TWI600538B - 改良斷裂韌性之增韌顆粒 - Google Patents

改良斷裂韌性之增韌顆粒 Download PDF

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Publication number
TWI600538B
TWI600538B TW102140927A TW102140927A TWI600538B TW I600538 B TWI600538 B TW I600538B TW 102140927 A TW102140927 A TW 102140927A TW 102140927 A TW102140927 A TW 102140927A TW I600538 B TWI600538 B TW I600538B
Authority
TW
Taiwan
Prior art keywords
particles
resin
insoluble
curable
curable resin
Prior art date
Application number
TW102140927A
Other languages
English (en)
Chinese (zh)
Other versions
TW201425021A (zh
Inventor
艾米利亞諾 佛羅尼
文森 艾爾茲
山繆 希爾
Original Assignee
塞特工業公司
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Application filed by 塞特工業公司 filed Critical 塞特工業公司
Publication of TW201425021A publication Critical patent/TW201425021A/zh
Application granted granted Critical
Publication of TWI600538B publication Critical patent/TWI600538B/zh

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/04Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/12Mixture of at least two particles made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/30Fillers, e.g. particles, powders, beads, flakes, spheres, chips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/72Cured, e.g. vulcanised, cross-linked
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/56Damping, energy absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2363/00Epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00Characterised by the use of unspecified polymers
    • C08J2300/22Thermoplastic resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249924Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994Fiber embedded in or on the surface of a polymeric matrix
    • Y10T428/24995Two or more layers
    • Y10T428/249952At least one thermosetting synthetic polymeric material layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Moulding By Coating Moulds (AREA)
TW102140927A 2012-12-19 2013-11-11 改良斷裂韌性之增韌顆粒 TWI600538B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB201222934A GB201222934D0 (en) 2012-12-19 2012-12-19 Particle toughening for improving fracture toughness

Publications (2)

Publication Number Publication Date
TW201425021A TW201425021A (zh) 2014-07-01
TWI600538B true TWI600538B (zh) 2017-10-01

Family

ID=47631022

Family Applications (1)

Application Number Title Priority Date Filing Date
TW102140927A TWI600538B (zh) 2012-12-19 2013-11-11 改良斷裂韌性之增韌顆粒

Country Status (15)

Country Link
US (2) US9517608B2 (fr)
EP (1) EP2900738B1 (fr)
JP (2) JP2016509082A (fr)
KR (1) KR20150095686A (fr)
CN (1) CN104781320B (fr)
AU (1) AU2013364187B2 (fr)
BR (1) BR112015010443B1 (fr)
CA (1) CA2895406A1 (fr)
ES (1) ES2590655T3 (fr)
GB (1) GB201222934D0 (fr)
MX (1) MX2015005716A (fr)
MY (1) MY182455A (fr)
RU (1) RU2616693C2 (fr)
TW (1) TWI600538B (fr)
WO (1) WO2014099149A1 (fr)

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US9567426B2 (en) 2009-05-29 2017-02-14 Cytec Technology Corp. Engineered crosslinked thermoplastic particles for interlaminar toughening
CN106459560B (zh) 2014-05-22 2019-05-10 塞特工业公司 用作增韧剂的官能化聚合物颗粒
US10472472B2 (en) 2014-09-23 2019-11-12 The Boeing Company Placement of modifier material in resin-rich pockets to mitigate microcracking in a composite structure
US9587076B2 (en) * 2014-09-23 2017-03-07 The Boeing Company Polymer nanoparticles for controlling resin reaction rates
US10808123B2 (en) 2014-09-23 2020-10-20 The Boeing Company Nanoparticles for improving the dimensional stability of resins
US10662302B2 (en) 2014-09-23 2020-05-26 The Boeing Company Polymer nanoparticles for improved distortion capability in composites
US10072126B2 (en) * 2014-09-23 2018-09-11 The Boeing Company Soluble nanoparticles for composite performance enhancement
JP6600982B2 (ja) * 2015-05-11 2019-11-06 三菱ケミカル株式会社 繊維強化プラスチック成形体及びその製造方法、並びに積層体
US10427382B2 (en) * 2015-10-29 2019-10-01 King Abdulaziz University Composite epoxy material with embedded MWCNT fibers and process of manufacturing
US10427378B2 (en) * 2015-10-29 2019-10-01 King Abdulaziz University Composite epoxy material with embedded silicon carbide and alumina nanoparticles
WO2017127644A1 (fr) * 2016-01-20 2017-07-27 Zephyros, Inc. Matériaux époxy thermoplastiques à phase cœur-écorce
US10472474B2 (en) 2016-06-22 2019-11-12 Hexcel Corporation Semipreg with thermoplastic toughened novolac-based epoxy resin matrix
US10106661B2 (en) 2016-06-22 2018-10-23 Hexcel Corporation Composite material with thermoplastic toughened novolac-based epoxy resin matrix
US10208176B2 (en) 2016-06-22 2019-02-19 Hexcel Corporation Composite material with thermoplastic toughened novolac-based epoxy resin matrix
CN110612205B (zh) 2017-03-07 2022-05-03 塞特工业公司 具有结构和阻燃能力的复合材料
US10710348B2 (en) 2017-07-26 2020-07-14 The Boeing Company Methods and apparatus to increase fire resistance and fracture toughness of a composite structure
CN111448244B (zh) * 2017-12-12 2023-04-07 赫克赛尔公司 具有热塑性增韧的线型酚醛基环氧树脂基质的半浸料
CN111087756A (zh) * 2018-10-23 2020-05-01 中国石油化工股份有限公司 耐高温高韧性预浸料及其制备方法
US20220041825A1 (en) * 2018-12-21 2022-02-10 Cytec Industries Inc. Toughened composite materials capable of delamination propagation resistance
US11376812B2 (en) 2020-02-11 2022-07-05 Helicoid Industries Inc. Shock and impact resistant structures
WO2022256022A1 (fr) 2021-06-01 2022-12-08 Helicoid Industries Inc. Contenants et procédés de protection de cuves sous pression
US11852297B2 (en) 2021-06-01 2023-12-26 Helicoid Industries Inc. Containers and methods for protecting pressure vessels
US11952103B2 (en) 2022-06-27 2024-04-09 Helicoid Industries Inc. High impact-resistant, reinforced fiber for leading edge protection of aerodynamic structures

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WO2009032809A1 (fr) * 2007-09-07 2009-03-12 Cytec Technology Corp. Matériaux composites et leurs utilisations
US20110048637A1 (en) * 2009-08-31 2011-03-03 Cytec Technology Corp. High performance adhesive compositions
TW201220977A (en) * 2010-07-01 2012-05-16 Sumitomo Bakelite Co Preppreg, circuit board, and semiconductor device
TW201221356A (en) * 2010-11-01 2012-06-01 Cytec Tech Corp Targeted deposition of particles on substrates used in the manufacture of composite articles
TW201229126A (en) * 2010-12-22 2012-07-16 Cytec Tech Corp Epoxy resin system containing insoluble and partially soluble or swellable toughening particles for use in prepreg and structural component applications

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US4957801A (en) * 1989-05-17 1990-09-18 American Cyanamid Company Advance composites with thermoplastic particles at the interface between layers
WO2009032809A1 (fr) * 2007-09-07 2009-03-12 Cytec Technology Corp. Matériaux composites et leurs utilisations
US20110048637A1 (en) * 2009-08-31 2011-03-03 Cytec Technology Corp. High performance adhesive compositions
TW201220977A (en) * 2010-07-01 2012-05-16 Sumitomo Bakelite Co Preppreg, circuit board, and semiconductor device
TW201221356A (en) * 2010-11-01 2012-06-01 Cytec Tech Corp Targeted deposition of particles on substrates used in the manufacture of composite articles
TW201229126A (en) * 2010-12-22 2012-07-16 Cytec Tech Corp Epoxy resin system containing insoluble and partially soluble or swellable toughening particles for use in prepreg and structural component applications

Also Published As

Publication number Publication date
JP2018024879A (ja) 2018-02-15
BR112015010443A2 (pt) 2017-07-11
ES2590655T3 (es) 2016-11-23
US20140170408A1 (en) 2014-06-19
CA2895406A1 (fr) 2014-06-26
US20160271927A1 (en) 2016-09-22
CN104781320B (zh) 2018-05-29
US9517608B2 (en) 2016-12-13
MX2015005716A (es) 2015-08-20
EP2900738B1 (fr) 2016-06-15
EP2900738A1 (fr) 2015-08-05
MY182455A (en) 2021-01-25
JP2016509082A (ja) 2016-03-24
GB201222934D0 (en) 2013-01-30
CN104781320A (zh) 2015-07-15
TW201425021A (zh) 2014-07-01
RU2015129475A (ru) 2017-01-25
AU2013364187B2 (en) 2015-09-10
BR112015010443B1 (pt) 2021-11-23
KR20150095686A (ko) 2015-08-21
AU2013364187A1 (en) 2015-05-14
JP6574463B2 (ja) 2019-09-11
WO2014099149A1 (fr) 2014-06-26
RU2616693C2 (ru) 2017-04-18

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