TWI683699B - 一種金屬改性ｙ沸石、其製備方法和應用 - Google Patents

一種金屬改性ｙ沸石、其製備方法和應用 Download PDF

Info

Publication number
TWI683699B
TWI683699B TW103136546A TW103136546A TWI683699B TW I683699 B TWI683699 B TW I683699B TW 103136546 A TW103136546 A TW 103136546A TW 103136546 A TW103136546 A TW 103136546A TW I683699 B TWI683699 B TW I683699B
Authority
TW
Taiwan
Prior art keywords
zeolite
metal
modified
organic solvent
zirconium
Prior art date
Application number
TW103136546A
Other languages
English (en)
Chinese (zh)
Other versions
TW201515702A (zh
Inventor
龍軍
田輝平
于善青
王振波
Original Assignee
中國石油化工科技開發有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 中國石油化工科技開發有限公司 filed Critical 中國石油化工科技開發有限公司
Publication of TW201515702A publication Critical patent/TW201515702A/zh
Application granted granted Critical
Publication of TWI683699B publication Critical patent/TWI683699B/zh

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
TW103136546A 2013-10-22 2014-10-22 一種金屬改性ｙ沸石、其製備方法和應用 TWI683699B (zh)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
CN201310499736 2013-10-22
CN201310499968.9 2013-10-22
CN201310499703.9 2013-10-22
CN201310499736.3 2013-10-22
CN201310499968 2013-10-22
CN201310501188 2013-10-22
CN201310501188.3 2013-10-22
CN201310499703 2013-10-22

Publications (2)

Publication Number Publication Date
TW201515702A TW201515702A (zh) 2015-05-01
TWI683699B true TWI683699B (zh) 2020-02-01

Family

ID=52781869

Family Applications (1)

Application Number Title Priority Date Filing Date
TW103136546A TWI683699B (zh) 2013-10-22 2014-10-22 一種金屬改性ｙ沸石、其製備方法和應用

Country Status (9)

Country Link
AU (1) AU2014253496B2 (pt)
BR (1) BR102014026338B1 (pt)
CA (1) CA2867947C (pt)
FR (1) FR3012125A1 (pt)
MX (1) MX356516B (pt)
MY (1) MY189261A (pt)
RU (1) RU2670744C9 (pt)
SG (1) SG10201406881YA (pt)
TW (1) TWI683699B (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835114B (zh) * 2018-08-17 2022-10-21 中国石油化工股份有限公司 改性y型分子筛及其制备方法
CN110316741B (zh) * 2019-05-09 2022-08-05 山东齐鲁华信高科有限公司 低钠高硅y型分子筛的制备方法
CN112138709A (zh) * 2019-06-28 2020-12-29 浙江恒澜科技有限公司 催化剂及其制备方法和在环己酮肟气相贝克曼重排反应中的应用
CN113683093A (zh) * 2021-08-20 2021-11-23 中国高岭土有限公司 一种裂化催化剂用高岭土的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103269795A (zh) * 2010-08-02 2013-08-28 沙特阿拉伯石油公司 用于烃油的加氢裂化催化剂、用于生产加氢裂化催化剂的方法以及用加氢裂化催化剂加氢裂化烃油的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3671191A (en) 1970-09-16 1972-06-20 Grace W R & Co Preparation of high silica synthetic faujasite
CN1112248C (zh) * 1999-12-02 2003-06-25 中国石油化工集团公司 一种超稳y型分子筛的制备方法
CN1111089C (zh) 2000-10-26 2003-06-11 中国石油化工股份有限公司 一种同时含贵金属与非贵金属的改性y沸石及其制备方法
ITMI20030347A1 (it) 2003-02-27 2004-08-28 Enitecnologie Spa Catalizzatore e processo per preparare alcani lineari.
CN100360221C (zh) 2004-10-29 2008-01-09 中国石油化工股份有限公司 一种含改性y沸石的氧化铝载体及其制备方法
CN100357399C (zh) * 2005-03-31 2007-12-26 中国石油化工股份有限公司 一种裂化催化剂的制备方法
WO2007032232A1 (ja) * 2005-09-12 2007-03-22 Petroleum Energy Center 炭化水素の水素化処理用触媒組成物および水素化処理方法
CN101134576B (zh) 2006-09-01 2010-09-08 中国石油大学(北京) 利用骨架杂原子提高y型分子筛水热稳定性的方法
RU2310509C1 (ru) * 2006-09-18 2007-11-20 ООО "Компания Катахим" Способ получения катализатора гидрокрекинга нефтяного сырья
UA99993C2 (en) * 2009-04-29 2012-10-25 ПиКью КОРПОРЕЙШН Zeolite y
CN101898144B (zh) 2009-05-27 2013-02-13 中国石油天然气股份有限公司 一种含骨架杂原子的y型分子筛的催化裂化催化剂及其制备方法
RU2440190C1 (ru) * 2010-09-24 2012-01-20 Государственное образовательное учреждение высшего профессионального образования "Уфимский государственный нефтяной технический университет" Способ получения катализатора алкилирования парафиновых углеводородов олефинами

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103269795A (zh) * 2010-08-02 2013-08-28 沙特阿拉伯石油公司 用于烃油的加氢裂化催化剂、用于生产加氢裂化催化剂的方法以及用加氢裂化催化剂加氢裂化烃油的方法

Also Published As

Publication number Publication date
FR3012125A1 (pt) 2015-04-24
AU2014253496B2 (en) 2018-10-18
RU2014142572A (ru) 2016-05-20
RU2014142572A3 (pt) 2018-05-07
BR102014026338B1 (pt) 2020-02-11
MX356516B (es) 2018-06-01
SG10201406881YA (en) 2015-05-28
RU2670744C9 (ru) 2018-12-13
MY189261A (en) 2022-01-31
BR102014026338A2 (pt) 2015-09-22
CA2867947C (en) 2021-11-09
AU2014253496A1 (en) 2015-05-07
CA2867947A1 (en) 2015-04-22
MX2014012902A (es) 2015-05-27
RU2670744C2 (ru) 2018-10-25
TW201515702A (zh) 2015-05-01

Similar Documents

Publication Publication Date Title
JP6587381B2 (ja) 金属修飾されたｙ型ゼオライト、その製法およびその使用
JP6383636B2 (ja) 金属修飾されたｙ型ゼオライト、その製法およびその使用
TWI683699B (zh) 一種金屬改性ｙ沸石、其製備方法和應用
CN106140289B (zh) 一种含改性β沸石的裂化催化剂
JP7437412B2 (ja) 接触分解触媒およびその調製方法
JP3565571B2 (ja) 変性アルミナ調製法及び変性アルミナを使用した流動接触クラッキング触媒
WO2018153303A1 (zh) 含镁的改性y型分子筛、其制备方法及包含它的催化剂
US9416322B2 (en) Process for making improved catalysts from clay-derived zeolites
WO2020001540A1 (zh) 改性y型分子筛、包含它的催化裂化催化剂、及其制备和应用
CN106145154A (zh) 一种改性y沸石及其制备方法
CN113582193B (zh) 一种改性β沸石、催化裂化催化剂及其制备方法和应用
CN110833854B (zh) 催化裂化催化剂及其制备方法和应用
CN113578375A (zh) 一种改性zsm-5沸石、催化裂化催化剂及其制备方法和应用
CN108452836B (zh) 一种催化裂化催化剂