TWI621639B - 環氧樹脂組成物及預浸漬物 - Google Patents
環氧樹脂組成物及預浸漬物 Download PDFInfo
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- TWI621639B TWI621639B TW103100348A TW103100348A TWI621639B TW I621639 B TWI621639 B TW I621639B TW 103100348 A TW103100348 A TW 103100348A TW 103100348 A TW103100348 A TW 103100348A TW I621639 B TWI621639 B TW I621639B
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- epoxy resin
- resin composition
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- cured
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- 239000012778 molding material Substances 0.000 description 1
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- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229920006284 nylon film Polymers 0.000 description 1
- GJTUEPSATYEPPR-UHFFFAOYSA-N octan-1-amine;trichloroborane Chemical compound ClB(Cl)Cl.CCCCCCCCN GJTUEPSATYEPPR-UHFFFAOYSA-N 0.000 description 1
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- 150000002924 oxiranes Chemical class 0.000 description 1
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- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
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- 229920000768 polyamine Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
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- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
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- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
- SDQCGKJCBWXRMK-UHFFFAOYSA-N propan-2-yl 4-methylbenzenesulfonate Chemical compound CC(C)OS(=O)(=O)C1=CC=C(C)C=C1 SDQCGKJCBWXRMK-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1477—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3227—Compounds containing acyclic nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Reinforced Plastic Materials (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361749703P | 2013-01-07 | 2013-01-07 | |
| US61/749703 | 2013-01-07 | ||
| US201361911386P | 2013-12-03 | 2013-12-03 | |
| US61/911386 | 2013-12-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201430007A TW201430007A (zh) | 2014-08-01 |
| TWI621639B true TWI621639B (zh) | 2018-04-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| TW103100348A TWI621639B (zh) | 2013-01-07 | 2014-01-06 | 環氧樹脂組成物及預浸漬物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9982086B2 (enExample) |
| EP (1) | EP2941452B1 (enExample) |
| JP (1) | JP6394610B2 (enExample) |
| KR (1) | KR102102191B1 (enExample) |
| CN (1) | CN104918987B (enExample) |
| TW (1) | TWI621639B (enExample) |
| WO (1) | WO2014107725A1 (enExample) |
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| JP6612498B2 (ja) * | 2014-11-21 | 2019-11-27 | スリーエム イノベイティブ プロパティズ カンパニー | エポキシ接着剤、並びに自動車用部材及びその製造方法 |
| EP3230339B1 (en) * | 2014-12-02 | 2022-03-23 | Toray Industries, Inc. | Epoxy resin composition, prepreg, fiber-reinforced plastic material, and manufacturing method for fiber-reinforced plastic material |
| KR102389775B1 (ko) * | 2015-02-09 | 2022-04-22 | 도레이 카부시키가이샤 | 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합재료 |
| US10327429B2 (en) | 2015-06-02 | 2019-06-25 | G-Rods International Llc | Incorporation of graphene in various components and method of manufacturing |
| US10064400B2 (en) | 2015-06-02 | 2018-09-04 | G-Rods International Llc | Fishing rod with graphene and method of manufacturing |
| WO2017038880A1 (ja) * | 2015-09-03 | 2017-03-09 | 東レ株式会社 | エポキシ樹脂組成物、プリプレグおよび炭素繊維強化複合材料 |
| JP6938897B2 (ja) * | 2015-12-10 | 2021-09-22 | 三菱ケミカル株式会社 | 内圧成形用プリプレグ、及び繊維強化複合材料の製造方法 |
| CN109312057B (zh) * | 2016-06-24 | 2021-09-03 | Sk化学株式会社 | 用于纤维增强复合材料的环氧树脂组合物及利用它的预浸料 |
| WO2017222339A1 (ko) * | 2016-06-24 | 2017-12-28 | 에스케이케미칼주식회사 | 섬유강화 복합재료용 에폭시 수지 조성물 및 이를 이용한 프리프레그 |
| CN105949962B (zh) * | 2016-07-18 | 2019-01-04 | 郑州四维特种材料有限责任公司 | 一种自发光环氧树脂液及其制备方法，自发光环氧树脂复合材料，自发光碳纤维预浸料 |
| KR102428285B1 (ko) * | 2016-09-13 | 2022-08-08 | 주식회사 테크위드 | 자전거 림을 위한 고온 수지 조성물 및 이를 이용한 자전거 림 |
| CN106626617B (zh) * | 2016-09-14 | 2018-12-18 | 四川东材科技集团股份有限公司 | 一种玻璃纤维毡层压板及其制备方法 |
| KR20180035990A (ko) * | 2016-09-29 | 2018-04-09 | 현대자동차주식회사 | 복층 프리프레그 구조 및 그 제조방법 |
| JP6995779B2 (ja) | 2016-12-27 | 2022-01-17 | 日鉄ケミカル＆マテリアル株式会社 | 硬化性エポキシ樹脂組成物、及びそれを用いた繊維強化複合材料 |
| JP6928908B2 (ja) * | 2017-04-07 | 2021-09-01 | パナソニックＩｐマネジメント株式会社 | プリプレグ、金属張積層板、プリント配線板及びフレックスリジッドプリント配線板 |
| US20200079917A1 (en) * | 2017-05-10 | 2020-03-12 | Toray Industries, Inc. | Method for producing fiber-reinforced composite material |
| EP3642256A1 (en) * | 2017-06-20 | 2020-04-29 | Dow Global Technologies LLC | Epoxy resin system for making fiber reinforced composites |
| KR102341161B1 (ko) * | 2017-08-10 | 2021-12-20 | 도레이첨단소재 주식회사 | 저밀도 프리프레그 및 이를 포함하는 샌드위치 복합 성형품 |
| US11427707B2 (en) | 2017-09-29 | 2022-08-30 | Nippon Steel Chemical & Material Co., Ltd. | Curable epoxy resin composition and fiber-reinforced composite material using same |
| CN111868149A (zh) * | 2018-03-01 | 2020-10-30 | 塞特工业公司 | 具有一致处理特征的快速固化树脂配制品 |
| JP7092263B2 (ja) * | 2019-05-28 | 2022-06-28 | Dic株式会社 | 成形材料、シートモールディングコンパウンド、及び成形品 |
| CN111073219A (zh) * | 2019-12-31 | 2020-04-28 | 达森(天津)材料科技有限公司 | 海绵城市建设高强度抗黄变抗冻融环氧树脂的制备方法 |
| CN112250999A (zh) * | 2020-10-21 | 2021-01-22 | 广德龙泰电子科技有限公司 | 一种耐热性环氧树脂组合物、无卤中Tg覆铜板及其制备方法 |
| JPWO2023053834A1 (enExample) * | 2021-09-29 | 2023-04-06 | ||
| CN116178894A (zh) * | 2023-02-03 | 2023-05-30 | 安徽恒泰新材料科技股份有限公司 | 一种环氧树脂复合材料及其处理装置 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010053278A (ja) * | 2008-08-29 | 2010-03-11 | Toray Ind Inc | エポキシ樹脂組成物、プリプレグ、および、繊維強化複合材料、ならびに、繊維強化複合材料の製造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58167625A (ja) * | 1982-03-26 | 1983-10-03 | Toho Rayon Co Ltd | プリプレグ |
| CA1243040A (en) * | 1982-08-12 | 1988-10-11 | Paul D. Mclean | Epoxy resin fortifiers based on aromatic amides |
| JPS63152644A (ja) * | 1987-11-21 | 1988-06-25 | Toho Rayon Co Ltd | プリプレグ |
| JPH0639519B2 (ja) * | 1988-12-02 | 1994-05-25 | 東邦レーヨン株式会社 | エポキシ樹脂組成物及びプリプレグ |
| US20030082385A1 (en) * | 2001-07-13 | 2003-05-01 | Toray Composites (America), Inc. | Quick cure carbon fiber reinforced epoxy resin |
| US7208228B2 (en) * | 2003-04-23 | 2007-04-24 | Toray Composites (America), Inc. | Epoxy resin for fiber reinforced composite materials |
| US8278389B2 (en) * | 2007-05-16 | 2012-10-02 | Toray Industries, Ltd. | Epoxy resin composition, prepreg, fiber-reinforced composite material |
| JP5061813B2 (ja) * | 2007-09-25 | 2012-10-31 | 東レ株式会社 | プリプレグおよびゴルフクラブシャフト |
| JP5175660B2 (ja) | 2008-08-27 | 2013-04-03 | 朝日電装株式会社 | スロットルグリップ装置 |
| JP5327964B2 (ja) * | 2009-04-16 | 2013-10-30 | 三菱レイヨン株式会社 | プレス成形用プリプレグ、及びそれを用いた成形品の製造方法 |
| TW201229084A (en) * | 2010-11-08 | 2012-07-16 | Toray Industries | Epoxy resin composition for fiber reinforced composite material prepreg, and fiber reinforced composite material |
| JP6008958B2 (ja) | 2011-06-30 | 2016-10-19 | ダウ グローバル テクノロジーズ エルエルシー | アミン硬化剤の混合物及び過剰のエポキシ基を含む硬化性エポキシ樹脂系 |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2010053278A (ja) * | 2008-08-29 | 2010-03-11 | Toray Ind Inc | エポキシ樹脂組成物、プリプレグ、および、繊維強化複合材料、ならびに、繊維強化複合材料の製造方法 |
Also Published As
| Publication number | Publication date |
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| TW201430007A (zh) | 2014-08-01 |
| US20160002390A1 (en) | 2016-01-07 |
| CN104918987B (zh) | 2018-11-06 |
| JP6394610B2 (ja) | 2018-09-26 |
| EP2941452A1 (en) | 2015-11-11 |
| KR102102191B1 (ko) | 2020-04-21 |
| EP2941452A4 (en) | 2016-08-10 |
| CN104918987A (zh) | 2015-09-16 |
| WO2014107725A9 (en) | 2014-09-18 |
| WO2014107725A1 (en) | 2014-07-10 |
| JP2016504472A (ja) | 2016-02-12 |
| EP2941452B1 (en) | 2018-12-26 |
| US9982086B2 (en) | 2018-05-29 |
| KR20150104120A (ko) | 2015-09-14 |
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| Publication | Publication Date | Title |
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