TWI390026B - 吸附灰塵用油劑 - Google Patents
吸附灰塵用油劑 Download PDFInfo
- Publication number
- TWI390026B TWI390026B TW94146766A TW94146766A TWI390026B TW I390026 B TWI390026 B TW I390026B TW 94146766 A TW94146766 A TW 94146766A TW 94146766 A TW94146766 A TW 94146766A TW I390026 B TWI390026 B TW I390026B
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- Taiwan
- Prior art keywords
- oil
- parts
- alcohol
- dust
- agent
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
- A47L13/17—Cloths; Pads; Sponges containing cleaning agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2311—Coating or impregnation is a lubricant or a surface friction reducing agent other than specified as improving the "hand" of the fabric or increasing the softness thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
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Description
本發明係有關具有過敏原不活性能之吸附灰塵用油劑。更詳細者係有關附著於吸附灰塵用拖把、踏墊、或刮水器等之清潔器具後使用之具有過敏原不活化能之吸附灰塵用油劑。
過敏症之原因如:源於花粉、塵蟎、及其屍體、糞便、狗、貓等寵物之毛、家塵、食物等例。此等過敏症之起源物質稱為過敏原。
特別是於屋內極多人困擾之過敏原有塵蟎、家塵、及寵物之毛。做為去除此等之方法者,先行技術中以使用吸塵器等之清潔用具即可。惟,藉由吸塵器去除過敏原,為使不產生過敏症,務必無數次的使用吸塵器,極為麻煩。
因此,近年來被揭示有使過敏原不活化之去除方法。此係務必使不活化過敏原之藥劑利用噴霧等散佈或塗佈後擦拭,使用吸塵器去除者,因此,極為麻煩(特開2003-334504號公報)。
另外,為去除如引起過敏症之主要過敏原之塵蟎及其繁殖之家塵為目的下,即使利用抹布、拖把、刮水器等擦拭後,由此等清潔器具所脫落之未經不活化之過敏原仍再度造成過敏症之原因的問題點存在。因此,務必使此等過敏原持續存在於清潔器具之同時為不活化者。
為去除家塵而於拖把、刮水器等清潔器具上塗佈吸附灰塵用油劑。惟,使過敏原不活化之藥劑多半為水溶性,因此,以吸附灰塵用油劑欲分散或溶解此藥劑並不容易。
本發明者發現,使用非離子界面活性劑,使過敏原不活化成份藉由分散或溶解於基劑油後,使過敏原不活化成份可穩定附著於拖把等之清潔器具用之纖維狀基材。
因此,本發明係有關含有基劑油(A)、非離子界面活性劑(B)、及過敏原不活化成份(C)之吸附灰塵用油劑。
本發明又有關以上述本發明之吸附灰塵用油劑所處理之吸附灰塵用纖維製品。
本發明吸附灰塵用油劑為具有良好之吸附灰塵性,同時可使所吸附之過敏原有效進行不活化。
理想之吸附灰塵用油劑(以下亦簡記為「油劑」。)之實施形態中,做為基劑油(A)例者如:鑛物油及其精製油,此等氫化及/或其分解油、聚矽氧油、菜籽油、及萞麻子油等動植物油例者,並未特別限定。此等可單獨使用,亦可混合2種以上使用之。
上述示例中又以鑛物油及其精製油、或此等之氫化及/或其分解油。
成份(A)之30℃中動黏度(以下簡單「黏度」)(藉由JIS Z 8803-1991、5.2.3.烏氏黏度計所測定之值)一般為10~250 mm2
/s,較佳者為35~200 mm2
/s。當成份(A)之動黏度超出250 mm2
/s時,則用於吸附灰塵用拖把等時,其吸附灰塵用油劑往地面等附著,恐造成做為吸附灰塵用油劑之性能問題。
理想之實施形態中,做為非離子界面活性劑(B)例者,如:脂肪族系醇之環氧烷(以下簡稱環氧烷為「AO」)加成物(B1)、脂肪族系羧酸酯(脂肪酸酯化合物)(B2)等例。
其中,「脂肪族系醇」係指含脂肪族醇與脂環式醇之兩者,「脂肪族系羧酸」係指含有脂肪族羧酸與脂環式羧酸之兩者。
做為構成上述加成物(B1)之脂肪族系醇例者,以碳數1~24之脂肪系醇(X)者宜,如:合成醇、天然醇均可其例如下。
碳數1~24之脂肪族1價醇(X1)(如:甲醇、2-乙基己基醇、月桂醇、棕櫚醇、異硬脂烯醇等脂肪族飽和1價醇;如:油烯醇等脂肪族不飽和1價醇)
碳數1~24之脂肪族多價(2~6價)醇或其縮合物(X2)(如:1,6-壬二醇、新戊二醇、甘油、三羥甲基丙烷、季戊四醇、山梨糖醇、山梨聚糖等)
碳數1~24之環狀脂肪族1價醇(X3)(如:乙基環己醇、丙基環己醇、辛基環己醇、壬基環己醇、金剛烷醇等)做為構成上述加成物(B1)之AO例者如:環氧乙烷(以下簡稱「EO」)、環氧丙烷(以下簡稱「PO」)、1,2-或2,3-環氧丁烷、四氫呋喃、及環氧苯乙烷等之碳數2~8之AO例。其中又以EO、PO為較佳。
AO之加成形式可為無規、或嵌段均可。AO之加成莫耳數由其對於基劑油之溶解性觀點視之,以1~50莫耳者宜,較佳者為1~30莫耳,更佳者為1~20莫耳。
做為構成上述加成物(B1)之烷基(源於上述(X)之烷基)例者如:碳數1~24之飽和或不飽和烷基例者。此烷基如:源於棕櫚油、牛脂、菜籽油、米糠油、魚油等天然油脂或合成系者均可。
構成脂肪酸酯化合物(B2)之脂肪族系羧酸(a)之例者如以下示例。
碳數1~24之脂肪族單羧酸(a1)(如:甲酸、乙酸、丙酸、月桂酸、棕櫚酸、硬脂酸、異硬脂酸、異花生酸等脂肪族飽和單羧酸;如:油酸、芥子酸等之脂肪族不飽和單羧酸)碳數1~24之脂肪族二羧酸(a2)(如:己二酸、反油酸等之脂肪族烴系飽和二羧酸)構成脂肪酸酯化合物(B2)之醇例者如以下示例者。其中又以碳數8~32之脂肪族1價醇(xx1)為較佳。
碳數8~32之脂肪族1價醇(xx1)(如:辛醇、2-乙基己酸、月桂酸、棕櫚醇、異硬脂烯醇等脂肪族飽和1價醇;如:油烯醇等脂肪族不飽和1價醇)碳數3~24之脂肪族多價(2~6價)醇或其縮合物(xx2)(如:1,6-己二醇、新戊二醇、甘油、三羥甲基丙烷、季戊四醇、山梨糖醇、山梨聚糖等)碳數1~24之脂肪族1價醇(x1)之AO加成物(xx3)(如:月桂醇之EO7莫耳加成物等)碳數1~24之脂肪族多價醇(x2)之AO加成物(xx4)聚伸烷基二醇(xx5)。
做為此等(B2)之具體例者可使用多價醇脂肪酸酯AO加成物(亦即,多價醇AO加成物之脂肪酸酯)(如:聚環氧乙烷甘油二油酸酯、聚環氧乙烷山梨聚糖三油酸酯等)、萞麻子油EO加成物、硬化麻子油EO加成物、(a1)與(xx1)所成之酯(如:2-乙基己基硬脂酸酯、異癸基硬脂酸酯、異硬脂烯基油酸酯、異二十基硬脂酸酯、異二十基油酸酯、異廿四基油酸酯、異花生基油酸酯、異硬脂烯基棕櫚酸酯、油烯油酸酯等);(a1)與(xx2)所成之酯(如:甘油二油酸酯、季戊四醇四油酸酯、山梨聚糖單油酸酯等);(a2)與(x1)所成之酯(如:二油烯己二酸酯、二異三癸基己二酸酯等己二酸酯等);(a1)與(xx3)所成之酯(如:EO為2莫耳所加成之dovanol 23(三菱化學股份公司製之合成醇)與月桂酸之酯、PO為2莫耳所加成之異三癸基醇與月桂酸之酯、ZO為2莫耳所加成之dovanol 23與己二酸之二酯);(a1)與(xx5)所成之酯(如:聚乙二醇單(二)硬脂酸酯、聚乙二醇之單(二)油酸酯等);(a2)與(xx3)所成之酯(如:月桂酸之EO 7莫耳加成物之己二酸酯等)等例。其他,除上述示例以外,亦可使用由上述(a1)、(a2)等羧酸成份與上述(x1)、(x2)、(x3)、(xx3)、(xx4)、(xx5)等之醇成份之任意組合所成之羧酸酯化合物。
此等非離子界面活性劑(B)中,由對於過敏原不活化成份(C)之基劑油(A)之分散或可溶化容易度之觀點視之,又以脂肪族系醇之AO加成物(B1)為較佳,更佳者如:下述一般式(1)所示之碳數1~24(較佳者為碳數8~24)之脂肪族系醇之AO加成物(B11)。
R1
-(OA)k
-OH (1)
上述式(1)中,R1
為碳數1~24之脂肪族烴基或碳數3~24之脂環式烴基,A為碳數2以上之1種以上之伸烷基,k為平均值1~50之0或1以上之整數。較佳者分別以R1
為碳數1~24(更佳者為碳數8~24)之直鏈或支鏈之烷基或環烷基,A為碳數2~8之伸烷基,k為平均值1~20之0或1以上之整數。
如上述,一般式(1)之加成物(B11)係加成環氧烷(B1b)於脂肪族系醇(B1a)所得之脂肪族系醇AO加成物,亦可為2種以上加成物之混合物者。
上述一般式(1)中,R1
為脂肪族系醇(B1a)之殘基,碳數通常為1~24之脂肪族烴基(烷基、烯基、二烯烴
基等)或碳數3~24之脂環式烴基(環烷基、多環烴基等)。R1
碳數為3以上時,可為直鏈與枝鏈狀等,2種以上基之混合物均可。只要碳數於此範圍即可取得與成份(A)之互溶性良好者。
做為R1
之具體例者有烷基例如:甲基、乙基、異丙基、丁基、辛基、壬基、癸基、月桂基、十二基、肉豆蔻基、鯨蠟基、硬脂烯基、壬癸基、2-乙基己基、2-乙基辛基等例。烯基例者如:辛烯基、癸烯基、十二烯基、十三烯基、戊癸烯基、油烯基、鱈油烯基等例。二烯烴基之例者如:亞油基等例。環烷基例者如:乙基環己基、丙基環己基、辛基環己基、壬基環己基等例。多環烴基例者如:金剛烷基等例。
一般式(1)中,A為碳數2以上,較佳者為碳數2~8之伸烷基,OA為碳數2以上,較佳者為碳數2~8之環氧烷(AO)。其具體示例亦含理想示例,做為加成物(B1)之AO與上述所載相同者。
一般式(1)中,K相當於環氧烷(B1b)之加成莫耳數,平均為1~50之整數,較佳者為1~20,更佳者為1~15,最佳者為1~10。當k超出50,則將極易降低與基劑油(A)之互溶性。
上述脂肪族系醇(B1a)為附有R1
殘基者,碳數以1~24者宜,較佳者為8~24,更佳者為8~18之醇。天然醇、合成醇(齊格勒醇、羰基合成醇等)均可。
具體例如:辛醇、壬醇、癸醇、十一醇、十二醇、十
三醇、十四醇、戊癸醇、辛癸醇、壬癸醇等飽和脂肪族醇;辛烯醇、癸烯醇、十二烯醇、十三烯醇、戊癸烯醇、油烯醇、鱈油烯醇、亞油烯醇等不飽和脂肪族醇;乙基環己醇、丙基環己醇、金剛烷醇等環狀脂肪族醇之例,此等可使用1種或2種以上。此等脂肪族系醇以1級或2級者宜,更佳者為1級。脂肪族系醇之烷基部份(R1
殘基)可為直鏈狀,亦可為枝鏈狀。
上述示例醇中又以異癸醇、十二醇、十三醇、異十三醇、十四醇、己癸醇、辛癸醇為特別理想者。
一般式(1)所示之加成物(B11)因其步驟並不繁雜,可直接由脂肪族系醇(B1a)與環氧烷(B1b)製造極為理想。其中「直接製造」係指上述加成物藉由精餾不同之未反應醇,加成莫耳數而無需分開進行,可直接取得之意。惟,並未以分開進行為目的,於簡單操作下使未反應之環氧烷,低沸點物進行剝離者並未包含其中之分開操作。
處理含吸附灰塵用油劑之廢液時,基於為提高水中油分離性之觀點而言,及由避免其包裝塗佈吸附灰塵用油劑之刮水器等製品之材料藉由含於吸附灰塵用油劑之未反應醇所造成凹凸等問題之觀點視之,其非離子界面活性劑(B)為一般式(1)所示之加成物(B11),且,滿足下式(2)或(3),由下式(4)求取之Weibull分佈定數(之值為1.0以下,具小於一般分子量分佈者宜。
Mw/Mn≦0.030×Ln(v)+1.010(其中,v<10) (2)
Mw/Mn≦-0.026×Ln(v)+1.139(其中,v≧10) (3)
c=(v+n0
/n00
-1)/[Ln(n00
/n0
)+n0
/n00
-1] (4)
上述式(2)及(3)中,Mw為重量平均分子量,Mn為數平均分子量,v為每碳數1~24之脂肪族系醇(B1a)1莫耳所加成環氧烷(B1b)之平均加成莫耳數,相當於上述一般式(1)中環氧烷之加成莫耳數k之平均。Ln(v)為v之自然對數。
若未滿足式(2)或(3),亦即,界面活性劑分子之分子量分佈太廣時,恐無法取得充份的水分離性。
Mw/Mn若能滿足下述關係式(2')或(3')者更佳。
Mw/Mn≦0.031×Ln(v)+1.000(其中,v<10) (2')
Mw/Mn≦-0.026×Ln(v)+1.129(其中,v≧10) (3')
關係式(4)係由下述Weibull分佈規則之式(7)所導出之式。
v=c×Ln(n00
/n0
)-(c-1)×(1-n0
/n00
) (7)
關係式(4)之分佈定數c由其水分離性之觀點視之,以1.0以下者宜,更佳者為0.7以下。
式(4)中,分佈定數c之值小,亦即,未反應脂肪族系醇之含量愈少,分子量分佈愈小之意。
通常,脂肪族系醇之AO加成物(B11)之AO為單獨之環氧乙烷時,以滿足下式(5)或(6),且由上式(4
)所求得之Weibull分佈定數c之值為1.0以下,分子量分佈小之加成物(B11)為更佳者。
Mw/Mn≦0.018×Ln(v)+1.015(其中,v<10) (5)
Mw/Mn≦-0.026×Ln(v)+1.116(其中,v≧10) (6)
甚至AO為單獨之環氧乙烷時,由其水分離性之觀點視之,若滿足(5')或(6')為更佳者。
Mw/Mn≦0.020×Ln(v)+1.010(其中,v<10) (5')
Mw/Mn≦-0.023×Ln(v)+1.113(其中,v≧10) (6')
有關脂肪族系醇之AO加成物(B11)之製造方法,如上述所說明,於脂肪族系醇(B1a)加成環氧烷後之「直接製造」者宜,惟,並未特別限定。做為加成物(B11)之具體製造法例者如:特開2002-069435號公報所載之製造方法例。
脂肪族系醇之AO加成物(B1)可於與基劑油(A)及過敏原不活化成份(C)配合前,或配合後,以「kiyuward 600」(協和化學工業(股份)製)等之吸附劑進行吸附處理後去除所含觸媒,亦可利用特開昭56-112931號公報,特公平2-53417號公報所載之氧基羧酸(乳酸)等進行中和處理、或直接殘留觸媒均可。
做為此等一般式(1)所示之脂肪族系醇之AO加成物(B11)之理想具體例者如:異癸醇之EO 7莫耳加成物、異癸醇EO 2莫耳PO 2莫耳EO 4莫耳加成物、月桂醇EO莫耳加成物、月桂醇EO 10莫耳加成物、月桂醇EO 2莫耳PO 2莫耳EO 4莫耳加成物等例。
過敏原係指造成過敏症原因之花粉、塵滿及其屍體、糞便、花粉、狗、貓等寵物之毛、家塵、食物等過敏原之不活化成份(C)係指降低此等過敏原所引起過敏作用之化合物。
做為此成份(C)例者如特開2003-55122號公報所載之過敏原不活化劑,如:至少1種選自木精科橄欖屬(橄欖)、或水蠟樹屬(水蠟、深山水蠟、大葉水蠟、小峽水蠟、細谷水蠟、鼠黐、唐鼠黐等)植物所萃取之成份(橄欖苦柑等)(C1)之例。而,只要藉由非離子界面活性劑(B)可穩定配合於基劑油(A)即可,未特別限定之。
做為上述(C1)以外之過敏原不活化成份例者如:除蟲菊系化合物(天然除蟲菊素、苯氧司林、倍爾美特林、等)、有機磷化合物(菲硫磷、馬拉硫磷、吩硫磷、艾爾吉能等)、苄醇、苄基苯甲酸酯、水楊酸苯酯、桂皮醛、幾克豪爾、雙氯苯基乙醇酸乙酯、黑克西契薩斯、牛藤草油、人參種子油、單寧酸、沒食子酸、茶萃取物等例。此等可單獨使用,亦可合併2種以上使用之,或可與上述之植物萃取物(C1)併用之。
非離子界面活性劑(B)之含量係以吸附灰塵用油劑100質量份為基準下,由其過敏原不活化成份之分散,可溶化之觀點視之,以1~50質量份(亦即,1~50質量%)者宜,更佳者為5~40質量份,特別以10~30質量份為最佳。
過敏原不活化成份(C)之含量以油劑100質量份為基準下,以0.01~15質量份(亦即0.01~15質量%)者宜,更佳者為0.01~5質量份,特別以0.02~5質量份為最佳。只要於此範圍者,即可取得良好之過敏原不活化效果。此成份(C)包含於油劑中呈可溶化或分散狀態者。
必要時,亦可於油劑中添加其他界面活性劑(高級醇燐酸酯鹽、高級醇硫酸酯鹽、高級醇磺酸鹽等陰離子界面活性劑;陽離子界面活性劑;兩性界面活性劑等)、醇(甲醇、乙醇、異丙醇、丁醇等)、靜電劑(磷酸酯系靜電劑、磷鹽系靜電劑、脂肪酸鹼等)、其他添加劑(香料、金屬離子封鎖劑、抗氧化劑、紫外線吸收劑、殺菌劑等)、水等。
上述其他界面活性劑之配合量於油劑中以10質量%以下者宜,更佳者為8質量%以下。
油劑中之上述靜電劑配合量以10質量%以下者宜,更佳者為5質量%以下。其他添加劑之總配合量以3質量%以下者宜,更佳者為1質量%以下。油劑中之水配合量以10質量%以下者宜,更佳者為5質量%以下。
油劑係上述成份(A)、(B)及必要時含其他成份,將此等成份於常溫或必要時進行加熱後,均勻混合取得。各成份之配合順序,配合方法等並未特別限定。
油劑之動黏度係依JIS A8803-1991(5.2.3烏氏黏度計)為基準所測定之值,30℃下以10~300mm2
/s者宜,更佳者為35~200 mm2
/s。油劑之動黏度若為10 mm2
/s以上時,則油劑之移行性變小。因此,油劑用於拖把時,於清掃時,油劑移行至家俱、地板等被覆灰塵去除物不致造成黏膩感,用於踏墊時,亦不致移行至鞋底而污染地板。反之,油劑之動黏度為300 mm2
/s以下時,則吸附灰塵性相當良好。
油劑一般於纖維進行附著處理,做為吸附灰塵用纖維製品使用之。此纖維製品之形態例如:腳踏墊、拖把、地毯、抹布等例。其中又以具有乾燥型纖維狀基材之室內用清潔擦拭用具等,乾燥型之纖維製品為更佳。可使用之纖維例如:纖維素系纖維(木棉、絲光棉、再生纖維素纖維等)、聚乙烯醇纖維、丙烯纖維、聚醯胺纖維、聚酯纖維、聚丙烯纖維等,及此等混合纖維例者。此等纖維以拈線、塞繩、桌布類之織物、踏墊類之毛絨網化織物、編物、不織布等形態使用之。
以吸附灰塵用纖維製品為對象之灰塵例者如:家庭、商店、事務所等花粉、塵蟎、或其屍體、糞便、狗、貓等寵物之毛、家塵、食物屑等例。
對於纖維製品之油劑的適用方法並未特別限定,通常如:直接以油劑、或油劑中加水後以機械分散之狀態下,於常溫、或必要時於90℃以下進行加熱後,附著於纖維。附著於纖維之方法例如:滾輥塗層法、刮油灰法、浸漬法、噴霧法等例。
附著於纖維之量以每100 g乾燥之纖維之固形份換算下,一般以0.3~40 g者宜,更佳者為1~25 g。
以下,藉由實施例進行本發明更詳細之說明,惟,本發明並未受限於此。製造例及實施例、比較例中,「份」代表重量份、「%」代表重量%。
藉由凝膠滲透色譜法(GPC)之分子量測定方法及氣體色譜法(GC)之未反應醇含量之測定方法為如下。依下述之測定條件,測定成份(B11)之各製造例反應物,求出Mw/Mn,未反應脂肪族系醇量,及式(4)中之分佈定數c。
《GPC之測定條件》柱體:TSK gel Super H4000:TSK gel Super H3000:TSK gel Super H2000(均為東曹股份公司製)柱體溫度:40℃檢測器:RI溶媒:四氫呋喃流速:0.6 ml/分試料濃度:0.25質量%注入量:10 μ l標準:聚環氧乙烷二醇(東曹股份公司製:TSK STANDARD POLY ETHYLENE OXIDE)數據處理裝置:SC-8020(東曹股份公司製)
《GC之測定條件》機種:氣體色譜法GC-14B(島津製作所製)檢測器:FID柱體:玻璃柱體(內徑=3mm、長度=約2m)柱體填充劑:聚矽氧GE SE-50 5%昇溫速度:90~280℃/4℃分試料:50%丙酮溶液注入量:1 μ l定量:以碳數少於成份(B11)合成所使用之脂肪族系醇2或3個之脂肪族系醇做為內部標準物質使用後,定量之。
於附有攪拌及溫度調節機能之不銹鋼製高壓鍋中投入月桂醇186份(1莫耳)、過氯酸鎂0.04份、及硫酸鎂7鉬0.01份、使混合系內以氯取代後,減壓下(約20 mmHg),於120℃下進行脫水1小時。再使EO 88份(2莫耳)於150℃,進行導入使表壓呈0.1~0.3 Mpa。所得加成物之weibull分佈定數c為0.42,未反應醇量為2.2%。
於此加成物加入氫氧化鉀0.3份,於150℃下反應EO 220份(5莫耳)。反應物投入3份「quoward 600(協和化學工業股份公司製;以下相同),於90℃下使觸媒吸附處理後,進行過濾。
所得反應物之Mw/Mn為1.015(滿足c式(5')之Mw/Mn之上限計算值:1.049),未反應脂肪族系醇量為0.02%,式(4)之分佈定數c的計算值為0.92。
以過氯酸鎂0.04份與過氯酸鋁9鉬0.01份取代製造例1之過氯酸鎂0.04份與硫酸鎂0.01份使用(所得加成物之分佈定數c為0.38,未反應醇量為1.7%),以EO 352份(8莫耳)取代鹼觸媒存在下之EO導入量220份使用之外,與製造例1同法進行。
所得反應物之Mw/Mn為1.052(滿足式(6')之Mw/Mn之上限計算值:1.056),未反應脂肪族系醇未被檢出(檢出界限:0.001%)。
於附有攪拌及溫度調節機能之不銹鋼製高壓鍋中投入月桂醇186份(1莫耳)、及過氯酸鎂0.05份,使混合系內以氮取代後,減壓下(約20 mmHg),120℃下進行脫水1小時。再使EO 88份(2莫耳)於150℃下導入使表壓呈0.1~0.3 MPa。所得加成物之分佈定數c為0.60,未反應醇量為4.5%。
於此加成物中加入氫氧化鉀1.3份,再依序使PO 116份(2莫耳)、EO 176份(4莫耳)於130℃下導入使表壓呈0.1~0.3 MPa。反應物中投入3份「quoward 600」,90℃下使觸媒吸附處理後,進行過濾。
所得反應物之Mw/Mn為1.067(滿足式(3)之Mw/Mn上限計算值:1.072),未反應脂肪族系醇量為0.006%,式(4)之分佈定數c的計算值為0.91。
於附有攪拌及溫度調節機能之不銹鋼製高壓鍋中投入異癸醇158份(1莫耳)、過氯酸鎂0.04份、及硫酸鎂7鉬0.01份,使混合系內以氮取代後,減壓下(約20 mmHg),120℃下進行脫水1小時。再使EO 88份(2莫耳)於150℃下導入使表壓呈0.01~0.3 MPa。所得加成物之weibull分佈定數c為0.42,未反應醇量為2.2%。
於此加成物中加入氫氧化鉀0.3份,使EO 220份(5莫耳)於150℃下進行反應。反應物中投入3份「quoward 600」,90℃下使觸媒進行吸附處理後過濾之。
所得反應物之Mw/Mn為1.048(滿足式(5')之Mw/Mn之上限計算值:1.049),未反應脂肪族系醇量為0.02%,式(4)之分佈定數c之計算值為0.92。
於附有攪拌及溫度調節機能之不銹鋼製高壓鍋中投入月桂醇186份(1莫耳)、及氫氧化鉀0.3份,使混合系內以氮取代後,減壓下(約20 mmHg),120℃下進行脫水1小時。再使EO 440份(10莫耳)於150℃下導入使表壓呈0.1~0.3 MPa。反應物中投入3份「quoward 600」,90℃下使觸媒吸附處理後,進行過濾。
所得反應物之Mw/Mn為1.101(滿足(式(6')之Mw/Mn之上限計算值:1.056),未反應脂肪族系醇量為0.7%,式(4)之分佈定數c之計算值為3.26。
於附有攪拌及溫度調節機能之不銹鋼製高壓鍋中投入月桂醇186份(1莫耳),使系內以氮取代後,減壓下(約20 mmHg),120℃下脫水,於40℃下投入三氟化硼二乙醚0.3份,使混合系內以氮取代。再使EO 88份(2莫耳),PO 116份(2莫耳)、EO 264份(6莫耳)依序於50℃下導入使表壓約為0.1 MPa,以鹼進行中和之。
所得反應物之Mw/Mn為1.096(滿足式(3)之Mw/Mn之上限計算值:1.072),未反應脂肪族系醇量為0.04%,式(4)之分佈定數c之計算值為1.60。
此製造例6中,確定約7%之聚伸烷基二醇副產物。
將載於特開2003-55122號公報之橄欖葉萃取液(20 g橄欖生葉置入100 g水中,以混合器進行粉碎,過濾其液者)進行乾燥後,取得過敏原不活化成份。
將下述各成份置入具有槳型攪拌器之配合槽,於20~30℃下混合,取得均勻的黃色液狀之油劑(1)1,000份。
鑛物油(30℃之黏度30 mm2
/s) 850份月桂醇EO 7莫耳加成物(製造例1) 50份山梨聚糖三油酸酯EO 20莫耳加成物 65份甲醇EO 5莫耳加成物 5份過敏原不活化成份 2份水 28份
使用下述成份,與實施例1同法取得均勻之黃色液狀油劑(2)1,000份。
鑛物油(30℃之黏度95 mm2
/s) 60份月桂醇EO 10莫耳加成物(製造例2) 50份山梨聚糖單油酸酯 45份椰子油脂肪酸二乙醇醯胺 5份過敏原不活化成份 4份水 30份乙醇 6份
使用下述各成份,與實施例1同法取得均勻之黃色液狀油劑(3)1,000份。
鑛物油(30℃之黏度110 mm2
/s) 850份硬化萞麻子油 15份月桂醇EO2PO2EO4莫耳加成物(製造例3) 40份月桂醇EO2莫耳加成物磷酸酯 5份山梨聚糖單油酸酯 50份山梨聚糖三油酸酯EO 20莫耳加成物 30份過敏原不活化成分 3份水 7份
使用下述各成份,與實施例1同法取得均勻之黃色液狀油劑(4)1,000份。
鑛物油(30℃之黏度120 mm2
/s) 800份月桂醇EO 7莫耳加成物(製造例1) 25份異癸醇EO 7莫耳加成物(製造例4) 30份萞麻子油EO 20莫耳加成物 30份山梨聚糖單油酸酯 70份過敏原不活化成份 10份水 35份
使用下述各成份,與實施例1同法取得均勻之黃色液狀油劑(5)1,000份。
鑛物油(30℃之黏度95 mm2
/s) 860份月桂醇EO 10莫耳加成物(製造例5) 50份山梨聚糖單油酸酯 45份椰子油脂肪酸二乙醇醯胺 5份過敏原不活化成份 4份水 30份乙醇 6份
使用下述各成份,與實施例1同法取得均勻之黃色液狀油劑(6)1,000份。
鑛物油(30℃之黏度95 mm2
/s) 900份鯨蠟醇EO3莫耳加成物磷酸酯二乙醇胺鹽 80份過敏原不活化成份 4份水 10份乙醇 6份
使用下述各成份,與實施例1同法取得均勻之黃色液狀油劑(7)1,000份。
鑛物油(30℃之黏度265 mm2
/s) 800份硬化萞麻子油 15份月桂醇EO2PO2EO4莫耳加成物(製造例6) 40份月桂醇EO 2莫耳加成物磷酸酯 5份山梨聚糖單油酸酯 80份山梨聚糖三油酸酯EO 20莫耳加成物 50份水 10份
使用上述實施例及比較例所得之油劑(1)~(7)進行做為吸附灰塵用油劑之性能試驗。其結果示於表1。
做為未處理拖把者,使用丙烯/人造纖維=70/30(質量比)之油劑未處理吸附灰塵用拖把。
於此未處理拖把以噴霧附著20倍量甲苯所稀釋之油劑。之後風乾後,製作油劑處理拖把。油劑處理拖把之油劑附著量對於拖把質量以固形份換算下為10%。
附著灰塵性:將油劑處理之拖把以5 cm長度裁切3 g,以2種JIS之4倍量試料質量(矽砂:JIS Z 8901試驗灰塵用)同時於聚乙烯袋中進行振盪1分鐘。之後,將試料置於JIS網篩(20篩號:JIS Z 8801標準網篩)上,以萬能振動篩進行振幅3.5 cm振動10分鐘,測定附著灰塵量。判定為A:附著灰塵量1 g以上、B:0.5 g~未達1 g、C:未達0.5 g。
經日安定性:將油劑置入300 g之玻璃瓶,室溫下靜置1週,目測判定外觀。A:無沈澱物產生及成份分離、B:彩虹或帶狀之分離出現、C:出現沈澱物或成份分離。
過敏原不活化性:將約含有0.05 g之塵蟎過敏原灰塵分散於平板上,以油劑處理拖把及未處理拖把進行擦拭。之後,萃取油劑處理拖把及未處理拖把之過敏原,藉由ELISA法定量過敏原。藉由不活化率=100-(油劑處理拖把之藉由ELISA法之過敏原量)/(未處理拖把藉由ELISA之過敏原量)算出不活化率,上述式中50%以上者為A、10~未達50%者為B、0~未達10%者為C。
廢水處理性(水分離性):於100 ml量筒中置入水80 ml,油劑4 g,上下振盪10次。測定振盪後上層回到4 ml之時間(秒)。A:未達120秒、B:120秒~未達180秒、C:180秒以上、D:完全未分離。
本發明油劑係具有良好的過敏原不活化成份之分散性或溶解性,因此,適用於具有乾式之纖維狀基材之清潔擦拭用具,踏墊等吸附灰塵用油劑。
此申請之揭示係與2004年12月28日所申請之特願2004-381680、及2005年8月26日所申請之特願2005-246058號所載之主題相關,此等揭示內容係經引用所應用者。
所有本明細書所載之文獻各揭示內容經引用而應用於此。
除上述之外,在未偏離本發明之新規且有利之特徵之範圍下,亦可加以修正或變更上述實施形態。因此,所有修正、變更意圖包含於添附申請範圍中。
Claims (7)
- 一種吸附灰塵用油劑,其係含有基礎油劑(A)、非離子界面活性劑(B)、及過敏原非活性成份(C)之吸附灰塵用油劑,其特徵為前述成份(B)為脂肪族系醇之環氧烷加成物(B1),及/或脂肪族系羧酸酯(B2),前述成份(C)為木精科橄欖屬(橄欖)、或水蠟樹屬之植物萃取物,前述非離子界面活性劑(B)之含量為前述吸附灰塵用油劑中之10~30質量%。
- 如申請專利範圍第1項之吸附灰塵用油劑,其中前述成份(B)為以一般式(1)所示之脂肪族系醇之環氧烷加成物(B11),R1 -(OA)k -OH (1)(式中,R1 為碳數1~24之脂肪族烴基或碳數3~24之脂環式烴基,A為碳數2以上之伸烷基,k為平均值1~50之0或1以上之整數)。
- 如申請專利範圍第2項之吸附灰塵用油劑,其中前述成份(B11)係滿足式(2)或(3),且由式(4)所求得之c為1.0以下者, Mw/Mn≦0.030×Ln(v)+1.010(但,v<10) (2) Mw/Mn≦-0.026×Ln(v)+1.139(但,v≧10) (3) c=(v+n0 /n00 -1)/[Ln(n00 /n0 )+n0 /n00 -1] (4)(式中,Mw為重量平均分子量,Mn為數平均分子量,v為一般式(1)之k的平均值,Ln(v)為v之自然對數,n00 係成份(B1)合成反應所使用之脂肪族系醇之莫耳數,n0 為未反應之脂肪族系醇之莫耳數)。
- 如申請專利範圍第2項之吸附灰塵用油劑,其中前述成份(B11),係於一般式(1)中A為伸乙基,且滿足式(5)或式(6)者,Mw/Mn≦0.018×Ln(v)+1.015(但,v<10) (5) Mw/Mn≦-0.026×Ln(v)+1.116(但,v≧10) (6)(式中,Mw為重量平均分子量,Mn為數平均分子量,v為一般式(1)之k的平均值,Ln(v)為v之自然對數)。
- 如申請專利範圍第1項至第4項中任一項之吸附灰塵用油劑,其中該吸附灰塵用油劑中之前述成分(C)的含量為0.01~15質量%。
- 如申請專利範圍第1項至第4項中任一項之吸附灰塵用油劑,其中於30℃之動黏度(藉由JIS Z8803-1991,5.2.3.烏氏黏度計所測定之值)為10~300 mm2 /s。
- 一種吸附灰塵用纖維製品,其特徵係以如申請專 利範圍第1項至第6項中任一項之吸附灰塵用油劑所處理者。
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CN103710078A (zh) * | 2013-12-06 | 2014-04-09 | 华阳新兴科技(天津)集团有限公司 | 一种环保安全型发动机润滑系统在线清洗剂 |
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CN101094911B (zh) | 2012-07-18 |
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CA2591192A1 (en) | 2006-07-06 |
CA2591192C (en) | 2013-08-20 |
KR101245466B1 (ko) | 2013-03-25 |
MX2007007922A (es) | 2007-11-07 |
TW200641105A (en) | 2006-12-01 |
EP1835015A1 (en) | 2007-09-19 |
WO2006070864A1 (ja) | 2006-07-06 |
EP2343358A1 (en) | 2011-07-13 |
US20060160447A1 (en) | 2006-07-20 |
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