MX356516B - Zeolita y modificada con metal, su preparacion y uso. - Google Patents

Zeolita y modificada con metal, su preparacion y uso.

Info

Publication number
MX356516B
MX356516B MX2014012902A MX2014012902A MX356516B MX 356516 B MX356516 B MX 356516B MX 2014012902 A MX2014012902 A MX 2014012902A MX 2014012902 A MX2014012902 A MX 2014012902A MX 356516 B MX356516 B MX 356516B
Authority
MX
Mexico
Prior art keywords
zeolite
preparation
metal
metal modified
group ivb
Prior art date
Application number
MX2014012902A
Other languages
English (en)
Other versions
MX2014012902A (es
Inventor
Jun Long
Huiping Tian
Shanqing Yu
Zhenbo Wang
Original Assignee
China Petroleum & Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum & Chem Corp filed Critical China Petroleum & Chem Corp
Publication of MX2014012902A publication Critical patent/MX2014012902A/es
Publication of MX356516B publication Critical patent/MX356516B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invención se relaciona con una zeolita Y modificada con metal, su preparación y uso; dicha zeolita contiene de 1 a 15% en peso de metal del grupo IVB en forma de óxido y está caracterizada porque: la relación del contenido de metal del grupo IVB de la superficie de la zeolita con el contenido de metal del grupo IVB del interior de la zeolita no es mayor que 0.2; y/o la relación del aluminio de estructura distorsionada en coordinación tetraédrica con el aluminio de estructura en coordinación tetraédrica en la estructura de celosía de zeolita es de (0.1 a 0.8):1.
MX2014012902A 2013-10-22 2014-10-22 Zeolita y modificada con metal, su preparacion y uso. MX356516B (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN201310499968 2013-10-22
CN201310499703 2013-10-22
CN201310499736 2013-10-22
CN201310501188 2013-10-22

Publications (2)

Publication Number Publication Date
MX2014012902A MX2014012902A (es) 2015-05-27
MX356516B true MX356516B (es) 2018-06-01

Family

ID=52781869

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014012902A MX356516B (es) 2013-10-22 2014-10-22 Zeolita y modificada con metal, su preparacion y uso.

Country Status (9)

Country Link
AU (1) AU2014253496B2 (es)
BR (1) BR102014026338B1 (es)
CA (1) CA2867947C (es)
FR (1) FR3012125A1 (es)
MX (1) MX356516B (es)
MY (1) MY189261A (es)
RU (1) RU2670744C9 (es)
SG (1) SG10201406881YA (es)
TW (1) TWI683699B (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835114B (zh) * 2018-08-17 2022-10-21 中国石油化工股份有限公司 改性y型分子筛及其制备方法
CN110316741B (zh) * 2019-05-09 2022-08-05 山东齐鲁华信高科有限公司 低钠高硅y型分子筛的制备方法
CN112138709A (zh) * 2019-06-28 2020-12-29 浙江恒澜科技有限公司 催化剂及其制备方法和在环己酮肟气相贝克曼重排反应中的应用
CN113683093A (zh) * 2021-08-20 2021-11-23 中国高岭土有限公司 一种裂化催化剂用高岭土的制备方法
CN118307008B (zh) * 2024-04-01 2025-10-31 福州大学 一种高硅zsm-5分子筛的合成方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3671191A (en) 1970-09-16 1972-06-20 Grace W R & Co Preparation of high silica synthetic faujasite
CN1112248C (zh) * 1999-12-02 2003-06-25 中国石油化工集团公司 一种超稳y型分子筛的制备方法
CN1111089C (zh) 2000-10-26 2003-06-11 中国石油化工股份有限公司 一种同时含贵金属与非贵金属的改性y沸石及其制备方法
ITMI20030347A1 (it) 2003-02-27 2004-08-28 Enitecnologie Spa Catalizzatore e processo per preparare alcani lineari.
CN100360221C (zh) 2004-10-29 2008-01-09 中国石油化工股份有限公司 一种含改性y沸石的氧化铝载体及其制备方法
CN100357399C (zh) * 2005-03-31 2007-12-26 中国石油化工股份有限公司 一种裂化催化剂的制备方法
CN101262945B (zh) * 2005-09-12 2010-05-19 财团法人石油能源中心 烃的氢化处理用催化剂组合物及氢化处理方法
CN101134576B (zh) 2006-09-01 2010-09-08 中国石油大学(北京) 利用骨架杂原子提高y型分子筛水热稳定性的方法
RU2310509C1 (ru) * 2006-09-18 2007-11-20 ООО "Компания Катахим" Способ получения катализатора гидрокрекинга нефтяного сырья
SG175067A1 (en) * 2009-04-29 2011-11-28 Pq Corp Zeolite y
CN101898144B (zh) 2009-05-27 2013-02-13 中国石油天然气股份有限公司 一种含骨架杂原子的y型分子筛的催化裂化催化剂及其制备方法
JP2012050976A (ja) * 2010-08-02 2012-03-15 Japan Cooperation Center Petroleum 炭化水素油の水素化分解触媒及びその製造方法並びにそれを用いた水素化分解方法
RU2440190C1 (ru) * 2010-09-24 2012-01-20 Государственное образовательное учреждение высшего профессионального образования "Уфимский государственный нефтяной технический университет" Способ получения катализатора алкилирования парафиновых углеводородов олефинами

Also Published As

Publication number Publication date
CA2867947A1 (en) 2015-04-22
RU2670744C2 (ru) 2018-10-25
RU2014142572A (ru) 2016-05-20
RU2670744C9 (ru) 2018-12-13
MX2014012902A (es) 2015-05-27
BR102014026338A2 (pt) 2015-09-22
CA2867947C (en) 2021-11-09
RU2014142572A3 (es) 2018-05-07
TWI683699B (zh) 2020-02-01
SG10201406881YA (en) 2015-05-28
MY189261A (en) 2022-01-31
BR102014026338B1 (pt) 2020-02-11
AU2014253496A1 (en) 2015-05-07
FR3012125A1 (es) 2015-04-24
TW201515702A (zh) 2015-05-01
AU2014253496B2 (en) 2018-10-18

Similar Documents

Publication Publication Date Title
CL2018000106A1 (es) Moléculas de anticuerpo que se unen a cd45
WO2014206561A8 (en) Novel antibody frameworks
EP3662927A3 (en) Vaccine composition
CL2016001547A1 (es) Composiciones para el cuidado oral
BR112016002391A2 (pt) composições tópicas e métodos de uso das mesmas
AR098882A1 (es) Composición dentífrica que comprende óxido de zinc y citrato de zinc
PL2959163T3 (pl) Siłownik i sposób udoskonalenia siłownika
MX356516B (es) Zeolita y modificada con metal, su preparacion y uso.
PH12016500284A1 (en) Oral care composition
ES2721530T3 (es) Uso de acetato de cis- o trans-(2-isobutil-4-metil-tetrahidropiran-4-ilo) isoméricamente puro o altamente enriquecido con isómeros
Brzdȩk et al. Remarks on the stability of Lie homomorphisms
MX378201B (es) Composicion de marcado.
EA201690036A1 (ru) Состав с отсроченным высвобождением, содержащий гранулы цистеамина, и способы его получения и применения
GT201500328A (es) Suplemento de hierro
CO2017000180A2 (es) Composiciones de alcohol polihídrico para deshidratacion de gas
AR110518A1 (es) Material compuesto transparente
BR112015027824A2 (pt) composições de vitamina e em pó
CL2017001277A1 (es) Productos a base de sulfato de calcio resistentes al fuego
EA033258B9 (ru) Композиция для ухода за полостью рта
MX2015012530A (es) Mezclas sinergicas de carbonato de calcio y arcilla calcinada.
SG11201807312UA (en) Plasterboard
CL2016000563A1 (es) Pigmentos compuestos
BR112016002086A2 (pt) materiais de lignina contendo composições
BR112015023730A2 (pt) uso de sedoeptulose como suplemento nutricional
MX362686B (es) Inmunógenos fúngicos y materiales y métodos relacionados.

Legal Events

Date Code Title Description
FG Grant or registration