TWI664217B - 橡膠組成物及使用其之交聯物、輪胎、以及橡膠組成物之製造方法 - Google Patents
橡膠組成物及使用其之交聯物、輪胎、以及橡膠組成物之製造方法 Download PDFInfo
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- TWI664217B TWI664217B TW104107846A TW104107846A TWI664217B TW I664217 B TWI664217 B TW I664217B TW 104107846 A TW104107846 A TW 104107846A TW 104107846 A TW104107846 A TW 104107846A TW I664217 B TWI664217 B TW I664217B
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- Prior art keywords
- rubber
- liquid diene
- mass
- modified
- diene rubber
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 149
- 239000005060 rubber Substances 0.000 title claims abstract description 149
- 239000000203 mixture Substances 0.000 title claims abstract description 122
- 238000004519 manufacturing process Methods 0.000 title claims description 76
- 239000007788 liquid Substances 0.000 claims abstract description 215
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 147
- 150000001875 compounds Chemical class 0.000 claims abstract description 86
- 125000000524 functional group Chemical group 0.000 claims abstract description 64
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 53
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- 238000000034 method Methods 0.000 claims description 44
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- 239000000377 silicon dioxide Substances 0.000 claims description 18
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 10
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- 150000001244 carboxylic acid anhydrides Chemical group 0.000 claims description 6
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- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical group O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 2
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 69
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- 229920002857 polybutadiene Polymers 0.000 description 63
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- 230000000052 comparative effect Effects 0.000 description 25
- 229920003048 styrene butadiene rubber Polymers 0.000 description 25
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- 239000003054 catalyst Substances 0.000 description 22
- 239000002174 Styrene-butadiene Substances 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 19
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 15
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 15
- 229920002554 vinyl polymer Polymers 0.000 description 15
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 14
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 13
- 229910052783 alkali metal Inorganic materials 0.000 description 13
- 150000001993 dienes Chemical class 0.000 description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 13
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- 244000043261 Hevea brasiliensis Species 0.000 description 12
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- 238000006467 substitution reaction Methods 0.000 description 10
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
- 150000001340 alkali metals Chemical class 0.000 description 9
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 description 9
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
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- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 4
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- 229930195733 hydrocarbon Natural products 0.000 description 4
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- 238000000691 measurement method Methods 0.000 description 4
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 4
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- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 4
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- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 2
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- VTFXHGBOGGGYDO-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-methylphenol Chemical compound CCCCCCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCCCCCC)=C1 VTFXHGBOGGGYDO-UHFFFAOYSA-N 0.000 description 2
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- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 2
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- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
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- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 238000011191 terminal modification Methods 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- FPBXRRDHCADTAL-UHFFFAOYSA-N triethoxy(3-nitropropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC[N+]([O-])=O FPBXRRDHCADTAL-UHFFFAOYSA-N 0.000 description 1
- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- KLFNHRIZTXWZHT-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltrisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSCCC[Si](OCC)(OCC)OCC KLFNHRIZTXWZHT-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- QPPXVBLDIDEHBA-UHFFFAOYSA-N trimethoxy(3-nitropropyl)silane Chemical compound CO[Si](OC)(OC)CCC[N+]([O-])=O QPPXVBLDIDEHBA-UHFFFAOYSA-N 0.000 description 1
- JSXKIRYGYMKWSK-UHFFFAOYSA-N trimethoxy-[2-(2-trimethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CO[Si](OC)(OC)CCSSSSCC[Si](OC)(OC)OC JSXKIRYGYMKWSK-UHFFFAOYSA-N 0.000 description 1
- NQRACKNXKKOCJY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSCCC[Si](OC)(OC)OC NQRACKNXKKOCJY-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
- C08K5/47—Thiazoles
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/548—Silicon-containing compounds containing sulfur
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
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| JP2014051806 | 2014-03-14 | ||
| JP2014-051806 | 2014-03-14 |
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| EP (1) | EP3118251B1 (enExample) |
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| HU (1) | HUE054116T2 (enExample) |
| PT (1) | PT3118251T (enExample) |
| TW (1) | TWI664217B (enExample) |
| WO (1) | WO2015137295A1 (enExample) |
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| EP3508526B1 (en) * | 2016-09-02 | 2023-07-12 | Kuraray Co., Ltd. | Rubber composition |
| US10730985B2 (en) | 2016-12-19 | 2020-08-04 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| JP6948887B2 (ja) * | 2017-08-31 | 2021-10-13 | 住友理工株式会社 | 塗膜親和性ゴム組成物および鉄道車両用外幌 |
| CA3074182A1 (en) * | 2017-09-01 | 2019-03-07 | Kuraray Co., Ltd. | High-grip tire rubber compositions |
| US20200392313A1 (en) * | 2017-09-01 | 2020-12-17 | Kuraray Co., Ltd. | High-grip tire rubber compositions |
| KR102550882B1 (ko) * | 2017-09-01 | 2023-07-03 | 주식회사 쿠라레 | 타이어용 고무 조성물 |
| CA3074435A1 (en) * | 2017-09-01 | 2019-03-07 | Kuraray Co., Ltd. | Heavy-duty tire rubber compositions and tires |
| CN111032769B (zh) * | 2017-09-01 | 2022-03-01 | 株式会社可乐丽 | 重载轮胎用橡胶组合物和轮胎 |
| CN111183179B (zh) * | 2017-10-05 | 2022-08-12 | 横滨橡胶株式会社 | 轮胎用橡胶组合物及充气轮胎 |
| CA3078383A1 (en) | 2017-10-05 | 2019-04-11 | Kuraray Co., Ltd. | Modified liquid diene rubbers |
| US11807704B2 (en) | 2017-12-15 | 2023-11-07 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| KR102167527B1 (ko) | 2017-12-19 | 2020-10-19 | 주식회사 엘지화학 | 공액디엔계 공중합체 조성물, 이의 제조방법 및 이를 포함하는 고무 조성물 |
| KR102651219B1 (ko) | 2018-03-07 | 2024-03-25 | 주식회사 쿠라레 | 변성 액상 디엔계 중합체 및 고무 조성물 |
| JP7314128B2 (ja) * | 2018-05-29 | 2023-07-25 | 株式会社クラレ | 補強繊維及びその製造方法、並びにそれを用いた成形体 |
| TW202022035A (zh) * | 2018-10-25 | 2020-06-16 | 日商Ｊｓｒ股份有限公司 | 聚合物組成物、交聯聚合物及輪胎 |
| FR3089988A3 (fr) * | 2018-12-17 | 2020-06-19 | Michelin & Cie | Composition de caoutchouc à base d’au moins un élastomère fonctionnalisé comprenant des groupes fonctionnels polaires et un composé phénolique spécifique |
| JP7636324B2 (ja) * | 2019-06-25 | 2025-02-26 | 日鉄ケミカル＆マテリアル株式会社 | 変性ビニル芳香族系共重合体及びその製造方法、それから得られる変性共役ジエン系共重合体、その組成物、ゴム架橋物及びタイヤ部材 |
| CN113004608B (zh) * | 2019-12-20 | 2022-07-12 | 万华化学集团股份有限公司 | 一种聚丙烯复合材料及其制备方法 |
| US20230272125A1 (en) * | 2020-05-14 | 2023-08-31 | Kuraray Co., Ltd. | Modified liquid diene rubbers, rubber compositions, and sealing materials |
| CN116262840A (zh) * | 2022-12-09 | 2023-06-16 | 中策橡胶集团股份有限公司 | 一种连续化制备高强度液态返原再生橡胶的方法 |
| CN116478458B (zh) * | 2022-12-22 | 2024-08-16 | 广东粤港澳大湾区黄埔材料研究院 | 一种新能源汽车轮胎用橡胶复合材料及其制备方法 |
| CN116003948B (zh) * | 2022-12-24 | 2025-05-16 | 广东东大科技有限公司 | 一种低成本高耐磨的tpe改性材料及其制备方法 |
| CN116376129B (zh) * | 2023-01-13 | 2024-04-19 | 赛轮集团股份有限公司 | 一种超高性能轮胎胎面胶及其制备方法 |
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| US4218349A (en) * | 1978-12-19 | 1980-08-19 | Kuraray Co., Ltd. | Rubber composition |
| US20040266915A1 (en) * | 2003-06-27 | 2004-12-30 | Yoshiaki Kirino | Rubber composition |
| CN101273086A (zh) * | 2005-09-22 | 2008-09-24 | 可乐丽股份有限公司 | 橡胶组合物以及交联物 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60124639A (ja) | 1983-12-09 | 1985-07-03 | Kuraray Plast Kk | ゴム組成物 |
| US4555547A (en) * | 1984-08-23 | 1985-11-26 | Nippon Zeon Co. Ltd. | Rubber composition for tire treads |
| JPH04225046A (ja) | 1990-12-27 | 1992-08-14 | Nippon Petrochem Co Ltd | ゴム組成物 |
| JP3457379B2 (ja) | 1994-04-26 | 2003-10-14 | 株式会社クラレ | ゴム組成物 |
| US20040024093A1 (en) * | 2002-07-30 | 2004-02-05 | Marc Weydert | Starch composite reinforced rubber composition and tire with at least one component thereof |
| ATE367417T1 (de) * | 2003-02-12 | 2007-08-15 | Kuraray Co | Kautschukzusammensetzung, vernetzbare kautschukzusammensetzungen und vernetzter artikel |
| JP4762562B2 (ja) | 2005-02-01 | 2011-08-31 | 東洋ゴム工業株式会社 | 空気入りタイヤ用ゴム組成物 |
| JP2008038059A (ja) * | 2006-08-08 | 2008-02-21 | Yokohama Rubber Co Ltd:The | ゴム組成物、その複合体、およびそれを用いた空気入りタイヤ |
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2015
- 2015-03-10 EP EP15761051.0A patent/EP3118251B1/en active Active
- 2015-03-10 WO PCT/JP2015/056903 patent/WO2015137295A1/ja not_active Ceased
- 2015-03-10 CN CN201910374468.XA patent/CN110256742A/zh active Pending
- 2015-03-10 CA CA2942255A patent/CA2942255C/en active Active
- 2015-03-10 US US15/125,420 patent/US10370525B2/en active Active
- 2015-03-10 KR KR1020167025868A patent/KR102270880B1/ko active Active
- 2015-03-10 JP JP2015537047A patent/JP5922850B2/ja active Active
- 2015-03-10 HU HUE15761051A patent/HUE054116T2/hu unknown
- 2015-03-10 PT PT157610510T patent/PT3118251T/pt unknown
- 2015-03-10 CN CN201580013681.8A patent/CN106164160B/zh active Active
- 2015-03-12 TW TW104107846A patent/TWI664217B/zh active
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2016
- 2016-04-14 JP JP2016080924A patent/JP2016172859A/ja active Pending
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| US20040266915A1 (en) * | 2003-06-27 | 2004-12-30 | Yoshiaki Kirino | Rubber composition |
| CN101273086A (zh) * | 2005-09-22 | 2008-09-24 | 可乐丽股份有限公司 | 橡胶组合物以及交联物 |
Also Published As
| Publication number | Publication date |
|---|---|
| PT3118251T (pt) | 2021-04-09 |
| EP3118251A1 (en) | 2017-01-18 |
| US20170073509A1 (en) | 2017-03-16 |
| CA2942255C (en) | 2021-08-17 |
| CN106164160A (zh) | 2016-11-23 |
| JPWO2015137295A1 (ja) | 2017-04-06 |
| CA2942255A1 (en) | 2015-09-17 |
| KR20160134689A (ko) | 2016-11-23 |
| HUE054116T2 (hu) | 2021-08-30 |
| CN106164160B (zh) | 2019-05-14 |
| EP3118251A4 (en) | 2017-12-06 |
| JP2016172859A (ja) | 2016-09-29 |
| WO2015137295A1 (ja) | 2015-09-17 |
| EP3118251B1 (en) | 2021-03-10 |
| JP5922850B2 (ja) | 2016-05-24 |
| KR102270880B1 (ko) | 2021-06-29 |
| TW201538584A (zh) | 2015-10-16 |
| US10370525B2 (en) | 2019-08-06 |
| CN110256742A (zh) | 2019-09-20 |
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