US20030061835A1 - Glass plate and method for tempering a glass plate - Google Patents

Glass plate and method for tempering a glass plate Download PDF

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Publication number
US20030061835A1
US20030061835A1 US10/103,987 US10398702A US2003061835A1 US 20030061835 A1 US20030061835 A1 US 20030061835A1 US 10398702 A US10398702 A US 10398702A US 2003061835 A1 US2003061835 A1 US 2003061835A1
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US
United States
Prior art keywords
mass
glass plate
tempering
cao
mgo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/103,987
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English (en)
Inventor
Kazushige Yoda
Yasumasa Kato
Shuichi Akada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Assigned to ASAHI GLASS COMPANY, LIMITED reassignment ASAHI GLASS COMPANY, LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: AKADA, SHUICHI, YODA, KAZUSHIGE, KATO, YASUMASA
Publication of US20030061835A1 publication Critical patent/US20030061835A1/en
Priority to US11/625,021 priority Critical patent/US7341968B2/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00—Tempering or quenching glass products
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00—Tempering or quenching glass products
    • C03B27/04—Tempering or quenching glass products using gas
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00—Tempering or quenching glass products
    • C03B27/04—Tempering or quenching glass products using gas
    • C03B27/0413—Stresses, e.g. patterns, values or formulae for flat or bent glass sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/007—Other surface treatment of glass not in the form of fibres or filaments by thermal treatment
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass

Definitions

  • the present invention relates to a glass plate capable of being readily tempered by heat and a method for tempering it.
  • a glass plate made of general soda lime silicate is used as a base plate for a tempered glass by heat.
  • a tempered glass is produced usually by quenching a base plate after heating it to a predetermined initial glass temperature of quenching. This quenching is carried out by blowing an air to the heated glass plate in many cases.
  • the present invention provides a method for tempering a glass plate having a thickness of from 2 to 3 mm, and having an average linear thermal expansion coefficient of at least 88 ⁇ 10 ⁇ 7 /° C. at a temperature of from 50 to 300° C. and a softening point of from 715 to 740° C., which comprises quenching the glass plate from an initial glass temperature of quenching at which the viscosity is within a range of from 10 9 to 10 10 poise to a temperature at which the viscosity is 10 12 poise, so that the heat transfer coefficient h (W/m 2 K) satisfies the following formula (1), where t (mm) is a glass plate thickness:
  • the present invention provides a method for tempering a glass plate having a thickness of from 2 to 3 mm, and having an average linear thermal expansion coefficient of at least 88 ⁇ 10 ⁇ 7 /° C. at a temperature of from 50 to 300° C. and a softening point of from 715 to 740° C., which comprises quenching the glass plate from an initial glass temperature of quenching at which the viscosity is within a range of from 10 9 to 10 10 poise to a temperature at which the viscosity is 10 12 poise, so that the heat transfer coefficient h (W/m 2 K) satisfies the following formula (2), where t (mm) is a glass plate thickness:
  • the present invention further provides the above method for tempering a glass plate, wherein a glass plate having the following composition is tempered: SiO 2 66.0-74.0 mass %, Al 2 O 3 1.5-4.0 mass %, CaO 7.0-10.0 mass %, MgO 3.8-6.0 mass %, Na 2 O 12.6-14.6 mass % and K 2 O 0.4-2.0 mass %,
  • the above glass plate preferably has a thickness of from 2 to 3 mm. Further, the above glass plate is preferably one produced by a conventional float glass process. Further, the above glass plate is preferably used as a window glass for automobiles.
  • the present invention provides a glass plate which has the following composition: SiO 2 66.0-74.0 mass %, Al 2 O 3 2.0-4.0 mass %, CaO 7.0-10.0 mass %, MgO 3.8-6.0 mass %, Na 2 O 12.6-14.6 mass % and K 2 O 0.4-2.0 mass %,
  • the glass plate to be used for the tempering method of the present invention has an average linear thermal expansion coefficient of at least 88 ⁇ 10 ⁇ 7 /° C. at a temperature of from 50 to 300° C. If the average linear thermal expansion coefficient is lower than this, the glass plate tends to be poor in readily tempering properties. It is preferably at least 89 ⁇ 10 ⁇ 7 /° C., particularly preferably at least 90 ⁇ 10 ⁇ 7 /° C.
  • a glass having an extremely high average linear thermal expansion coefficient has significantly different physical properties such as a softening point as compared with a conventionally used soda lime silicate glass in many cases. Accordingly, it is necessary to change a production process to use such a glass, such being impractical. Practically, the upper limit of the average linear thermal expansion coefficient at a temperature of from 50 to 300° C. is at a level of 92 ⁇ 10 ⁇ 7 /° C., particularly at a level of 91 ⁇ 10 ⁇ 7 /° C.
  • the glass plate to be used for the tempering method of the present invention has a softening point of from 715 to 740° C.
  • the softening point is defined as a temperature measured by a test method as disclosed in JIS R3104. If the softening point exceeds this range, it may be necessary to change the existing production process. Particularly, in a case where a ceramic paint which crystallizes by heating in a thermal tempering step is used together, it may be necessary to employ a composition of a ceramic paint which is different from a conventional one, such as one which crystallizes at a temperature different from a conventional one, in some cases, such being disadvantageous.
  • the softening point is preferably at least 720° C., particularly preferably at least 725° C. Further, it is preferably at most 735° C., particularly preferably at most 730° C.
  • the glass plate is quenched from an initial glass temperature of quenching at which the viscosity is within a range of from 10 9 to 10 10 poise, to a temperature at which the viscosity is 10 12 poise, so that the heat transfer coefficient h (W/m 2 K) satisfies the above formula (1) or (2), where t (mm) is a glass plate thickness.
  • h W/m 2 K
  • the initial glass temperature of quenching is higher than a temperature at which the viscosity is 10 9 poise, the glass plate is softened too much, whereby optical quality may not be maintained.
  • the initial glass temperature of quenching is at most a temperature at which the viscosity is 10 9.3 poise.
  • the initial glass temperature of quenching is lower than a temperature at which the viscosity is 10 10 poise, the glass plate tends to be poor in readily tempering properties.
  • the initial glass temperature of quenching is at least a temperature at which the viscosity is 10 9.7 poise.
  • the glass plate may not adequately be tempered.
  • the formulae (1) and (2) are obtained by calculating heat transfer coefficients with which predetermined midplane tensile residual stresses are caused when a glass plate having a coefficient of linear thermal expansion of 90 ⁇ 10 ⁇ 7 /° C. is quenched from 660° C., at thicknesses of 2.25 mm, 2.5 mm and 2.8 mm, and fitting the obtained respective heat transfer coefficients with a parabola, in accordance with Narayanaswamy O.S., Journal of the American Ceramics Society, vol. 61, No.3-4 (1978), 146-152.
  • the predetermined midplane tensile residual stresses are 50 MPa with a thickness of 2.8 mm, 51 MPa with a thickness of 2.5 mm and 54 MPa with a thickness of 2.25 mm, and it can be assumed that the glass plate is adequately tempered when such a midplane tensile residual stress is caused.
  • the glass plate of the present invention preferably has the following composition: SiO 2 66.0-74.0 mass %, Al 2 O 3 1.5-4.0 mass %, CaO 7.0-10.0 mass %, MgO 3.8-6.0 mass %, Na 2 O 12.6-14.6 mass % and K 2 O 0.4-2.0 mass %,
  • SiO 2 is a component to secure weather resistance, and if it is less than 66.0 mass %, the weather resistance may decrease. It is more preferably at least 67.0 mass %. Further, if it exceeds 74.0 mass %, the viscosity tends to be high, and melting may be difficult. It is more preferably at most 73.0 mass %, particularly preferably at most 72.0 mass %.
  • Al 2 O 3 is a component to secure weather resistance, and if it is less than 1.5 mass %, the weather resistance may decrease. It is more preferably at least 1.7 mass %, particularly preferably at least 1.8 mass %. Further, if it exceeds 4.0 mass %, the viscosity tends to be high, and melting may be difficult. From this viewpoint, it is more preferably at most 3.5 mass %, particularly preferably at most 3.3 mass %.
  • CaO is a component to improve melting ability of raw materials, and if it is less than 7.0 mass %, the melting ability may decrease. It is more preferably at least 7.4 mass %, particularly preferably at least 8.4 mass %. Further, if it exceeds 10.0 mass %, the glass is likely to be devitrified, and stability when formed into a float glass may decrease. It is more preferably at most 9.8 mass %, particularly preferably at most 9.6 mass %.
  • MgO is a component to improve melting ability of raw materials, and if it is less than 3.8 mass %, the melting ability may decrease. It is more preferably at least 4.0 mass %, particularly preferably at least 4.2 mass %. Further, if it exceeds 6.0 mass %, the glass is likely to be devitrified, and stability when formed into a float glass may decrease. It is more preferably most 5.8 mass %, particularly preferably at most 5.6 mass %.
  • Na 2 O is a component to improve melting ability of raw materials, and if it is less than 12.6 mass %, the melting ability may decrease. It is more preferably at least 12.8 mass %, particularly preferably at least 13.0 mass %. Further, if it exceeds 14.6 mass %, the weather resistance may decrease. It is more preferably at most 13.8 mass %, particularly preferably at most 13.6 mass %.
  • K 2 O is a component to improve melting ability of raw materials, and if it is less than 0.4 mass %, the melting ability may decrease. It is more preferably at least 0.5 mass %, particularly preferably at least 0.9 mass %. Further, if it exceeds 2.0 mass %, the weather resistance may decrease, and the cost of the glass plate tends to increase. It is more preferably at most 1.8 mass %, particularly preferably at most 1.6 mass %.
  • the total amount of SiO 2 , Al 2 O 3 , CaO, MgO, Na 2 O and K 2 O is preferably at least 96 mass %. If it is less than this, physical properties depart from those of a conventionally used soda lime silicate glass, and it may be necessary to significantly change a production process of a conventional glass plate.
  • the total amount of SiO 2 and Al 2 O 3 is preferably at least 70.0 mass % so as to prevent lowering of the softening point, and it is preferably at most 74.0 mass % so as to prevent decrease in the coefficient of linear thermal expansion and a resulting decrease in readily tempering properties.
  • the total amount of CaO and MgO is preferably at least 12.0 mass % so as to prevent decrease in the coefficient of linear thermal expansion and a resulting decrease in readily tempering properties, and preferably at most 14.5 mass % so as to prevent lowering of the softening point.
  • the total amount of Na 2 O and K 2 O is preferably at least 13.5 mass % so as to prevent decrease in the coefficient of linear thermal expansion and a resulting decrease in readily tempering properties, and preferably at most 15.5 mass % so as to prevent lowering of the softening point.
  • SrO or BaO may be used instead of CaO or MgO within a range of not impairing the effects of the present invention.
  • Li 2 O may be used instead of Na 2 O or K 2 O within a range of not impairing the effects of the present invention.
  • the glass plate of the present invention as e.g. a residual component of refining agents, coloring components or components improving light transmission and absorption function, Fe 2 O 3 , CoO, Se, NiO, Cr 2 O 3 , MnO, V 2 O 5 , TiO 2 , CeO 2 , SnO, ZnO or SO 3 may be added within a range of not impairing the effects of the present invention.
  • tempering viscosity temperature difference a difference between a temperature at which the viscosity is 10 9 poise and a temperature at which the viscosity is 10 12 poise. If the tempering viscosity temperature difference is small, the readily tempering properties tend to improve. Specifically, the tempering viscosity temperature difference is preferably at most 100° C., particularly preferably at most 95° C. However, glass having an extremely small tempering viscosity temperature difference tends to have significantly different physical properties such as a softening point as compared with conventionally used soda lime silicate glass in many cases. Accordingly, it may be necessary to change a production process to use such a glass, such being impractical. Practically, the tempering viscosity temperature difference is at least 90° C.
  • the method for producing the glass plate of the present invention is not particularly limited, but the glass plate can be produced as follows for example.
  • a blended material is continuously supplied to a melter and heated to about 1,500° C. by e.g. heavy oil for vitrification. Then, this molten glass is refined, and then formed into a glass plate having a predetermined thickness by e.g. a float process. Then, this glass plate is cut into a predetermined shape to produce the glass plate of the present invention.
  • the cut glass plate is subjected to a tempering treatment.
  • the tempering treatment is carried out, as mentioned above, by heating the glass plate to a predetermined temperature and then quenching it. Simultaneously with the heating for the tempering treatment, bending or baking of a ceramic paint may be carried out.
  • the coefficient of linear thermal expansion is an average linear thermal expansion coefficient at a temperature of from 50 to 300° C. as measured in accordance with JIS R3102, and the unit is ⁇ 10 ⁇ 7 /° C. Further, the softening point was measured in accordance with JIS R3104, and the unit is ° C. The unit of each component is mass %. Here, the values were obtained by extrapolation except for Examples 5 and 6.
  • the readily tempering properties were evaluated from a difference between a temperature at which the viscosity was 10 9 poise and a temperature at which the viscosity was 10 12 poise, and shown in the column “tempering viscosity temperature difference” in Table 1. It can be said that the readily tempering properties are high when the tempering viscosity temperature difference is at most 100° C., and the readily tempering properties are particularly high when it is at most 95° C.
  • Example 8 of Table 1 the glass as identified in Example 8 of Table 1 was formed into a glass plate of 1,350 ⁇ 550 mm with a thickness of 2.5 mm, and quenched for tempering from 640° C. at a heat transfer coefficient of 648 W/m 2 K.
  • the obtained tempered glass plate was subjected to a test wherein the position of point 3 was fractured, in accordance with JIS R3212, whereupon the number of roughest fragments was from 63 to 142, and an adequate tempering was confirmed.
  • a glass plate which is a thin glass plate having a thickness at a level of from 2 to 3 mm, and which has a degree of tempering which is by no means inferior to a conventional glass plate of at least 3 mm, can be obtained.
  • a tempered glass plate is useful as e.g. a glass plate for vehicles such as automobiles and trains and further for buildings.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Mathematical Physics (AREA)
  • Glass Compositions (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
US10/103,987 2001-03-30 2002-03-25 Glass plate and method for tempering a glass plate Abandoned US20030061835A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/625,021 US7341968B2 (en) 2001-03-30 2007-01-19 Glass plate and method for tempering a glass plate

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2001099201 2001-03-30
JP2001-099201 2001-03-30
JP2001293601 2001-09-26
JP2001-293601 2001-09-26

Related Child Applications (1)

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US (2) US20030061835A1 (fr)
EP (1) EP1245545B1 (fr)
JP (1) JP2003171131A (fr)
KR (1) KR100814300B1 (fr)
CN (2) CN1208266C (fr)
BR (1) BR0201005A (fr)
CZ (1) CZ2002998A3 (fr)
MX (1) MXPA02003319A (fr)

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US20090197088A1 (en) * 2007-08-03 2009-08-06 Nippon Electric Glass Co., Ltd. Tempered glass substrate and method of producing the same
US20120131961A1 (en) * 2010-11-30 2012-05-31 Thierry Luc Alain Dannoux Method and apparatus for bending a sheet of material into a shaped article
EP2682374A1 (fr) * 2011-02-28 2014-01-08 Asahi Glass Company, Limited Plaque de verre trempé
US20150158757A1 (en) * 2012-08-24 2015-06-11 Asahi Glass Company, Limited Tempered glass

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EP2634150B1 (fr) * 2010-10-27 2021-11-24 AGC Inc. Plaque de verre, et procédé de fabrication de celle-ci
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JP2015105216A (ja) * 2013-12-02 2015-06-08 旭硝子株式会社 フロートガラス製造装置、およびフロートガラス製造方法
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US10144198B2 (en) 2014-05-02 2018-12-04 Corning Incorporated Strengthened glass and compositions therefor
CN106488887A (zh) * 2014-07-07 2017-03-08 旭硝子株式会社 颜料印刷用玻璃板、颜料印刷玻璃板、其制造方法和图像显示装置
US11097974B2 (en) 2014-07-31 2021-08-24 Corning Incorporated Thermally strengthened consumer electronic glass and related systems and methods
US10611664B2 (en) 2014-07-31 2020-04-07 Corning Incorporated Thermally strengthened architectural glass and related systems and methods
WO2017123573A2 (fr) 2016-01-12 2017-07-20 Corning Incorporated Articles à base de verre fin renforcé chimiquement et thermiquement
US11795102B2 (en) 2016-01-26 2023-10-24 Corning Incorporated Non-contact coated glass and related coating system and method
US20190127257A1 (en) * 2016-04-18 2019-05-02 Corning Incorporated Method of thermally tempering glass laminates using selective microwave heating and active cooling
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CN112624587A (zh) * 2021-01-13 2021-04-09 洛阳北方玻璃技术股份有限公司 一种水平辊道式玻璃连续钢化方法

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US8017537B2 (en) * 2005-10-31 2011-09-13 Nippon Sheet Glass Company, Limited Glass article and method of producing the same
US20090181843A1 (en) * 2005-10-31 2009-07-16 Nippon Sheet Glass Company, Limited Glass Article and Method of Producing the Same
US8679631B2 (en) 2007-08-03 2014-03-25 Nippon Electric Glass Co., Ltd. Tempered glass substrate and method of producing the same
US8168295B2 (en) 2007-08-03 2012-05-01 Nippon Electric Glass Co., Ltd. Tempered glass substrate and method of producing the same
US20090197088A1 (en) * 2007-08-03 2009-08-06 Nippon Electric Glass Co., Ltd. Tempered glass substrate and method of producing the same
US9034469B2 (en) 2007-08-03 2015-05-19 Nippon Electric Glass Co., Ltd. Tempered glass substrate and method of producing the same
US9054250B2 (en) 2007-08-03 2015-06-09 Nippon Electric Glass Co., Ltd Tempered glass substrate and method of producing the same
US9299869B2 (en) 2007-08-03 2016-03-29 Nippon Electric Glass Co., Ltd. Tempered glass substrate and method of producing the same
US20120131961A1 (en) * 2010-11-30 2012-05-31 Thierry Luc Alain Dannoux Method and apparatus for bending a sheet of material into a shaped article
US9284212B2 (en) * 2010-11-30 2016-03-15 Corning Incorporated Method and apparatus for bending a sheet of material into a shaped article
US9676653B2 (en) 2010-11-30 2017-06-13 Corning Incorporated Method and apparatus for bending a sheet of material into a shaped article
EP2682374A1 (fr) * 2011-02-28 2014-01-08 Asahi Glass Company, Limited Plaque de verre trempé
EP2682374A4 (fr) * 2011-02-28 2015-04-29 Asahi Glass Co Ltd Plaque de verre trempé
US20150158757A1 (en) * 2012-08-24 2015-06-11 Asahi Glass Company, Limited Tempered glass

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EP1245545B1 (fr) 2011-08-10
EP1245545A1 (fr) 2002-10-02
CN1208266C (zh) 2005-06-29
BR0201005A (pt) 2003-01-14
CN1623946A (zh) 2005-06-08
MXPA02003319A (es) 2004-07-16
KR100814300B1 (ko) 2008-03-18
US7341968B2 (en) 2008-03-11
CZ2002998A3 (cs) 2003-11-12
JP2003171131A (ja) 2003-06-17
US20070117707A1 (en) 2007-05-24
CN1266063C (zh) 2006-07-26
CN1378983A (zh) 2002-11-13
KR20020077256A (ko) 2002-10-11

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