TWI344149B - - Google Patents

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TWI344149B
TWI344149B TW094140516A TW94140516A TWI344149B TW I344149 B TWI344149 B TW I344149B TW 094140516 A TW094140516 A TW 094140516A TW 94140516 A TW94140516 A TW 94140516A TW I344149 B TWI344149 B TW I344149B
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TW
Taiwan
Prior art keywords
substrate
layer
stamper
information layer
forming
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TW094140516A
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English (en)
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TW200634811A (en
Inventor
Yoshihiro Sugiura
Takeshi Koitabashi
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Sony Disc & Digital Solutions
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Publication of TW200634811A publication Critical patent/TW200634811A/zh
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Publication of TWI344149B publication Critical patent/TWI344149B/zh

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    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/2403Layers; Shape, structure or physical properties thereof
    • G11B7/24035Recording layers
    • G11B7/24038Multiple laminated recording layers
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/26Apparatus or processes specially adapted for the manufacture of record carriers
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/254Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
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    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
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    • G11B7/254Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
    • G11B7/2542Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers consisting essentially of organic resins
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    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
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    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
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    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
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    • G11B7/263Preparing and using a stamper, e.g. pressing or injection molding substrates
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    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
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    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/25706Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing transition metal elements (Zn, Fe, Co, Ni, Pt)
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    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/2571Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing group 14 elements except carbon (Si, Ge, Sn, Pb)
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    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/25715Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing oxygen
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    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
    • G11B2007/25705Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials
    • G11B2007/25716Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of inorganic materials containing sulfur
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/21Circular sheet or circular blank

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacturing Optical Record Carriers (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Optical Integrated Circuits (AREA)
  • Holo Graphy (AREA)

Description

1344149 九、發明說明: 【發明所屬之技術領域】 本發明關於光碟之製造方法及光碟。 【先前技術】 最近,有藍光光碟(Blu-ray Disk(登錄商標之類之高密 度光碟被提案。高密度光碟中,雖與DVD(Digiul
Disc)形狀相同,惟單面單層可具有約乃Gb(i Gb =十億萬位 元)的記錄容量,單面雙層可具有約5〇 Gb之記錄容量。 高密度光碟令,光源波長為4〇5 nm,藉由使對物鏡之孔 徑值NA加大成〇_85,記錄播放用之光點徑縮小至〇 58 , 相較於DVD,可得到約ι/5之點面積。 如此一般,提高對物鏡之孔徑值NA的話,光碟面與雷射 光之光軸所升> 成之角度由9〇。傾斜時所容許之角度誤差(稱 為tile margin ;傾角容許範圍)會變小。 在此,單面單層之高密度光碟中,乃將被覆資訊層之保 護層薄到0.1軸。在單面雙層之高密度光碟的情況t,則 在由雷射光射入方向來看〇1 mm(1〇〇 μιη)深之位置上設有 成為基準層(第〇記錄層)之資訊層,在75 pm深之位置上設 置成為追加層(第—記錄層)之資訊層。在此,資訊層意指唯 讀光碟中之反射層及可覆寫光碟中之記錄層雙方。以下, 適宜地稱第〇記錄層SL0層,第1記錄層為L1層。 如上述奴地,為了實現進—步之大容量化,咸認為以資 訊層複數層之多層構造之光碟較有希望。 以往作為唯讀之單面雙層構造之高密度光碟之製造方 104l73.doc 1344149 法,已知有在形成基板時於一主面上形成1〇層之凹槽,在 該L0層之形成有凹槽之基板的一主面上,形成紫外線(uv) 硬化型樹脂所形成之中間層,在該中間層之表面上,使用 為了形成L1層之凹槽而形成有凹凸之具透光性之轉印用樹 脂壓模來轉印L 1層之凹槽,透過樹脂壓模照射紫外線,使 紫外線硬化型樹脂硬化後’剝下樹脂壓模而形成L丨層之凹 槽的方法。 例如’曰本國之特開2002-260307號公報中,記載了藉由 樹脂壓模使用聚碳酸酯’使得樹脂壓模價格便宜且重量輕 之内容。 然而’上述般之光碟製造中,有以下之問題癥結。聚碳 酸δ旨所形成之樹脂壓模具有與中間層之剝離性不佳之問 題。作為壓模之材料’雖可使用與中間層剝離性良好之環 稀系樹脂材料,惟會有價格昂貴、及經複數次使用後貼合 性增強而剝離性變差等之問題β再者,樹脂壓模會因紫外 線照射等而導致樹脂材料劣化或變形,因此,難以用來複 數次轉印。從而’通常,樹脂壓模每用於轉印一次,便加 以拋棄。如此一來,會有浪費材料、產生廢棄處理負擔等 之問題。 此外,例如在上述般之高密度光碟中,有必要便基板厚 度成為1.1 mm左右,並在以射出成形來形成具有如此般之 厚度的基板時,成形後冷卻基板所需之時間會拉長,而有 光碟製造過程時間變長之問題。 此外’例如上述般之高密度光碟般地,在厚i 1 mm之基 104l73.doc 1344149 板上設置O.i mm左右之保護層等的厚度構造不平衡的光碟 棉,有易於因吸濕等而發生光碟翹曲等之變化的問題。 從而’本發明之目的在於提供—種光碟之製造方法及以 .該製造方法所製造之光碟,其係在不浪費樹脂壓模的情況 下,有效率且低成本地形成良好之資訊層,並進一步可抑 制翹曲等之形狀變化者。 【發明内容】 為了解決上述之課題,本發明為一種光碟之製造方法, ^ 該光碟係以對基板之一主面上照射記錄及/或播放光之 方式進行資訊信號之記錄及/或播放者; 該方法之特徵為包含: 使在一主面上藉壓模基板形成有資訊層用凹凸之基板成 形之步驟; 在凹凸上形成資訊層之步驟; 資訊層上形成具透光性之保護層之步驟;及 _ 在基板之另一主面上貼合上述壓模基板或為了在其他基 板上形成凹凸所用之壓模基板之步驟。 此外’本發明為一種光碟之製造方法, 該光碟係以對基板之一主面上照射記錄及/或播放光之 方式進行資訊信號之記錄及/或播放者; 該方法之特徵為包含: 使在一主面上形成有第一資訊層用凹凸之基板成形之步 驟; 在凹凸上形成第一資訊層之步驟; 104173.doc 1344149 在第一資訊層上及在壓模基板上形成有凹凸之主面上分 別塗佈樹脂材料之步驟; 藉由使第一資訊層上及壓模基板上分別塗佈之樹脂材料 中至少一者半硬化後貼合,並在貼合之樹脂材料硬化後, 剝離壓模基板,以在第一資訊層上形成形成有第二資訊層 用凹凸之中間層之步驟; 在中間層上形成第二資訊層之步驟; 在第二資訊層上形成具有透光性之保護層之步驟;及 在基板之另一主面上貼合上述壓模基板或為了在其他基 板上形成第二資訊層用凹凸所用之壓模基板之步驟。 此外,本發明為一種光碟之製造方法, 該光碟係以在基板之一主面上照射記錄及/或播放光之 方式進行資訊信號之記錄及/或播放者; 該方法之特徵為包含: 使在一主©上形成有第—f訊層用凹凸之基板成形之步 驟; 在凹凸上形成第一資訊層之步驟; 藉由在第-資訊層上塗佈具有透光性之樹脂材料,在塗 佈之樹脂材料上轉印壓模基板之凹凸後使樹脂材料硬化, 以形成在第一資訊層上形成形成有第二資訊層用凹凸之中 間層之步驟; 在中間層上形成第二資訊層之步驟; 在第二資訊層上形成具有透光性之保護層之步驟;及 在基板之另-主面上貼合上述壓模基板或為了在其他基 104173.doc 板上形成第二資訊層凹凸所用之壓模基板之步驟。 此外,本發明係一種光碟, 其係以在基板之一主面上照射記錄及/或播放光之方式 進行資訊信號之記錄及/或播放者; 其特徵為包含: 基板’其係在一主面上以壓模基板形成有資訊層用之凹 凸; 資訊層’其係形成於凹凸上; 保濩層,其係在資訊層上所形成之具透光性者;及 壓模基板或為了在其他基板上形成凹凸而用之壓模基 板,其係貼合於基板之另一主面上。 此外,本發明係一種光碟, 其係以在基板之一主面上照射記錄及/或播放光之方式 進行資訊信號之記錄及/或播放者; 其特徵為包含: 基板,其係在一主面上形成有第一資訊層用之凹凸; 第一資訊層’其係形成於凹凸上; 形成有第二資訊層用之凹凸之中間層,其係以在第一資 訊層上及壓模基板之形成有凹凸之主面上分別塗佈樹脂材 料,並使第一資訊層上及壓模基板上分別塗佈之樹脂材料 中至少一者半硬化後貼合,並在使貼合之樹脂材料硬化 後,剝離壓模基板之方式,形成在第一資訊層上; 第二資訊層,其係形成於_間層上; 保護層,其係在第二資訊層上所形成之具透光性者;及 104173.doc 1344149 壓模基板或為了在其他基板上形成第二資訊層用凹凸所 用之壓模基板,其係貼合於基板之另一主面上。 此外,本發明係一種光碟, 其係以在基板之一主面上照射記錄及/或播放光之方式 進行資訊信號之記錄及/或播放者; 其特徵為包含: 基板,其係在一主面上形成有第一資訊層用之凹凸; 第一資訊層’其係形成於凹凸上; 形成有第二資訊層用凹凸之中間層,其係以在第一資訊 層上塗佈之具透光性之樹脂材料,並在塗佈之樹脂材料上 轉印壓模基板之凹凸後,使樹脂材料硬化之方式形成在 第一資訊層上; 第二資訊層,其係形成於中間層: 保護層,其係在第二資訊層上所形成之具透光性者:及 壓模基板或為了在其他基板上形成第:f訊層用凹凸所 用之壓模基板,其係貼合於基板之另一主面上。 依此發明,藉由使基板與壓模基板貼合,不再需要廢棄 壓模基板,可減少材料費、廢棄費等之成本開銷。此外, 可將藉由壓模基板之轉印減至僅1次,因此,可轉印出沒有 因多次轉印所造成之形狀劣化等之良好的凹凸。 精由貼合基板及壓模基板而形成出所需之厚度,可防止 翹曲等之形狀變化。此外’可薄化欲成形之基板厚度,縮 短製造週期時間β此外’例如在製造與DVD相同形狀之高 密度先碟時,可沿用或共用DVD用之光碟基板成形用模具 104l73.doc 1344149 及DVD製造裝置。 【實施方式】 以下,參照圖式來說明本發明之一實施方式。依本發明 之一實施方式的光碟’其係以貼合在一主面上形成有L0層 之L0層基板及作為壓模使用之壓模基板方式來構成光碟基 板。圖1及圖2係顯示一實施方式所適用之單面雙層構造之 光碟之製造步驟之一例的流程圖。此外’圖3至圖8係放大 該製造步驟之每一步驟中之光碟之剖面者。此外,圖〖所示 之記號「A」意指接續於圖2所示之記號「A」。 首先,將圖3A所示之L0層基板10、及圖4A所示之壓模基 板20以例如射出成形來成形(步驟S1)。L0層基板1〇為由合 成樹脂等形成之光碟基板,一主面上具有L0層用之微細凹 凸。一實施方式中之資訊層雙指唯讀用光碟中之反射層及 可覆寫光碟中之記錄層。L0層用之微細凹凸對應於l〇層之 凹槽或凸軌(land)/凹軌(groove)等》 壓模基板20為由樹脂材料等所形成之具透光性之基板, 在一主面上具有為了轉印出L1層用之微細凹凸的凹凸。Μ 層用之微細凹凸對應於L1層之凹槽或凸軌/凹軌等。壓模基 板20具有與L0層基板〖0相等直徑之主面,使用作為壓模。 此外,L0層基板10及壓模基板20中設有未圖示之中央孔。 此等L0層基板10及壓模基板2〇各一主面上所形成之微細 凹凸係例如在射出成形時’以處理室内所配置之由鎳等之 壓模所形成之壁模凹凸轉印而成者a亦即,L〇層基板丨〇及 壓模基板20例如乃以先將藉周知方法所成形之由鎳等構成 I04173.doc -11 - 1344149 之金屬製壓模安裝於射出成形機之模具上,對模具所形成 之模穴内,射出充填藉熱所熔融之樹脂材料之方式,轉印 出金屬製之壓模之凹凸而成形。。 L〇層基板10及壓模基板20可藉由兩台成形機個別成形, 惟以例如在DVD等之製造上所使用之可同時成形兩片基板 之所謂雙模穴之射出成形機來同時成形為佳。藉此,可有 效率地使L0層基板10及壓模基板20成形。 壓模基板20之材料以轉印性佳且變形少的低價者為佳。 例如作為壓模基板20之材料,如使用與L0層基板1〇相同 者’可與光碟基板製造同樣地使壓模基板20成形》具體而 言’作為L0層基板10及壓模基板20之材料,使用的為在藉 射出成形而成形時作為光碟基板之材料所廣泛使用之聚碳 酸i旨。 此外,L0層基板10及壓模基板20之厚度以約略相等為 佳。此外’ L0層基板10及壓模基板20之厚度則選擇成1〇層 基板10及壓模基板20貼合時能夠形成所需厚度之光碟。如 此一來,使L0層基板10及壓模基板20之材料、厚度、成形 時機等之成形條件相同,以彼此翹曲方向相反地貼合L〇層 基板10及壓模基板20,將可抑制光碟组曲。 如此一來’在一實施方式中,將原本由一片構成之光碟 基板以L0層基板10及壓模基板20之兩片光碟基板之貼合來 構成,因此,例如應用於與DVD相同形狀之高密度光碟之 製造時’如適當地設定欲成形之光碟基板之厚度的話,可 沿用將兩片光碟基板貼合的DVD之模具及成形裝置β此 104173.doc •12· 外,由於可使欲成形之光碟基板之厚度變薄,因此,可大 幅縮短光碟基板之冷卻時間。 成形之L0層基板1〇及壓模基板2〇會分別運送至下個步驟 之進行成膜之成膜裝置。將L0層基板10及壓模基板20以射 出成形機成形時’ L0層基板1〇及壓模基板20會在冷卻至特 定溫度後運送。 對於運送至成膜裝置之L0層基板10,將施以以下之處 理。首先’如圖3B所示,在形成有凹凸之L0層基板1〇之一 主面上’藉由濺鍍等形成資訊層(L0層)11(步驟S2)。例如, 唯讀光碟的情況中,乃以Ag(銀)、Ag類合金等之膜材來成 膜出全反射膜,而在可覆寫光碟的情況中,則形成記錄層。 記錄層例如係依序成膜出藉Ag、Ag合金等之反射膜、藉 ZnS-Si02等之保護膜、Ge-Sb-Te系之記錄膜、及藉ZnS-Si02 等之保護膜而成。 在L0層基板10之一主面上形成資訊層(L0層)11後,將l〇 層基板10運送至接著劑塗佈裝置,如圖3C所示般地,在成 膜有資訊層(L0層)11之L0層基板10之一主面上塗佈中間層 形成有之具透光性之紫外線硬化型樹脂(UV樹脂)12(步驟 S3)。紫外線硬化型樹脂12在L0層基板10之一主面上,例如 藉旋轉塗佈法塗佈成均勻之厚度。在此,關於欲塗佈之紫 外線硬化型樹脂12,為了塗佈後之膜厚均勻,例如使用的 為約500至3000 mPs黏度jij者。在中間層厚25 μπι之單面雙 層構造之高密度光碟的情況中,例如,乃將該紫外線硬化 型樹脂12之厚度塗佈成20至22 μιη。 104173.doc 13 1344149 在L0層基板10之一主面上塗佈紫外線硬化型樹脂12後, 如圖3D所示,對紫外線硬化型樹脂12照射紫外線,硬化中 間層用之紫外線硬化型樹脂12(步驟S4)。此時,為了提高 在後續步驟中與壓模基板20之接著力,紫外線之照射強度 調整成紫外線硬化型樹脂12不會完全硬化而成半硬化狀 態。 另一方面,對於運送至成膜裝置之壓模基板20,則施以 如下之處理。首先,如圖4B所示,在形成有凹凸之壓模基 板20之一主面上濺鍵機等成膜出剝離暨防濕層2i(步驟 S5)。作為剝離暨防濕膜21,例如會使用siN(氮化矽)、Ag、 Ag系合金等之對紫外線硬化型樹脂22的剝離性及防濕性佳 之具有半透性之金屬膜。此外,剝離暨防濕膜21藉由使用 與資訊層(L0層)11或例如後述之資訊層(l 1層)1 3所使用者 相同之材料,可有效率地進行成膜。 一在壓模基板20之一主面上成膜出剝離暨防濕膜21,就 將壓模基板20運送至接著劑塗佈裝置,如圖4C所示般地, 在成膜有剝離暨防濕膜21之壓模基板20之一主面上,塗佈 凹凸轉印用之具透光性之紫外線硬化型樹脂22(步驟S6) » 作為紫外線硬化型樹脂22,以聚碳酸酯等之樹脂材料及 與剝離暨防濕膜21之接著力低且轉印性高者為佳。紫外線 硬化型樹脂22在壓模基板20之一主面上,例如藉旋轉塗佈 法而塗佈成均勻的厚度。藉由以旋轉塗佈法來塗佈,壓模 基板2 0之凹凸上會毫無縫隙地塗佈有紫外線硬化型樹脂 22,可良好地轉印凹凸。在此,欲塗佈之紫外線硬化型樹 104173.doc 14 1344149 脂22為了使塗佈後之膜厚變薄,所使用的為例如約5〇至3〇〇 mPs之黏度偏低者。藉此,可抑制膜厚之誤差。在中間層厚 25 μπι之單面雙層構造之高密度光碟的情況中,例如,乃將 該紫外線硬化型樹脂22之厚度塗佈成3至5 μηι。如此般地, 藉由使紫外線硬化型樹脂22之厚度變薄,例如即使以比紫 外線硬化型樹脂12貴的材料來用作為紫外線硬化型樹脂 22,仍可抑制成本上升。
在壓模基板20之一主面上塗佈紫外線硬化型樹脂22後’ 如圖4D所示,對紫外線硬化型樹脂22照射紫外線,硬化凹 凸轉印用之紫外線硬化型樹脂22(步驟S7)。此時,為了提 高在後續步驟中與L0層基板1〇之接著力,紫外線之照射強 度調整成紫外線硬化型樹脂22不會完全硬化而成半硬化狀 態。在一實施方式中,貼合前之紫外線硬化型樹脂丨2及紫 外線硬化型樹腊22均為半硬化,惟亦可紫外線硬化型樹脂 12及紫外線硬化型樹脂22中僅其中一方為半硬化,亦可使 紫外線硬化型樹脂12及紫外線硬化型樹脂22中其中一方為 半硬化,使另一方硬化。 此外’對此等L0層基板1〇及壓模基板2〇所施之處理,例 如,可用DVD等之通常之貼合用光碟製造裝置來平行進 行。藉此,可縮短週期時間。 接著’如圖5A所示’重疊塗佈有紫外線硬化型樹脂12之 L0層基板10之一主面及塗佈有紫外線硬化型樹脂22之壓模 基板20之一主面’貼合l〇層基板10及壓模基板20(步驟S8)。 在貼合L0層基板1〇及壓模基板2〇後,如圖5B所示,對藉 104173.doc •15· 1344149 貼合而成之包含紫外線硬化型樹脂12及紫外線硬化型樹脂 22之中間層32由壓模基板20側照射紫外線,以完全硬化中 間層32(步驟S9)。 完全硬化中間層32後,由貼合之光碟基板剝離下壓模基 板20(步驟S 10)。例如’以真空吸附墊吸附保持貼合之光碟 基板之兩面,由中央孔侧將楔形模具插入L〇層基板1〇與壓 模基板20之間,將壓縮空氣供應至藉上述形成之間隙,剝 離壓模基板20。此時’壓模基板2〇之一主面上之剝離暨防 濕膜21及紫外線硬化型樹脂22的接著力低,因此,如圖5C 所示,壓模基板20之一主面上所塗佈之紫外線硬化型樹脂 22會由壓模基板20剝離’而在L0層基板10之一主面上轉印 壓模基板20之凹凸’形成出形成有資訊層(匕丨層)用微細凹 凸之紫外線硬化型樹脂22之層。 剝離壓模基板20後,如圖6A所示,藉紫外線硬化型樹脂 22在形成有資訊層(L1層)用微細凹凸之l〇層基板1〇之一主 面上’以濺鍍機等形成資訊層(L1層)13(步驟S11)。例如, 在唯讀光碟的情況中’乃藉由Ag(銀)、Ag系合金等之膜材 來成膜出半透光膜,至於在可覆寫光碟的情況中,則形成 記錄層。記錄層例如係依序成膜出藉Ag、Ag合金等之反射 膜、藉ZnS-Si〇2等之保護膜、(}e_sb_Te系之記錄膜、及藉 ZnS-Si02等之保護膜而成。 在L0層基板1〇之一主面上形成資訊層(^層口^後,如圖 6B所示’在形成有資訊層(L1層)13之L0層基板10之一主面 上,塗佈保護層用之具透光性之紫外線硬化型樹脂,形成 104I73.doc •16· 1344149 保護層14(步驟S12)。此時,紫外線硬化型樹脂為了能夠均 句厚度’乃藉例如旋轉塗佈法來塗佈於資訊層(1^層)13上。 另一方面,對於剝離後之壓模基板20,如圖7所示,在未 形成凹凸之另一主面上厚度均勻地塗佈貼合用之接著劑 23(步驟S13)。作為貼合用之接著劑23,為了確保光碟厚度 之均勻性’例如以使用亦為其他步驟所使用之紫外線硬化 型樹脂為佳◊此外,為使紫外線硬化型樹脂能夠成為均勻 之厚度’例如乃以旋轉塗佈法來塗佈於壓模基板2〇之另一 主面上。接著劑23塗佈成例如約2、3 μιη之厚度。 對於此等L0潛基板10及壓模基板20之處理,藉由平行進 行’可縮短製造裝置之週期。 接著,如圖8Α所示,貼合L0層基板10之另一主面及壓模 基板20之另一主面,並硬化接著劑(步驟S14)。例如,在接 著劑23為紫外線硬化型樹脂的情況中,藉由由壓模基板側 照射紫外線來硬化接著劑23。藉此,形成藉由貼合之光碟 基板。此外,關於上述步驟S12中之保護層14之形成,亦可 於該L0層基板1〇及壓模基板20之貼合後進行。 在貼合L0層基板10及壓模基板20後,如圖8B所示,在形 成有保護層14之L0層基板10之一主面上,亦即在保護層μ 的表面上’塗佈具有透光性之已知之硬膜劑,形成硬膜層 15(步驟S15)。硬膜層15之厚度形成例如約2、3 μπι 〇形成 有該硬膜層15之面側成為光碟之讀取面或寫入面。硬膜層 1 5係為了保護成為讀取面或寫入面之保護層者,視必要而 形成於保護層14上。 I04173.doc 17 1344149 在L0層基板10上之一主面上形成硬膜層15後,如圖8C, 在壓模基板20之一主面上,亦即成膜有剝離暨防濕膜2 1之 凹凸形成面上,塗佈保護膜用之紫外線硬化型樹脂,對塗 佈之紫外線硬化型樹脂照射紫外線來硬化紫外線硬化型樹 脂,形成保護層24(步驟S16)。該紫外線硬化型樹脂之塗佈 勿例如藉旋轉塗佈法而塗佈成均勻之厚度。保護層24之厚 度例如形成約2、3 μιη »形成有該保護層24之面側成為光碟 之印刷面。藉由設置保護層24,不僅可防止剝離暨防濕膜 21氧化,並可提升在下個步驟中之標籤印刷25令之墨水的 密合力。 在壓模基板20之一主面上形成保護層24後,將貼合之光 碟運送至進行檢查暨標籤印刷步驟之裝置。 標籤印刷步驟中,如圖8D所示,在形成有保護層24之壓 模基板20之一主面上施以標籤印刷25(步驟s丨7)。此外,保 護層14及硬膜層15、保護層24及標藏印刷25之形成並不特 別限於以上述之步驟來形成’例如’亦可在形成保護層Μ 後形成保護層14及硬膜層15。藉此,製造出單面雙層構造 之光碟。 圖9所示的為上述般製成之高密度光碟之剖面構造之一 例。由讀取面/寫入面至印刷面為止之光碟整體之厚度“為 1.2mmeL0層至讀取面/寫入面為止之厚度d2gi〇(^m,u 層至讀取面/寫入面止之厚度们為75 μη^亦即,中間層“ 之厚度d4為25 pm»L0層基板10及壓模基板2〇之厚度仏仏 均為0.55 _左右,貼合L〇層純1 〇及壓模基板2〇之由印刷 I04173.doc ^ 18- 1344149 面至L0層止之光碟基板之厚度d7則為1·1 mm。此外,該光 碟基板之厚度為包含資訊層(L0層)11、剝離暨防濕膜21、 接著劑23、保護層24及標籤印刷25等之厚度。 該光碟之構造係藉由讀取面/寫入面側將焦點對準於L0 層或L1層照射雷射光,以進行對L0層或L1層之資料讀取或 寫入。 如上述之說明,在本發明之一實施方式中,可縮短製造 週期(cycle time)。此外,每次轉印會使用新的壓模基板2〇, 因此,可良好地進行L1層之凹凸轉印。此外,有將轉印用 之壓模基板20貼合於L0層基板,因此,不需要廢棄壓模基 板20’可減少材料費、廢棄費用。此外,藉由l〇層基板10 及壓模基板20之貼合來構成光碟基板,因此,特別在l〇層 基板10及壓模基板20以相同條件成形的情況中,藉由以勉 曲方向會相反的方向貼合,可抑制貼合之L0層基板1〇及壓 模基板20經時產生之麵曲等之變形。藉由L0層基板1〇及壓 模基板20之間之接著劑23,可進一步抑制光碟想曲等之變 形。 此外,例如,在用於與DVD相同形狀之高密度光碟製造 的情況中’可利用貼合光碟基板之既有之DVD製造設備。 藉此,可無需花費成本及時間地製造。 本發明並不限於上述之本發明之實施方式,在不超脫本 發明要旨之範圍内,可實施各種變形及應用。例如,在上 述之一實施方式令,乃將L1層用凹凸轉印用之壓模基板2〇 貼合於L0層基板1〇上,惟貼合之壓模基板2〇亦可為其他光 104173.doc •19- 1344149 碟製造所用者^ 此外,上述之一實施方式中,雖將令間層32以紫外線硬 化型樹脂12及紫外線硬化型樹脂22之貼合來形成,惟中間 層之形成並不以此為限。例如,亦可在資訊層(L〇層)丨丨上 塗佈具有透光性之樹脂材料,在塗佈之樹脂材料上轉印壓 模基板20之凹凸後,使樹脂材料硬化來形成中間層32 ^ 此外,上述之一實施方式中,唯對單面雙層構造之光碟 加以說明,惟光碟構造並不以此為限。例如,亦可轉印壓 模基板20之凹凸而在L0層基板1〇之一主面上形成[〇層用之 凹凸,藉以應用於單層構造之光碟。此外’例如,亦可不 在L0層基板1〇之一主面上形成資訊層用之凹凸,進一步不 形成資訊層(L0層),而僅以上述之中間層32上之u層作為 資訊層,藉此成為單層構造之光碟a 此外,藉由形成上述中間層32及資訊層(1^層)13之組合2 個以上,則可應用於三層以上構造之光碟。在此情況中, 乃將各層之凹凸轉印用之複數片壓模基板2〇重疊貼合於L〇 層基板10上而形成光碟基板。此外,亦可重疊貼合複數片 其他光碟製造所用者,即使為單層及雙層以上構造之光 碟’亦可重疊貼合複數片壓模基板2〇。 此外,作為壓模基板2〇 ,亦可使用作為壓模用之以外的 不良基板及虛設基板等。此外,上述之紫外線硬化型樹脂 如具有所需特性的話,亦可使用熱可塑性樹脂等之其他材 料。此外,L0層基板10及壓模基板2〇之形狀亦不限於具有 中央孔之光碟形狀》 104173.doc -20· 【圖式簡單說明】 圖1係本發明之·一眘& + b 賞知方式所適用之光碟製造步驟之— 例之流程圖(前半)。 圖2係本發明之一實施方式所適用之光碟製造步驟之— 例之流程圖(後半)。 圖3 A至圖3D係為了說明L〇層基板之成形步驟的光碟之 剖面放大圖。 圖4A至圖4D係為了說明壓模基板之成形步驟的光碟之 剖面放大圖。 圖5A至圖5C係為了說明貼合及剝離步驟的光碟之剖面 放大圖。 圖6A及圖6B係為了說明l〇層基板側之步驟的光碟之剖 面放大圖。 圖7係為了說明壓模基板側之步驟的光碟之剖面放大圖。 圖8Α至圖8D係為了說明貼合後之步驟的光碟之剖面放 大圖。 圖9係以一實施方式所適用之單面雙層構造之高密度光 碟之剖面構造之一例為示之概略線圖。 【主要元件符號說明】 10 L0層基板 11 資訊層(L0層) 12 紫外線硬化型樹脂 13 資訊層(L1層) 14 保護層 104173.doc -21 - 1344149 15 硬膜層 20 壓模基板 21 剝離暨防濕膜 22 紫外線硬化型樹脂 23 接著劑 24 保護層 25 標籤印刷 32 中間層 SI L0層及壓模基板成形 S2 資訊層(L0層)形成 S3 中間層用UV樹脂塗佈 S4 中間層用UV樹脂硬化 S5 剥離暨防濕膜成膜 S6 凹凸轉印用UV樹脂塗佈 S7 凹凸轉印用UV樹脂硬化 S8 L0層基板及壓模基板之貼合 S9 中間層UV硬化 S10 壓模基板剝離 Sll 資訊層(L1層)形成 S12 透光性保護層形成 S13 貼合用接著劑塗佈 S14 L0層基板及壓模基板之貼合 S15 硬膜層形成(讀取面側) S16 保護層形成(印刷面側) S17 標籤印刷 I04173.doc -22-

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1344149 十、申請專利範圍: L 一種光碟之製造方法, 該光碟係以在基板之一主面上照射記錄及/或播放光之 方式進行資訊信號之記錄及/或播放者; 該方法之特徵為包含: 使在一主面上藉壓模基板形成有資訊層用凹凸之基板 成形之步驟; 在上述凹凸上形成資訊層之步驟; 在上述資訊層上形成具有透光性之保護層之步驟;及 在上述基板之另一主面上貼合上述壓模基板或為了在 其他基板上形成上述凹凸所用之壓模基板之步驟。 2· 一種光碟之製造方法, 該光碟係以在基板之一主面上照射記錄及/或播放光之 方式進行資訊信號之記錄及/或播放者; 該方法之特徵為包含: 使在一主面上形成有第一資訊層用凹凸之基板成形之 步驟; 在上述凹凸上形成第一資訊層之步驟; 在上述第一資訊層上及在壓模基板形成有凹凸之主面 上分別塗佈樹脂材料之步驟; 藉由使在上述第一資訊層上及壓模基板上分別塗佈之 上述樹脂材料中至少一者半硬化後貼合,使貼合之上述 樹脂材料硬化後,剝離上述壓模基板,以在上述第一資 訊層上形成形成有第二資訊層用凹凸之中間層之步驟; I04173.doc 1344149 在上述中間層上形成第二資訊層之步驟; 在上述第一資訊層上形成具有透光性之保護層之步 驟;及 在上述基板之另一主面上貼合上述壓模基板或為了在 其他基板上形成上述第二資訊層用凹凸所用之壓模基板 之步驟。 3.如請求項2之光碟之製造方法,其中 上述基板及上述壓模基板以樹脂材料構成,並將上述 基板及上述壓模基板以雙模穴射出成形機來並行成形。 4‘如請求項2之光碟之製造方法,其中 上述壓模基板含具透光性之材料,使用紫外線硬化型 樹脂作為上述樹脂材料,並對上述樹脂材料經由上述壓 模基板照射紫外線而使上述樹脂材料硬化。 5. 如請求項2之光碟之製造方法,其中 上述壓模基板與上述基板的材料相同。 6. 如請求項2之光碟之製造方法,其中 上述基板及上述壓模基板之厚度約略相同。 7. 如請求項2之光碟之製造方法,其中 在上述壓模基板形成有凹凸之主面上,形成防濕性佳 且與上述樹脂材料之剝離性良好之薄膜後,將上述樹脂 材料塗佈於上述壓模基板。 8. 如請求項7之光碟之製造方法,其中 上述薄膜之材料係使用氮化矽β 9. 如請求項7之光碟之製造方法,其中 I04l73.doc 1344149 上述薄膜之材料係使用上述第一資訊層或上述第二資 訊層之形成用之膜材。 10·如請求項2之光碟之製造方法,其中 以上述壓模基板之形成有凹凸之主面為外側,貼合上 述基板及上述壓模基板,在該主面上形成保護層。 11. 如請求項10之光碟之製造方法,其中 在上述壓模基板之主面上所形成之保護層上實施印 刷。 12. 如請求項2之光碟之製造方法,其令 在上述具透光性之保護層上形成具透光性之硬膜層。 13. 如請求項2之光碟之製造方法,其中 重複實施複數次上述塗佈樹脂材料之步驟、上述形成 中間層之步驟、及上述形成第二資訊層之步驟。 14. 如請求項2之光碟之製造方法,其中 在上述基板之另一主面上貼合複數片上述壓模基板及/ 或為了在其他基板上形成上述第二資訊層用凹凸所用之 壓模基板。 15. —種光碟之製造方法, 該光碟係以在基板之一主面上照射記錄及/或播放光之 方式進行資訊信號之記錄及/或播放者; 該方法之特徵為包含: 使在一主面上形成有第一資訊層用凹凸之基板成形之 步驟; 在上述凹凸上形成第一資訊層之步驟; 104l73.doc 藉由在上述第一資訊層上塗佈具有透光性之樹脂材 料在塗佈之樹脂材料上轉印壓模基板之凹凸後使上述 樹脂材料硬化,以在上述第一資訊層上形成形成有第二 資訊層用凹凸之中間層之步驟; 在上述中間層上形成第二資訊層之步驟; 在上述第二資訊層上形成具有透光性之保護層之步 驟;及 在上述基板之另一主面上貼合上述壓模基板或為了在 其他基板上形成上述第二資訊層凹凸所用之壓模基板之 步驟。 16. —種光碟, 其係以在基板之一主面上照射記錄及/或播放光之方式 進行資訊信號之記錄及/或播放者; 其特徵為包含: 基板’其係在一主面上以壓模基板形成有資訊層用之 凹凸; 資訊層,其係形成於上述凹凸上; 保護層’其係在上述資訊層上所形成之具透光性者; 及 上述壓模基板或為了在其他基板上形成凹凸所用之壓 模基板,其係貼合於基板之另一主面上。 17·—種光碟’ 其係以在基板之一主面上照射記錄及/或播放光之方式 進行資訊信號之記錄及/或播放者; 104173.doc 1344149 其特徵為包含: 基板’其係在一主面上形成有第一資訊層用之凹凸; 第一資訊層,其係形成於上述凹凸上; 形成有第二資訊層用之凹凸之中間層,其係以在上述 第一資訊層上及壓模基板之形成有凹凸之主面上分別塗 佈樹脂材料,並使上述第一資訊層上及上述壓模基板上 刀別塗佈之上述樹脂材料中至少一者半硬化後貼合,使 貼合之上述樹脂材料硬化後’剝離上述壓模基板之方 式’形成在上述第一資訊層上; 第二資訊層,其係形成於上述中間層上; 保護層’其係在上述第二資訊層上所形成之具透光性 者;及 壓模基板或為了在其他基板上形成上述第二資訊層用 凹凸所用之壓模基板,其係貼合於上述基板之另一主面 上。 18. 如請求項17之光碟,其中 上述基板及上述壓模基板以樹脂材料構成,且上述基 板及上述壓模基板係以雙模穴射出成形機來並行成形。 19. 如請求項17之光碟,其中 上述壓杈基板含具透光性之材料,使用紫外線硬化型 樹脂作為上述樹脂材料。 20·如請求項π之光碟,其中 上述壓模基板係與上述基板的材料相同。 21.如請求項17之光碟,其中 104173.doc 1344149 上述基板及上述壓模基板之厚度約略相同。 22.如請求項17之光碟,其中 在上述壓模基板形成有凹凸之主面上,形成有防濕性 佳且與上述樹脂材料之剝離性良好之薄膜。 23_如請求項22之光碟,其中 上述薄臈之材料係使用氮化矽。 24. 如請求項22之光碟,其中 上述薄膜之材料係使用上述第一資訊層或上述第二資 訊層之形成用之膜材。 25. 如請求項17之光碟,其中 上述基板及上述壓模基板係以上述壓模基板之形成有 凹凸之主面為外側而貼合,並在該主面上形成有保護層。 26. 如請求項25之光碟,其中 在上述壓模基板之主面上所形成之保護層上施有印 刷。 27. 如請求項17之光碟,其中 上述具透光性之保護層上形成有具透光性之硬膜層。 28. 如清求項17之光碟,其中 上述中間層及上述第二資訊層之組合形成有2組以上。 29,如請求項17之光碟,其中 在上述基板之另一主面上貼合有複數片上述壓模基板 及/或為了在其他基板上形成上述第二資訊層用凹凸所用 之壓模基板》 30. —種光碟, 104173.doc ^44149 其係以在基板之一主面上照射記錄及/或播放光之方式 進行資訊信號之記錄及/或播放者; 其特徵為包含: 基板,其係在一主面上形成有第一資訊層用之凹凸; 第一資訊層,其係形成於上述凹凸上; 形成有第二資訊層用之凹凸之中間層,其係藉由在上 述第一資訊層上塗佈之具透光性之樹脂材料,並在塗佈 之樹脂材料上轉印壓模基板之凹凸後,使樹脂材料硬 化’形成在上述第一資訊層上; 第一資訊層,其係形成於上述中間層上; 保護層,其係在上述第二資訊層上所形成之具透光性 者;及 壓模基板或為了在其他基板上形成上述第二資訊層用 凹凸所用之壓模基板,其係貼合於上述基板之另一主面 上0
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