UA102222C2 - Использование твердых веществ на основе феррита цинка в способе глубокого обессеривания кислородсодержащего сырья - Google Patents
Использование твердых веществ на основе феррита цинка в способе глубокого обессеривания кислородсодержащего сырьяInfo
- Publication number
- UA102222C2 UA102222C2 UAA200910236A UAA200910236A UA102222C2 UA 102222 C2 UA102222 C2 UA 102222C2 UA A200910236 A UAA200910236 A UA A200910236A UA A200910236 A UAA200910236 A UA A200910236A UA 102222 C2 UA102222 C2 UA 102222C2
- Authority
- UA
- Ukraine
- Prior art keywords
- oxygen
- raw material
- zinc ferrite
- base
- containing raw
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 229910001308 Zinc ferrite Inorganic materials 0.000 title abstract 2
- 238000006477 desulfuration reaction Methods 0.000 title abstract 2
- 230000023556 desulfurization Effects 0.000 title abstract 2
- 239000002994 raw material Substances 0.000 title abstract 2
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 title abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title 1
- 229910052760 oxygen Inorganic materials 0.000 title 1
- 239000001301 oxygen Substances 0.000 title 1
- 239000000126 substance Substances 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 235000013980 iron oxide Nutrition 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 235000014692 zinc oxide Nutrition 0.000 abstract 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Изобретение относится к способу обессеривания сырья, содержащего кислородсодержащие соединения, углеводородные соединения и серосодержащие органические соединения, улавливанием серы на улавливающей массе, содержащей оксиды железа или оксиды цинка и более 20 мас. % феррита цинка. Способ осуществляют в присутствии водорода при температуре, находящейся в интервале от 200 °C до 400 °C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0805624A FR2937045B1 (fr) | 2008-10-10 | 2008-10-10 | Mise en oeuvre de solides a base de ferrite de zinc dans un procede de desulfuration profonde de charges oxygenees |
Publications (1)
Publication Number | Publication Date |
---|---|
UA102222C2 true UA102222C2 (ru) | 2013-06-25 |
Family
ID=40652233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA200910236A UA102222C2 (ru) | 2008-10-10 | 2009-10-08 | Использование твердых веществ на основе феррита цинка в способе глубокого обессеривания кислородсодержащего сырья |
Country Status (8)
Country | Link |
---|---|
US (1) | US8697920B2 (ru) |
EP (1) | EP2174710A1 (ru) |
JP (2) | JP2010100620A (ru) |
CN (1) | CN101723323B (ru) |
BR (1) | BRPI0904022B1 (ru) |
FR (1) | FR2937045B1 (ru) |
RU (1) | RU2500791C2 (ru) |
UA (1) | UA102222C2 (ru) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2576634C1 (ru) * | 2014-12-12 | 2016-03-10 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Адсорбент для улавливания, концентрирования и хранения диоксида углерода |
CN104741123A (zh) * | 2015-03-11 | 2015-07-01 | 大连理工大学 | 一种新型纳米铁氧体吸附脱硫催化剂及其制备方法 |
CN106609166B (zh) * | 2015-10-22 | 2020-09-04 | 中国石油化工股份有限公司 | 脱硫剂及其制备方法 |
KR102239677B1 (ko) * | 2017-04-12 | 2021-04-13 | 주식회사 엘지화학 | 산화적 탈수소화 반응용 촉매, 이의 제조방법 및 이를 이용한 산화적 탈수소화방법 |
CN111085213A (zh) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | 一种具有脱硫作用的规整载体催化剂及其制备和应用 |
CN111085191A (zh) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | 一种具有脱硫作用的规整载体催化剂及其制备和应用 |
Family Cites Families (29)
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US3620969A (en) | 1969-10-15 | 1971-11-16 | Union Carbide Corp | Desulfurization by selective adsorption with a crystalline zeolitic molecular sieve |
SU403715A1 (ru) * | 1970-06-15 | 1973-10-26 | С. А. Апостолов Северо Западный заочный политехнический институт | Способ каталитического гидрообессеривания углеводородов |
US3832455A (en) * | 1972-10-25 | 1974-08-27 | Smith G Labor | Preparation of zinc ferrite yellow pigments |
PL139785B1 (en) * | 1984-01-03 | 1987-02-28 | Gdanskie Zaklady Rafineryjne | Method of obtaining a catalyst for hydrorefining of lubricating oils in particular for refining processes being carried out under mild conditions |
US4769045A (en) * | 1986-04-10 | 1988-09-06 | The United States Department Of Energy | Method for the desulfurization of hot product gases from coal gasifier |
JP2911961B2 (ja) * | 1990-05-17 | 1999-06-28 | 日揮株式会社 | 高濃度アルコールの精製法及び精製用吸着剤 |
JP3762795B2 (ja) * | 1993-07-29 | 2006-04-05 | 財団法人電力中央研究所 | 脱硫剤およびその製造方法 |
US5914288A (en) * | 1997-09-29 | 1999-06-22 | Research Triangle Institute | Metal sulfide initiators for metal oxide sorbent regeneration |
US5882614A (en) | 1998-01-23 | 1999-03-16 | Exxon Research And Engineering Company | Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes |
US6156084A (en) | 1998-06-24 | 2000-12-05 | International Fuel Cells, Llc | System for desulfurizing a fuel for use in a fuel cell power plant |
US6290734B1 (en) * | 1999-07-28 | 2001-09-18 | Chevron U.S.A. Inc. | Blending of summer gasoline containing ethanol |
JP2001064076A (ja) * | 1999-08-26 | 2001-03-13 | Tdk Corp | 磁性フェライト材料およびその製造方法 |
US6271173B1 (en) | 1999-11-01 | 2001-08-07 | Phillips Petroleum Company | Process for producing a desulfurization sorbent |
US6454935B1 (en) | 1999-12-22 | 2002-09-24 | Utc Fuel Cells, Llc | Method for desulfurizing gasoline or diesel fuel for use in a fuel cell power plant |
WO2001070393A1 (en) * | 2000-03-21 | 2001-09-27 | Phillips Petroleum Company | Desulfurization and novel sorbents for same |
US6346190B1 (en) * | 2000-03-21 | 2002-02-12 | Phillips Petroleum Company | Desulfurization and novel sorbents for same |
EP1236495A1 (en) | 2001-03-02 | 2002-09-04 | Engelhard Corporation | Process and apparatus for removing sulfur compounds from a hydrocarbon stream |
JPWO2002074883A1 (ja) * | 2001-03-21 | 2004-07-08 | 学校法人早稲田大学 | 脱硫剤、その製造方法及び利用方法 |
RU2197323C1 (ru) * | 2001-05-23 | 2003-01-27 | Открытое акционерное общество "Катализатор" | Катализатор гидроочистки нефтяных фракций и способ его получения |
WO2003020850A2 (en) | 2001-09-04 | 2003-03-13 | The Regents Of The University Of Michigan | Selective sorbents for purification of hydrocarbons |
GB0201015D0 (en) | 2002-01-17 | 2002-03-06 | Ici Plc | Hydrocarbon treating |
US20030183803A1 (en) | 2002-03-28 | 2003-10-02 | Price Ashley G. | Desulfurization and novel compositions for same |
JP4625970B2 (ja) * | 2003-03-11 | 2011-02-02 | 学校法人早稲田大学 | 脱硫剤及びその製造方法、脱硫方法並びに燃料電池用水素の製造方法 |
JP4521172B2 (ja) * | 2003-09-26 | 2010-08-11 | 出光興産株式会社 | 脱硫剤及びこれを用いた脱硫方法 |
FR2861403B1 (fr) | 2003-10-27 | 2006-02-17 | Inst Francais Du Petrole | Procede de purification d'un gaz naturel par adsorption des mercaptans |
JP4722414B2 (ja) * | 2004-06-02 | 2011-07-13 | 学校法人早稲田大学 | 脱硫剤及びその製造方法、脱硫方法並びに高純度水素の製造方法 |
US7427385B2 (en) | 2004-12-17 | 2008-09-23 | Exxonmobil Research And Engineering Company | Systems and processes for reducing the sulfur content of hydrocarbon streams |
CN101146894B (zh) * | 2005-03-24 | 2012-12-19 | 出光兴产株式会社 | 脱硫剂以及使用该脱硫剂的脱硫方法 |
FR2889539B1 (fr) | 2005-08-08 | 2011-05-13 | Inst Francais Du Petrole | Procede de desulfuration des essences comportant une desulfuration par adsorption de la fraction legere et une hydrodesulfuration de la fraction lourde |
-
2008
- 2008-10-10 FR FR0805624A patent/FR2937045B1/fr active Active
-
2009
- 2009-09-25 EP EP09290729A patent/EP2174710A1/fr not_active Ceased
- 2009-10-05 BR BRPI0904022-6A patent/BRPI0904022B1/pt active IP Right Grant
- 2009-10-08 UA UAA200910236A patent/UA102222C2/ru unknown
- 2009-10-09 RU RU2009137577/04A patent/RU2500791C2/ru active
- 2009-10-09 JP JP2009234672A patent/JP2010100620A/ja active Pending
- 2009-10-09 US US12/576,675 patent/US8697920B2/en active Active
- 2009-10-10 CN CN200910204657.9A patent/CN101723323B/zh active Active
-
2014
- 2014-11-10 JP JP2014227728A patent/JP5933667B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
US8697920B2 (en) | 2014-04-15 |
EP2174710A1 (fr) | 2010-04-14 |
CN101723323A (zh) | 2010-06-09 |
JP5933667B2 (ja) | 2016-06-15 |
CN101723323B (zh) | 2015-11-25 |
FR2937045B1 (fr) | 2012-11-30 |
FR2937045A1 (fr) | 2010-04-16 |
RU2500791C2 (ru) | 2013-12-10 |
BRPI0904022A2 (pt) | 2010-07-20 |
BRPI0904022B1 (pt) | 2018-02-06 |
JP2015061851A (ja) | 2015-04-02 |
RU2009137577A (ru) | 2011-04-20 |
US20100089798A1 (en) | 2010-04-15 |
JP2010100620A (ja) | 2010-05-06 |
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