TWI404699B

TWI404699B - 鹽起始劑

鹽起始劑 Download PDF

Info

Publication number: TWI404699B
Authority: TW; Taiwan
Prior art keywords: acid; group; compound; substituted; alkyl
Prior art date: 2006-04-13

Application number

TW096112895A

Other languages

English (en)

Chinese (zh)

Other versions

TW200804260A (en

Inventor

Pascal Hayoz

Stephan Ilg

Original Assignee

Ciba Sc Holding Ag

Priority date

2006-04-13

Filing date

2007-04-12

Publication date

2013-08-11

2007-04-12 Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag

2008-01-16 Publication of TW200804260A publication Critical patent/TW200804260A/zh

2013-08-11 Application granted granted Critical

2013-08-11 Publication of TWI404699B publication Critical patent/TWI404699B/zh

Links

239000003999 initiator Substances 0.000 title description 4
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title description 2
150000001875 compounds Chemical class 0.000 claims abstract description 180
239000001257 hydrogen Substances 0.000 claims abstract description 102
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 102
239000002253 acid Substances 0.000 claims abstract description 68
229910052760 oxygen Inorganic materials 0.000 claims abstract description 56
229910052717 sulfur Inorganic materials 0.000 claims abstract description 55
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 24
150000001449 anionic compounds Chemical class 0.000 claims abstract description 15
150000002891 organic anions Chemical class 0.000 claims abstract description 15
-1 R 1 Chemical class 0.000 claims description 178
239000000203 mixture Substances 0.000 claims description 109
125000000217 alkyl group Chemical group 0.000 claims description 105
150000002431 hydrogen Chemical class 0.000 claims description 76
125000000753 cycloalkyl group Chemical group 0.000 claims description 54
238000000576 coating method Methods 0.000 claims description 51
238000000034 method Methods 0.000 claims description 49
229910052736 halogen Inorganic materials 0.000 claims description 48
150000002367 halogens Chemical class 0.000 claims description 48
125000003118 aryl group Chemical group 0.000 claims description 35
GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 claims description 33
238000002360 preparation method Methods 0.000 claims description 33
229920005989 resin Polymers 0.000 claims description 33
239000011347 resin Substances 0.000 claims description 33
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 30
230000005855 radiation Effects 0.000 claims description 28
238000004519 manufacturing process Methods 0.000 claims description 27
239000003054 catalyst Substances 0.000 claims description 26
239000000463 material Substances 0.000 claims description 21
229920002554 vinyl polymer Polymers 0.000 claims description 21
150000001450 anions Chemical class 0.000 claims description 19
125000005915 C6-C14 aryl group Chemical group 0.000 claims description 18
125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 17
125000003342 alkenyl group Chemical group 0.000 claims description 17
239000000758 substrate Substances 0.000 claims description 17
238000007639 printing Methods 0.000 claims description 16
239000000654 additive Substances 0.000 claims description 14
LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 12
239000011230 binding agent Substances 0.000 claims description 11
125000000392 cycloalkenyl group Chemical group 0.000 claims description 11
125000005010 perfluoroalkyl group Chemical group 0.000 claims description 11
239000008199 coating composition Substances 0.000 claims description 10
230000008569 process Effects 0.000 claims description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
230000009471 action Effects 0.000 claims description 7
229910052799 carbon Inorganic materials 0.000 claims description 7
150000001767 cationic compounds Chemical class 0.000 claims description 7
150000002892 organic cations Chemical class 0.000 claims description 7
125000006755 (C2-C20) alkyl group Chemical group 0.000 claims description 6
125000002091 cationic group Chemical group 0.000 claims description 6
239000000945 filler Substances 0.000 claims description 5
229910017008 AsF 6 Inorganic materials 0.000 claims description 4
229910018286 SbF 6 Inorganic materials 0.000 claims description 4
230000000996 additive effect Effects 0.000 claims description 4
230000000181 anti-adherent effect Effects 0.000 claims description 4
239000002243 precursor Substances 0.000 claims description 4
239000000843 powder Substances 0.000 claims description 3
125000005647 linker group Chemical group 0.000 abstract description 8
229920000180 alkyd Polymers 0.000 description 60
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 50
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 43
238000006243 chemical reaction Methods 0.000 description 41
239000011248 coating agent Substances 0.000 description 40
125000002887 hydroxy group Chemical group [H]O* 0.000 description 35
GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 32
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 31
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 27
229920001577 copolymer Polymers 0.000 description 26
229920000642 polymer Polymers 0.000 description 25
238000005160 1H NMR spectroscopy Methods 0.000 description 24
239000000178 monomer Substances 0.000 description 24
238000009472 formulation Methods 0.000 description 23
239000004593 Epoxy Substances 0.000 description 22
KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Substances CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 22
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 21
229920005862 polyol Polymers 0.000 description 21
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 19
229910002091 carbon monoxide Inorganic materials 0.000 description 19
239000012948 isocyanate Substances 0.000 description 19
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 19
239000000126 substance Substances 0.000 description 19
150000001252 acrylic acid derivatives Chemical class 0.000 description 18
239000002904 solvent Substances 0.000 description 18
229960000834 vinyl ether Drugs 0.000 description 18
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 17
125000001931 aliphatic group Chemical group 0.000 description 17
229920002120 photoresistant polymer Polymers 0.000 description 17
239000000049 pigment Substances 0.000 description 17
150000003254 radicals Chemical class 0.000 description 17
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 16
150000002513 isocyanates Chemical class 0.000 description 16
150000003077 polyols Chemical class 0.000 description 16
239000004814 polyurethane Substances 0.000 description 16
229920002635 polyurethane Polymers 0.000 description 16
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 15
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 15
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 15
POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 15
125000000524 functional group Chemical group 0.000 description 15
229920000728 polyester Polymers 0.000 description 15
239000000600 sorbitol Substances 0.000 description 15
125000003277 amino group Chemical group 0.000 description 14
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 14
229920000647 polyepoxide Polymers 0.000 description 14
238000005727 Friedel-Crafts reaction Methods 0.000 description 13
229920000877 Melamine resin Polymers 0.000 description 13
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
150000002148 esters Chemical class 0.000 description 12
239000010410 layer Substances 0.000 description 12
229910052751 metal Inorganic materials 0.000 description 12
239000002184 metal Substances 0.000 description 12
229920001228 polyisocyanate Polymers 0.000 description 12
239000005056 polyisocyanate Substances 0.000 description 12
239000004925 Acrylic resin Substances 0.000 description 11
DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 11
150000001241 acetals Chemical class 0.000 description 11
150000001412 amines Chemical class 0.000 description 11
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 11
125000003700 epoxy group Chemical group 0.000 description 11
239000003607 modifier Substances 0.000 description 11
DJNIFZYQFLFGDT-UHFFFAOYSA-N 1-(4-phenoxyphenyl)ethanone Chemical compound C1=CC(C(=O)C)=CC=C1OC1=CC=CC=C1 DJNIFZYQFLFGDT-UHFFFAOYSA-N 0.000 description 10
150000007513 acids Chemical class 0.000 description 10
239000000976 ink Substances 0.000 description 10
229920000570 polyether Polymers 0.000 description 10
239000000047 product Substances 0.000 description 10
125000003837 (C1-C20) alkyl group Chemical group 0.000 description 9
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
239000000853 adhesive Substances 0.000 description 9
230000001070 adhesive effect Effects 0.000 description 9
125000004432 carbon atom Chemical group C* 0.000 description 9
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 9
150000001735 carboxylic acids Chemical class 0.000 description 9
150000002009 diols Chemical class 0.000 description 9
238000010438 heat treatment Methods 0.000 description 9
229920000178 Acrylic resin Polymers 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 8
150000002118 epoxides Chemical class 0.000 description 8
125000004185 ester group Chemical group 0.000 description 8
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 8
229910052757 nitrogen Inorganic materials 0.000 description 8
239000005011 phenolic resin Substances 0.000 description 8
229920000058 polyacrylate Polymers 0.000 description 8
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
239000007787 solid Substances 0.000 description 8
239000003381 stabilizer Substances 0.000 description 8
125000001424 substituent group Chemical group 0.000 description 8
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 8
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 7
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
239000004721 Polyphenylene oxide Substances 0.000 description 7
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 7
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 7
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 7
239000012952 cationic photoinitiator Substances 0.000 description 7
238000001723 curing Methods 0.000 description 7
125000004122 cyclic group Chemical group 0.000 description 7
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 7
239000000975 dye Substances 0.000 description 7
239000003822 epoxy resin Substances 0.000 description 7
150000002170 ethers Chemical class 0.000 description 7
229910052731 fluorine Inorganic materials 0.000 description 7
235000011187 glycerol Nutrition 0.000 description 7
150000002576 ketones Chemical class 0.000 description 7
239000007788 liquid Substances 0.000 description 7
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 7
239000011976 maleic acid Substances 0.000 description 7
229920001568 phenolic resin Polymers 0.000 description 7
229920000768 polyamine Polymers 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
238000005809 transesterification reaction Methods 0.000 description 7
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
239000000460 chlorine Substances 0.000 description 6
238000004132 cross linking Methods 0.000 description 6
235000014113 dietary fatty acids Nutrition 0.000 description 6
238000005516 engineering process Methods 0.000 description 6
229940052303 ethers for general anesthesia Drugs 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
229930195729 fatty acid Natural products 0.000 description 6
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
150000002734 metacrylic acid derivatives Chemical class 0.000 description 6
230000000269 nucleophilic effect Effects 0.000 description 6
150000004714 phosphonium salts Chemical class 0.000 description 6
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
229920001225 polyester resin Polymers 0.000 description 6
229920006395 saturated elastomer Polymers 0.000 description 6
239000007858 starting material Substances 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 5
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
239000002202 Polyethylene glycol Substances 0.000 description 5
239000000370 acceptor Substances 0.000 description 5
238000007259 addition reaction Methods 0.000 description 5
229910052782 aluminium Inorganic materials 0.000 description 5
150000008064 anhydrides Chemical class 0.000 description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 5
229940106691 bisphenol a Drugs 0.000 description 5
238000006555 catalytic reaction Methods 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
125000005442 diisocyanate group Chemical group 0.000 description 5
238000001704 evaporation Methods 0.000 description 5
230000008020 evaporation Effects 0.000 description 5
150000004665 fatty acids Chemical class 0.000 description 5
239000011737 fluorine Substances 0.000 description 5
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 5
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
239000004645 polyester resin Substances 0.000 description 5
229920001223 polyethylene glycol Polymers 0.000 description 5
YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 5
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 4
PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 4
KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
LSTZTHCEEPHCNQ-UHFFFAOYSA-N 3-(2,5-dioxabicyclo[2.1.0]pentan-3-yloxy)-2,5-dioxabicyclo[2.1.0]pentane Chemical compound C1(C2C(O2)O1)OC1C2C(O2)O1 LSTZTHCEEPHCNQ-UHFFFAOYSA-N 0.000 description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
241000208340 Araliaceae Species 0.000 description 4
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 4
235000003140 Panax quinquefolius Nutrition 0.000 description 4
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 4
125000002723 alicyclic group Chemical group 0.000 description 4
125000003545 alkoxy group Chemical group 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 4
125000005228 aryl sulfonate group Chemical group 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
238000009835 boiling Methods 0.000 description 4
239000004359 castor oil Substances 0.000 description 4
235000019438 castor oil Nutrition 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
229920002678 cellulose Polymers 0.000 description 4
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 4
238000011161 development Methods 0.000 description 4
125000004386 diacrylate group Chemical group 0.000 description 4
150000005690 diesters Chemical class 0.000 description 4
238000010894 electron beam technology Methods 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
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