US20030045863A1 - Cosmetic paper - Google Patents

Cosmetic paper Download PDF

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Publication number
US20030045863A1
US20030045863A1 US10/089,245 US8924502A US2003045863A1 US 20030045863 A1 US20030045863 A1 US 20030045863A1 US 8924502 A US8924502 A US 8924502A US 2003045863 A1 US2003045863 A1 US 2003045863A1
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US
United States
Prior art keywords
paper
sebum
inorganic filler
lipid
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/089,245
Other languages
English (en)
Inventor
Toshihiro Sadaoka
Hiroaki Katsube
Yuji Takechi
Akira Takeda
Yoshio Matsumoto
Katsuji Matsumoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Assigned to SHISEIDO COMPANY, LTD. reassignment SHISEIDO COMPANY, LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KATSUBE, HIROAKI, SADAOKA, TOSHIHIRO, TAKECHI, YUJI, TAKEDA, AKIRA, MATSUMOTO, KATSUJI, MATSUMOTO, YOSHIO
Publication of US20030045863A1 publication Critical patent/US20030045863A1/en
Abandoned legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D33/00—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances
    • A45D33/38—Papers containing cosmetic powder or other powdery toiletry substances
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D44/00—Other cosmetic or toiletry articles, e.g. for hairdressers' rooms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24—Phosphorous; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/008—Preparations for oily skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00—Details not otherwise provided for in A45D
    • A45D2200/10—Details of applicators
    • A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1027—Tissues, i.e. thin applicator sheets

Definitions

  • the invention relates to a sebum absorbing paper containing inorganic filler comprising hydroxyapatite.
  • the skin surface On a human's face, the skin surface, in particular around the nose and chin and at the middle of the forehead, tends to be oily due to the frequent secretion of sebum. Makeup on such oily skin surface avoids a cosmetic product such as a moisture retaining agent or toilet powder from being applied properly to the skin surface, resulting in decreased makeup-effect. Additionally, the human skin is damaged by the oxidized sebum generated by its exposure to the air while the time passes after its secretion.
  • the sebum forms film on the skin surface so as to prevent transepidermal water loss. Therefore, it is not desirable, from the viewpoint of skin care, that the sebum is removed excessively.
  • the conventional cosmetic tissues, particularly sebum absorbing papers may remove the sebum excessively. Precisely, they may absorb not only old sebum, which became acid due to oxidation while the time passes after its secretion, but also new sebum, which keeps freshness soon after its secretion and would be required for retaining the moisture of skin.
  • the oxidized sebum is harmful to user's skin, thus, a sebum absorbing paper is required to absorb such sebum selectively among the several kinds of sebum so that the damage to the user's skin can be decreased.
  • the main object of the present invention is to provide a sebum absorbing paper, which excels in the absorbency of the oxidized sebum selectively among the several kinds of sebum.
  • a sebum absorbing paper used for applying to skin or for cleaning the skin which contains 1 to 30 weight % of inorganic filler and which has the basis weight of 5 to 25 g/m 2 as defined in JIS P-8124, wherein the above inorganic filler comprises hydroxyapatite.
  • this sebum absorbing paper contains 1 to 30 weight % of inorganic filler and has the basis weight of 5 to 25 g/m 2 as defined in JIS P-8124, this paper can be thin and soft so as to be used comfortably.
  • this paper contains the inorganic filler comprising at least 1 to 100 weight % of hydroxyapatite so that this paper can absorb efficiently the oxidized sebum.
  • this paper has the density of 0.4 to 1 g/m 3 as defined in JIS P-8118. It is also preferable that the average particle size of the above inorganic filler is 0.5 to 8 ⁇ m. Further, it is more preferable that this paper contains the inorganic filler, which comprises 0.5 to 90 weight % of talc as well as the hydroxyapatite. If the average particle size of the inorganic filler is smaller than 0.5 ⁇ m, the stability of the filler in the paper will be decreased, resulting in disadvantageous cost effectiveness and small removability of the lipid.
  • the average particle size of the inorganic filler is larger than 8 ⁇ m, some problems will be caused, precisely, the texture of the paper will be much lowered and the particles will be easily pulled off from the paper.
  • this paper contains the inorganic filler comprising 0.5 to 90 weight % of talc, the smoothness and thereby the texture of this paper will be improved.
  • thanking to the talc contained in this paper it can become easily and surely transparent when it absorbs the lipid.
  • pulverized talc has the average particle size of 0.5 to 2 ⁇ m. Due to the talc having such particle size, the smoothness and thereby the texture of the paper will be improved.
  • This paper may comprise moisture retaining agent and/or toilet powder. Due to those comprised, the paper further excels in skin care-effect and makeup-effect.
  • FIG. 1 is a schematic illustration of apparatus used for measuring the adsorptivity for lipid peroxide.
  • the hydroxyapatite [Ca 10 (PO 4 ) 6 (OH) 2 ] is included in calcium phosphate and known as a component of a human bone or tooth. Then, the hydroxyapatite has attracted interest as an industrial material, for example, a material having sufficient adsorptivity for positive ion, negative ion, protein, amino acid, and the like, and a material having biological compatibility due to its small effect on organism, e.g. as the material of an artificial tooth root.
  • the hydroxyapatite excels in adsorption of lipid peroxide selectively among several kinds of lipid.
  • this hydroxyapatite can adsorb oxidized sebum selectively among the several kinds of sebum generated by secretion on the skin.
  • the present inventors considered such property of the hydroxyapatite and attained its application to a cosmetic tissue. Consequently, there is provided a sebum absorbing paper, which contains 1 to 30 weight % of inorganic filler and which has the basis weight of 5 to 25 g/m 2 as defined in JIS P-8124, wherein the above inorganic filler comprises 1 to 100 weight % of hydroxyapatite.
  • the resultant paper is thin and soft and the oxidized sebum occupies high proportion in all sebum absorbed into this paper.
  • the sebum absorbing paper is a cosmetic tissue which is applied to skin for absorbing the sebum or which cleans the skin by absorbing the sebum.
  • the filler is originally added into the paper, or the inorganic filler containing the hydroxyapatite is coated on a base paper, which has been produced through a paper machine. If the amount of inorganic filler contained in the sebum absorbing paper exceeds 30 weight %, the paper will exhibit hardness, which means insufficient softness. On the other hand, if the amount of hydroxyapatite contained in the above inorganic filler is smaller than 1 weight %, this paper will not absorb the oxidized sebum, which leads to ineffectiveness.
  • the sebum absorbing paper in the present invention can be produced in a known method with a known paper machine.
  • the sebum absorbing paper can be produced through a known paper machine from fibrous pulp slurry, which contains the inorganic filler comprising the hydroxyapatite.
  • the fiber used for the material of the sebum absorbing paper the following materials are listed. There are wood pulp fiber, bast fiber such as Manila hemp, flax, hemp, jute, paper mulberry, paper bush, and ganpi, bast fiber such as cotton, straw, bamboo, and kenaf, chemical fiber such as acrylic fiber and rayon, and animal fiber such as silk. It is possible that one of these fibers is solely used as the material. Then, it is also possible that two or more than two of these fibers are combined and used. In the present invention, since the sebum absorbing paper produced through a paper machine has the basis weight of 5 to 25 g/m 2 , thin and soft paper can be attained.
  • bast fiber such as Manila hemp, flax, hemp, jute, paper mulberry, paper bush, and ganpi
  • bast fiber such as cotton, straw, bamboo, and kenaf
  • chemical fiber such as acrylic fiber and rayon
  • animal fiber such as silk. It is possible that one of these fibers is solely used as
  • the paper has the basis weight of smaller than 5 g/m 2 , the mechanical strength of this paper will be lowered, resulting in that the paper will be twisted and torn easily in use.
  • the basis weight exceeds 25 g/m 2 , it will take much cost to produce this paper and the softness of this paper will be decreased, which leads to uncomfortable use.
  • the amount of absorbed lipid equals or exceeds 1 g/m 2 as defined in the following measuring method for the amount of pseudo absorbed lipid. If the amount of absorbed lipid is smaller than 1 g/m 2 , the paper will not suitable because of too small absorptivity. On the other hand, when the amount of absorbed lipid equals or exceeds 1 g/m 2 , it can be said that this paper may absorb the sufficient amount of the sebum. That is to say, in this sebum absorbing paper, contained hydroxyapatite fulfills the function for adsorbing the oxidized sebum selectively among the various kinds of sebum.
  • a sample sheet having the dimension of 21 cm ⁇ 25 cm is fixed by means of adhesive tape or the like on the circumferential face of a printability tester's drum so that the sample sheet has the effective area of 19 cm ⁇ 18 cm.
  • 0.5 ml of oil liquid 80 weight % of caster oil and 20 weight % of benzyl alcohol
  • the thickness of the coated oil liquid is 4.8 ⁇ m.
  • the printer roller is turned fully once at the transfer revolution speed of 30 rpm with the nip of 5 mm between the above drum and printer roller so that the above oil liquid can be transferred to the above sample sheet.
  • Weight increase of the sample sheet having the effective area due to the transfer is calculated by subtracting its weight before the transfer from its weight after the transfer. On the basis of this weight increase, the amount of absorbed lipid per 1 m 2 of sample sheet can be obtained as shown in the following equation.
  • the present inventors use the value for punch force.
  • the punch force can be calculated from color difference of sample paper caused by the absorbing of the lipid. As the transparency on the absorbing of the lipid is increased, value for the punch force is also increased, which gives satisfaction to the user.
  • the above punch force of the sebum absorbing paper preferably equals or exceeds 5.0.
  • the paper having such punch force shows, on the absorbing of the lipid, the increase in the transparency, whereby the user can recognize visually the effect of the lipid absorbency.
  • the measuring method of the punch force will be stated.
  • the back face of a sample paper is covered with a black plate, then with a white plate.
  • the values Lw, Aw, and Bw, then the values Lb, Ab, and Bb of the paper, respectively, are measured before transfer with a light spectrophotometer “EPR-80WX” (manufactured by Tokyo Denshoku Kabushikigaisha).
  • the color difference ⁇ E1 between these two cases is calculated according to the following equation (4).
  • transfer is carried out in the same manner as the above measurement of the amount of absorbed sebum. Precisely, a sample sheet having the dimension of 21 cm ⁇ 25 cm is fixed by means of adhesive tape or the like on the circumferential face of a printability tester's drum so that the sample sheet has the effective area of 19 cm ⁇ 18 cm. Consequently, 0.5 ml of oil liquid (80 weight % of caster oil and 20 weight % of benzyl alcohol) is coated uniformly on a printer roller of the above printability tester so that the thickness of the coated oil liquid is 4.8 ⁇ m.
  • oil liquid 80 weight % of caster oil and 20 weight % of benzyl alcohol
  • the printer roller is turned fully once at the transfer revolution speed of 30 rpm with the nip of 5 mm between the above drum and printer roller so that the above oil liquid can be transferred to the above sample sheet.
  • the color difference ⁇ E2 between these two cases is calculated according to the above equation (2) in the same manner as the sample paper before the transfer.
  • the punch force ⁇ E can be obtained from the color difference of the sample paper before the transfer ⁇ E1 and the color difference of the sample paper after the transfer ⁇ E2, according to the following equation (3).
  • Lw represents the value of paper covered with the white plate
  • Lb represents the value of paper covered with the black plate
  • Aw represents the blue to yellow-hue of the paper covered with the white plate
  • Ab represents the blue to yellow-hue of the paper covered with the black plate
  • Bw represents the red to green-hue of the paper covered with the white plate
  • Bb represents the red to green-hue of the paper covered with the black plate.
  • ⁇ E represents the punch force
  • the inorganic filler contained in the sebum absorbing paper in accordance with the present invention comprises 0.5 to 90 weight % of talc as well as the hydroxyapatite.
  • the average particle size of the talc is 0.5 to 8 ⁇ m. It is more preferable that pulverized talc has the average particle size of 0.5 to 2 ⁇ m.
  • the average particle size of the talc can be measured by a known device Microtrack. Graded talc, which is available from market, e.g. SG-2000 manufactured by Nihon Talc Kabushikigaisha can be used.
  • the talc contained in the paper contributes the smoothness and thereby the texture of this paper, resulting in great comfortable use.
  • the sebum absorbing paper surpasses in the texture and in the absorbency of the oxidized sebum.
  • a cosmetic tissue particularly in the sebum absorbing paper, when it absorbs the sebum, its transparency increases at the parts where the sebum is absorbed.
  • the sebum absorbing paper in accordance with the present invention excels in improvement of the transparency, whereby the user can recognize visually and clearly the effect of the sebum absorbency, which leads to user's satisfaction.
  • the sebum absorbing paper according to the present invention may contain moisture retaining agent, toilet powder and so on.
  • moisture retaining agent a material having such function can be used.
  • the sebum absorbing paper of the present invention can be colored with a coloring agent.
  • a coloring agent known dye like basic dye, acid dye, direct dye or the like and known pigment can be used.
  • the paper is neither blurred nor faded with the pigment.
  • food dye is preferably used, because the paper is brought into direct contact with the skin.
  • the sebum absorbing paper of the present invention As for the sebum absorbing paper of the present invention, its punch force, amount of absorbed lipid, adsorptivity for lipid peroxide, durability in use and productivity through a paper machine were tested at the different proportions of components in its inorganic filler. The results are shown in the following Table. The method for measuring the punch force and the amount of absorbed lipid were already stated above. The adsorptivity for the lipid peroxide was measured in the following. First, 1 g of sample was introduced into a column 1 of apparatus configured as shown in FIG. 1. Next, 2 g of olive oil (manufactured by Wako Pure Chemical Industries Ltd.) was diluted with 4 g of n-hexane.
  • mark X means “smaller than 5”
  • mark ⁇ means “exceeds 5 but maller than 15”
  • mark ⁇ means “equals or exceeds 15”.
  • mark X means “smaller than 1.0”
  • mark ⁇ means “exceeds 1.0 but is smaller than 2.0”
  • mark ⁇ means “equals or exceeds 2.0”.
  • mark X means “smaller than 5”
  • mark ⁇ means “exceeds 5 but is smaller than 20”
  • mark ⁇ means “equals or exceeds 20”.
  • mark X means “this paper is twisted torn” and mark ⁇ means “this paper is neither twisted nor torn”.
  • mark X means “problems such as paper break, dehydration failure and the like are caused” and mark ⁇ means “any problems are not caused”.
  • mark ⁇ means “the effect of the present invention can be attained, in other words, the lipid peroxide can be adsorbed”, mark ⁇ means “taking account of the smoothness, amount of absorbed lipid and punch force, this paper can be suitably used, particularly as the sebum absorbing paper”.
  • the sebum absorbing paper which has the basis weight and inorganic filler as defined in the present invention, is thin and soft and has enough durability in use for the application to a cosmetic tissue, particularly to a sebum absorbing paper.
  • the sample containing no hydroxyapatite does not have the effect of the present invention, i.e., adsorptivity for the lipid peroxide. Then, it is confirmed that the sample comprising talc and/or hydroxyapatite has the preferable punch force. In addition, it is recognized that the sebum absorbing paper in accordance with the present invention has no problem as for the productivity through a paper machine.
  • the sebum absorbing paper in accordance with the present invention is thin and soft and excels in the absorbency of the oxidized lipid. Further, it should be noted that this sebum absorbing paper preferably contains talc in order to serve as a cosmetic tissue, particularly as a sebum absorbing paper.
  • hydroxyapatite was obtained by synthesis through a wet process. Then, the obtained material was dehydrated centrifugally and dried for 24 hours at the temperature of 70° C. The resultant hydroxyapatite was sized so as to have the mesh size of 400 or smaller, whereby the sample was finally obtained.
  • comparative materials of the inorganic filler ⁇ -alumina, sericite, talc and silica were used.
  • pseudo sebum three materials, i.e., oleic acid, oleic oxide and olive oil were used respectively.
  • the olive oil was fed through a column packed with the hydroxyapatite and the peroxide value of the olive oil was measured. As a result, the peroxide value was decreased, which means that the hydroxyapatite has the adsorptivity for the lipid peroxide.
  • the samples were applied on a cheek of an experimental subject. Then, for each sample, the amount of adsorbed sebum was measured by a thermal analysis. As a result, it is found that the hydroxyapatite has the largest adsorptivity for the sebum and for the oxidized sebum.
  • a sebum absorbing paper which is thin and soft, which can remove efficiently the acid sebum selectively among the various kinds of sebum and which excels in skin-care.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Paper (AREA)
  • Sanitary Thin Papers (AREA)
  • Cosmetics (AREA)
  • Body Washing Hand Wipes And Brushes (AREA)
US10/089,245 2000-08-02 2001-08-02 Cosmetic paper Abandoned US20030045863A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000-234908 2000-08-02
JP2000234908A JP4936583B2 (ja) 2000-08-02 2000-08-02 化粧用紙

Publications (1)

Publication Number Publication Date
US20030045863A1 true US20030045863A1 (en) 2003-03-06

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US10/089,245 Abandoned US20030045863A1 (en) 2000-08-02 2001-08-02 Cosmetic paper

Country Status (8)

Country Link
US (1) US20030045863A1 (enrdf_load_stackoverflow)
EP (1) EP1306030B1 (enrdf_load_stackoverflow)
JP (1) JP4936583B2 (enrdf_load_stackoverflow)
KR (1) KR100814997B1 (enrdf_load_stackoverflow)
CN (1) CN1202775C (enrdf_load_stackoverflow)
DE (1) DE60119532T2 (enrdf_load_stackoverflow)
TW (1) TW576723B (enrdf_load_stackoverflow)
WO (1) WO2002011580A1 (enrdf_load_stackoverflow)

Families Citing this family (7)

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Publication number Priority date Publication date Assignee Title
JP4668456B2 (ja) * 2001-05-11 2011-04-13 大王製紙株式会社 皮膚清拭用化粧用紙
JP4535485B2 (ja) * 2003-05-14 2010-09-01 スキルプリント有限会社 脂取り紙の製本方法
JP2008188072A (ja) * 2007-01-31 2008-08-21 Daio Paper Corp ドライタイプの皮膚清拭用シート
JP5098062B2 (ja) * 2009-06-17 2012-12-12 大王製紙株式会社 模様加工紙
DE102011078260A1 (de) * 2011-06-29 2013-01-03 Beiersdorf Ag Reinigungsartikel mit Perlenhydrolysat
CN108478482A (zh) * 2018-04-23 2018-09-04 广东柏文生物科技股份有限公司 一种补妆蜜粉吸油纸及其制备方法
JP2020081363A (ja) * 2018-11-26 2020-06-04 日本製紙パピリア株式会社 化粧紙及びその製造方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4659617A (en) * 1984-09-11 1987-04-21 Toa Nenryo Kogyo Kabushiki Kaisha Fibrous apatite and method for producing the same

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Publication number Priority date Publication date Assignee Title
DE3017064C2 (de) * 1980-05-03 1984-04-05 Gimmler, Luise Maria, 6618 Wadern-Bardenbach Böschungsformstein
JPS6327411A (ja) * 1986-07-22 1988-02-05 Shiseido Co Ltd 粉末系皮膚外用剤
JP2613488B2 (ja) * 1989-04-21 1997-05-28 旭光学工業株式会社 機能紙
EP0673667B1 (en) * 1989-04-21 2000-09-20 Asahi Kogaku Kogyo Kabushiki Kaisha Filter sheet
US5328690A (en) * 1991-02-21 1994-07-12 University Of South Alabama Polyamino acid dispersants
JPH09224868A (ja) * 1996-02-22 1997-09-02 Daifuku Seishi Kk 抗菌化粧紙及びその製造方法
CN1221335A (zh) * 1996-05-02 1999-06-30 普罗克特和甘保尔公司 包含分散的表面活性剂复合物的局部用组合物
JP3019249B2 (ja) * 1996-06-14 2000-03-13 大福製紙株式会社 高吸油化粧用脂取り紙及びその製造方法
JPH11127955A (ja) * 1997-10-29 1999-05-18 Oike Ind Co Ltd 化粧紙
JP3875781B2 (ja) * 1997-11-10 2007-01-31 大福製紙株式会社 化粧用あぶら取り紙及びその製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4659617A (en) * 1984-09-11 1987-04-21 Toa Nenryo Kogyo Kabushiki Kaisha Fibrous apatite and method for producing the same

Also Published As

Publication number Publication date
CN1202775C (zh) 2005-05-25
JP4936583B2 (ja) 2012-05-23
CN1386054A (zh) 2002-12-18
EP1306030B1 (en) 2006-05-10
EP1306030A4 (en) 2004-04-28
DE60119532T2 (de) 2006-09-21
KR100814997B1 (ko) 2008-03-18
TW576723B (en) 2004-02-21
WO2002011580A1 (fr) 2002-02-14
EP1306030A1 (en) 2003-05-02
KR20020095161A (ko) 2002-12-20
JP2002045228A (ja) 2002-02-12
DE60119532D1 (de) 2006-06-14

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