TWI395773B - 可交聯之纖維素酯組合物及由其形成之薄膜 - Google Patents
可交聯之纖維素酯組合物及由其形成之薄膜 Download PDFInfo
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- TWI395773B TWI395773B TW95118853A TW95118853A TWI395773B TW I395773 B TWI395773 B TW I395773B TW 95118853 A TW95118853 A TW 95118853A TW 95118853 A TW95118853 A TW 95118853A TW I395773 B TWI395773 B TW I395773B
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- Prior art keywords
- cellulose
- group
- film
- polarizing plate
- butyrate
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- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 210000002858 crystal cell Anatomy 0.000 description 1
- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005401 electroluminescence Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical class CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 210000000416 exudates and transudate Anatomy 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
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- 239000010419 fine particle Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000005968 oxazolinyl group Chemical group 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
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- 239000000049 pigment Substances 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 229960005335 propanol Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000001448 refractive index detection Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/005—Crosslinking of cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
- C08L1/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
- C08L1/14—Mixed esters, e.g. cellulose acetate-butyrate
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3083—Birefringent or phase retarding elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Polarising Elements (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Liquid Crystal (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68480805P | 2005-05-26 | 2005-05-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200704684A TW200704684A (en) | 2007-02-01 |
| TWI395773B true TWI395773B (zh) | 2013-05-11 |
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| TW95118853A TWI395773B (zh) | 2005-05-26 | 2006-05-26 | 可交聯之纖維素酯組合物及由其形成之薄膜 |
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|---|---|
| US (2) | US8304086B2 (https=) |
| EP (2) | EP1883531B1 (https=) |
| JP (2) | JP4965563B2 (https=) |
| KR (2) | KR20130045952A (https=) |
| CN (2) | CN101184618B (https=) |
| TW (1) | TWI395773B (https=) |
| WO (1) | WO2006127834A2 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US8304086B2 (en) * | 2005-05-26 | 2012-11-06 | Eastman Chemical Company | Crosslinkable, cellulose ester compositions and films formed therefrom |
| US8349921B2 (en) | 2007-08-24 | 2013-01-08 | Eastman Chemical Company | Mixed cellulose ester films having +C plate and −A plate optical properties |
| WO2009029220A1 (en) * | 2007-08-24 | 2009-03-05 | Eastman Chemical Company | Mixed cellulose esters having low bifringence and films made therefrom |
| US9068063B2 (en) | 2010-06-29 | 2015-06-30 | Eastman Chemical Company | Cellulose ester/elastomer compositions |
| US9273195B2 (en) | 2010-06-29 | 2016-03-01 | Eastman Chemical Company | Tires comprising cellulose ester/elastomer compositions |
| US9708474B2 (en) | 2011-12-07 | 2017-07-18 | Eastman Chemical Company | Cellulose esters in pneumatic tires |
| US9523794B2 (en) * | 2013-03-07 | 2016-12-20 | Konica Minolta, Inc. | Optical film of cellulose ester and cellulose ether for vertical alignment liquid crystal displays |
| KR20150143715A (ko) * | 2013-05-17 | 2015-12-23 | 코니카 미놀타 가부시키가이샤 | 편광판 및 그것을 구비한 표시 장치 |
| TWI529206B (zh) * | 2014-12-12 | 2016-04-11 | 財團法人紡織產業綜合研究所 | 酯化纖維素薄膜及其製備方法 |
| CN106279453B (zh) * | 2015-05-28 | 2019-12-10 | 易媛 | 交联的高分子化合物及其制备方法、水凝胶、水基压裂液和用途 |
| US10077342B2 (en) | 2016-01-21 | 2018-09-18 | Eastman Chemical Company | Elastomeric compositions comprising cellulose ester additives |
| KR20170123828A (ko) * | 2016-04-29 | 2017-11-09 | 동우 화인켐 주식회사 | 편광판 및 이를 포함하는 액정표시장치 |
| KR20180000577A (ko) * | 2016-06-23 | 2018-01-03 | 동우 화인켐 주식회사 | 편광판 및 이를 포함하는 액정표시장치 |
| JP7127327B2 (ja) * | 2018-03-29 | 2022-08-30 | 東ソー株式会社 | セルロース系樹脂組成物およびそれを用いた光学フィルム |
| US11384224B1 (en) * | 2018-10-05 | 2022-07-12 | Celanese International Corporation | Cellulose acetate film with optical properties |
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| JP4479175B2 (ja) | 2003-06-06 | 2010-06-09 | コニカミノルタオプト株式会社 | ハードコートフィルム、その製造方法、偏光板及び表示装置 |
| JP2005115341A (ja) * | 2003-09-16 | 2005-04-28 | Fuji Photo Film Co Ltd | 光学補償シート、偏光板及びそれを用いた液晶表示装置 |
| JP4330410B2 (ja) * | 2003-09-22 | 2009-09-16 | 富士フイルム株式会社 | セルロースフィルム、偏光板および液晶表示装置 |
| US8304086B2 (en) * | 2005-05-26 | 2012-11-06 | Eastman Chemical Company | Crosslinkable, cellulose ester compositions and films formed therefrom |
-
2006
- 2006-05-23 US US11/439,002 patent/US8304086B2/en not_active Expired - Fee Related
- 2006-05-24 CN CN2006800182817A patent/CN101184618B/zh not_active Expired - Fee Related
- 2006-05-24 KR KR1020137009618A patent/KR20130045952A/ko not_active Ceased
- 2006-05-24 EP EP20060760349 patent/EP1883531B1/en not_active Not-in-force
- 2006-05-24 WO PCT/US2006/020123 patent/WO2006127834A2/en not_active Ceased
- 2006-05-24 KR KR1020077027306A patent/KR101323545B1/ko not_active Expired - Fee Related
- 2006-05-24 CN CN201010173889A patent/CN101840016A/zh active Pending
- 2006-05-24 JP JP2008513682A patent/JP4965563B2/ja not_active Expired - Fee Related
- 2006-05-24 EP EP20100003617 patent/EP2196311A3/en not_active Withdrawn
- 2006-05-26 TW TW95118853A patent/TWI395773B/zh not_active IP Right Cessation
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2012
- 2012-01-26 JP JP2012014286A patent/JP2012098752A/ja active Pending
- 2012-04-11 US US13/444,183 patent/US8449939B2/en not_active Expired - Fee Related
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| US3833289A (en) * | 1970-05-28 | 1974-09-03 | Polaroid Corp | Composite light-polarizing element |
| JP2003128838A (ja) * | 2001-10-23 | 2003-05-08 | Fuji Photo Film Co Ltd | セルロースアシレートドープ溶液およびそれを用いたセルロースアシレートフィルムの製造方法 |
| TW200422660A (en) * | 2002-10-24 | 2004-11-01 | Fuji Photo Film Co Ltd | Process for producing cellulose acylate film, cellulose acylate film, optical compensation sheet, polarizing plate, and image display device |
| JP2004292558A (ja) * | 2003-03-26 | 2004-10-21 | Konica Minolta Holdings Inc | セルロースエステルフィルムとその製造方法および偏光板保護フィルム |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101323545B1 (ko) | 2013-10-29 |
| US8304086B2 (en) | 2012-11-06 |
| CN101840016A (zh) | 2010-09-22 |
| JP4965563B2 (ja) | 2012-07-04 |
| TW200704684A (en) | 2007-02-01 |
| EP1883531B1 (en) | 2014-03-12 |
| WO2006127834A2 (en) | 2006-11-30 |
| US20060286397A1 (en) | 2006-12-21 |
| EP1883531A2 (en) | 2008-02-06 |
| US20120222793A1 (en) | 2012-09-06 |
| CN101184618A (zh) | 2008-05-21 |
| US8449939B2 (en) | 2013-05-28 |
| JP2008546011A (ja) | 2008-12-18 |
| WO2006127834A3 (en) | 2007-06-07 |
| EP2196311A3 (en) | 2010-07-07 |
| JP2012098752A (ja) | 2012-05-24 |
| KR20130045952A (ko) | 2013-05-06 |
| CN101184618B (zh) | 2012-09-05 |
| KR20080013930A (ko) | 2008-02-13 |
| EP2196311A2 (en) | 2010-06-16 |
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