UA76308C2 - A plastic shaped article of impact-resistant polymethylacrylate - Google Patents
A plastic shaped article of impact-resistant polymethylacrylate Download PDFInfo
- Publication number
- UA76308C2 UA76308C2 UA20040807146A UA20040807146A UA76308C2 UA 76308 C2 UA76308 C2 UA 76308C2 UA 20040807146 A UA20040807146 A UA 20040807146A UA 20040807146 A UA20040807146 A UA 20040807146A UA 76308 C2 UA76308 C2 UA 76308C2
- Authority
- UA
- Ukraine
- Prior art keywords
- impact
- modifier
- impact resistance
- molded product
- resistant
- Prior art date
Links
- 239000004033 plastic Substances 0.000 title claims description 7
- 229920003023 plastic Polymers 0.000 title claims description 7
- 229920002319 Poly(methyl acrylate) Polymers 0.000 title 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 10
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 10
- 239000003607 modifier Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 14
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000004609 Impact Modifier Substances 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 238000012876 topography Methods 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000011258 core-shell material Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- -1 polysiloxane Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical class C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 101100532451 Rattus norvegicus Slc22a17 gene Proteins 0.000 description 1
- 101150015964 Strn gene Proteins 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical class C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Dental Preparations (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10203565A DE10203565C1 (de) | 2002-01-29 | 2002-01-29 | Verfahren zur Herstellung eines schlagzähen Polymethylmethacrylat- Formkörpers und Verwendung des so hergestellten Kunststoffformkörpers |
| PCT/EP2003/000336 WO2003064485A1 (de) | 2002-01-29 | 2003-01-15 | Verfahren zur herstellung eines schlagzähen polymethylmethacrylats und schlagzähes polymethylmethacrylat (pmma) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA76308C2 true UA76308C2 (en) | 2006-07-17 |
Family
ID=7713388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA20040807146A UA76308C2 (en) | 2002-01-29 | 2003-01-15 | A plastic shaped article of impact-resistant polymethylacrylate |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US7173093B2 (xx) |
| EP (1) | EP1470169B1 (xx) |
| JP (1) | JP4980556B2 (xx) |
| KR (1) | KR100872004B1 (xx) |
| CN (1) | CN1274732C (xx) |
| AT (1) | ATE324390T1 (xx) |
| AU (1) | AU2003205603B2 (xx) |
| CA (1) | CA2471285C (xx) |
| DE (2) | DE10203565C1 (xx) |
| ES (1) | ES2263951T3 (xx) |
| HK (1) | HK1073318A1 (xx) |
| HR (1) | HRP20040681A2 (xx) |
| NO (1) | NO20043340L (xx) |
| NZ (1) | NZ532500A (xx) |
| RS (1) | RS50920B (xx) |
| RU (1) | RU2288236C2 (xx) |
| TW (1) | TWI280258B (xx) |
| UA (1) | UA76308C2 (xx) |
| WO (1) | WO2003064485A1 (xx) |
| ZA (1) | ZA200406037B (xx) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10349544A1 (de) * | 2003-10-22 | 2005-05-25 | Röhm GmbH & Co. KG | Herstellung von farblosen, transparent oder gedeckt eingefärbten PLEXIGLAS-Blöcken aus restinitiatorfreiem Präpolymerisat durch thermische Polymerisation |
| DE102005055793A1 (de) | 2005-11-21 | 2007-05-24 | Röhm Gmbh | Transparente TPU (thermoplastische Polyurethane)/ PMMA (Polymethyl(meth)acrylat) Abmischungen mit verbesserter Kältesschlagzähigkeit |
| KR100725940B1 (ko) | 2005-12-06 | 2007-06-11 | 엘지엠엠에이 주식회사 | 폴리메틸메타크릴레이트 수지 조성물 |
| US7740951B2 (en) * | 2007-04-11 | 2010-06-22 | Lyondellbasell Advanced Polyolefins Usa Inc. | Multilayered polymeric structure and methods |
| GB0922255D0 (en) * | 2009-12-21 | 2010-02-03 | Lucite Int Uk Ltd | Method of producing acrylic and methacrylic acid |
| KR101219140B1 (ko) * | 2009-12-28 | 2013-01-07 | 제일모직주식회사 | 내충격성 및 표면경도가 우수한 액정화면 보호용 투명시트 및 그 제조방법 |
| WO2012069813A1 (en) * | 2010-11-24 | 2012-05-31 | Lucite International Uk Limited | A process for the production of methacrylic acid and its derivatives and polymers produced therefrom |
| BR112013019323B1 (pt) | 2011-02-09 | 2019-12-24 | Lucite Int Uk Ltd | método de extrair ácido (met)acrílico a partir de um meio de reação aquoso, processo para a produção de ácido (met)acrílico, e, método de preparar polímeros ou copolímeros de ácido (met)acrílico ou ésteres de ácido (met)acrílico |
| SG193435A1 (en) * | 2011-03-28 | 2013-10-30 | Evonik Roehm Gmbh | Plastic mouldings for use as windows for cars or utility vehicles |
| DE102011006185A1 (de) | 2011-03-28 | 2012-10-04 | Evonik Röhm Gmbh | Transparente bzw. semitransparente Bauteile mit reduzierter Gesamtsolartransmission bzw. erhöhter Gesamtsolarreflexion |
| DE102012207100A1 (de) | 2012-04-27 | 2013-10-31 | Evonik Industries Ag | Coextrudierte schlagzähmodifizierte PMMA-Folie |
| CA2919711C (en) | 2013-07-30 | 2022-08-16 | Dentsply International Inc. | Impact modified denture base compositions |
| CN103756227A (zh) * | 2014-01-20 | 2014-04-30 | 苏州新区华士达工程塑胶有限公司 | 一种高强改性聚甲基丙烯酸甲酯塑料 |
| CN104962025A (zh) * | 2015-07-28 | 2015-10-07 | 张家港市德力特新材料有限公司 | 一种抗冲击改性有机玻璃 |
| CN104962024A (zh) * | 2015-07-28 | 2015-10-07 | 张家港市德力特新材料有限公司 | 一种防刮有机玻璃 |
| FR3046605B1 (fr) * | 2016-01-11 | 2019-09-06 | Arkema France | Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation |
| FR3046606B1 (fr) * | 2016-01-11 | 2019-09-06 | Arkema France | Composition (meth)acrylique liquide comprenant un polymere a phases multiples et un monomere (meth)acrylique, son procede de preparation et son utilisation |
| FR3053348B1 (fr) * | 2016-06-29 | 2020-03-27 | Arkema France | Composition comprenant un polymere a phases multiples et deux polymeres (meth)acryliques differents, son procede de preparation et article la compenant |
| CN106977641A (zh) * | 2017-04-14 | 2017-07-25 | 苏州双象光学材料有限公司 | 一步法合成光学级pmma板材的方法 |
| CN108329633A (zh) * | 2018-03-16 | 2018-07-27 | 湖州知维技术服务有限公司 | 一种耐用有机玻璃加工工艺 |
| CN114316125B (zh) * | 2022-01-27 | 2023-05-23 | 江苏铁锚玻璃股份有限公司 | 高耐热性有机玻璃配方及其制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3793402A (en) * | 1971-11-05 | 1974-02-19 | F Owens | Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer |
| JPS55147514A (en) * | 1979-04-27 | 1980-11-17 | Sumitomo Chem Co Ltd | Continuous preparation of rubber-modified methyl methacrylate syrup |
| US4598123A (en) * | 1983-07-14 | 1986-07-01 | Unites States Steel Corporation | Impact modified methyl methacrylate polymer |
| GB8715193D0 (en) * | 1987-06-29 | 1987-08-05 | Ici Plc | Impact resistant acrylic sheet |
| US5084495A (en) * | 1988-03-21 | 1992-01-28 | Aristech Chemical Corporation | Method of transferring latex particles from an aqueous to an organic phase and making an impact resistant acrylic sheet |
| JPH0347856A (ja) | 1989-04-18 | 1991-02-28 | Kuraray Co Ltd | 耐光性に優れたメタクリル樹脂 |
| ATE120773T1 (de) * | 1989-12-21 | 1995-04-15 | Atochem Elf Sa | Verfahren zur herstellung einer gegossenen platte aus thermoplastischem harz. |
| US5258423A (en) * | 1990-03-26 | 1993-11-02 | Rohm And Haas Company | Stabilization of methacrylic polymers against sterilizing radiation |
| NZ330698A (en) * | 1997-07-23 | 1999-07-29 | Premark Rwp Holdings Inc | Translucent or opaque thermoplastic acrylic sheet suitable for lamination of structural plastics and high pressure decorative laminate |
| DE10054051A1 (de) * | 2000-10-31 | 2002-05-29 | Roehm Gmbh | PMMA-Formmasse mit verbesserter Kälteschlagzähigkeit |
| DE10054053A1 (de) * | 2000-10-31 | 2002-05-29 | Roehm Gmbh | PMMA-Formmassen mit verbesserter Kälteschlagzähigkeit |
-
2002
- 2002-01-29 DE DE10203565A patent/DE10203565C1/de not_active Expired - Fee Related
-
2003
- 2003-01-15 EP EP03702440A patent/EP1470169B1/de not_active Expired - Lifetime
- 2003-01-15 US US10/494,356 patent/US7173093B2/en not_active Expired - Fee Related
- 2003-01-15 JP JP2003564102A patent/JP4980556B2/ja not_active Expired - Fee Related
- 2003-01-15 CN CNB038015110A patent/CN1274732C/zh not_active Expired - Fee Related
- 2003-01-15 NZ NZ532500A patent/NZ532500A/xx not_active IP Right Cessation
- 2003-01-15 RU RU2004126449/04A patent/RU2288236C2/ru not_active IP Right Cessation
- 2003-01-15 AU AU2003205603A patent/AU2003205603B2/en not_active Ceased
- 2003-01-15 RS YUP-353/04A patent/RS50920B/sr unknown
- 2003-01-15 WO PCT/EP2003/000336 patent/WO2003064485A1/de active IP Right Grant
- 2003-01-15 CA CA002471285A patent/CA2471285C/en not_active Expired - Fee Related
- 2003-01-15 UA UA20040807146A patent/UA76308C2/uk unknown
- 2003-01-15 ES ES03702440T patent/ES2263951T3/es not_active Expired - Lifetime
- 2003-01-15 KR KR1020047011586A patent/KR100872004B1/ko not_active IP Right Cessation
- 2003-01-15 AT AT03702440T patent/ATE324390T1/de not_active IP Right Cessation
- 2003-01-15 DE DE50303107T patent/DE50303107D1/de not_active Expired - Lifetime
- 2003-01-28 TW TW092101806A patent/TWI280258B/zh not_active IP Right Cessation
-
2004
- 2004-07-23 HR HR20040681A patent/HRP20040681A2/xx not_active Application Discontinuation
- 2004-07-28 ZA ZA2004/06037A patent/ZA200406037B/en unknown
- 2004-08-11 NO NO20043340A patent/NO20043340L/no not_active Application Discontinuation
-
2005
- 2005-07-11 HK HK05105819A patent/HK1073318A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1274732C (zh) | 2006-09-13 |
| TWI280258B (en) | 2007-05-01 |
| EP1470169B1 (de) | 2006-04-26 |
| HRP20040681A2 (en) | 2004-10-31 |
| JP4980556B2 (ja) | 2012-07-18 |
| RS50920B (sr) | 2010-08-31 |
| JP2005516089A (ja) | 2005-06-02 |
| KR20040089125A (ko) | 2004-10-20 |
| RU2288236C2 (ru) | 2006-11-27 |
| RU2004126449A (ru) | 2006-02-10 |
| US20050085607A1 (en) | 2005-04-21 |
| EP1470169A1 (de) | 2004-10-27 |
| NZ532500A (en) | 2006-03-31 |
| US7173093B2 (en) | 2007-02-06 |
| DE50303107D1 (de) | 2006-06-01 |
| CA2471285C (en) | 2009-09-29 |
| CN1592762A (zh) | 2005-03-09 |
| ATE324390T1 (de) | 2006-05-15 |
| ZA200406037B (en) | 2005-08-31 |
| KR100872004B1 (ko) | 2008-12-05 |
| DE10203565C1 (de) | 2003-07-10 |
| RS35304A (xx) | 2007-04-10 |
| ES2263951T3 (es) | 2006-12-16 |
| WO2003064485A1 (de) | 2003-08-07 |
| NO20043340L (no) | 2004-08-11 |
| TW200302848A (en) | 2003-08-16 |
| HK1073318A1 (en) | 2005-09-30 |
| AU2003205603B2 (en) | 2007-08-02 |
| CA2471285A1 (en) | 2003-08-07 |
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