TWI775097B - 用於在大氣氧存在下交聯聚合物之組成物和方法 - Google Patents
用於在大氣氧存在下交聯聚合物之組成物和方法 Download PDFInfo
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- TWI775097B TWI775097B TW109120218A TW109120218A TWI775097B TW I775097 B TWI775097 B TW I775097B TW 109120218 A TW109120218 A TW 109120218A TW 109120218 A TW109120218 A TW 109120218A TW I775097 B TWI775097 B TW I775097B
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- Prior art keywords
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- organic peroxide
- sulfur
- tertiary
- poly
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- 239000000203 mixture Substances 0.000 title claims abstract 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract 6
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract 6
- 239000001301 oxygen Substances 0.000 title claims abstract 6
- 238000004132 cross linking Methods 0.000 title claims 2
- 238000000034 method Methods 0.000 title claims 2
- 229920000642 polymer Polymers 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 17
- 238000009472 formulation Methods 0.000 claims abstract 17
- 150000001451 organic peroxides Chemical class 0.000 claims abstract 15
- 229920001971 elastomer Polymers 0.000 claims abstract 14
- 239000000806 elastomer Substances 0.000 claims abstract 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract 13
- 239000011593 sulfur Substances 0.000 claims abstract 13
- -1 organophosphite compounds Chemical class 0.000 claims abstract 4
- 239000000843 powder Substances 0.000 claims 13
- 239000007787 solid Substances 0.000 claims 12
- RIIWOXJAAGZDLD-UHFFFAOYSA-N 2-pentyl-3,8-dithiatricyclo[5.1.0.02,4]oct-5-en-4-ol Chemical group C1=CC2SC2C2(CCCCC)SC21O RIIWOXJAAGZDLD-UHFFFAOYSA-N 0.000 claims 4
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- LGBYJXBCVZKJBL-UHFFFAOYSA-N 1-[(2-oxoazepan-1-yl)disulfanyl]azepan-2-one Chemical compound O=C1CCCCCN1SSN1C(=O)CCCCC1 LGBYJXBCVZKJBL-UHFFFAOYSA-N 0.000 claims 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims 3
- 229920006395 saturated elastomer Polymers 0.000 claims 3
- 150000003923 2,5-pyrrolediones Chemical class 0.000 claims 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 claims 1
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims 1
- PMAAOHONJPSASX-UHFFFAOYSA-N 2-butylperoxypropan-2-ylbenzene Chemical group CCCCOOC(C)(C)C1=CC=CC=C1 PMAAOHONJPSASX-UHFFFAOYSA-N 0.000 claims 1
- ZLPORNPZJNRGCO-UHFFFAOYSA-N 3-methylpyrrole-2,5-dione Chemical compound CC1=CC(=O)NC1=O ZLPORNPZJNRGCO-UHFFFAOYSA-N 0.000 claims 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 239000000378 calcium silicate Substances 0.000 claims 1
- 229910052918 calcium silicate Inorganic materials 0.000 claims 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 229910052570 clay Inorganic materials 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims 1
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 claims 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 claims 1
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical compound CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 abstract 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000004611 light stabiliser Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 150000004053 quinones Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/242—Applying crosslinking or accelerating agent onto compounding ingredients such as fillers, reinforcements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
- C08K5/08—Quinones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/205—Compounds containing groups, e.g. carbamates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3437—Six-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/019—Specific properties of additives the composition being defined by the absence of a certain additive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/40—Thiurams, i.e. compounds containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
- C08K5/47—Thiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462089421P | 2014-12-09 | 2014-12-09 | |
| US62/089,421 | 2014-12-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202035547A TW202035547A (zh) | 2020-10-01 |
| TWI775097B true TWI775097B (zh) | 2022-08-21 |
Family
ID=56107969
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW109120218A TWI775097B (zh) | 2014-12-09 | 2015-12-09 | 用於在大氣氧存在下交聯聚合物之組成物和方法 |
| TW111127047A TWI858357B (zh) | 2014-12-09 | 2015-12-09 | 用於在大氣氧存在下交聯聚合物之組成物和方法 |
| TW104141367A TWI698473B (zh) | 2014-12-09 | 2015-12-09 | 用於在大氣氧存在下交聯聚合物之組成物和方法 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW111127047A TWI858357B (zh) | 2014-12-09 | 2015-12-09 | 用於在大氣氧存在下交聯聚合物之組成物和方法 |
| TW104141367A TWI698473B (zh) | 2014-12-09 | 2015-12-09 | 用於在大氣氧存在下交聯聚合物之組成物和方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (3) | US10316154B2 (enExample) |
| EP (1) | EP3230350B1 (enExample) |
| JP (3) | JP6830063B2 (enExample) |
| KR (3) | KR102646961B1 (enExample) |
| CN (2) | CN107207744B (enExample) |
| BR (2) | BR112017012179B1 (enExample) |
| CA (1) | CA2970291A1 (enExample) |
| ES (1) | ES3016647T3 (enExample) |
| MX (2) | MX2017007414A (enExample) |
| PL (1) | PL3230350T3 (enExample) |
| TW (3) | TWI775097B (enExample) |
| WO (1) | WO2016094163A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11203672B2 (en) | 2016-12-20 | 2021-12-21 | Arkema Inc. | Efficient curative for free radically-crosslinkable polymers |
| JP2018127510A (ja) * | 2017-02-06 | 2018-08-16 | Nok株式会社 | 過酸化物架橋ゴム用遅延剤マスターバッチとその製造方法 |
| JPWO2019003885A1 (ja) * | 2017-06-28 | 2020-04-02 | Nok株式会社 | ゴム組成物および燃料電池セパレータ用シール材 |
| US11634568B2 (en) * | 2017-09-30 | 2023-04-25 | Dow Global Technologies Llc | Air curable ethylene/alpha-olefin/diene interpolymer composition |
| US11898026B2 (en) * | 2017-11-08 | 2024-02-13 | Dow Global Technologies Llc | Air-curable ethylene/alpha-olefin/diene interpolymer composition |
| US11325009B2 (en) * | 2019-12-11 | 2022-05-10 | Acushnet Company | Golf ball and method of making same |
| EP4265675A4 (en) | 2020-12-18 | 2024-10-30 | NOF Corporation | Rubber composition for hot air cross-linking, cross-linked rubber, and production method of cross-linked rubber |
| EP4569031A1 (en) * | 2022-08-12 | 2025-06-18 | Dow Global Technologies LLC | Air curable ethylene/alpha-olefin interpolymer compositions |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5120779A (en) * | 1987-08-28 | 1992-06-09 | Uniroyal Chemical Company, Inc. | Tire sidewall |
| CN101023127A (zh) * | 2004-09-22 | 2007-08-22 | 阿肯马法国公司 | 延迟焦烧的组合物 |
| TW201446860A (zh) * | 2013-03-26 | 2014-12-16 | Akzo Nobel Chemicals Int Bv | 交聯ｅｐｍ及ｅｐｄｍ之方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2842520A (en) | 1958-07-08 | Vinyl containing silicone elastomers | ||
| US2422156A (en) | 1943-10-15 | 1947-06-10 | Sharples Chemicals Inc | Vulcanization of rubberlike butadiene-1,3 polymerizates with phenol sulfides |
| CH555327A (de) | 1971-05-26 | 1974-10-31 | Inventa Ag | Verfahren zur herstellung von polythiobisphenolen. |
| US3919171A (en) | 1974-01-10 | 1975-11-11 | Pennwalt Corp | Process for preparing tertiary amyl phenol sulfides in a friable state |
| US3968062A (en) | 1974-08-23 | 1976-07-06 | Fairfield Chemical Services | Use of para-tert. butyl phenol disulfide for vulcanizing chlorobutyl rubber compositions |
| US4129700A (en) * | 1975-07-17 | 1978-12-12 | Pennwalt Corporation | Peroxy compounds and vulcanizable compositions thereof |
| JPS5813093B2 (ja) | 1980-02-27 | 1983-03-11 | 信越化学工業株式会社 | ゴム組成物 |
| US4743656A (en) * | 1985-02-20 | 1988-05-10 | Uniroyal Chemical Company, Inc. | Elastomeric composition of EPDM and ethylene-nitrile polymers |
| GB8516480D0 (en) * | 1985-06-28 | 1985-07-31 | Exxon Chemical Patents Inc | Weather resistant construction elements |
| US4655962A (en) * | 1986-03-25 | 1987-04-07 | Uniroyal Chemical Company, Inc. | Blowing agent composition |
| IN167956B (enExample) | 1986-05-23 | 1991-01-12 | Uniroyal Chem Co Inc | |
| US4983685A (en) | 1986-06-10 | 1991-01-08 | Sumitomo Chemical Company, Limited | Methods for production of crosslinked rubber products |
| US5084924A (en) | 1988-01-12 | 1992-02-04 | Spitz Melvin P | Mounting apparatus for wall beds with safety jamming feature |
| US5091471A (en) * | 1989-01-17 | 1992-02-25 | Bridgestone/Firestone, Inc. | Elastomer blends having improved extrusion resistance and method for the preparation thereof |
| US5219904A (en) | 1989-07-31 | 1993-06-15 | Nippon Mektron Limited | Crosslinkable, fluorine-containing elastomer composition |
| CA2026183A1 (en) * | 1989-10-31 | 1991-05-01 | Joseph M. Bohen | Organic peroxides and organic sulfide antioxidant compositions |
| US5070124A (en) * | 1989-10-31 | 1991-12-03 | Atochem North America, Inc. | Sulfide antioxidants for stabilizing crosslinked polyolefins |
| US5096947A (en) * | 1989-10-31 | 1992-03-17 | Atochem North America, Inc. | Organic peroxide and organic sulfide antioxidant composition |
| US4948840A (en) * | 1989-11-14 | 1990-08-14 | Himont Incorporated | Thermoplastic elastomer of propylene polymer material and crosslinked ethylene-propylene rubber |
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