of the delivery system is generally lowered which increases the release rate of the active component.
- reduced amounts of fats or oils are employed typically for higher tensile strength delivery systems exhibiting lower release rates.
- Polyvinyl acetate was melted at a temperature of about 110° C. in a continuous extruder.
- the hydrogenated oil and glycerol monostearate (fat) were added to the molten polyvinyl acetate.
- Aspartame was then added to the resulting mixture and mixed under high shear to completely disperse the ingredients.
- the resulting extrudate was cooled and then sized to a particle size of less than 420 microns to produce the corresponding delivery system containing the encapsulated high intensity sweetener aspartame as the active component.
- the tensile strength of each of the final delivery systems was measured in accordance with ASTM Standard D638-02a and is shown in Table 1.
- the addition of fats and oils exhibits two effects on the tensile strength of the delivery system when a portion of the encapsulating material (polyvinyl acetate) is replaced by the fats and oils.
- a portion of the encapsulating material polyvinyl acetate
- there is a sharp increase in tensile strength when 5% by weight of polyvinyl acetate is replaced by a corresponding amounts of fats and oils.
- the replacement is 10% by weight the tensile strength drops significantly but remains above the level of the fat and oil free delivery system (delivery system no. 1).
- fats and oils are used in relatively large amounts (i.e., 20% by weight), the delivery system tends to exhibit a much lower tensile strength as compared to delivery system no. 3.
- the chewing gum composition was prepared as follows. The gum base was melted at a suitable temperature in a mixer. The remaining ingredients were then added to the melted gum base and mixed until the ingredients were completely dispersed. The resulting chewing gum composition was sized and conditioned for about 1 week and evaluated using a pool of human subjects. Each of the human subjects were asked to sample the chewing gum compositions by chewing each of the samples listed in Table 2 and rating the sweetness intensity of each sample at 10 minute intervals over a 30 minute time period. The resulting data is shown in FIG. 1 .
- Gum 3 prepared with fat and oil free delivery system no. 3 provided extended sweetener release with higher sweetener intensity measured at each of the intervals as compared to Gums 1 and 2 each of which contained a delivery system with some level of oil and fat.
- each of the chewing gum compositions prepared in accordance with Example 1 could readily be modified to include one or more additional delivery systems each containing a different active component.
- the following study examined the relationship between tensile strength of the delivery system and the release rate of the encapsulated active component.
- the presence of fats or oils were varied to modify the tensile strength of the delivery system, thereby allowing the release rate of the encapsulated active component to be adjusted as desired.
- the above delivery systems (i.e., delivery system nos. 4 to 7) were prepared in the following manner.
- the polyvinyl acetate encapsulating materials were melted at a temperature of about 110° C. in a continuous extruder.
- Hydrogenated oil and glycerol monostearate were added to the molten encapsulating materials.
- the sweetener was then added to the resulting mixture.
- the mixture was thoroughly mixed under high shear to completely disperse the ingredients to yield an extrudate.
- the mixed extrudate was thereafter allowed to cool and comminuted to yield particles of the respective delivery systems having a particle size of about less than 600 microns.
- the delivery systems were each formulated to exhibit a specific tensile strength, in part based on the amount and strength of the polyvinyl acetate and the amount of the fats and oils and other components.
- the tensile strength of each of delivery system nos. 4 through 7 is listed in Table 3.
- Gums 4 and 5 Two test samples of chewing gum compositions referred to herein as Gums 4 and 5 were prepared and formulated with the ingredients listed in Table 4 below.
- Gum 4 was formulated with a combination of delivery system nos. 5 and 6 shown in Table 3 in the specified amounts to yield a chewing gum having a relatively low tensile strength delivery system.
- Gum 5 was formulated with a combination of delivery system nos. 4 and 7 in the specified amounts to yield a chewing gum having a relatively high tensile strength delivery system.
- the above test sample chewing gums were each prepared in the following manner.
- the gum base was melted in a mixer.
- the remaining ingredients were added to the melted gum base.
- the melted gum base was mixed to completely disperse the ingredients.
- the resulting chewing gum was allowed to cool.
- the cooled chewing gum was sized and conditioned for about a week.
- each of the chewing gum compositions prepared in accordance with Example 2 could readily be modified to include one or more additional delivery systems each containing a different active component.
- a pool of human subjects was assembled to taste and rate the sweetness intensity of the chewing gum test samples over time. Each of the human subjects were asked to sample by chewing the test sample gums 4 and 5 over a 30 minute period. At each 5-minute interval, the human subjects were asked to rate the perceived sweetness intensity of the chewing gum sampled on a scale of 1 to 10. The results are shown in FIG. 2 .
- the chewing gums chewed by the human subjects were also subjected to chemical analysis at 5-minute intervals to measure the amount of the residual sweetener remaining in the gum bolus. Every 5 minutes over the 30-minute period, the bolus of the chewing gum was retrieved from each of the human subjects and tested by high-performance liquid chromatography (HPLC). The results are shown in FIG. 3 .
- the results indicate that Gum 5 possessing the higher tensile strength delivery system exhibited an initial perceived bitterness intensity that was relatively higher than Gum 4 (i.e., lower tensile strength delivery system). However, over the course of the next 20 minutes, the perceived bitterness in Gum 5 (higher tensile strength) decreased over time, while the perceived bitterness (lower tensile strength) increased over time and remained above the bitter intensity of Gum 5 .
- the results show that the release rate of the sweetener affects the perception of the inherent bitter flavor that may be normally present in chewing gum compositions. The slower release rate of the sweetener in Gum 5 (higher tensile strength) extended the duration of the taste masking over the course of the 25 minutes, thus reducing the perception of bitter taste as compared to Gum 4 (lower tensile strength).
- Gum 4 having a delivery system with a relatively lower tensile strength exhibited a higher rate of sweetener release than Gum 5 having a delivery system with a relatively higher tensile strength over the 30 minute period. Accordingly, by increasing the tensile strength of the delivery system, a lower rate of release of the sweetener can thereby be achieved. Conversely, reducing the tensile strength of the delivery system increases the rate of release of the sweetener.
- Chewing Gum 4 with the relatively lower tensile strength delivery system further showed a lower residual amount aspartame in the chewed cuds as compared to Gum 5 with the relatively higher tensile strength delivery system.
- the data shows that higher tensile strength delivery systems generally provide a slower rate of release of the sweeteners.
- the results shown in FIG. 3 are consistent with the results shown in FIG. 2 in that faster release of the sweetener results in less sweetener retained in the gum overtime.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Confectionery (AREA)
- Medicinal Preparation (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Non-Alcoholic Beverages (AREA)
- General Preparation And Processing Of Foods (AREA)
- Seasonings (AREA)
Priority Applications (23)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/719,298 US20050112236A1 (en) | 2003-11-21 | 2003-11-21 | Delivery system for active components as part of an edible composition having preselected tensile strength |
CN2004800340652A CN1882361B (zh) | 2003-11-21 | 2004-11-22 | 具有预选抗拉强度的、可食用组合物的活性组分释放系统 |
JP2006541237A JP5284588B2 (ja) | 2003-11-21 | 2004-11-22 | あらかじめ選択された引張強度を有する、食用組成物の一部としての活性成分のための送達システム |
PCT/US2004/037185 WO2005051427A1 (en) | 2003-11-21 | 2004-11-22 | A delivery system for active components as part of an endible composition having preselected tensile strength |
BRPI0416794-5A BRPI0416794A (pt) | 2003-11-21 | 2004-11-22 | sistema de distribuição para componentes ativos, como parte de uma composição comestìvel, tendo resistência à tração pré-selecionada |
EP04810526.6A EP1689438B1 (en) | 2003-11-21 | 2004-11-22 | A delivery system for active components as part of an edible composition having preselected tensile strength |
ARP040104322A AR047131A1 (es) | 2003-11-21 | 2004-11-22 | Sistema de administracion para componentes activos como partes de una composicion comestible que tiene una resistencia a la traccion preseleccionada |
PL04810526.6T PL1689438T3 (pl) | 2003-11-21 | 2004-11-22 | System podawania aktywnych składników jako część kompozycji jadalnej o wstępnie dobranej wytrzymałości na rozciąganie |
ES04810526.6T ES2576252T3 (es) | 2003-11-21 | 2004-11-22 | Un sistema de suministro para componentes activos como parte de una composición comestible que tiene una resistencia a la tracción previamente seleccionada |
ZA200603466A ZA200603466B (en) | 2003-11-21 | 2004-11-22 | A delivery system for active components as part of a n endible composition having pre-selected tensile strength |
AU2004292409A AU2004292409B2 (en) | 2003-11-21 | 2004-11-22 | A delivery system for active components as part of an edible composition having preselected tensile strength |
CA2544512A CA2544512C (en) | 2003-11-21 | 2004-11-22 | A delivery system for active components as part of an edible composition having preselected tensile strength |
MXPA06005706A MXPA06005706A (es) | 2003-11-21 | 2004-11-22 | Sistema de administracion para componentes activos como partes de una composicion comestible que tiene una resistencia a la traccion preseleccionada. |
RU2006121996/15A RU2351364C2 (ru) | 2003-11-21 | 2004-11-22 | Имеющая заданную прочность система доставки активных компонентов в качестве части пищевой композиции |
US11/083,968 US8828423B2 (en) | 2003-11-21 | 2005-03-21 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US11/135,153 US9271904B2 (en) | 2003-11-21 | 2005-05-23 | Controlled release oral delivery systems |
US11/134,367 US8591974B2 (en) | 2003-11-21 | 2005-05-23 | Delivery system for two or more active components as part of an edible composition |
US11/134,368 US20050214348A1 (en) | 2003-11-21 | 2005-05-23 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US11/913,104 US20090089167A1 (en) | 2003-11-21 | 2006-05-22 | Indicia-Bearing Package for Delivery Systems for Managing Release of Functional Ingredients in an Edible Composition |
CO06048810A CO5690619A2 (es) | 2003-11-21 | 2006-05-22 | Sistema de administracion para componentes activos como partes de una composicion comestible que tiene una resistencia a la traccion preseleccionada |
US11/913,260 US20090220642A1 (en) | 2003-11-21 | 2006-05-22 | Compressible gum based delivery systems for the release of ingredients |
US12/577,986 US20100028452A1 (en) | 2003-11-21 | 2009-10-13 | Delivery system for active components as part of an edible composition having preselected tensile strength |
JP2011039906A JP2011152134A (ja) | 2003-11-21 | 2011-02-25 | あらかじめ選択された引張強度を有する、食用組成物の一部としての活性成分のための送達システム |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/719,298 US20050112236A1 (en) | 2003-11-21 | 2003-11-21 | Delivery system for active components as part of an edible composition having preselected tensile strength |
Related Child Applications (6)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2004/037185 Continuation WO2005051427A1 (en) | 2003-11-21 | 2004-11-22 | A delivery system for active components as part of an endible composition having preselected tensile strength |
PCT/US2004/037185 Continuation-In-Part WO2005051427A1 (en) | 2003-11-21 | 2004-11-22 | A delivery system for active components as part of an endible composition having preselected tensile strength |
US11/083,968 Continuation-In-Part US8828423B2 (en) | 2003-11-21 | 2005-03-21 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US11/134,367 Continuation-In-Part US8591974B2 (en) | 2003-11-21 | 2005-05-23 | Delivery system for two or more active components as part of an edible composition |
US11/134,368 Continuation US20050214348A1 (en) | 2003-11-21 | 2005-05-23 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US12/577,986 Continuation US20100028452A1 (en) | 2003-11-21 | 2009-10-13 | Delivery system for active components as part of an edible composition having preselected tensile strength |
Publications (1)
Publication Number | Publication Date |
---|---|
US20050112236A1 true US20050112236A1 (en) | 2005-05-26 |
Family
ID=34591283
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/719,298 Abandoned US20050112236A1 (en) | 2003-11-21 | 2003-11-21 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US11/083,968 Expired - Fee Related US8828423B2 (en) | 2003-11-21 | 2005-03-21 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US11/134,368 Abandoned US20050214348A1 (en) | 2003-11-21 | 2005-05-23 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US12/577,986 Abandoned US20100028452A1 (en) | 2003-11-21 | 2009-10-13 | Delivery system for active components as part of an edible composition having preselected tensile strength |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/083,968 Expired - Fee Related US8828423B2 (en) | 2003-11-21 | 2005-03-21 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US11/134,368 Abandoned US20050214348A1 (en) | 2003-11-21 | 2005-05-23 | Delivery system for active components as part of an edible composition having preselected tensile strength |
US12/577,986 Abandoned US20100028452A1 (en) | 2003-11-21 | 2009-10-13 | Delivery system for active components as part of an edible composition having preselected tensile strength |
Country Status (15)
Country | Link |
---|---|
US (4) | US20050112236A1 (zh) |
EP (1) | EP1689438B1 (zh) |
JP (2) | JP5284588B2 (zh) |
CN (1) | CN1882361B (zh) |
AR (1) | AR047131A1 (zh) |
AU (1) | AU2004292409B2 (zh) |
BR (1) | BRPI0416794A (zh) |
CA (1) | CA2544512C (zh) |
CO (1) | CO5690619A2 (zh) |
ES (1) | ES2576252T3 (zh) |
MX (1) | MXPA06005706A (zh) |
PL (1) | PL1689438T3 (zh) |
RU (1) | RU2351364C2 (zh) |
WO (1) | WO2005051427A1 (zh) |
ZA (1) | ZA200603466B (zh) |
Cited By (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040120919A1 (en) * | 2002-12-20 | 2004-06-24 | L'oreal | Hair compositions |
US20060034897A1 (en) * | 2003-11-21 | 2006-02-16 | Cadbury Adams Usa Llc | Delivery system for two or more active components as part of an edible composition |
US20060177383A1 (en) * | 2005-02-07 | 2006-08-10 | Cadbury Adams Usa, Llc. | Stable tooth whitening gum with reactive ingredients |
US20060275361A1 (en) * | 2005-06-03 | 2006-12-07 | Cadbury Adams Usa Llc. | Rapidly dissolving gelatin compositions and products made therefrom |
WO2007022317A2 (en) * | 2005-08-17 | 2007-02-22 | Cadbury Adams Usa Llc | Dusting compositions for chewing gum products |
US20070148284A1 (en) * | 2004-08-25 | 2007-06-28 | Cadbury Adams Usa Llc. | Liquid-filled chewing gum |
US20070148286A1 (en) * | 2004-08-25 | 2007-06-28 | Cadbury Adams Usa Llc. | Liquid-filled chewing gum composition |
US20070237855A1 (en) * | 2006-04-05 | 2007-10-11 | Cadbury Adams Usa Llc | Calcium phosphate complex in acid containing confectionery |
WO2006127067A3 (en) * | 2005-05-23 | 2008-01-10 | Cadbury Adams Usa Llc | A delivery system for coated active components as part of an edible composition |
WO2006127070A3 (en) * | 2005-05-23 | 2008-01-17 | Cadbury Adams Usa Llc | An edible composition including a delivery system for active components |
WO2006127069A3 (en) * | 2005-05-23 | 2008-01-24 | Cadbury Adams Usa Llc | A delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component |
EP1885205A1 (en) * | 2005-05-23 | 2008-02-13 | Cadbury Adams USA LLC | Methods for managing release of one or more ingredients in an edible composition based on ratios of ingredients to encapsulating materials |
WO2008019685A1 (en) * | 2006-08-17 | 2008-02-21 | Gumlink A/S | Resin encapsulated high intensity sweetener |
US20080063747A1 (en) * | 2004-08-25 | 2008-03-13 | Cadbury Adams Usa Llc | Dusting compositions for chewing gum products |
US20080166449A1 (en) * | 2006-11-29 | 2008-07-10 | Cadbury Adams Usa Llc | Confectionery compositions including an elastomeric component and a saccharide component |
US20080199564A1 (en) * | 2005-05-23 | 2008-08-21 | Cadbury Adams Usa Llc | Confectionery Composition Including an Elastomeric Component and a Cooked Saccharide Component |
WO2009007717A1 (en) | 2007-07-10 | 2009-01-15 | Cadbury Holdings Limited | Chocolate compositions having improved flavour characteristics |
US20090098252A1 (en) * | 2004-09-30 | 2009-04-16 | Cadbury Adams Usa Llc | Thermally stable, high tensile strength encapsulation compositions for actives |
US20090098241A1 (en) * | 2006-02-20 | 2009-04-16 | Gumlink A/S | Resin encapsulated food acid |
US20090162476A1 (en) * | 2007-12-21 | 2009-06-25 | Cadbury Adams Usa Llc | Parallel Gum Component Mixing Systems And Methods |
US20090175982A1 (en) * | 2005-05-23 | 2009-07-09 | Cadbury Adams Usa Llc., | Methods for managing release of one or more ingredients in an edible composition |
US20090220642A1 (en) * | 2003-11-21 | 2009-09-03 | Cadbury Adams Usa Llc | Compressible gum based delivery systems for the release of ingredients |
US20100028452A1 (en) * | 2003-11-21 | 2010-02-04 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US20100034871A1 (en) * | 2007-04-04 | 2010-02-11 | Rikke Mikkelsen | Center-Filled Chewing Gum Product For Dental Care |
US7727565B2 (en) | 2004-08-25 | 2010-06-01 | Cadbury Adams Usa Llc | Liquid-filled chewing gum composition |
US7851005B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and beverages containing same |
US7851006B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and beverages containing same |
US7851000B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and edible confectionery and chewing gum products containing same |
US7955630B2 (en) | 2004-09-30 | 2011-06-07 | Kraft Foods Global Brands Llc | Thermally stable, high tensile strength encapsulated actives |
WO2012016161A1 (en) | 2010-07-30 | 2012-02-02 | Kraft Foods Global Brands Llc | A delivery system for active components as part of an edible composition |
US8133476B2 (en) | 2006-04-05 | 2012-03-13 | Cadbury Adams Usa Llc | Calcium phosphate complex and salts in oral delivery systems |
WO2012034012A1 (en) | 2010-09-09 | 2012-03-15 | Kraft Foods Global Brands Llc | Chewing gum compositions providing flavor release profiles |
WO2012125397A2 (en) | 2011-03-11 | 2012-09-20 | Kraft Foods Global Brands Llc | System and method of forming multilayer confectionery |
EP2520312A1 (en) * | 2006-06-28 | 2012-11-07 | Kraft Foods Global Brands LLC | A process for manufacturing a delivery system for active components as part of an edible composition |
WO2013013045A2 (en) | 2011-07-21 | 2013-01-24 | Kraft Foods Global Brands Llc | Advanced gum forming |
WO2013013041A2 (en) | 2011-07-21 | 2013-01-24 | Kraft Foods Global Brands Llc | Advanced gum forming |
US8389032B2 (en) | 2005-05-23 | 2013-03-05 | Kraft Foods Global Brands Llc | Delivery system for active components as part of an edible composition having selected particle size |
US8389031B2 (en) | 2005-05-23 | 2013-03-05 | Kraft Foods Global Brands Llc | Coated delivery system for active components as part of an edible composition |
WO2013158291A2 (en) | 2012-04-20 | 2013-10-24 | Kraft Foods Global Brands Llc | System and method for manufacturing chewing gum |
US8591973B2 (en) | 2005-05-23 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for active components and a material having preselected hydrophobicity as part of an edible composition |
WO2014047263A1 (en) | 2012-09-21 | 2014-03-27 | Intercontinental Great Brands Llc | Advanced gum forming |
EP2774492A2 (en) | 2005-05-23 | 2014-09-10 | Intercontinental Great Brands LLC | Sweetener potentiator compositions |
WO2014172287A1 (en) | 2013-04-17 | 2014-10-23 | Intercontinental Great Brands Llc | A system and method for forming a chewing gum product with at least one inclusion |
US9271904B2 (en) | 2003-11-21 | 2016-03-01 | Intercontinental Great Brands Llc | Controlled release oral delivery systems |
CN108135244A (zh) * | 2015-10-28 | 2018-06-08 | 洲际大品牌有限责任公司 | 制备用于可食用组合物的包封组合物的方法 |
WO2018147842A1 (en) * | 2017-02-08 | 2018-08-16 | Intercontinental Great Brands Llc | Advanced encapsulation process for controlled release of active ingredients from a chewing gum |
US10334867B2 (en) | 2014-03-03 | 2019-07-02 | Intercontinental Great Brands Llc | Method for manufacturing a comestible |
EP3530121A1 (en) | 2010-01-21 | 2019-08-28 | Intercontinental Great Brands LLC | System and method of forming and sizing chewing gum and/or altering temperature of chewing gum |
US11122815B2 (en) | 2011-07-21 | 2021-09-21 | Intercontinental Great Brands Llc | System and method for forming and cooling chewing gum |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL1919462T3 (pl) | 2005-05-23 | 2019-01-31 | Intercontinental Great Brands Llc | Kompozycja gumy do żucia z nadzieniem |
US20070275119A1 (en) * | 2006-05-26 | 2007-11-29 | Cadbury Adams Usa Llc | Confectionery compositions containing reactable ingredients |
US20080171085A1 (en) * | 2007-01-11 | 2008-07-17 | Natrol, Inc. | Novel biphasic delivery system for a pharmaceutical or nutraceutical composition and method of administration |
GB0915264D0 (en) * | 2009-09-02 | 2009-10-07 | Cadbury Adams Usa Llc | Gum base |
RU2451294C1 (ru) * | 2010-11-19 | 2012-05-20 | Саубан Нурлыгаянович Хунафин | Способ выбора местных антисептических средств в различные периоды ожоговой болезни |
BR112014008837A2 (pt) * | 2011-10-11 | 2017-04-25 | Intercontinental Great Brands Llc | composição edulcorante encapsulada, método para a preparação da mesma e goma de mascar compreendendo a mesma |
AR101774A1 (es) * | 2014-09-12 | 2017-01-11 | Wrigley W M Jun Co | Composición de goma de mascar que comprenden varios edulcorantes |
SG11201805944YA (en) * | 2015-12-22 | 2018-08-30 | Mccormick & Co Inc | High integrity encapsulation product |
DE102016203008A1 (de) | 2016-02-25 | 2017-08-31 | Wacker Chemie Ag | Verkapselte Süßstoffe und Verfahren zur ihrer Herstellung |
JP2021048885A (ja) * | 2021-01-07 | 2021-04-01 | インターコンチネンタル グレート ブランズ エルエルシー | チューインガムから有効成分を制御放出するための高度なカプセル化プロセス |
US20220408771A1 (en) * | 2021-06-25 | 2022-12-29 | Trucapsol Llc | Flavor delivery system |
US11878280B2 (en) | 2022-04-19 | 2024-01-23 | Trucapsol Llc | Microcapsules comprising natural materials |
Citations (70)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3341416A (en) * | 1963-12-11 | 1967-09-12 | Ncr Co | Encapsulation of aspirin in ethylcellulose and its product |
US3691090A (en) * | 1969-01-16 | 1972-09-12 | Fuji Photo Film Co Ltd | Encapsulation method |
US4139639A (en) * | 1977-01-24 | 1979-02-13 | General Foods Corporation | Fixation of APM in chewing gum |
US4384004A (en) * | 1981-06-02 | 1983-05-17 | Warner-Lambert Company | Encapsulated APM and method of preparation |
US4386106A (en) * | 1981-12-01 | 1983-05-31 | Borden, Inc. | Process for preparing a time delayed release flavorant and an improved flavored chewing gum composition |
US4485118A (en) * | 1983-04-21 | 1984-11-27 | Warner-Lambert Company | Gum composition with plural time releasing flavors and method of preparation |
US4515769A (en) * | 1981-12-01 | 1985-05-07 | Borden, Inc. | Encapsulated flavorant material, method for its preparation, and food and other compositions incorporating same |
US4520142A (en) * | 1984-02-17 | 1985-05-28 | Minnesota Mining And Manufacturing Company | Aerosol application of encapsulated materials |
US4590075A (en) * | 1984-08-27 | 1986-05-20 | Warner-Lambert Company | Elastomer encapsulation of flavors and sweeteners, long lasting flavored chewing gum compositions based thereon and process of preparation |
US4597970A (en) * | 1984-10-05 | 1986-07-01 | Warner-Lambert Company | Chewing gum compositions containing novel sweetener delivery systems and method of preparation |
US4634593A (en) * | 1985-07-31 | 1987-01-06 | Nabisco Brands, Inc. | Composition and method for providing controlled release of sweetener in confections |
US4673577A (en) * | 1983-02-18 | 1987-06-16 | Wm. Wrigley Jr. Company | Shellac encapsulant for high-potency sweeteners in chewing gum |
US4711784A (en) * | 1986-01-07 | 1987-12-08 | Warner-Lambert Company | Encapsulation composition for use with chewing gum and edible products |
US4722845A (en) * | 1986-12-23 | 1988-02-02 | Warner-Lambert Company | Stable cinnamon-flavored chewing gum composition |
US4726953A (en) * | 1986-10-01 | 1988-02-23 | Nabisco Brands, Inc. | Sweet flavorful soft flexible sugarless chewing gum |
US4740376A (en) * | 1986-01-07 | 1988-04-26 | Warner-Lambert Company | Encapsulation composition for use with chewing gum and edible products |
US4752481A (en) * | 1986-06-19 | 1988-06-21 | Warner-Lambert Company | Flavor emulsions and chewing gum compositions containing the same |
US4764382A (en) * | 1984-11-15 | 1988-08-16 | Hercon Laboratories Corporation | Device for controlled release drug delivery |
US4771784A (en) * | 1987-02-17 | 1988-09-20 | Kuibyshevksy Politekhnichesky Institut | Ophthalmorheographic transducer |
US4804548A (en) * | 1984-10-05 | 1989-02-14 | Warner-Lambert Company | Novel sweetener delivery systems |
US4816265A (en) * | 1986-12-23 | 1989-03-28 | Warner-Lambert Company | Sweetener delivery systems containing polyvinyl acetate |
US4824681A (en) * | 1986-12-19 | 1989-04-25 | Warner-Lambert Company | Encapsulated sweetener composition for use with chewing gum and edible products |
US4828857A (en) * | 1984-10-05 | 1989-05-09 | Warner-Lambert Company | Novel sweetener delivery systems |
US4911934A (en) * | 1986-12-19 | 1990-03-27 | Warner-Lambert Company | Chewing gum composition with encapsulated sweetener having extended flavor release |
US4915958A (en) * | 1986-12-10 | 1990-04-10 | Warner-Lambert Company | High-base gum composition with extended flavor release |
US4929447A (en) * | 1986-01-07 | 1990-05-29 | Warner-Lambert Company | Encapsulation composition for use with chewing gum and edible products |
US4931293A (en) * | 1986-12-23 | 1990-06-05 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US4933190A (en) * | 1986-12-23 | 1990-06-12 | Warner-Lambert Co. | Multiple encapsulated sweetener delivery system |
US4981698A (en) * | 1986-12-23 | 1991-01-01 | Warner-Lambert Co. | Multiple encapsulated sweetener delivery system and method of preparation |
US4997659A (en) * | 1989-03-28 | 1991-03-05 | The Wm. Wrigley Jr. Company | Alitame stability in chewing gum by encapsulation |
US5043169A (en) * | 1990-05-25 | 1991-08-27 | Warner-Lambert Company | Stabilized Sweetner Composition |
US5057328A (en) * | 1988-11-14 | 1991-10-15 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US5057327A (en) * | 1989-12-29 | 1991-10-15 | Wm. Wrigley Jr. Company | Chewing gum with longer lasting sweetness using alitame |
US5064658A (en) * | 1990-10-31 | 1991-11-12 | Warner-Lamber Company | Encapsulated synergistic sweetening agent compositions comprising aspartame and acesulfame-K and methods for preparing same |
US5100678A (en) * | 1990-11-15 | 1992-03-31 | Wm. Wrigley Jr. Company | Chewing gum with prolonged flavor release incorporating unsaturated, purified monoglycerides |
US5108763A (en) * | 1991-04-03 | 1992-04-28 | Warner-Lambert Company | Microencapsulated high intensity sweetening agents having prolonged sweetness release and methods for preparing same |
US5126151A (en) * | 1991-01-24 | 1992-06-30 | Warner-Lambert Company | Encapsulation matrix |
US5139793A (en) * | 1990-07-10 | 1992-08-18 | Wm. Wrigley Jr. Company | Method of prolonging flavor in chewing gum by the use of cinnamic aldehyde propylene glycol acetal |
US5139798A (en) * | 1990-11-21 | 1992-08-18 | Wm. Wrigley Jr. Company | Polyvinyl acetate encapsulation of codried sucralose for use in chewing gum |
US5139794A (en) * | 1989-04-19 | 1992-08-18 | Wm. Wrigley Jr. Company | Use of encapsulated salts in chewing gum |
US5154939A (en) * | 1989-04-19 | 1992-10-13 | Wm. Wrigley Jr. Company | Use of salt to improve extrusion encapsulation of chewing gum ingredients |
US5164210A (en) * | 1991-10-08 | 1992-11-17 | Wm. Wrigley Jr. Company | Zein/shellac encapsulation of high intensity sweeteners in chewing gum |
US5169658A (en) * | 1989-04-19 | 1992-12-08 | Wm. Wrigley Jr. Company | Polyvinyl acetate encapsulation of crystalline sucralose for use in chewing gum |
US5169657A (en) * | 1991-07-17 | 1992-12-08 | Wm. Wrigley Jr. Company | Polyvinyl acetate encapsulation of sucralose from solutions for use in chewing gum |
US5198251A (en) * | 1989-04-19 | 1993-03-30 | Wm. Wrigley Jr. Company | Gradual release structures for chewing gum |
US5226335A (en) * | 1990-04-11 | 1993-07-13 | Hellmuth Sitte | Automatic initial-cutting device for microtomes, particularly ultramicrotomes |
US5413799A (en) * | 1994-04-12 | 1995-05-09 | Wm. Wrigley Jr. Company | Method of making fruit-flavored chewing with prolonged flavor intensity |
US5415880A (en) * | 1994-04-12 | 1995-05-16 | Wm. Wrigley Jr. Company | Fruit flavored chewing gum with prolonged flavor intensity |
US5480668A (en) * | 1992-11-12 | 1996-01-02 | Nofre; Claude | N-substituted derivatives of aspartame useful as sweetening agents |
US5532004A (en) * | 1993-06-23 | 1996-07-02 | Nabisco, Inc. | Chewing gum containing hydrophobic flavorant encapsulated in a hydrophilic shell |
US5589194A (en) * | 1993-09-20 | 1996-12-31 | Minnesota Mining And Manufacturing Company | Method of encapsulation and microcapsules produced thereby |
US5629035A (en) * | 1995-12-18 | 1997-05-13 | Church & Dwight Co., Inc. | Chewing gum product with encapsulated bicarbonate and flavorant ingredients |
US5693334A (en) * | 1995-10-05 | 1997-12-02 | Church & Dwight Co., Inc. | Chewing gum product with dental health benefits |
US5789002A (en) * | 1996-10-03 | 1998-08-04 | Warner-Lambert Company | Gum sweetener/acid processing system |
US6174514B1 (en) * | 1999-04-12 | 2001-01-16 | Fuisz Technologies Ltd. | Breath Freshening chewing gum with encapsulations |
US6365209B2 (en) * | 2000-06-06 | 2002-04-02 | Capricorn Pharma, Inc. | Confectionery compositions and methods of making |
US6428827B1 (en) * | 1999-04-01 | 2002-08-06 | Wm. Wrigley Jr. Company | Long flavor duration releasing structures for chewing gum and method of making |
US20020122842A1 (en) * | 2000-12-15 | 2002-09-05 | Seielstad Donald A. | Encapsulated acid mixtures and products including same |
US6479071B2 (en) * | 2000-03-10 | 2002-11-12 | Warner-Lambert Company | Chewing gum and confectionery compositions with encapsulated stain removing agent compositions, and methods of making and using the same |
US6555145B1 (en) * | 2000-06-06 | 2003-04-29 | Capricorn Pharma, Inc. | Alternate encapsulation process and products produced therefrom |
US6692778B2 (en) * | 1998-06-05 | 2004-02-17 | Wm. Wrigley Jr. Company | Method of controlling release of N-substituted derivatives of aspartame in chewing gum |
US6759066B2 (en) * | 2000-09-12 | 2004-07-06 | Wm. Wrigley Jr. Company | Chewing gum formulations including encapsulated aspartame and sodium pyrophosphate |
US20050220867A1 (en) * | 2003-11-21 | 2005-10-06 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US20050260266A1 (en) * | 2003-11-21 | 2005-11-24 | Cadbury Adams Usa, Llc. | Controlled release oral delivery systems |
US20060034897A1 (en) * | 2003-11-21 | 2006-02-16 | Cadbury Adams Usa Llc | Delivery system for two or more active components as part of an edible composition |
US20060263480A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having selected particle size |
US20060263479A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component |
US20060263478A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Coated delivery system for active components as part of an edible composition |
US20060263413A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Delivery system for active components and a material having preselected hydrophobicity as part of an edible composition |
US20060263477A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Edible composition including a delivery system for active components |
Family Cites Families (300)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3124459A (en) | 1964-03-10 | Organoleptic compositions | ||
US27562A (en) * | 1860-03-20 | Francis odell | ||
US1633336A (en) | 1925-09-28 | 1927-06-21 | Winford P Larson | Dentifrice |
US1936456A (en) | 1929-05-01 | 1933-11-21 | Wm S Merrell Co | Therapeutic preparation |
US1952886A (en) | 1932-06-14 | 1934-03-27 | William J O'brien | Pigment |
US2191199A (en) | 1937-09-17 | 1940-02-20 | Hall Lab Inc | Abrasive detergent composition |
US2197719A (en) | 1938-12-07 | 1940-04-16 | Wrigley W M Jun Co | Chewing gum |
BE543046A (zh) | 1954-11-24 | |||
US3004897A (en) | 1955-02-09 | 1961-10-17 | Shore Joseph | Dental preparation |
US2886441A (en) | 1956-07-03 | 1959-05-12 | Gen Foods Corp | Product and process |
US2886440A (en) | 1956-07-03 | 1959-05-12 | Gen Foods Corp | Chewing gum and method of producing |
US2886442A (en) | 1956-07-27 | 1959-05-12 | Gen Foods Corp | Chewing gum and method of producing |
US2886444A (en) | 1956-08-15 | 1959-05-12 | Gen Foods Corp | Process of preparing a chewing gum and the resulting product |
US2886443A (en) | 1956-08-15 | 1959-05-12 | Gen Foods Corp | Process for making chewing gum and product |
US2886446A (en) | 1958-12-08 | 1959-05-12 | Gen Foods Corp | Process for making chewing gum and product |
US2886445A (en) | 1958-12-08 | 1959-05-12 | Gen Foods Corp | Process for making chewing gum and product |
US2886449A (en) | 1959-03-10 | 1959-05-12 | Gen Foods Corp | Method of making chewing gum and the resulting product |
GB875763A (en) | 1959-05-01 | 1961-08-23 | Gen Foods Corp | Chewing gum having controlled flavour release |
US3052552A (en) | 1959-09-16 | 1962-09-04 | Beech Nut Life Savers Inc | Printing on confection items and the resulting product |
US3117027A (en) | 1960-01-08 | 1964-01-07 | Wisconsin Alumni Res Found | Apparatus for coating particles in a fluidized bed |
US3159585A (en) | 1961-04-12 | 1964-12-01 | Nat Starch Chem Corp | Method of encapsulating water insoluble oils and product thereof |
US3241520A (en) | 1964-10-19 | 1966-03-22 | Wisconsin Alumni Res Found | Particle coating apparatus |
US3475533A (en) | 1966-05-19 | 1969-10-28 | Extar Co | Water-free toothpastes containing metaphosphates,calcium carbonate,and mineral oil |
US3538230A (en) | 1966-12-05 | 1970-11-03 | Lever Brothers Ltd | Oral compositions containing silica xerogels as cleaning and polishing agents |
US3664963A (en) | 1969-10-22 | 1972-05-23 | Balchem Corp | Encapsulation process |
US3819838A (en) | 1970-08-04 | 1974-06-25 | Bush Boake Allen Ltd | Encapsulated flavoring composition |
US3677771A (en) | 1970-09-21 | 1972-07-18 | Ralston Purina Co | Process for the manufacture of caramels |
US3795744A (en) | 1970-10-21 | 1974-03-05 | Lotte Co Ltd | Flavor variable chewing gum and methods of preparing the same |
US3826847A (en) | 1970-10-21 | 1974-07-30 | Lotte Co Ltd | Process for preparation of flavor durable chewing gum |
US3821417A (en) | 1970-11-09 | 1974-06-28 | Warner Lambert Co | Flavor preservation in chewing gum compositions and candy products |
US3664962A (en) | 1971-01-11 | 1972-05-23 | Jerry D Kelly | Stain remover |
US3962416A (en) | 1971-01-25 | 1976-06-08 | Sol Katzen | Preserved nutrients and products |
US4136163A (en) | 1971-02-04 | 1979-01-23 | Wilkinson Sword Limited | P-menthane carboxamides having a physiological cooling effect |
US4193936A (en) | 1971-02-04 | 1980-03-18 | Wilkinson Sword Limited | N-substituted paramenthane carboxamides |
GB1351761A (en) | 1971-02-04 | 1974-05-01 | Wilkinson Sword Ltd | Substituted p-menthane carboxamides and compositions containing them |
US3878938A (en) | 1971-04-08 | 1975-04-22 | Lever Brothers Ltd | Toothpastes |
US4033994A (en) | 1972-01-28 | 1977-07-05 | Wilkinson Sword Limited | Substituted p-menthanes |
US4060091A (en) | 1972-01-28 | 1977-11-29 | Wilkinson Sword Limited | Tobacco and tobacco-containing manufactures containing an ingredient having physiological cooling activity |
US4059118A (en) | 1972-01-28 | 1977-11-22 | Wilkinson Sword Limited | Tobacco and tobacco-containing manufactures containing an ingredient having physiological cooling activity |
US3962463A (en) | 1972-04-03 | 1976-06-08 | Life Savers, Inc. | Chewing gum having surface impregnated, microencapsulated flavor particles |
GB1421743A (en) | 1972-04-18 | 1976-01-21 | Wilkinson Sword Ltd | Ingestible topical and other compositions |
CA1027347A (en) | 1972-07-20 | 1978-03-07 | David G. Rowsell | Compounds having a physiological cooling effect and compositions containing them |
US3943258A (en) | 1972-10-05 | 1976-03-09 | General Foods Corporation | Chewing gums of longer lasting sweetness and flavor |
US4070449A (en) | 1972-10-24 | 1978-01-24 | Wilkinson Sword Limited | Compounds having a physiological cooling effect and compositions containing them |
US3872021A (en) | 1972-11-13 | 1975-03-18 | Audrey M Mcknight | Cleaning composition |
US3857964A (en) | 1973-02-09 | 1974-12-31 | Brook D | Controlled release flavor compositions |
US3862307A (en) | 1973-04-09 | 1975-01-21 | Procter & Gamble | Dentifrices containing a cationic therapeutic agent and improved silica abrasive |
GB1444024A (en) | 1973-07-20 | 1976-07-28 | Passwaterr A | Food and feed supplents |
US3912817A (en) | 1973-10-03 | 1975-10-14 | Topps Chewing Gum Inc | Gum product and method of making the same |
US3897566A (en) | 1973-12-06 | 1975-07-29 | Gen Foods Corp | Chewing gums having longer lasting sweetness and flavor |
US3930026A (en) | 1974-08-28 | 1975-12-30 | Squibb & Sons Inc | Chewing gum having enhanced flavor |
US3984574A (en) | 1975-04-11 | 1976-10-05 | Wm. Wrigley Jr. Company | Non-tack chewing gum composition |
US4045581A (en) | 1975-05-15 | 1977-08-30 | Life Savers, Inc. | Long-lasting mint-flavored chewing gum |
GB1501484A (en) | 1975-10-24 | 1978-02-15 | Tate & Lyle Ltd | Icing mixture |
US3974293A (en) | 1975-11-26 | 1976-08-10 | Life Savers, Inc. | Non-adhesive chewing gum composition |
US4083995A (en) | 1976-07-22 | 1978-04-11 | The United States Of America As Represented By The Secretary Of Agriculture | (Z)-9-Tetradecen-1-ol formate and its use as a communication disruptant for Heliothis |
US4130638A (en) | 1976-11-03 | 1978-12-19 | Richardson-Merrell Inc. | Mouthwash compositions |
US4107360A (en) | 1976-11-04 | 1978-08-15 | Sagapha A. G. | Process for packing a pasty stain remover in portion capsules |
US4217368A (en) | 1977-07-08 | 1980-08-12 | Life Savers, Inc. | Long-lasting chewing gum and method |
US4159315A (en) | 1977-11-28 | 1979-06-26 | General Mills, Inc. | Plaque inhibiting composition and method |
US4160054A (en) | 1977-11-28 | 1979-07-03 | General Mills, Inc. | Plaque inhibiting composition and method |
US4148872A (en) | 1977-11-28 | 1979-04-10 | General Mills, Inc. | Plaque inhibiting composition and method |
US4157385A (en) | 1977-11-28 | 1979-06-05 | General Mills, Inc. | Plaque inhibiting composition and method |
US4160820A (en) | 1977-11-28 | 1979-07-10 | General Mills, Inc. | Plaque inhibiting composition and method |
US4150112A (en) | 1977-11-28 | 1979-04-17 | General Mills, Inc. | Plaque inhibiting composition and method |
US4156716A (en) | 1977-11-28 | 1979-05-29 | General Mills, Inc. | Plaque inhibiting composition and method |
US4156715A (en) | 1977-11-28 | 1979-05-29 | General Mills, Inc. | Plaque inhibiting composition and method |
US4187320A (en) | 1978-05-01 | 1980-02-05 | Warner-Lambert Company | Process for preparing chewing gum base using solid elastomer |
US4208431A (en) | 1978-05-05 | 1980-06-17 | Life Savers, Inc. | Long-lasting chewing gum having good processibility and method |
US4276312A (en) | 1978-05-25 | 1981-06-30 | Merritt Carleton G | Encapsulation of materials |
US4224345A (en) | 1978-10-16 | 1980-09-23 | Lotte Co., Ltd | Chewing gum base and a combination of a chewing gum with fatty matter |
US4340583A (en) | 1979-05-23 | 1982-07-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
US4363756A (en) | 1979-06-18 | 1982-12-14 | Lever Brothers Company | Pretreatment composition for stain removal |
US4295845A (en) | 1979-06-18 | 1981-10-20 | Lever Brothers Company | Pretreatment composition for stain removal |
US4271197A (en) | 1979-06-21 | 1981-06-02 | Walter Hopkins | Chewing gum containing sugar substitute |
US4314990A (en) | 1979-10-15 | 1982-02-09 | The Procter & Gamble Company | Toothpaste compositions |
US4271199A (en) | 1979-11-23 | 1981-06-02 | Life Savers, Inc. | Sugar-containing chewing gum having smooth texture and long-lasting sweetness |
US4370350A (en) | 1980-04-28 | 1983-01-25 | Wm. Wrigley Jr. Company | Chewing gum method |
US4457857A (en) | 1980-10-20 | 1984-07-03 | Lever Brothers Company | Pretreatment composition for stain removal |
US4352822A (en) | 1980-12-15 | 1982-10-05 | Nabisco Brands Inc. | Gum base, chewing gum containing same and method |
US4352825A (en) | 1981-02-23 | 1982-10-05 | Nabisco Brands, Inc. | Coextruded chewing gum containing a soft core portion |
US4352823A (en) | 1981-04-13 | 1982-10-05 | Nabisco Brands, Inc. | Coextruded chewing gum containing a soft non-SBR gum core portion |
US4663152A (en) | 1981-09-30 | 1987-05-05 | Colgate-Palmolive Co. | Functional agglomerated speckles, method for manufacture thereof and dentifrices containing such speckles |
US4388328A (en) | 1981-10-15 | 1983-06-14 | Warner-Lambert Company | Sorbitol containing mixture encapsulated flavor |
JPS5888334A (ja) | 1981-11-20 | 1983-05-26 | Takasago Corp | 3−l−メントキシプロパン−1、2−ジオ−ル |
US4452821A (en) | 1981-12-18 | 1984-06-05 | Gerhard Gergely | Confectionery product, particularly chewing gum, and process for its manufacture |
US4613512A (en) | 1982-09-30 | 1986-09-23 | General Foods Corporation | Edible material containing m-aminobenzoic acid or salt |
US4472437A (en) | 1983-03-01 | 1984-09-18 | Warner-Lambert Company | Dicalcium phosphate as gum base filler |
US4627987A (en) | 1983-03-22 | 1986-12-09 | General Foods Corporation | Edible material containing meta-hydroxybenzoic or salts |
US4871570A (en) | 1983-03-22 | 1989-10-03 | General Foods Corp. | Foodstuffs containing hydrobenzene organic acids as sweetness modifying agents |
US4497832A (en) | 1983-04-18 | 1985-02-05 | Warner-Lambert Company | Chewing gum composition having enhanced flavor-sweetness |
US4513012A (en) | 1983-05-13 | 1985-04-23 | Warner-Lambert Company | Powdered center-filled chewing gum compositions |
FR2548874B1 (fr) | 1983-07-13 | 1986-11-28 | Gen Foods Corp | Produit alimentaire contenant des modificateurs de douceur et procede de modification du gout sucre d'un produit alimentaire |
CA1208966A (en) | 1983-07-13 | 1986-08-05 | Ronald E. Barnett | Foodstuffs containing sweetness modifying agents |
US4751095A (en) | 1983-07-28 | 1988-06-14 | Karl Curtis L | Aspartame stabilization with cyclodextrin |
US4518615A (en) | 1983-08-23 | 1985-05-21 | Warner-Lambert Company | Non-adhesive chewing gum base composition |
US4749575A (en) | 1983-10-03 | 1988-06-07 | Bio-Dar Ltd. | Microencapsulated medicament in sweet matrix |
US4614649A (en) | 1983-12-09 | 1986-09-30 | Sterling Drug Inc. | Antiplaque saccharin salt dentrifices and method of use thereof |
US4971806A (en) | 1984-01-31 | 1990-11-20 | Warner-Lambert Company | Multi-layered chewing gum composition having different rates of flavor release |
FR2559755A1 (fr) | 1984-02-20 | 1985-08-23 | Rhone Poulenc Spec Chim | Oxyde cerique a nouvelles caracteristiques morphologiques et son procede d'obtention |
US4568560A (en) | 1984-03-16 | 1986-02-04 | Warner-Lambert Company | Encapsulated fragrances and flavors and process therefor |
US4614654A (en) | 1984-08-24 | 1986-09-30 | Wm. Wrigley Jr. Company | Taffy-like chewing gum confection and method |
IE58110B1 (en) | 1984-10-30 | 1993-07-14 | Elan Corp Plc | Controlled release powder and process for its preparation |
US4585649A (en) | 1984-12-21 | 1986-04-29 | Ici Americas Inc. | Dentifrice formulation and method of treating teeth, mouth and throat therewith to reduce plaque accumulation and irritation |
JPH0788519B2 (ja) | 1985-06-07 | 1995-09-27 | ダウブランズ・インコーポレーテッド | 洗濯用汚れおよびしみ除去剤 |
US4741905A (en) | 1986-06-19 | 1988-05-03 | Warner-Lambert Company | Chewing gum candy |
ZA874574B (en) | 1986-06-25 | 1988-03-30 | Nabisco Brands Inc | Encapsulated active ingredients and use in ingested products |
GB8617222D0 (en) | 1986-07-15 | 1986-08-20 | Tate & Lyle Plc | Sweetener |
US4786502A (en) | 1986-10-06 | 1988-11-22 | The Procter & Gamble Company | Palatable solid pharmaceutical compositions |
US4863745A (en) | 1986-10-22 | 1989-09-05 | Wm. Wrigley Jr. Company | Chewing gum containing zein coated high-potency sweetener and method |
GB8627139D0 (en) | 1986-11-13 | 1986-12-10 | Tate & Lyle Plc | Sweetening composition |
US4800087A (en) | 1986-11-24 | 1989-01-24 | Mehta Atul M | Taste-masked pharmaceutical compositions |
US4828845A (en) | 1986-12-16 | 1989-05-09 | Warner-Lambert Company | Xylitol coated comestible and method of preparation |
US4753790A (en) | 1986-12-16 | 1988-06-28 | Warner-Lambert Company | Sorbitol coated comestible and method of preparation |
US5004595A (en) | 1986-12-23 | 1991-04-02 | Warner-Lambert Company | Multiple encapsulated flavor delivery system and method of preparation |
US5043154A (en) | 1987-01-30 | 1991-08-27 | Colgate-Palmolive Co. | Antibacterial, antiplaque, anticalculus oral composition |
US4986991A (en) | 1987-05-15 | 1991-01-22 | Wm Wrigley, Jr., Company | Chewing gum having an extended sweetness |
US4822599A (en) | 1987-08-26 | 1989-04-18 | The Procter & Gamble Company | Oral compositions |
US4803082A (en) | 1987-10-28 | 1989-02-07 | Warner-Lambert Company | Flavor and sweetness enhancement delivery systems and method of preparation |
DK505588D0 (da) | 1988-02-26 | 1988-09-09 | Jesper Hamburger | Middel og anvendelse af samme |
US6056992A (en) | 1988-06-02 | 2000-05-02 | Campbell Soup Company | Encapsulated additives |
US4919841A (en) | 1988-06-06 | 1990-04-24 | Lever Brothers Company | Wax encapsulated actives and emulsion process for their production |
US4952407A (en) | 1988-09-12 | 1990-08-28 | Wm. Wrigley Jr. Company | Chewing gum containing glycerol mono laurate |
JP2623769B2 (ja) * | 1988-09-20 | 1997-06-25 | ライオン株式会社 | マイクロカプセル |
EP0370296B1 (en) | 1988-11-25 | 1994-01-19 | The Procter & Gamble Company | Chewing gum |
US4904482A (en) | 1988-12-22 | 1990-02-27 | Wm. Wrigley Jr. Company | Chewing gums containing hydrated emulsifier and methods of preparation |
US4971797A (en) | 1988-12-22 | 1990-11-20 | Warner-Lambert Company | Stabilized sucralose complex |
US5334375A (en) | 1988-12-29 | 1994-08-02 | Colgate Palmolive Company | Antibacterial antiplaque oral composition |
US4954353A (en) | 1988-12-29 | 1990-09-04 | Warner-Lambert Company | Anhydrous chewing gum with improved stability |
US5273741A (en) | 1988-12-29 | 1993-12-28 | Colgate-Palmolive Company | Packaged anti-plaque oral compositions |
US5202112A (en) | 1991-08-01 | 1993-04-13 | Colgate-Palmolive Company | Viscoelastic dentifrice composition |
US4994490A (en) * | 1989-04-03 | 1991-02-19 | The Nutrasweet Company | Novel N-(sulfomethyl)-N'-arylureas |
US5229148A (en) | 1989-04-19 | 1993-07-20 | Wm. Wrigley Jr. Company | Method of combining active ingredients with polyvinyl acetates |
US4978537A (en) | 1989-04-19 | 1990-12-18 | Wm. Wrigley Jr. Company | Gradual release structures for chewing gum |
US4985236A (en) | 1989-05-08 | 1991-01-15 | Beecham Inc. | Tripolyphosphate-containing anti-calculus toothpaste |
US4923684A (en) | 1989-05-08 | 1990-05-08 | Beecham, Inc. | Tripolyphosphate-containing anti-calculus toothpaste |
US5084278A (en) | 1989-06-02 | 1992-01-28 | Nortec Development Associates, Inc. | Taste-masked pharmaceutical compositions |
EP0401956A3 (en) | 1989-06-05 | 1991-04-10 | Warner-Lambert Company | High melting point sweetener delivery system |
US5009893A (en) | 1989-07-17 | 1991-04-23 | Warner-Lambert Company | Breath-freshening edible compositions of methol and a carboxamide |
DK365389D0 (da) | 1989-07-24 | 1989-07-24 | Fertin Lab As | Antifungalt tyggegummipraeparat |
US5009900A (en) | 1989-10-02 | 1991-04-23 | Nabisco Brands, Inc. | Glassy matrices containing volatile and/or labile components, and processes for preparation and use thereof |
NZ235372A (en) | 1989-10-10 | 1992-05-26 | Wrigley W M Jun Co | Slow release delivery system made by fibre melt spinning techniques producing a fibre about 1mm diameter, exterior is substantially wall material and core mostly active agent dispersed through the fibre material which is porous overall |
US5059429A (en) | 1989-10-27 | 1991-10-22 | Warner-Lambert Company | Sucralose sweetened chewing gum |
US5082671A (en) | 1989-10-27 | 1992-01-21 | Warner-Lambert Company | Low moisture sucralose sweetened chewing gum |
GB9001621D0 (en) | 1990-01-24 | 1990-03-21 | Procter & Gamble | Confectionery product |
US5284659A (en) | 1990-03-30 | 1994-02-08 | Cherukuri Subraman R | Encapsulated flavor with bioadhesive character in pressed mints and confections |
US5035882A (en) | 1990-04-12 | 1991-07-30 | Warner-Lambert Company | Combination of formate esters and pepper-like constituents as an orally-consumable chloroform substitute |
US5041294A (en) | 1990-04-24 | 1991-08-20 | Wm. Wrigley Jr. Company | Sorbitol-modified flavor |
US5266335A (en) | 1990-05-04 | 1993-11-30 | Warner-Lambert Company | Microencapsulated flavoring agents and methods for preparing same |
US5637618A (en) | 1990-06-01 | 1997-06-10 | Bioresearch, Inc. | Specific eatable taste modifiers |
US5096699A (en) | 1990-12-20 | 1992-03-17 | Colgate-Palmolive Company | Anticalculus oral compositions |
US5208009A (en) | 1990-12-20 | 1993-05-04 | Colgate-Palmolive Company | Anticalculus oral compositions |
IT1243391B (it) | 1990-11-23 | 1994-06-10 | Savio Spa | Dispositivo posafilo con elementi guidafilo rotanti su due piani inclinati convergenti |
US5096701A (en) | 1990-12-18 | 1992-03-17 | The Procter & Gamble Company | Oral compositions |
US5176900A (en) | 1990-12-18 | 1993-01-05 | The Procter & Gamble Company | Compositions for reducing calculus |
US5244670A (en) | 1991-04-04 | 1993-09-14 | The Procter & Gamble Company | Ingestible pharmaceutical compositions for treating upper gastrointestinal tract distress |
DE4110973A1 (de) | 1991-04-05 | 1992-10-08 | Haarmann & Reimer Gmbh | Mittel mit physiologischem kuehleffekt und fuer diese mittel geeignete wirksame verbindungen |
JPH04372679A (ja) * | 1991-06-21 | 1992-12-25 | Sekisui Chem Co Ltd | 塩ビ基材粘着テープ |
US5227182A (en) | 1991-07-17 | 1993-07-13 | Wm. Wrigley Jr. Company | Method of controlling release of sucralose in chewing gum using cellulose derivatives and gum produced thereby |
US5385729A (en) | 1991-08-01 | 1995-01-31 | Colgate Palmolive Company | Viscoelastic personal care composition |
US5227154A (en) | 1991-08-22 | 1993-07-13 | The University Of Melbourne | Phosphopeptides for the treatment of dental calculus |
US5300305A (en) | 1991-09-12 | 1994-04-05 | The Procter & Gamble Company | Breath protection microcapsules |
US5256402A (en) | 1991-09-13 | 1993-10-26 | Colgate-Palmolive Company | Abrasive tooth whitening dentifrice of improved stability |
US5158790A (en) | 1991-09-17 | 1992-10-27 | Wm. Wrigley, Jr. Company | L-carvone enhanced fruit flavored chewing gum |
US5391315A (en) | 1991-09-27 | 1995-02-21 | Ashkin; Abraham | Solid cake detergent carrier composition |
US5240697A (en) | 1991-10-17 | 1993-08-31 | Colgate-Palmolive Company | Desensitizing anti-tartar dentifrice |
CA2117351C (en) | 1992-01-13 | 1998-03-03 | Julian Belknap Lo | Preparation of tablets of increased strength |
JPH09309822A (ja) * | 1992-02-18 | 1997-12-02 | Nippon Shinyaku Co Ltd | 口腔内溶解型速溶錠 |
US5286500A (en) | 1992-03-03 | 1994-02-15 | Wm. Wrigley Jr. Company | Wax-free chewing gum base |
US5462754A (en) | 1992-03-03 | 1995-10-31 | Wm. Wrigley Jr. Company | Abhesive chewing gum with improved sweetness profile |
JPH07506868A (ja) | 1992-05-18 | 1995-07-27 | ザ、プロクター、エンド、ギャンブル、カンパニー | 冷却剤組成物 |
US5424080A (en) | 1992-06-30 | 1995-06-13 | Wm. Wrigley Jr. Company | Wax-free chewing gum base |
US5405604A (en) | 1992-10-16 | 1995-04-11 | The Procter & Gamble Company | Concentrated mouthrinse for efficient delivery of antimicrobials |
US5334396A (en) | 1992-10-19 | 1994-08-02 | Wm. Wrigley Jr. Company | Chewing gum sweetened with alitame and having a high level of lecithin |
US5380530A (en) | 1992-12-29 | 1995-01-10 | Whitehill Oral Technologies | Oral care composition coated gum |
US5370882A (en) | 1993-01-26 | 1994-12-06 | Nestec S.A. | Taste-enhancement of sodium chloride-reduced compositions |
US5437876A (en) | 1993-03-02 | 1995-08-01 | Wm. Wrigley Jr. Company | Wax-free chewing gums with controlled sweetener release |
US5372824A (en) | 1993-03-25 | 1994-12-13 | The Wm. Wrigley Jr. Company | Mint flavored chewing gum having reduced bitterness and methods for making same |
AU6701694A (en) | 1993-04-16 | 1994-11-08 | Mccormick & Company, Inc. | Encapsulation compositions |
US5437878A (en) | 1993-11-10 | 1995-08-01 | Nabisco, Inc. | Chewing gum exhibiting reduced adherence to dental work |
US5498378A (en) | 1993-11-12 | 1996-03-12 | Lever Brothers Company, Division Of Conopco, Inc. | Process for preparing capsules with structuring agents |
US5626892A (en) | 1993-11-24 | 1997-05-06 | Nabisco, Inc. | Method for production of multi-flavored and multi-colored chewing gum |
US5407665A (en) | 1993-12-22 | 1995-04-18 | The Procter & Gamble Company | Ethanol substitutes |
US5458879A (en) | 1994-03-03 | 1995-10-17 | The Procter & Gamble Company | Oral vehicle compositions |
CA2222170A1 (en) | 1995-05-26 | 1996-11-28 | Tom Kalili | Chewing gum with fluoride and citric acid |
US5429827A (en) | 1994-04-12 | 1995-07-04 | Wm. Wrigley Jr. Company | Method of making improved gum base for fruit-flavored chewing gum |
US5431930A (en) | 1994-08-18 | 1995-07-11 | Wm. Wrigley Jr. Co. | Chewing gum containing medium chain triglycerides |
US5505933A (en) | 1994-06-27 | 1996-04-09 | Colgate Palmolive Company | Desensitizing anti-tartar dentifrice |
AU698788B2 (en) | 1994-07-25 | 1998-11-05 | Warner-Lambert Company Llc | Antiseptic dentifrice |
US5556652A (en) | 1994-08-05 | 1996-09-17 | Fuisz Technologies Ltd. | Comestibles containing stabilized highly odorous flavor component delivery systems |
US5603920A (en) | 1994-09-26 | 1997-02-18 | The Proctor & Gamble Company | Dentifrice compositions |
US5545424A (en) | 1994-10-12 | 1996-08-13 | Takasago International Corporation | 4-(1-menthoxymethyl)-2-phenyl-1,3-dioxolane or its derivatives and flavor composition containing the same |
US5474787A (en) | 1994-10-21 | 1995-12-12 | The Wm. Wrigley Jr. Company | Chewing gum containing a lecithin/glycerol triacetate blend |
US5599527A (en) | 1994-11-14 | 1997-02-04 | Colgate-Palmolive Company | Dentifrice compositions having improved anticalculus properties |
IL139728A (en) | 1995-01-09 | 2003-06-24 | Penwest Pharmaceuticals Compan | Aqueous slurry composition containing microcrystalline cellulose for preparing a pharmaceutical excipient |
FR2729967A1 (fr) | 1995-01-30 | 1996-08-02 | Oreal | Compositions a base d'un systeme abrasif et d'un systeme tensio-actif |
US5676932A (en) | 1995-05-02 | 1997-10-14 | J.M. Huber Corporation | Silica abrasive compositions |
US5589160A (en) | 1995-05-02 | 1996-12-31 | The Procter & Gamble Company | Dentifrice compositions |
US5651958A (en) | 1995-05-02 | 1997-07-29 | The Procter & Gamble Company | Dentifrice compositions |
US5658553A (en) | 1995-05-02 | 1997-08-19 | The Procter & Gamble Company | Dentifrice compositions |
US5582816A (en) | 1995-06-01 | 1996-12-10 | Colgate Palmolive Company | Preparation of a visually clear gel dentifrice |
US5800848A (en) | 1995-06-20 | 1998-09-01 | The Wm. Wrigley Jr. Company | Chewing gum containing sucrose polyesters |
US5725865A (en) | 1995-08-29 | 1998-03-10 | V. Mane Fils S.A. | Coolant compositions |
US5618517A (en) | 1995-10-03 | 1997-04-08 | Church & Dwight Co., Inc. | Chewing gum product with dental care benefits |
US5702687A (en) | 1995-10-03 | 1997-12-30 | Church & Dwight Co., Inc. | Chewing gum product with plaque-inhibiting benefits |
US5645821A (en) | 1995-10-06 | 1997-07-08 | Libin; Barry M. | Alkaline oral hygiene composition |
US5713738A (en) | 1995-12-12 | 1998-02-03 | Britesmile, Inc. | Method for whitening teeth |
US5879728A (en) | 1996-01-29 | 1999-03-09 | Warner-Lambert Company | Chewable confectionary composition and method of preparing same |
DE19607278A1 (de) | 1996-02-27 | 1997-08-28 | Haarmann & Reimer Gmbh | Stabilisierter Milchsäurementhylester |
US5736175A (en) * | 1996-02-28 | 1998-04-07 | Nabisco Technology Co. | Chewing gums containing plaque disrupting ingredients and method for preparing it |
US5912007A (en) | 1996-02-29 | 1999-06-15 | Warner-Lambert Company | Delivery system for the localized administration of medicaments to the upper respiratory tract and methods for preparing and using same |
US5891421A (en) | 1996-03-22 | 1999-04-06 | J.M. Huber Corporation | Precipitated silicas having improved dentifrice performance characteristics and methods of preparation |
US5716601A (en) | 1996-03-22 | 1998-02-10 | The Procter & Gamble Company | Dentifrice compositions |
PL332669A1 (en) | 1996-10-09 | 1999-09-27 | Givaudan Roure Int | Method of obtaining minute beads constituting a food additive |
US8828432B2 (en) | 1996-10-28 | 2014-09-09 | General Mills, Inc. | Embedding and encapsulation of sensitive components into a matrix to obtain discrete controlled release particles |
US6159509A (en) | 1996-10-28 | 2000-12-12 | Wm. Wrigley Jr. Company | Method of making chewing gum products containing perillartine |
US7025999B2 (en) | 2001-05-11 | 2006-04-11 | Wm. Wrigley Jr. Company | Chewing gum having prolonged sensory benefits |
ES2565163T3 (es) | 1996-10-28 | 2016-03-31 | General Mills, Inc. | Imbibición y encapsulación de partículas de liberación controlada y producto encapsulado |
US6190644B1 (en) | 1996-11-21 | 2001-02-20 | The Procter & Gamble Company | Dentifrice compositions containing polyphosphate and monofluorophosphate |
US6475469B1 (en) | 1996-11-21 | 2002-11-05 | Applied Dental Sciences, Inc. | Compositions for removing tooth stains |
GB9707979D0 (en) | 1997-04-21 | 1997-06-11 | Procter & Gamble | Confectionery compositions |
US6027746A (en) | 1997-04-23 | 2000-02-22 | Warner-Lambert Company | Chewable soft gelatin-encapsulated pharmaceutical adsorbates |
GB9711643D0 (en) | 1997-06-05 | 1997-07-30 | Janssen Pharmaceutica Nv | Glass thermoplastic systems |
US5824291A (en) | 1997-06-30 | 1998-10-20 | Media Group | Chewing gum containing a teeth whitening agent |
US6627233B1 (en) | 1997-09-18 | 2003-09-30 | Wm. Wrigley Jr. Company | Chewing gum containing physiological cooling agents |
US6261540B1 (en) | 1997-10-22 | 2001-07-17 | Warner-Lambert Company | Cyclodextrins and hydrogen peroxide in dental products |
GB9723743D0 (en) | 1997-11-12 | 1998-01-07 | Philips Electronics Nv | Battery economising in a communications system |
US6630182B1 (en) | 1997-12-30 | 2003-10-07 | Cadbury Adams Usa Llc | System for continuously producing gum with improved texture and flavor release |
ES2134743B1 (es) | 1998-02-06 | 2000-05-01 | Biocosmetics Sl | Composicion para el tratamiento de la halitosis. |
US5939051A (en) | 1998-02-27 | 1999-08-17 | Colgate-Palmolive Company | Dental abrasive |
JPH11293209A (ja) * | 1998-04-14 | 1999-10-26 | Yazaki Corp | 塩ビ基材粘着テープ |
IN191070B (zh) | 1998-05-28 | 2003-09-13 | Internat Dev Res Ct | |
BR9912529A (pt) | 1998-07-07 | 2001-05-02 | Johnson & Johnson | Método de aperfeiçoamento da liberação de doçura da sucralose |
US6599542B1 (en) | 1998-08-11 | 2003-07-29 | Warner-Lambert Company | Non-stick chewing gum base |
NZ509832A (en) | 1998-08-21 | 2003-11-28 | Novartis Ag | New oral formulation for 5-HT4 agonists or antagonists |
DE19845247A1 (de) | 1998-10-01 | 2000-04-06 | Henkel Kgaa | Flüssiges Zahnreinigungsgel |
ATE258417T1 (de) | 1999-07-02 | 2004-02-15 | Cognis Iberia Sl | Mikrokapseln - i |
CA2384098A1 (en) * | 1999-09-03 | 2001-03-15 | L'oreal S.A. | Cosmetic compositions containing specific polysaccharide resins |
JP4141600B2 (ja) | 1999-09-17 | 2008-08-27 | 株式会社ロッテ | チューインガム組成物及びその製造方法 |
EP1163853B1 (en) | 1999-11-29 | 2007-02-21 | Kyowa Hakko Food Specialties Co., Ltd. | Method of strengthenig the taste of sodium chloride, agent for strengthening the taste of sodium chloride, sodium chloride-taste seasoning and food having strengthened taste of sodium chloride |
AU7247000A (en) | 2000-01-11 | 2001-07-19 | Givaudan Sa | Composite materials |
JP4414535B2 (ja) | 2000-01-13 | 2010-02-10 | 進 野田 | 半導体装置の製造方法 |
US6780443B1 (en) | 2000-02-04 | 2004-08-24 | Takasago International Corporation | Sensate composition imparting initial sensation upon contact |
US7041277B2 (en) | 2000-03-10 | 2006-05-09 | Cadbury Adams Usa Llc | Chewing gum and confectionery compositions with encapsulated stain removing agent compositions, and methods of making and using the same |
US6485739B2 (en) | 2000-03-10 | 2002-11-26 | Warner-Lambert Company | Stain removing chewing gum and confectionery compositions, and methods of making and using the same |
US6471945B2 (en) | 2000-03-10 | 2002-10-29 | Warner-Lambert Company | Stain removing chewing gum and confectionery compositions, and methods of making and using the same |
DE10012199A1 (de) | 2000-03-13 | 2001-09-20 | Haarmann & Reimer Gmbh | Eingekapselte Substanzen mit kontrollierter Freisetzung |
IT1320188B1 (it) * | 2000-04-26 | 2003-11-26 | Perfetti Spa | Gomma da masticare. |
US6290933B1 (en) | 2000-05-09 | 2001-09-18 | Colgate-Palmolive Company | High cleaning dentifrice |
US6413573B1 (en) | 2000-06-27 | 2002-07-02 | Nestac, S.A. | Flavor composition |
US6379654B1 (en) | 2000-10-27 | 2002-04-30 | Colgate Palmolive Company | Oral composition providing enhanced tooth stain removal |
JP3497466B2 (ja) | 2000-12-12 | 2004-02-16 | 高砂香料工業株式会社 | 温感組成物 |
JP4454838B2 (ja) | 2000-12-12 | 2010-04-21 | 高砂香料工業株式会社 | 温感組成物 |
US20020078243A1 (en) | 2000-12-15 | 2002-06-20 | International Business Machines Corporation | Method and apparatus for time synchronization in a network data processing system |
US6623266B2 (en) | 2001-01-19 | 2003-09-23 | Cadbury Adams Usa Llc | Apparatus for making a center-filled gum lollipop with hard candy shell |
WO2002076227A1 (en) | 2001-03-23 | 2002-10-03 | Gumlink A/S | Coated degradable chewing gum with improved shelf life and process for preparing same |
AU2002247620B2 (en) | 2001-03-23 | 2005-10-20 | Gumlink A/S | Biodegradable chewing gum and method manufacturing such chewing gum |
US20030004215A1 (en) | 2001-06-15 | 2003-01-02 | Van Laere Katrien Maria Jozefa | Dietetic preparation and method for inhibiting intestinal carbohydrate absorption |
US6416744B1 (en) | 2001-06-21 | 2002-07-09 | Colgate Palmolive Company | Tooth whitening chewing gum |
JP2003054368A (ja) * | 2001-08-16 | 2003-02-26 | Hitachi Electronics Service Co Ltd | IPv6を使用した駆動制御装置及びこれを搭載した車両 |
US7850990B2 (en) * | 2001-10-03 | 2010-12-14 | Celator Pharmaceuticals, Inc. | Compositions for delivery of drug combinations |
US20030077362A1 (en) | 2001-10-23 | 2003-04-24 | Panhorst Dorothy A. | Encapsulated flavors as inclusion in candy confections |
US7585516B2 (en) * | 2001-11-12 | 2009-09-08 | Advanced Cardiovascular Systems, Inc. | Coatings for drug delivery devices |
DE10226942A1 (de) | 2002-06-17 | 2003-12-24 | Symrise Gmbh & Co Kg | Verwendung von Mandelsäurealkylamiden als Aromastoffe |
EP1523339B2 (en) | 2002-07-11 | 2011-12-14 | Firmenich SA | Composition for controlled release of perfumes and flavours |
WO2004008872A2 (en) | 2002-07-23 | 2004-01-29 | Wm. Wrigley Jr. Company | Encapsulated flavors and chewing gum using same |
AR040680A1 (es) * | 2002-07-25 | 2005-04-13 | Pharmacia Corp | Composicion de tabletas de liberacion sostenida |
US7445769B2 (en) | 2002-10-31 | 2008-11-04 | Cadbury Adams Usa Llc | Compositions for removing stains from dental surfaces and methods of making and using the same |
US6685916B1 (en) | 2002-10-31 | 2004-02-03 | Cadbury Adams Usa Llc | Compositions for removing stains from dental surfaces, and methods of making and using the same |
WO2004064544A1 (en) | 2003-01-22 | 2004-08-05 | Durafizz, Llc | Microencapsulation for sustained delivery of carbon dioxide |
AU2004218409A1 (en) | 2003-03-03 | 2004-09-16 | Wm. Wrigley Jr. Company | Fast flavor release coating for confectionery |
ATE360370T1 (de) | 2003-08-14 | 2007-05-15 | Cargill Inc | Monatinhaltige kaugummizusammensetzungen und verfahren zu ihrer herstellung |
GB2388581A (en) | 2003-08-22 | 2003-11-19 | Danisco | Coated aqueous beads |
US20060263473A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Compressed delivery system for active components as part of an edible composition |
US20090220642A1 (en) | 2003-11-21 | 2009-09-03 | Cadbury Adams Usa Llc | Compressible gum based delivery systems for the release of ingredients |
US8591972B2 (en) | 2005-05-23 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for coated active components as part of an edible composition |
US20060263474A1 (en) | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc. | Enhanced flavor-release comestible compositions and methods for same |
CA2553048A1 (en) | 2004-01-23 | 2005-09-01 | Firmenich Sa | Large glassy beads |
CA2558683A1 (en) | 2004-03-05 | 2005-09-22 | Sunil Srivastava | High-intensity sweetener-polyol compositions |
US20050202143A1 (en) | 2004-03-12 | 2005-09-15 | Soumya Roy | Dry mix compositions and method for making and utilizing the same having an enhanced anti-microbial shelf life |
US7189760B2 (en) | 2004-04-02 | 2007-03-13 | Millennium Specialty Chemicals | Physiological cooling compositions containing highly purified ethyl ester of N-[[5-methyl-2-(1-methylethyl) cyclohexyl] carbonyl]glycine |
ATE534301T1 (de) | 2004-06-30 | 2011-12-15 | Cadbury Holdings Ltd | Kaugummi mit aromastoffemulsion |
US20060068059A1 (en) | 2004-09-30 | 2006-03-30 | Cadbury Adams Usa Llc | Encapsulated compositions and methods of preparation |
US20080063747A1 (en) | 2004-08-25 | 2008-03-13 | Cadbury Adams Usa Llc | Dusting compositions for chewing gum products |
US7955630B2 (en) | 2004-09-30 | 2011-06-07 | Kraft Foods Global Brands Llc | Thermally stable, high tensile strength encapsulated actives |
US20060068058A1 (en) | 2004-09-30 | 2006-03-30 | Cadbury Adams Usa Llc | Thermally stable, high tensile strength encapsulation compositions for actives |
WO2006079056A1 (en) | 2005-01-20 | 2006-07-27 | Stephen Holt | Herbal compositions containing hoodia |
US9198448B2 (en) | 2005-02-07 | 2015-12-01 | Intercontinental Great Brands Llc | Stable tooth whitening gum with reactive ingredients |
US20050196517A1 (en) | 2005-02-14 | 2005-09-08 | Mars, Incorporated | Edible product having discrete regions with different heats of solution |
US20060204613A1 (en) | 2005-02-18 | 2006-09-14 | Castro Armando J | Chewing gum containing flavor delivery systems |
US20070298061A1 (en) * | 2005-02-25 | 2007-12-27 | Cadbury Adams Usa Llc | Process for manufacturing a delivery system for active components as part of an edible compostion |
US20060193896A1 (en) * | 2005-02-25 | 2006-08-31 | Cadbury Adams Usa Llc | Process for manufacturing a delivery system for active components as part of an edible composition |
US20090175982A1 (en) | 2005-05-23 | 2009-07-09 | Cadbury Adams Usa Llc., | Methods for managing release of one or more ingredients in an edible composition |
US8703228B2 (en) | 2005-05-23 | 2014-04-22 | Intercontinental Great Brands Llc | Confectionery composition including an elastomeric component, a cooked saccharide component, and a modified release component |
EP1895992A4 (en) * | 2005-05-23 | 2012-03-28 | Kraft Foods Global Brands Llc | PHARMACEUTICAL SYSTEMS COMPRISING COMPRESSIBLE KAUGUMMIBASIS FOR INGREDIENT RELIEF |
US20090074911A1 (en) | 2005-05-23 | 2009-03-19 | Cadbury Adams Usa Llc | Indicia-Bearing Package For Delivery Systems |
US20090162418A1 (en) | 2005-05-23 | 2009-06-25 | Cadbury Adams Usa Llc | Indicia-bearing package for delivery systems for managing release of flavors in an edible composition |
US20070036733A1 (en) | 2005-08-12 | 2007-02-15 | Takasago International Corp. (Usa) | Sensation masking composition |
US20070048424A1 (en) | 2005-09-01 | 2007-03-01 | Moza Ashok K | Liquid composition of 2-Isopropyl-N,2,3-trimethylbutyramide and N-Ethyl-p-menthane-3-carboxamide, its preparation method and its applications as a cooling agent and flavor enhancer |
US20080166449A1 (en) | 2006-11-29 | 2008-07-10 | Cadbury Adams Usa Llc | Confectionery compositions including an elastomeric component and a saccharide component |
-
2003
- 2003-11-21 US US10/719,298 patent/US20050112236A1/en not_active Abandoned
-
2004
- 2004-11-22 ZA ZA200603466A patent/ZA200603466B/en unknown
- 2004-11-22 MX MXPA06005706A patent/MXPA06005706A/es active IP Right Grant
- 2004-11-22 BR BRPI0416794-5A patent/BRPI0416794A/pt active Search and Examination
- 2004-11-22 ES ES04810526.6T patent/ES2576252T3/es active Active
- 2004-11-22 PL PL04810526.6T patent/PL1689438T3/pl unknown
- 2004-11-22 AU AU2004292409A patent/AU2004292409B2/en not_active Ceased
- 2004-11-22 WO PCT/US2004/037185 patent/WO2005051427A1/en active Application Filing
- 2004-11-22 JP JP2006541237A patent/JP5284588B2/ja not_active Expired - Fee Related
- 2004-11-22 AR ARP040104322A patent/AR047131A1/es not_active Application Discontinuation
- 2004-11-22 EP EP04810526.6A patent/EP1689438B1/en not_active Not-in-force
- 2004-11-22 CN CN2004800340652A patent/CN1882361B/zh not_active Expired - Fee Related
- 2004-11-22 RU RU2006121996/15A patent/RU2351364C2/ru active
- 2004-11-22 CA CA2544512A patent/CA2544512C/en not_active Expired - Fee Related
-
2005
- 2005-03-21 US US11/083,968 patent/US8828423B2/en not_active Expired - Fee Related
- 2005-05-23 US US11/134,368 patent/US20050214348A1/en not_active Abandoned
-
2006
- 2006-05-22 CO CO06048810A patent/CO5690619A2/es not_active Application Discontinuation
-
2009
- 2009-10-13 US US12/577,986 patent/US20100028452A1/en not_active Abandoned
-
2011
- 2011-02-25 JP JP2011039906A patent/JP2011152134A/ja not_active Withdrawn
Patent Citations (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3341416A (en) * | 1963-12-11 | 1967-09-12 | Ncr Co | Encapsulation of aspirin in ethylcellulose and its product |
US3691090A (en) * | 1969-01-16 | 1972-09-12 | Fuji Photo Film Co Ltd | Encapsulation method |
US4139639A (en) * | 1977-01-24 | 1979-02-13 | General Foods Corporation | Fixation of APM in chewing gum |
US4384004B1 (zh) * | 1981-06-02 | 1993-06-22 | Warner Lambert Co | |
US4384004A (en) * | 1981-06-02 | 1983-05-17 | Warner-Lambert Company | Encapsulated APM and method of preparation |
US4515769A (en) * | 1981-12-01 | 1985-05-07 | Borden, Inc. | Encapsulated flavorant material, method for its preparation, and food and other compositions incorporating same |
US4386106A (en) * | 1981-12-01 | 1983-05-31 | Borden, Inc. | Process for preparing a time delayed release flavorant and an improved flavored chewing gum composition |
US4673577A (en) * | 1983-02-18 | 1987-06-16 | Wm. Wrigley Jr. Company | Shellac encapsulant for high-potency sweeteners in chewing gum |
US4485118A (en) * | 1983-04-21 | 1984-11-27 | Warner-Lambert Company | Gum composition with plural time releasing flavors and method of preparation |
US4520142A (en) * | 1984-02-17 | 1985-05-28 | Minnesota Mining And Manufacturing Company | Aerosol application of encapsulated materials |
US4590075A (en) * | 1984-08-27 | 1986-05-20 | Warner-Lambert Company | Elastomer encapsulation of flavors and sweeteners, long lasting flavored chewing gum compositions based thereon and process of preparation |
US4597970A (en) * | 1984-10-05 | 1986-07-01 | Warner-Lambert Company | Chewing gum compositions containing novel sweetener delivery systems and method of preparation |
US4828857A (en) * | 1984-10-05 | 1989-05-09 | Warner-Lambert Company | Novel sweetener delivery systems |
US4804548A (en) * | 1984-10-05 | 1989-02-14 | Warner-Lambert Company | Novel sweetener delivery systems |
US4764382A (en) * | 1984-11-15 | 1988-08-16 | Hercon Laboratories Corporation | Device for controlled release drug delivery |
US4634593A (en) * | 1985-07-31 | 1987-01-06 | Nabisco Brands, Inc. | Composition and method for providing controlled release of sweetener in confections |
US4740376A (en) * | 1986-01-07 | 1988-04-26 | Warner-Lambert Company | Encapsulation composition for use with chewing gum and edible products |
US4711784A (en) * | 1986-01-07 | 1987-12-08 | Warner-Lambert Company | Encapsulation composition for use with chewing gum and edible products |
US4929447A (en) * | 1986-01-07 | 1990-05-29 | Warner-Lambert Company | Encapsulation composition for use with chewing gum and edible products |
US4752481A (en) * | 1986-06-19 | 1988-06-21 | Warner-Lambert Company | Flavor emulsions and chewing gum compositions containing the same |
US4726953A (en) * | 1986-10-01 | 1988-02-23 | Nabisco Brands, Inc. | Sweet flavorful soft flexible sugarless chewing gum |
US4915958A (en) * | 1986-12-10 | 1990-04-10 | Warner-Lambert Company | High-base gum composition with extended flavor release |
US4824681A (en) * | 1986-12-19 | 1989-04-25 | Warner-Lambert Company | Encapsulated sweetener composition for use with chewing gum and edible products |
US4911934A (en) * | 1986-12-19 | 1990-03-27 | Warner-Lambert Company | Chewing gum composition with encapsulated sweetener having extended flavor release |
US4816265A (en) * | 1986-12-23 | 1989-03-28 | Warner-Lambert Company | Sweetener delivery systems containing polyvinyl acetate |
US4722845A (en) * | 1986-12-23 | 1988-02-02 | Warner-Lambert Company | Stable cinnamon-flavored chewing gum composition |
US4931293A (en) * | 1986-12-23 | 1990-06-05 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US4933190A (en) * | 1986-12-23 | 1990-06-12 | Warner-Lambert Co. | Multiple encapsulated sweetener delivery system |
US4981698A (en) * | 1986-12-23 | 1991-01-01 | Warner-Lambert Co. | Multiple encapsulated sweetener delivery system and method of preparation |
US4771784A (en) * | 1987-02-17 | 1988-09-20 | Kuibyshevksy Politekhnichesky Institut | Ophthalmorheographic transducer |
US5057328A (en) * | 1988-11-14 | 1991-10-15 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US4997659A (en) * | 1989-03-28 | 1991-03-05 | The Wm. Wrigley Jr. Company | Alitame stability in chewing gum by encapsulation |
US5169658A (en) * | 1989-04-19 | 1992-12-08 | Wm. Wrigley Jr. Company | Polyvinyl acetate encapsulation of crystalline sucralose for use in chewing gum |
US5139794A (en) * | 1989-04-19 | 1992-08-18 | Wm. Wrigley Jr. Company | Use of encapsulated salts in chewing gum |
US5198251A (en) * | 1989-04-19 | 1993-03-30 | Wm. Wrigley Jr. Company | Gradual release structures for chewing gum |
US5154939A (en) * | 1989-04-19 | 1992-10-13 | Wm. Wrigley Jr. Company | Use of salt to improve extrusion encapsulation of chewing gum ingredients |
US5057327A (en) * | 1989-12-29 | 1991-10-15 | Wm. Wrigley Jr. Company | Chewing gum with longer lasting sweetness using alitame |
US5226335A (en) * | 1990-04-11 | 1993-07-13 | Hellmuth Sitte | Automatic initial-cutting device for microtomes, particularly ultramicrotomes |
US5043169A (en) * | 1990-05-25 | 1991-08-27 | Warner-Lambert Company | Stabilized Sweetner Composition |
US5139793A (en) * | 1990-07-10 | 1992-08-18 | Wm. Wrigley Jr. Company | Method of prolonging flavor in chewing gum by the use of cinnamic aldehyde propylene glycol acetal |
US5064658A (en) * | 1990-10-31 | 1991-11-12 | Warner-Lamber Company | Encapsulated synergistic sweetening agent compositions comprising aspartame and acesulfame-K and methods for preparing same |
US5100678A (en) * | 1990-11-15 | 1992-03-31 | Wm. Wrigley Jr. Company | Chewing gum with prolonged flavor release incorporating unsaturated, purified monoglycerides |
US5139798A (en) * | 1990-11-21 | 1992-08-18 | Wm. Wrigley Jr. Company | Polyvinyl acetate encapsulation of codried sucralose for use in chewing gum |
US5126151A (en) * | 1991-01-24 | 1992-06-30 | Warner-Lambert Company | Encapsulation matrix |
US5108763A (en) * | 1991-04-03 | 1992-04-28 | Warner-Lambert Company | Microencapsulated high intensity sweetening agents having prolonged sweetness release and methods for preparing same |
US5169657A (en) * | 1991-07-17 | 1992-12-08 | Wm. Wrigley Jr. Company | Polyvinyl acetate encapsulation of sucralose from solutions for use in chewing gum |
US5164210A (en) * | 1991-10-08 | 1992-11-17 | Wm. Wrigley Jr. Company | Zein/shellac encapsulation of high intensity sweeteners in chewing gum |
US5480668A (en) * | 1992-11-12 | 1996-01-02 | Nofre; Claude | N-substituted derivatives of aspartame useful as sweetening agents |
US5532004A (en) * | 1993-06-23 | 1996-07-02 | Nabisco, Inc. | Chewing gum containing hydrophobic flavorant encapsulated in a hydrophilic shell |
US5589194A (en) * | 1993-09-20 | 1996-12-31 | Minnesota Mining And Manufacturing Company | Method of encapsulation and microcapsules produced thereby |
US5501864A (en) * | 1994-04-12 | 1996-03-26 | Wm. Wrigley Jr. Company | Method of making sugar-containing chewing gum with prolonged sweetness intensity |
US5415880A (en) * | 1994-04-12 | 1995-05-16 | Wm. Wrigley Jr. Company | Fruit flavored chewing gum with prolonged flavor intensity |
US5413799A (en) * | 1994-04-12 | 1995-05-09 | Wm. Wrigley Jr. Company | Method of making fruit-flavored chewing with prolonged flavor intensity |
US5693334A (en) * | 1995-10-05 | 1997-12-02 | Church & Dwight Co., Inc. | Chewing gum product with dental health benefits |
US5629035A (en) * | 1995-12-18 | 1997-05-13 | Church & Dwight Co., Inc. | Chewing gum product with encapsulated bicarbonate and flavorant ingredients |
US5789002A (en) * | 1996-10-03 | 1998-08-04 | Warner-Lambert Company | Gum sweetener/acid processing system |
US6692778B2 (en) * | 1998-06-05 | 2004-02-17 | Wm. Wrigley Jr. Company | Method of controlling release of N-substituted derivatives of aspartame in chewing gum |
US6428827B1 (en) * | 1999-04-01 | 2002-08-06 | Wm. Wrigley Jr. Company | Long flavor duration releasing structures for chewing gum and method of making |
US6174514B1 (en) * | 1999-04-12 | 2001-01-16 | Fuisz Technologies Ltd. | Breath Freshening chewing gum with encapsulations |
US6479071B2 (en) * | 2000-03-10 | 2002-11-12 | Warner-Lambert Company | Chewing gum and confectionery compositions with encapsulated stain removing agent compositions, and methods of making and using the same |
US6365209B2 (en) * | 2000-06-06 | 2002-04-02 | Capricorn Pharma, Inc. | Confectionery compositions and methods of making |
US6555145B1 (en) * | 2000-06-06 | 2003-04-29 | Capricorn Pharma, Inc. | Alternate encapsulation process and products produced therefrom |
US6759066B2 (en) * | 2000-09-12 | 2004-07-06 | Wm. Wrigley Jr. Company | Chewing gum formulations including encapsulated aspartame and sodium pyrophosphate |
US20020122842A1 (en) * | 2000-12-15 | 2002-09-05 | Seielstad Donald A. | Encapsulated acid mixtures and products including same |
US20050220867A1 (en) * | 2003-11-21 | 2005-10-06 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US20050260266A1 (en) * | 2003-11-21 | 2005-11-24 | Cadbury Adams Usa, Llc. | Controlled release oral delivery systems |
US20060034897A1 (en) * | 2003-11-21 | 2006-02-16 | Cadbury Adams Usa Llc | Delivery system for two or more active components as part of an edible composition |
US20060263480A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having selected particle size |
US20060263479A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component |
US20060263478A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Coated delivery system for active components as part of an edible composition |
US20060263413A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Delivery system for active components and a material having preselected hydrophobicity as part of an edible composition |
US20060263477A1 (en) * | 2005-05-23 | 2006-11-23 | Cadbury Adams Usa Llc | Edible composition including a delivery system for active components |
Cited By (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040120919A1 (en) * | 2002-12-20 | 2004-06-24 | L'oreal | Hair compositions |
US8591974B2 (en) | 2003-11-21 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for two or more active components as part of an edible composition |
US8828423B2 (en) | 2003-11-21 | 2014-09-09 | Intercontinental Great Brands Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US9271904B2 (en) | 2003-11-21 | 2016-03-01 | Intercontinental Great Brands Llc | Controlled release oral delivery systems |
US20060034897A1 (en) * | 2003-11-21 | 2006-02-16 | Cadbury Adams Usa Llc | Delivery system for two or more active components as part of an edible composition |
US20090220642A1 (en) * | 2003-11-21 | 2009-09-03 | Cadbury Adams Usa Llc | Compressible gum based delivery systems for the release of ingredients |
US20100028452A1 (en) * | 2003-11-21 | 2010-02-04 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US20070148286A1 (en) * | 2004-08-25 | 2007-06-28 | Cadbury Adams Usa Llc. | Liquid-filled chewing gum composition |
US20070148284A1 (en) * | 2004-08-25 | 2007-06-28 | Cadbury Adams Usa Llc. | Liquid-filled chewing gum |
US7727565B2 (en) | 2004-08-25 | 2010-06-01 | Cadbury Adams Usa Llc | Liquid-filled chewing gum composition |
US20080063747A1 (en) * | 2004-08-25 | 2008-03-13 | Cadbury Adams Usa Llc | Dusting compositions for chewing gum products |
US7955630B2 (en) | 2004-09-30 | 2011-06-07 | Kraft Foods Global Brands Llc | Thermally stable, high tensile strength encapsulated actives |
US20090098252A1 (en) * | 2004-09-30 | 2009-04-16 | Cadbury Adams Usa Llc | Thermally stable, high tensile strength encapsulation compositions for actives |
US8524295B2 (en) | 2004-09-30 | 2013-09-03 | Intercontinental Great Brands Llc | Thermally stable, high tensile strength encapsulated actives |
US20060177383A1 (en) * | 2005-02-07 | 2006-08-10 | Cadbury Adams Usa, Llc. | Stable tooth whitening gum with reactive ingredients |
US9198448B2 (en) | 2005-02-07 | 2015-12-01 | Intercontinental Great Brands Llc | Stable tooth whitening gum with reactive ingredients |
WO2006127070A3 (en) * | 2005-05-23 | 2008-01-17 | Cadbury Adams Usa Llc | An edible composition including a delivery system for active components |
US9486002B2 (en) | 2005-05-23 | 2016-11-08 | Intercontinental Great Brands Llc | Confectionery composition including an elastomeric component, a cooked saccharine component, and a functional ingredient |
US20080199564A1 (en) * | 2005-05-23 | 2008-08-21 | Cadbury Adams Usa Llc | Confectionery Composition Including an Elastomeric Component and a Cooked Saccharide Component |
EP1885205A1 (en) * | 2005-05-23 | 2008-02-13 | Cadbury Adams USA LLC | Methods for managing release of one or more ingredients in an edible composition based on ratios of ingredients to encapsulating materials |
WO2006127069A3 (en) * | 2005-05-23 | 2008-01-24 | Cadbury Adams Usa Llc | A delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component |
US8703228B2 (en) | 2005-05-23 | 2014-04-22 | Intercontinental Great Brands Llc | Confectionery composition including an elastomeric component, a cooked saccharide component, and a modified release component |
US20090175982A1 (en) * | 2005-05-23 | 2009-07-09 | Cadbury Adams Usa Llc., | Methods for managing release of one or more ingredients in an edible composition |
US8389032B2 (en) | 2005-05-23 | 2013-03-05 | Kraft Foods Global Brands Llc | Delivery system for active components as part of an edible composition having selected particle size |
US8597703B2 (en) | 2005-05-23 | 2013-12-03 | Kraft Foods Global Brands Llc | Delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component |
WO2006127067A3 (en) * | 2005-05-23 | 2008-01-10 | Cadbury Adams Usa Llc | A delivery system for coated active components as part of an edible composition |
US8591973B2 (en) | 2005-05-23 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for active components and a material having preselected hydrophobicity as part of an edible composition |
EP2774492A2 (en) | 2005-05-23 | 2014-09-10 | Intercontinental Great Brands LLC | Sweetener potentiator compositions |
US7851005B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and beverages containing same |
US7851006B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and beverages containing same |
US7851000B2 (en) | 2005-05-23 | 2010-12-14 | Cadbury Adams Usa Llc | Taste potentiator compositions and edible confectionery and chewing gum products containing same |
US7879376B2 (en) | 2005-05-23 | 2011-02-01 | Cadbury Adams Usa Llc | Taste potentiator compositions and edible confectionery and chewing gum products containing same |
EP2305046A2 (en) | 2005-05-23 | 2011-04-06 | Cadbury Adams USA LLC | Taste potentiator compositions and beverages containing the same |
US8389031B2 (en) | 2005-05-23 | 2013-03-05 | Kraft Foods Global Brands Llc | Coated delivery system for active components as part of an edible composition |
US8591968B2 (en) | 2005-05-23 | 2013-11-26 | Kraft Foods Global Brands Llc | Edible composition including a delivery system for active components |
US8455033B2 (en) | 2005-05-23 | 2013-06-04 | Kraft Foods Global Brands Llc | Taste potentiator compositions and edible confectionery and chewing gum products containing same |
US8591972B2 (en) | 2005-05-23 | 2013-11-26 | Kraft Foods Global Brands Llc | Delivery system for coated active components as part of an edible composition |
US20060275361A1 (en) * | 2005-06-03 | 2006-12-07 | Cadbury Adams Usa Llc. | Rapidly dissolving gelatin compositions and products made therefrom |
WO2007022317A2 (en) * | 2005-08-17 | 2007-02-22 | Cadbury Adams Usa Llc | Dusting compositions for chewing gum products |
WO2007022317A3 (en) * | 2005-08-17 | 2007-10-11 | Cadbury Adams Usa Llc | Dusting compositions for chewing gum products |
US20090098241A1 (en) * | 2006-02-20 | 2009-04-16 | Gumlink A/S | Resin encapsulated food acid |
US20070237855A1 (en) * | 2006-04-05 | 2007-10-11 | Cadbury Adams Usa Llc | Calcium phosphate complex in acid containing confectionery |
US8133476B2 (en) | 2006-04-05 | 2012-03-13 | Cadbury Adams Usa Llc | Calcium phosphate complex and salts in oral delivery systems |
US8133475B2 (en) | 2006-04-05 | 2012-03-13 | Cadbury Adams Usa, Llc | Calcium phosphate complex in acid containing chewing gum |
EP2520312A1 (en) * | 2006-06-28 | 2012-11-07 | Kraft Foods Global Brands LLC | A process for manufacturing a delivery system for active components as part of an edible composition |
WO2008019685A1 (en) * | 2006-08-17 | 2008-02-21 | Gumlink A/S | Resin encapsulated high intensity sweetener |
US20090246327A1 (en) * | 2006-08-17 | 2009-10-01 | Gumlink A/S | Resin encapsulated high intensity sweetener |
US20080166449A1 (en) * | 2006-11-29 | 2008-07-10 | Cadbury Adams Usa Llc | Confectionery compositions including an elastomeric component and a saccharide component |
US20100034871A1 (en) * | 2007-04-04 | 2010-02-11 | Rikke Mikkelsen | Center-Filled Chewing Gum Product For Dental Care |
WO2009007717A1 (en) | 2007-07-10 | 2009-01-15 | Cadbury Holdings Limited | Chocolate compositions having improved flavour characteristics |
US20090162475A1 (en) * | 2007-12-21 | 2009-06-25 | Cadbury Adams Usa Llc | Gum Structure Mixing Systems And Methods |
US20090162476A1 (en) * | 2007-12-21 | 2009-06-25 | Cadbury Adams Usa Llc | Parallel Gum Component Mixing Systems And Methods |
EP3530121A1 (en) | 2010-01-21 | 2019-08-28 | Intercontinental Great Brands LLC | System and method of forming and sizing chewing gum and/or altering temperature of chewing gum |
WO2012016161A1 (en) | 2010-07-30 | 2012-02-02 | Kraft Foods Global Brands Llc | A delivery system for active components as part of an edible composition |
WO2012034012A1 (en) | 2010-09-09 | 2012-03-15 | Kraft Foods Global Brands Llc | Chewing gum compositions providing flavor release profiles |
WO2012125397A2 (en) | 2011-03-11 | 2012-09-20 | Kraft Foods Global Brands Llc | System and method of forming multilayer confectionery |
US10973238B2 (en) | 2011-03-11 | 2021-04-13 | Intercontinental Great Brands Llc | System and method of forming multilayer confectionery |
US11930830B2 (en) | 2011-03-11 | 2024-03-19 | Intercontinental Great Brands Llc | System and method of forming multilayer confectionery |
US11122815B2 (en) | 2011-07-21 | 2021-09-21 | Intercontinental Great Brands Llc | System and method for forming and cooling chewing gum |
WO2013013045A2 (en) | 2011-07-21 | 2013-01-24 | Kraft Foods Global Brands Llc | Advanced gum forming |
WO2013013041A2 (en) | 2011-07-21 | 2013-01-24 | Kraft Foods Global Brands Llc | Advanced gum forming |
EP3738440A1 (en) | 2011-07-21 | 2020-11-18 | Intercontinental Great Brands LLC | Advanced chewing gum forming |
WO2013158291A2 (en) | 2012-04-20 | 2013-10-24 | Kraft Foods Global Brands Llc | System and method for manufacturing chewing gum |
EP3666084A1 (en) | 2012-04-20 | 2020-06-17 | Intercontinental Great Brands LLC | System and method for manufacturing chewing gum |
EP3262951A1 (en) | 2012-09-21 | 2018-01-03 | Intercontinental Great Brands LLC | Advanced gum forming |
WO2014047263A1 (en) | 2012-09-21 | 2014-03-27 | Intercontinental Great Brands Llc | Advanced gum forming |
WO2014172287A1 (en) | 2013-04-17 | 2014-10-23 | Intercontinental Great Brands Llc | A system and method for forming a chewing gum product with at least one inclusion |
US10334867B2 (en) | 2014-03-03 | 2019-07-02 | Intercontinental Great Brands Llc | Method for manufacturing a comestible |
CN108135244A (zh) * | 2015-10-28 | 2018-06-08 | 洲际大品牌有限责任公司 | 制备用于可食用组合物的包封组合物的方法 |
CN110248553A (zh) * | 2017-02-08 | 2019-09-17 | 洲际大品牌有限责任公司 | 用于控制咀嚼型胶基糖的活性成分的释放的高级包封方法 |
WO2018147842A1 (en) * | 2017-02-08 | 2018-08-16 | Intercontinental Great Brands Llc | Advanced encapsulation process for controlled release of active ingredients from a chewing gum |
US20210307354A1 (en) * | 2017-02-08 | 2021-10-07 | Intercontinental Great Brands Llc | Advanced encapsulation process for controlled release of active ingredients from a chewing gum |
Also Published As
Publication number | Publication date |
---|---|
AR047131A1 (es) | 2006-01-11 |
US8828423B2 (en) | 2014-09-09 |
ES2576252T3 (es) | 2016-07-06 |
US20100028452A1 (en) | 2010-02-04 |
RU2351364C2 (ru) | 2009-04-10 |
RU2006121996A (ru) | 2007-12-27 |
MXPA06005706A (es) | 2006-12-14 |
US20050220867A1 (en) | 2005-10-06 |
EP1689438A4 (en) | 2011-10-26 |
JP2007512330A (ja) | 2007-05-17 |
BRPI0416794A (pt) | 2007-03-06 |
JP2011152134A (ja) | 2011-08-11 |
CO5690619A2 (es) | 2006-10-31 |
ZA200603466B (en) | 2007-07-25 |
CN1882361B (zh) | 2012-08-29 |
JP5284588B2 (ja) | 2013-09-11 |
WO2005051427A1 (en) | 2005-06-09 |
AU2004292409A1 (en) | 2005-06-09 |
CA2544512A1 (en) | 2005-06-09 |
US20050214348A1 (en) | 2005-09-29 |
EP1689438A1 (en) | 2006-08-16 |
PL1689438T3 (pl) | 2016-09-30 |
CA2544512C (en) | 2012-06-12 |
AU2004292409B2 (en) | 2010-03-11 |
EP1689438B1 (en) | 2016-03-16 |
CN1882361A (zh) | 2006-12-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20050112236A1 (en) | Delivery system for active components as part of an edible composition having preselected tensile strength | |
CA2598572C (en) | A delivery system for active components and a material having preselected hydrophobicity as part of an edible composition | |
CA2598574C (en) | A delivery system for active components as part of an edible composition including a ratio of encapsulating material and active component | |
EP0454833B1 (en) | Polyvinyl acetate encapsulation of crystalline sucralose for use in chewing gum | |
KR101321452B1 (ko) | 수지로 캡슐화된 고강도 감미료 | |
EP0426428A1 (en) | Encapsulated sweetener-flavour delivery system, and its production | |
US20070248717A1 (en) | Confections Containing a Blend of Physiological Cooling Agents | |
EP1971215B1 (en) | Coated chewing gum | |
CA2204142C (en) | Breath-freshening edible compositions comprising menthol and an n-substituted-p-menthane carboxamide and methods for preparing same | |
JPH0547182B2 (zh) | ||
EP0413539B1 (en) | Flavour delivery system and its preparation | |
EP1996027A1 (en) | RESlN ENCAPSULATED FOOD ACID | |
US20160100605A1 (en) | Chewing gum products containing ethyl ester of n-[[5-methyl-2-(1-methylethyl)-cyclohexyl] carbonyl] glycine | |
US5175009A (en) | Stabilized chewing gum containing acidified humectant | |
US20060222734A1 (en) | Coated chewing gum products and methods for making same | |
CA3037711C (en) | Stable flavor compositions containing mint leaves |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: CADBURY ADAMS USA LLC, DELAWARE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BOGHANI, NAVROZ;GEBRESELASSIE, PETROS;REEL/FRAME:015107/0415 Effective date: 20040123 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |