US1968793A - Sulphuric ester of higher alcohols - Google Patents

Sulphuric ester of higher alcohols Download PDF

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Publication number
US1968793A
US1968793A US350135A US35013529A US1968793A US 1968793 A US1968793 A US 1968793A US 350135 A US350135 A US 350135A US 35013529 A US35013529 A US 35013529A US 1968793 A US1968793 A US 1968793A
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US
United States
Prior art keywords
sulphuric
ester
acid
sulphuric ester
higher alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US350135A
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English (en)
Inventor
Bertsch Heinrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AMERICAN HYALSOL Corp
Original Assignee
AMERICAN HYALSOL CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AMERICAN HYALSOL CORP filed Critical AMERICAN HYALSOL CORP
Application granted granted Critical
Publication of US1968793A publication Critical patent/US1968793A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071—Foams
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B26—HAND CUTTING TOOLS; CUTTING; SEVERING
    • B26D—CUTTING; DETAILS COMMON TO MACHINES FOR PERFORATING, PUNCHING, CUTTING-OUT, STAMPING-OUT OR SEVERING
    • B26D7/00—Details of apparatus for cutting, cutting-out, stamping-out, punching, perforating, or severing by means other than cutting
    • B26D7/06—Arrangements for feeding or delivering work of other than sheet, web, or filamentary form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/08—Sulfation or sulfonation products of fats, oils, waxes, or higher fatty acids or esters thereof with monovalent alcohols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03—Organic sulfoxy compound containing

Definitions

  • the sulphuric ester of hydroxystearic acid may be produced from oleic acid or by treatment with sulphuric acid the sulphuric ester of a di-hydroxysteario acid may be obtained from ricinoleic acid, and so forth.
  • Oils heretofore treated with sulphuric acid to produce these agents include castor oil, cottonseed oil, arachis oil, and olive oil.
  • estersi have a low resistance to lime, which is very deleterious in the textile industry, this objectionable property being ascribed in great part to the fact that the saturation of the carboxyl group may result in salts which are diflicultly soluble.
  • corresponding alcohols more specifically, higher unsaturated normal-primary alcohols are subjected to the sulphation, that is the corresponding alcohols are esterifled with for example, sulphuric acid.
  • sulphuric acid for instance oleyl alcohol is ⁇ converted to its sulphuric ester.
  • stearyl alcohol may be esterified directly with sulfuric acid.
  • the esteriflcation may, for example, be effected with concentrated or fuming sulphuric acid or other sulphonating agents which have strongly water-binding properties as for instance chlorosulphonic acid in the cold, that is at temperatures round about 0 C.
  • the resultant sulphuric esters are readily soluble in water and are strongly wetting and foaming substances which may be employed for manifoldtextile purposes. Since they contain no carboxyl groups they are not precipitated by the hardness-forming constituents in the water and are thus far superior in their properties to the ordinary sulphuric esters of the fats and fatty acids.
  • the reaction may be, illustrated by 55 the following sulphation procedure:
  • a wetting, cleaning,.foaming and dispersing agent of the class described comprising a sulphuric ester of a higher unsaturated normal-primary alcohol.
  • a compound for use in the treatment of flbrous materials comprising a sulphuric ester of a higher unsaturated normal primary alcohol corresponding in number of carbon atoms with the fatty acid radicals of the fatty acids and fatty acid esters heretofore employed in the form of 10 their sulphuric derivatives as wetting, cleaning and impregnating agents in the textile industry.
  • a wetting, cleaning. foaming and dispersing agent comprising a sulphuric ester of a higher unsaturated normal primary alcohol in which the 35 alcohol is ester-flied both at the double bond and at the end of the chain.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Forests & Forestry (AREA)
  • Business, Economics & Management (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Emergency Management (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
  • Detergent Compositions (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
US350135A 1928-03-30 1929-03-26 Sulphuric ester of higher alcohols Expired - Lifetime US1968793A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB150315D DE659277C (de) 1928-03-30 1928-03-30 Dispergier-, Netz-, Reinigungs- und Durchdringungsmittel

Publications (1)

Publication Number Publication Date
US1968793A true US1968793A (en) 1934-07-31

Family

ID=7002162

Family Applications (2)

Application Number Title Priority Date Filing Date
US350135A Expired - Lifetime US1968793A (en) 1928-03-30 1929-03-26 Sulphuric ester of higher alcohols
US650203A Expired - Lifetime US1968797A (en) 1928-03-30 1933-01-04 Sulphuric derivative of higher alcohols

Family Applications After (1)

Application Number Title Priority Date Filing Date
US650203A Expired - Lifetime US1968797A (en) 1928-03-30 1933-01-04 Sulphuric derivative of higher alcohols

Country Status (5)

Country Link
US (2) US1968793A (enrdf_load_stackoverflow)
DE (1) DE659277C (enrdf_load_stackoverflow)
FR (1) FR671456A (enrdf_load_stackoverflow)
GB (1) GB308824A (enrdf_load_stackoverflow)
NL (1) NL24700C (enrdf_load_stackoverflow)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2619467A (en) * 1952-11-25 Detergent mixtures containing
US2666527A (en) * 1945-06-22 1954-01-19 Peterson Filters & Eng Method of promoting filtration
US3959334A (en) * 1969-01-10 1976-05-25 Chevron Research Company Lime soap dispersant compounds
US4000081A (en) * 1969-01-10 1976-12-28 Chevron Research Company Lime soap dispersant compounds
US5037992A (en) * 1989-12-18 1991-08-06 The Procter & Gamble Company Process for sulfating unsaturated alcohols
US6239093B1 (en) * 1996-06-28 2001-05-29 The Procter & Gamble Company Liquid cleaning compositions and shampoos containing dianionic or alkoxylated dianionic surfactants

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2603606A (en) * 1952-07-15 Alkyl sulfates
DE763809C (de) * 1933-07-21 1954-05-03 Hydrierwerke A G Deutsche Verfahren zur Herstellung von Sulfonierungserzeugnissen
DE763234C (de) * 1935-06-09 1953-01-19 Wacker Chemie Gmbh Verfahren zur Herstellung von Schwefelsaeure- oder Phosphorsaeure-estern hoehermolekularer, einwertiger, gesaettigter, aliphatischer, primaerer Alkohole
FR720590A (fr) * 1939-07-24 1932-02-22 Ig Farbenindustrie Ag Procédé de lavage de matières textiles
US2489955A (en) * 1943-08-25 1949-11-29 Colgate Palmolive Peet Co Preparation of nondusting organic detergent compositions
US2480579A (en) * 1943-10-21 1949-08-30 Colgate Palmolive Peet Co Detergent products and their preparation
US2553716A (en) * 1946-07-19 1951-05-22 Rare Galen Inc Mild detergent and method of making same
US2613218A (en) * 1950-06-12 1952-10-07 Purex Corp Ltd Vacuum neutralization of detergents
US2819318A (en) * 1953-12-02 1958-01-07 Ethyl Corp Alcohols derived from babassu oil
US3249550A (en) * 1964-05-27 1966-05-03 Dow Corning Glass cleaning compositions
DE4322968A1 (de) * 1993-07-09 1995-01-12 Henkel Kgaa Verfahren zur Herstellung von Alkylsulfaten
DE19503061A1 (de) * 1995-02-01 1996-08-08 Henkel Kgaa Dimeralkohol-bis- und Trimeralkohol-tris-sulfate und -ethersulfate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2619467A (en) * 1952-11-25 Detergent mixtures containing
US2666527A (en) * 1945-06-22 1954-01-19 Peterson Filters & Eng Method of promoting filtration
US3959334A (en) * 1969-01-10 1976-05-25 Chevron Research Company Lime soap dispersant compounds
US4000081A (en) * 1969-01-10 1976-12-28 Chevron Research Company Lime soap dispersant compounds
US5037992A (en) * 1989-12-18 1991-08-06 The Procter & Gamble Company Process for sulfating unsaturated alcohols
US6239093B1 (en) * 1996-06-28 2001-05-29 The Procter & Gamble Company Liquid cleaning compositions and shampoos containing dianionic or alkoxylated dianionic surfactants

Also Published As

Publication number Publication date
DE659277C (de) 1938-04-29
GB308824A (enrdf_load_stackoverflow)
NL24700C (enrdf_load_stackoverflow)
FR671456A (fr) 1929-12-18
US1968797A (en) 1934-07-31

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