CN1274732C - 抗冲聚甲基丙烯酸甲酯的生产方法和抗冲聚甲基丙烯酸甲酯(pmma) - Google Patents
抗冲聚甲基丙烯酸甲酯的生产方法和抗冲聚甲基丙烯酸甲酯(pmma) Download PDFInfo
- Publication number
- CN1274732C CN1274732C CNB038015110A CN03801511A CN1274732C CN 1274732 C CN1274732 C CN 1274732C CN B038015110 A CNB038015110 A CN B038015110A CN 03801511 A CN03801511 A CN 03801511A CN 1274732 C CN1274732 C CN 1274732C
- Authority
- CN
- China
- Prior art keywords
- impact modifier
- impact
- plexiglas
- polymethylmethacrylate
- pmma
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Polymerisation Methods In General (AREA)
- Dental Preparations (AREA)
Abstract
Description
PLEXIGLASGS | PLEXIGLASXT |
铸塑 | 挤出 |
完全无色和透明 | 完全无色和透明 |
耐断裂 | 耐断裂到抗冲击(RESIST) |
尚未达到过的耐候性和耐老化性 | 尚未达到过的耐候性和耐老化性 |
高质量表面和平面性 | 非常良好的表面 |
实心板、块、管、圆棒和方棒 | 实心板、管、圆棒、多层板、波纹板、镜子 |
2mm-200mm实心厚度 | 实心板为1.5mm-25mm厚,多层板为16mm和32mm |
最大至3050×2030mm的标准规格 | 最大至4050×2050mm(+展开的长度)的标准规格 |
超过30种标准着色 | 超过20种标准着色 |
良好的耐稀酸性 | 良好的耐稀酸性 |
PLEXIGLASGS | PLEXIGLASXT |
铸塑 | 挤出 |
有限的耐有机溶剂性 | 有限的耐有机溶剂性 |
良好的耐碱性 | 良好的耐碱性 |
非常容易加工,类似于硬木 | 容易加工,类似于硬木 |
可以在宽的加工范围内良好地热成形 | 可以在最佳的不变的条件下非常好地热成形 |
能够非常好和牢固的粘合,如使用反应性粘合剂(如ACRIFIX190,192) | 能够非常好的粘合,也用溶剂基粘合剂(如ACRIFIX116,117) |
能够大约如硬木一样燃烧;产生非常少的烟雾 | 能够大约如硬木一样燃烧;产生非常少的烟雾 |
可在最高至约80℃下使用 | 可在最高至约70℃下使用 |
核: | 94-97wt% | 甲基丙烯酸甲酯 |
2-5wt% | 丙烯酸乙酯 | |
1-0.1wt% | 交联剂 | |
壳I | 79-82wt% | 丙烯酸丁酯 |
13-18wt% | 苯乙烯或α-甲基苯乙烯 | |
0.1-1wt% | 交联剂 | |
壳II | 90-98wt% | 甲基丙烯酸甲酯 |
10-2wt% | 丙烯酸乙酯 |
单位 | 对照物:PLEXIGLASGS 233 | 本发明的配方 | |
Charpy | kJ/m2 | 18.4 | 34.7 |
维卡 | ℃ | 115.75 | 113.3 |
E-模量 | 3.227 | 2.890 | |
透光率 | % | 92.45 | 92.05 |
Claims (5)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10203565A DE10203565C1 (de) | 2002-01-29 | 2002-01-29 | Verfahren zur Herstellung eines schlagzähen Polymethylmethacrylat- Formkörpers und Verwendung des so hergestellten Kunststoffformkörpers |
DE10203565.2 | 2002-01-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1592762A CN1592762A (zh) | 2005-03-09 |
CN1274732C true CN1274732C (zh) | 2006-09-13 |
Family
ID=7713388
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038015110A Expired - Fee Related CN1274732C (zh) | 2002-01-29 | 2003-01-15 | 抗冲聚甲基丙烯酸甲酯的生产方法和抗冲聚甲基丙烯酸甲酯(pmma) |
Country Status (20)
Country | Link |
---|---|
US (1) | US7173093B2 (zh) |
EP (1) | EP1470169B1 (zh) |
JP (1) | JP4980556B2 (zh) |
KR (1) | KR100872004B1 (zh) |
CN (1) | CN1274732C (zh) |
AT (1) | ATE324390T1 (zh) |
AU (1) | AU2003205603B2 (zh) |
CA (1) | CA2471285C (zh) |
DE (2) | DE10203565C1 (zh) |
ES (1) | ES2263951T3 (zh) |
HK (1) | HK1073318A1 (zh) |
HR (1) | HRP20040681A2 (zh) |
NO (1) | NO20043340L (zh) |
NZ (1) | NZ532500A (zh) |
RS (1) | RS50920B (zh) |
RU (1) | RU2288236C2 (zh) |
TW (1) | TWI280258B (zh) |
UA (1) | UA76308C2 (zh) |
WO (1) | WO2003064485A1 (zh) |
ZA (1) | ZA200406037B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108779316A (zh) * | 2016-01-11 | 2018-11-09 | 阿肯马法国公司 | 包含多级聚合物和(甲基)丙烯酸类单体的液体(甲基)丙烯酸类组合物,其制备方法和其用途 |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10349544A1 (de) * | 2003-10-22 | 2005-05-25 | Röhm GmbH & Co. KG | Herstellung von farblosen, transparent oder gedeckt eingefärbten PLEXIGLAS-Blöcken aus restinitiatorfreiem Präpolymerisat durch thermische Polymerisation |
DE102005055793A1 (de) | 2005-11-21 | 2007-05-24 | Röhm Gmbh | Transparente TPU (thermoplastische Polyurethane)/ PMMA (Polymethyl(meth)acrylat) Abmischungen mit verbesserter Kältesschlagzähigkeit |
KR100725940B1 (ko) | 2005-12-06 | 2007-06-11 | 엘지엠엠에이 주식회사 | 폴리메틸메타크릴레이트 수지 조성물 |
US7740951B2 (en) * | 2007-04-11 | 2010-06-22 | Lyondellbasell Advanced Polyolefins Usa Inc. | Multilayered polymeric structure and methods |
GB0922255D0 (en) * | 2009-12-21 | 2010-02-03 | Lucite Int Uk Ltd | Method of producing acrylic and methacrylic acid |
KR101219140B1 (ko) * | 2009-12-28 | 2013-01-07 | 제일모직주식회사 | 내충격성 및 표면경도가 우수한 액정화면 보호용 투명시트 및 그 제조방법 |
ES2552981T3 (es) * | 2010-11-24 | 2015-12-03 | Lucite International Uk Limited | Un proceso para la producción de ácido metacrílico y sus derivados y los polímeros producidos a partir de los mismos |
CA2825258C (en) * | 2011-02-09 | 2019-03-26 | Lucite International Uk Limited | A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom |
DE102011006185A1 (de) | 2011-03-28 | 2012-10-04 | Evonik Röhm Gmbh | Transparente bzw. semitransparente Bauteile mit reduzierter Gesamtsolartransmission bzw. erhöhter Gesamtsolarreflexion |
MX2013011037A (es) * | 2011-03-28 | 2013-12-06 | Evonik Cyro Llc | Molduras de plastico para uso como ventanas para automoviles o vehiculos utilitarios. |
DE102012207100A1 (de) | 2012-04-27 | 2013-10-31 | Evonik Industries Ag | Coextrudierte schlagzähmodifizierte PMMA-Folie |
CN105722494B (zh) | 2013-07-30 | 2020-11-03 | 登士柏国际公司 | 抗冲改性的义齿基托组合物 |
CN103756227A (zh) * | 2014-01-20 | 2014-04-30 | 苏州新区华士达工程塑胶有限公司 | 一种高强改性聚甲基丙烯酸甲酯塑料 |
CN104962025A (zh) * | 2015-07-28 | 2015-10-07 | 张家港市德力特新材料有限公司 | 一种抗冲击改性有机玻璃 |
CN104962024A (zh) * | 2015-07-28 | 2015-10-07 | 张家港市德力特新材料有限公司 | 一种防刮有机玻璃 |
FR3046605B1 (fr) * | 2016-01-11 | 2019-09-06 | Arkema France | Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation |
FR3053348B1 (fr) * | 2016-06-29 | 2020-03-27 | Arkema France | Composition comprenant un polymere a phases multiples et deux polymeres (meth)acryliques differents, son procede de preparation et article la compenant |
CN106977641A (zh) * | 2017-04-14 | 2017-07-25 | 苏州双象光学材料有限公司 | 一步法合成光学级pmma板材的方法 |
CN108329633A (zh) * | 2018-03-16 | 2018-07-27 | 湖州知维技术服务有限公司 | 一种耐用有机玻璃加工工艺 |
CN114316125B (zh) * | 2022-01-27 | 2023-05-23 | 江苏铁锚玻璃股份有限公司 | 高耐热性有机玻璃配方及其制备方法 |
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US3793402A (en) * | 1971-11-05 | 1974-02-19 | F Owens | Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer |
JPS55147514A (en) * | 1979-04-27 | 1980-11-17 | Sumitomo Chem Co Ltd | Continuous preparation of rubber-modified methyl methacrylate syrup |
US4598123A (en) * | 1983-07-14 | 1986-07-01 | Unites States Steel Corporation | Impact modified methyl methacrylate polymer |
GB8715193D0 (en) * | 1987-06-29 | 1987-08-05 | Ici Plc | Impact resistant acrylic sheet |
US5084495A (en) * | 1988-03-21 | 1992-01-28 | Aristech Chemical Corporation | Method of transferring latex particles from an aqueous to an organic phase and making an impact resistant acrylic sheet |
JPH0347856A (ja) * | 1989-04-18 | 1991-02-28 | Kuraray Co Ltd | 耐光性に優れたメタクリル樹脂 |
DE69018407T2 (de) * | 1989-12-21 | 1995-11-09 | Atochem Elf Sa | Verfahren zur Herstellung einer gegossenen Platte aus thermoplastischem Harz. |
US5258423A (en) * | 1990-03-26 | 1993-11-02 | Rohm And Haas Company | Stabilization of methacrylic polymers against sterilizing radiation |
NZ330698A (en) * | 1997-07-23 | 1999-07-29 | Premark Rwp Holdings Inc | Translucent or opaque thermoplastic acrylic sheet suitable for lamination of structural plastics and high pressure decorative laminate |
DE10054051A1 (de) * | 2000-10-31 | 2002-05-29 | Roehm Gmbh | PMMA-Formmasse mit verbesserter Kälteschlagzähigkeit |
DE10054053A1 (de) * | 2000-10-31 | 2002-05-29 | Roehm Gmbh | PMMA-Formmassen mit verbesserter Kälteschlagzähigkeit |
-
2002
- 2002-01-29 DE DE10203565A patent/DE10203565C1/de not_active Expired - Fee Related
-
2003
- 2003-01-15 JP JP2003564102A patent/JP4980556B2/ja not_active Expired - Fee Related
- 2003-01-15 RU RU2004126449/04A patent/RU2288236C2/ru not_active IP Right Cessation
- 2003-01-15 WO PCT/EP2003/000336 patent/WO2003064485A1/de active IP Right Grant
- 2003-01-15 DE DE50303107T patent/DE50303107D1/de not_active Expired - Lifetime
- 2003-01-15 AU AU2003205603A patent/AU2003205603B2/en not_active Ceased
- 2003-01-15 CN CNB038015110A patent/CN1274732C/zh not_active Expired - Fee Related
- 2003-01-15 UA UA20040807146A patent/UA76308C2/uk unknown
- 2003-01-15 US US10/494,356 patent/US7173093B2/en not_active Expired - Fee Related
- 2003-01-15 RS YUP-353/04A patent/RS50920B/sr unknown
- 2003-01-15 CA CA002471285A patent/CA2471285C/en not_active Expired - Fee Related
- 2003-01-15 ES ES03702440T patent/ES2263951T3/es not_active Expired - Lifetime
- 2003-01-15 NZ NZ532500A patent/NZ532500A/xx not_active IP Right Cessation
- 2003-01-15 AT AT03702440T patent/ATE324390T1/de not_active IP Right Cessation
- 2003-01-15 KR KR1020047011586A patent/KR100872004B1/ko not_active IP Right Cessation
- 2003-01-15 EP EP03702440A patent/EP1470169B1/de not_active Expired - Lifetime
- 2003-01-28 TW TW092101806A patent/TWI280258B/zh not_active IP Right Cessation
-
2004
- 2004-07-23 HR HR20040681A patent/HRP20040681A2/xx not_active Application Discontinuation
- 2004-07-28 ZA ZA2004/06037A patent/ZA200406037B/en unknown
- 2004-08-11 NO NO20043340A patent/NO20043340L/no not_active Application Discontinuation
-
2005
- 2005-07-11 HK HK05105819A patent/HK1073318A1/xx not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108779316A (zh) * | 2016-01-11 | 2018-11-09 | 阿肯马法国公司 | 包含多级聚合物和(甲基)丙烯酸类单体的液体(甲基)丙烯酸类组合物,其制备方法和其用途 |
CN108779316B (zh) * | 2016-01-11 | 2022-07-12 | 阿肯马法国公司 | 包含多级聚合物和(甲基)丙烯酸类单体的液体(甲基)丙烯酸类组合物,其制备方法和其用途 |
Also Published As
Publication number | Publication date |
---|---|
NO20043340L (no) | 2004-08-11 |
ES2263951T3 (es) | 2006-12-16 |
EP1470169B1 (de) | 2006-04-26 |
JP2005516089A (ja) | 2005-06-02 |
US7173093B2 (en) | 2007-02-06 |
RU2004126449A (ru) | 2006-02-10 |
UA76308C2 (en) | 2006-07-17 |
WO2003064485A1 (de) | 2003-08-07 |
DE10203565C1 (de) | 2003-07-10 |
KR100872004B1 (ko) | 2008-12-05 |
CA2471285C (en) | 2009-09-29 |
RS35304A (en) | 2007-04-10 |
DE50303107D1 (de) | 2006-06-01 |
TWI280258B (en) | 2007-05-01 |
ZA200406037B (en) | 2005-08-31 |
NZ532500A (en) | 2006-03-31 |
ATE324390T1 (de) | 2006-05-15 |
US20050085607A1 (en) | 2005-04-21 |
KR20040089125A (ko) | 2004-10-20 |
CN1592762A (zh) | 2005-03-09 |
JP4980556B2 (ja) | 2012-07-18 |
CA2471285A1 (en) | 2003-08-07 |
RS50920B (sr) | 2010-08-31 |
RU2288236C2 (ru) | 2006-11-27 |
AU2003205603B2 (en) | 2007-08-02 |
TW200302848A (en) | 2003-08-16 |
HK1073318A1 (en) | 2005-09-30 |
EP1470169A1 (de) | 2004-10-27 |
HRP20040681A2 (en) | 2004-10-31 |
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