UA102222C2 - Использование твердых веществ на основе феррита цинка в способе глубокого обессеривания кислородсодержащего сырья - Google Patents

Использование твердых веществ на основе феррита цинка в способе глубокого обессеривания кислородсодержащего сырья

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Publication number
UA102222C2
UA102222C2 UAA200910236A UAA200910236A UA102222C2 UA 102222 C2 UA102222 C2 UA 102222C2 UA A200910236 A UAA200910236 A UA A200910236A UA A200910236 A UAA200910236 A UA A200910236A UA 102222 C2 UA102222 C2 UA 102222C2
Authority
UA
Ukraine
Prior art keywords
oxygen
raw material
zinc ferrite
base
containing raw
Prior art date
Application number
UAA200910236A
Other languages
English (en)
Ukrainian (uk)
Inventor
Арно БОДО
Тьерри ЮАР
Мишель ТОМА
Original Assignee
Ифп
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ифп filed Critical Ифп
Publication of UA102222C2 publication Critical patent/UA102222C2/ru

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229Compounds of Fe
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/024Compounds of Zn, Cd, Hg
    • B01J20/0244Compounds of Zn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005Spinels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006Temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018Spatial velocity, e.g. LHSV, WHSV

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Изобретение относится к способу обессеривания сырья, содержащего кислородсодержащие соединения, углеводородные соединения и серосодержащие органические соединения, улавливанием серы на улавливающей массе, содержащей оксиды железа или оксиды цинка и более 20 мас. % феррита цинка. Способ осуществляют в присутствии водорода при температуре, находящейся в интервале от 200 °C до 400 °C.
UAA200910236A 2008-10-10 2009-10-08 Использование твердых веществ на основе феррита цинка в способе глубокого обессеривания кислородсодержащего сырья UA102222C2 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0805624A FR2937045B1 (fr) 2008-10-10 2008-10-10 Mise en oeuvre de solides a base de ferrite de zinc dans un procede de desulfuration profonde de charges oxygenees

Publications (1)

Publication Number Publication Date
UA102222C2 true UA102222C2 (ru) 2013-06-25

Family

ID=40652233

Family Applications (1)

Application Number Title Priority Date Filing Date
UAA200910236A UA102222C2 (ru) 2008-10-10 2009-10-08 Использование твердых веществ на основе феррита цинка в способе глубокого обессеривания кислородсодержащего сырья

Country Status (8)

Country Link
US (1) US8697920B2 (ru)
EP (1) EP2174710A1 (ru)
JP (2) JP2010100620A (ru)
CN (1) CN101723323B (ru)
BR (1) BRPI0904022B1 (ru)
FR (1) FR2937045B1 (ru)
RU (1) RU2500791C2 (ru)
UA (1) UA102222C2 (ru)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2576634C1 (ru) * 2014-12-12 2016-03-10 ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) Адсорбент для улавливания, концентрирования и хранения диоксида углерода
CN104741123A (zh) * 2015-03-11 2015-07-01 大连理工大学 一种新型纳米铁氧体吸附脱硫催化剂及其制备方法
CN106609166B (zh) * 2015-10-22 2020-09-04 中国石油化工股份有限公司 脱硫剂及其制备方法
KR102239677B1 (ko) * 2017-04-12 2021-04-13 주식회사 엘지화학 산화적 탈수소화 반응용 촉매, 이의 제조방법 및 이를 이용한 산화적 탈수소화방법
CN111085213A (zh) * 2018-10-23 2020-05-01 中国石油化工股份有限公司 一种具有脱硫作用的规整载体催化剂及其制备和应用
CN111085191A (zh) * 2018-10-23 2020-05-01 中国石油化工股份有限公司 一种具有脱硫作用的规整载体催化剂及其制备和应用

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3620969A (en) 1969-10-15 1971-11-16 Union Carbide Corp Desulfurization by selective adsorption with a crystalline zeolitic molecular sieve
SU403715A1 (ru) * 1970-06-15 1973-10-26 С. А. Апостолов Северо Западный заочный политехнический институт Способ каталитического гидрообессеривания углеводородов
US3832455A (en) * 1972-10-25 1974-08-27 Smith G Labor Preparation of zinc ferrite yellow pigments
PL139785B1 (en) * 1984-01-03 1987-02-28 Gdanskie Zaklady Rafineryjne Method of obtaining a catalyst for hydrorefining of lubricating oils in particular for refining processes being carried out under mild conditions
US4769045A (en) * 1986-04-10 1988-09-06 The United States Department Of Energy Method for the desulfurization of hot product gases from coal gasifier
JP2911961B2 (ja) * 1990-05-17 1999-06-28 日揮株式会社 高濃度アルコールの精製法及び精製用吸着剤
JP3762795B2 (ja) * 1993-07-29 2006-04-05 財団法人電力中央研究所 脱硫剤およびその製造方法
US5914288A (en) * 1997-09-29 1999-06-22 Research Triangle Institute Metal sulfide initiators for metal oxide sorbent regeneration
US5882614A (en) 1998-01-23 1999-03-16 Exxon Research And Engineering Company Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes
US6156084A (en) 1998-06-24 2000-12-05 International Fuel Cells, Llc System for desulfurizing a fuel for use in a fuel cell power plant
US6290734B1 (en) * 1999-07-28 2001-09-18 Chevron U.S.A. Inc. Blending of summer gasoline containing ethanol
JP2001064076A (ja) * 1999-08-26 2001-03-13 Tdk Corp 磁性フェライト材料およびその製造方法
US6271173B1 (en) 1999-11-01 2001-08-07 Phillips Petroleum Company Process for producing a desulfurization sorbent
US6454935B1 (en) 1999-12-22 2002-09-24 Utc Fuel Cells, Llc Method for desulfurizing gasoline or diesel fuel for use in a fuel cell power plant
WO2001070393A1 (en) * 2000-03-21 2001-09-27 Phillips Petroleum Company Desulfurization and novel sorbents for same
US6346190B1 (en) * 2000-03-21 2002-02-12 Phillips Petroleum Company Desulfurization and novel sorbents for same
EP1236495A1 (en) 2001-03-02 2002-09-04 Engelhard Corporation Process and apparatus for removing sulfur compounds from a hydrocarbon stream
JPWO2002074883A1 (ja) * 2001-03-21 2004-07-08 学校法人早稲田大学 脱硫剤、その製造方法及び利用方法
RU2197323C1 (ru) * 2001-05-23 2003-01-27 Открытое акционерное общество "Катализатор" Катализатор гидроочистки нефтяных фракций и способ его получения
WO2003020850A2 (en) 2001-09-04 2003-03-13 The Regents Of The University Of Michigan Selective sorbents for purification of hydrocarbons
GB0201015D0 (en) 2002-01-17 2002-03-06 Ici Plc Hydrocarbon treating
US20030183803A1 (en) 2002-03-28 2003-10-02 Price Ashley G. Desulfurization and novel compositions for same
JP4625970B2 (ja) * 2003-03-11 2011-02-02 学校法人早稲田大学 脱硫剤及びその製造方法、脱硫方法並びに燃料電池用水素の製造方法
JP4521172B2 (ja) * 2003-09-26 2010-08-11 出光興産株式会社 脱硫剤及びこれを用いた脱硫方法
FR2861403B1 (fr) 2003-10-27 2006-02-17 Inst Francais Du Petrole Procede de purification d'un gaz naturel par adsorption des mercaptans
JP4722414B2 (ja) * 2004-06-02 2011-07-13 学校法人早稲田大学 脱硫剤及びその製造方法、脱硫方法並びに高純度水素の製造方法
US7427385B2 (en) 2004-12-17 2008-09-23 Exxonmobil Research And Engineering Company Systems and processes for reducing the sulfur content of hydrocarbon streams
CN101146894B (zh) * 2005-03-24 2012-12-19 出光兴产株式会社 脱硫剂以及使用该脱硫剂的脱硫方法
FR2889539B1 (fr) 2005-08-08 2011-05-13 Inst Francais Du Petrole Procede de desulfuration des essences comportant une desulfuration par adsorption de la fraction legere et une hydrodesulfuration de la fraction lourde

Also Published As

Publication number Publication date
US8697920B2 (en) 2014-04-15
EP2174710A1 (fr) 2010-04-14
CN101723323A (zh) 2010-06-09
JP5933667B2 (ja) 2016-06-15
CN101723323B (zh) 2015-11-25
FR2937045B1 (fr) 2012-11-30
FR2937045A1 (fr) 2010-04-16
RU2500791C2 (ru) 2013-12-10
BRPI0904022A2 (pt) 2010-07-20
BRPI0904022B1 (pt) 2018-02-06
JP2015061851A (ja) 2015-04-02
RU2009137577A (ru) 2011-04-20
US20100089798A1 (en) 2010-04-15
JP2010100620A (ja) 2010-05-06

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