TW589330B - Process for the preparation of monodisperse polymer particles - Google Patents
Process for the preparation of monodisperse polymer particles Download PDFInfo
- Publication number
- TW589330B TW589330B TW089107457A TW89107457A TW589330B TW 589330 B TW589330 B TW 589330B TW 089107457 A TW089107457 A TW 089107457A TW 89107457 A TW89107457 A TW 89107457A TW 589330 B TW589330 B TW 589330B
- Authority
- TW
- Taiwan
- Prior art keywords
- seed particles
- aqueous dispersion
- particles
- organic compound
- monomer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/10—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2347/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Paper (AREA)
Description
589330
申清專利範園 聚合引發劑。 項之方法,其中具有 泛乙婦吡咯烷被用作 根據申請專利範圍第1至3項中任 一 Ά 重量平均分予量為1〇至2〇〇〇 kD之聚 該空間安定劑。 •根據申請專利範圍第1至3 J員中任一項之方法,其中聚乙 婦峨錢被用作空間安定劑而該膨脹之晶種顆粒的模式 直徑取多為16 //m。 6·根據申請專利範圍第1至3項中任一項之方法,其中當該 膨脹之晶種顆粒之水性分散液在聚合時之水相更包含水 溶性纖維素醚料空間安定齊卜該_服之晶種顆粒^模 式直徑大於15 //m 〇 7·根據申請專利範圍第丨至3項中任一項之方法,其中羥基 丙基甲基纖維素被用作該空間安定劑。 8.根據中請專利範圍第7項之方法,纟中職基丙基甲基
9·根據申請專利範圍第丨至3項中任一項之方法,其中具有 分子量1 0至100 kD之纖維素醚被用作該空間安定劑。 10. —種多孔性單分散聚合物顆粒之製備方法,該方法包 (1)形成水性分散液,其包含⑴單分散可膨脹晶種 聚合物(或寡聚物)顆粒,(⑴含有分子量在5〇〇〇道爾頓 以下及在25 C下水溶解度為低於1〇-2 g/L之有機化合物 之液滴’(in)陰離子介面活性劑,及視需要而定,(iv) 該有機化合物可溶於其中之有機溶劑;及使該有機化 本紙張尺度適用中國國家標準(cns) A4規格(210x 297公董) 589330
合物擴散於該晶種顆粒中, =將晶種顆粒之水性分散液接觸單體,且使該單體 :晶種顆粒中以形成膨脹之晶種顆粒之水性分 :履’且如需要,則加入水溶性空間安定劑,如需 双則加入普《精(porogen),及如需要,則加入聚合 引發劑;以及 引發該單體於膨脹之晶種顆粒的水性分散液中之 二奋,其特徵為該膨脹之晶種顆粒包含至少二個普洛 ,’至其中為溶劑供步驟(3)製成之聚合物及至 少其中之一並非溶劑供步驟(3)製成之聚合物。 Π·—種多孔性單分«合物顆粒之製備方法,該方法包 括: (1) 形成水性分散液,其包含單分散可膨脹晶種寡聚 物顆粒與較佳為陰離子介面活性劑; (2) 將晶種顆粒之水性分散液接觸單體,且使該單體 ,散於該晶種顆粒中以形成膨脹之晶種顆粒之水性分 政液,且如需要,則加入水溶性空間安定劑,如需 要’則加入普洛精(P〇r〇gen),及如需要,則加入聚合 引發劑;以及 (3 )引發該單體於膨脹之晶種顆粒的水性分散液中之 聚合’其特徵為該膨脹之晶種顆粒包含至少二個普洛 精’至少其中之一為溶劑供步驟製成之聚合物及至 少其中之一並非溶劑供步驟(3)製成之聚合物。 12·根據申請專利範圍第丨〇項之方法,其中該有機化合物為 -4- 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公楚) 589330 申清專利範圍
A BCD 月 > ¼
正 ι合引發劑。 13.根據申請專利範圍第1〇至12項中任一項之方法,其中該 普洛精包含甲苯及正庚烷。 14·根據申請專利範圍第1或1〇項之方法,其中: (1) 早分散可膨脹晶種顆粒係藉乳液聚合製備,其中 陰離子介面活性劑在實質上無氧條件下被用作乳化 劑,該可膨脹晶種顆粒具有模式粒徑範圍為0 2至i V m ; (2) 當孩晶種顆粒為非寡聚合(及視需要當其為寡聚 合時)時,⑷將該晶種顆粒接觸含有分子量在5〇〇〇道爾 頓以下及在25°C下水溶解度為低於1〇-2 g/L之有機化合 物之水性分散液、陰離子介面活性劑及視需要該有機 化合物可溶於其中之有機溶劑,及0)使該有機化合物 擴散於該晶種顆粒内; (3) 將晶種顆粒之水性分散液接觸單體,當該有機化 合物存在時,該單體較該有機化合物具至少倍以上 水溶性;如需要水溶性空間安定劑,如需要普洛精 (porogen),及如需要聚合引發劑,則使該單體擴散於 該晶種顆粒中以形成膨脹之晶種顆粒之水性分散液; 及 (4) 引發該單體於含空間安定劑之水性分散液内於連 續相中之聚合。 15.根據申請專利範圍第丨4項之方法,其中該有機化合物為 聚合引發劑。 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公釐)
16·根射請專利範圍第14項之方法,其中在步驟⑴中水 相之氧含量為〇與1 ppm之間。 17·根據申請專利範圍第1至3及1 〇至1 2項中任一項之方 法’其中該單體包含至少3 〇重量%二乙烯苯。 18·根據申請專利範園第j、3、i 〇及丨2項中任一項之方 法’其中該有機化合物為過氧化二辛醯。 19·根據申請專利範圍第i、2、i 〇及丨丨項中任一項之方 法,其特徵另為該單體包括至少二個丙烯酸或甲基丙 酸或酿單體。 ' 20.根據申請專利範圍第19項之方法,其中甲基丙埽酸縮水 甘油酯被用作該單體。 21·根據申請專利範圍第1 4項之方法,其中,當單體為胺其 耳能化之單體(或當使用二或以上個單體而一共聚用單體 為胺基官能化之單體)時,該有機化合物,若存在時,為 非引發劑,而聚合引發劑在該晶種顆粒已膨脹後被加 入0 22·根據申請專利範圍第2或η項之方法,其中該單體為胺 基官能化之單體(或當使用二或以上個單體時,一共聚用 單體為胺基官能化之單體)。 23.根據申請專利範圍第2 2項之方法,其中步驟(2)係使用 聚合引發劑。 24·根據申請專利範圍第21項之方法,其中該非引發劑為二 辛基己二酸酯。 25·根據申請專利範圍第21項之方法,其中該聚合引發劑為 -6- 本紙張尺度適用中國國家標準(CNS) Α4規格(210X 297公釐) 589330
2,2’-偶氮雙_(2_甲基丁腈)。 26·根據申請專利範圍第24項之方法,其中該聚合引發劑為 2,2、偶氮雙- (2 -甲基丁腈)。 27·根據申請專利範圍第22項之方法,其中該聚合引發劑為 2,2’_偶氮雙_(2-甲基丁腈)。 28·根據申請專利範圍第2 3項之方法,其中該聚合引發劑為 2,2、偶氮雙-(2-甲基丁腈)。 29·根據申請專利範圍第i至3及丨〇至丨2項中任一項之方 法’其中該陰離子介面活性劑為硫酸十二烷基鈉。 30·根據申請專利範圍第i至3及丨〇至丨2項中任一項之方 法其中该單分散聚合物顆粒後續被塗佈、浸潰或衍生 化。 31·種清潔由申請專利範圍第1至3及1 〇至1 2項中任_项 足万法所製得之單分散聚合物顆粒之方法,該方法包 括將該單分散聚合物顆粒接觸乙酸丁酯。 ^紙張尺度適用中國國家標準(CNS) A4:規格(210X 297公楚) "-—
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9908163.0A GB9908163D0 (en) | 1999-04-09 | 1999-04-09 | Process |
GBGB0007008.6A GB0007008D0 (en) | 1999-04-09 | 2000-03-22 | Process |
Publications (1)
Publication Number | Publication Date |
---|---|
TW589330B true TW589330B (en) | 2004-06-01 |
Family
ID=26243944
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW089107457A TW589330B (en) | 1999-04-09 | 2000-04-20 | Process for the preparation of monodisperse polymer particles |
Country Status (8)
Country | Link |
---|---|
US (6) | US7217762B1 (zh) |
EP (2) | EP1177231B1 (zh) |
CN (2) | CN1311005C (zh) |
AU (2) | AU777829B2 (zh) |
CA (1) | CA2369293C (zh) |
NO (1) | NO332815B1 (zh) |
TW (1) | TW589330B (zh) |
WO (1) | WO2000061647A1 (zh) |
Families Citing this family (66)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1177231B1 (en) | 1999-04-09 | 2009-08-19 | Invitrogen Dynal AS | Process for the preparation of monodisperse polymer particles |
GB0228914D0 (en) | 2002-12-11 | 2003-01-15 | Dynal Biotech Asa | Particles |
NO20041205L (no) | 2004-03-22 | 2005-09-23 | Polymers Holding As | Lagringsstabile polymer-oligomer partikler og anvendelse av disse i seed polymerisasjon |
EP2295471B1 (en) * | 2005-09-16 | 2019-10-23 | Rohm and Haas Company | Method for making swellable particles |
US8444898B2 (en) * | 2006-03-30 | 2013-05-21 | Honeywell International Inc | High molecular weight poly(alpha-olefin) solutions and articles made therefrom |
WO2007127799A2 (en) * | 2006-04-25 | 2007-11-08 | Research Foundation Of The City University Of New York | Polymer submicron particle preparation by surfactant- mediated precipitation |
US9738745B2 (en) | 2006-06-29 | 2017-08-22 | Life Technologies As | Particles containing multi-block polymers |
JP5493248B2 (ja) * | 2007-04-25 | 2014-05-14 | 日油株式会社 | コア−シェル微粒子の製造方法及びその中間体の製造方法 |
CN101186661B (zh) * | 2007-12-14 | 2012-09-19 | 深圳市纳微科技有限公司 | 一种聚合物颗粒的制备方法 |
WO2009142231A1 (ja) * | 2008-05-21 | 2009-11-26 | 東レ株式会社 | ポリマー微粒子の製造方法 |
GB0907372D0 (en) * | 2009-04-29 | 2009-06-10 | Invitrogen Dynal As | Particles |
US8790916B2 (en) | 2009-05-14 | 2014-07-29 | Genestream, Inc. | Microfluidic method and system for isolating particles from biological fluid |
JP5483451B2 (ja) * | 2009-12-30 | 2014-05-07 | ローム アンド ハース カンパニー | 均一なポリマービーズを製造する方法 |
JP5474745B2 (ja) * | 2009-12-30 | 2014-04-16 | ローム アンド ハース カンパニー | 均一なオリゴマー液滴を製造する方法 |
US9822010B2 (en) | 2010-01-21 | 2017-11-21 | CoLabs International Corporation | Ceramic encapsulation by use of one or more specialized silanes to template oil in an oil in water emulsion |
US8747084B2 (en) | 2010-07-21 | 2014-06-10 | Aperia Technologies, Inc. | Peristaltic pump |
US8822663B2 (en) | 2010-08-06 | 2014-09-02 | Moderna Therapeutics, Inc. | Engineered nucleic acids and methods of use thereof |
AU2011308496A1 (en) | 2010-10-01 | 2013-05-02 | Moderna Therapeutics, Inc. | Engineered nucleic acids and methods of use thereof |
GB201018380D0 (en) | 2010-10-29 | 2010-12-15 | Conpart As | Process |
GB201018379D0 (en) | 2010-10-29 | 2010-12-15 | Conpart As | Conductive rf particles |
EP2663639B1 (en) | 2011-01-14 | 2017-09-13 | Life Technologies Corporation | Methods for isolation, identification, and quantification of mirnas |
DE12722942T1 (de) | 2011-03-31 | 2021-09-30 | Modernatx, Inc. | Freisetzung und formulierung von manipulierten nukleinsäuren |
JP2012255135A (ja) * | 2011-05-17 | 2012-12-27 | Rohm & Haas Co | 熱可塑性ポリマーを吸収したラテックス粒子 |
US9464124B2 (en) | 2011-09-12 | 2016-10-11 | Moderna Therapeutics, Inc. | Engineered nucleic acids and methods of use thereof |
US20130109596A1 (en) | 2011-09-26 | 2013-05-02 | Life Technologies Corporation | High efficiency, small volume nucleic acid synthesis |
WO2014153188A2 (en) | 2013-03-14 | 2014-09-25 | Life Technologies Corporation | High efficiency, small volume nucleic acid synthesis |
WO2013052523A1 (en) | 2011-10-03 | 2013-04-11 | modeRNA Therapeutics | Modified nucleosides, nucleotides, and nucleic acids, and uses thereof |
CA2859387A1 (en) | 2011-12-16 | 2013-06-20 | Moderna Therapeutics, Inc. | Modified nucleoside, nucleotide, and nucleic acid compositions |
CN104203964B (zh) | 2012-02-09 | 2017-07-18 | 生命技术公司 | 疏水的二丙烯酰胺化合物 |
EP2812446B1 (en) | 2012-02-09 | 2017-05-10 | Life Technologies Corporation | Conjugated polymeric particle and method of making same |
WO2013119936A2 (en) | 2012-02-09 | 2013-08-15 | Life Technologies Corporation | Hydrophilic polymeric particles and methods for making same |
US9039392B2 (en) | 2012-03-20 | 2015-05-26 | Aperia Technologies, Inc. | Tire inflation system |
US9572897B2 (en) | 2012-04-02 | 2017-02-21 | Modernatx, Inc. | Modified polynucleotides for the production of cytoplasmic and cytoskeletal proteins |
US10501512B2 (en) | 2012-04-02 | 2019-12-10 | Modernatx, Inc. | Modified polynucleotides |
WO2013151669A1 (en) | 2012-04-02 | 2013-10-10 | modeRNA Therapeutics | Modified polynucleotides for the production of cytoplasmic and cytoskeletal proteins |
US9283287B2 (en) | 2012-04-02 | 2016-03-15 | Moderna Therapeutics, Inc. | Modified polynucleotides for the production of nuclear proteins |
TWI557160B (zh) * | 2012-04-19 | 2016-11-11 | 國家中山科學研究院 | 高交聯度均一粒徑高分子微球製備方法 |
GB201212489D0 (en) | 2012-07-13 | 2012-08-29 | Conpart As | Improvements in conductive adhesives |
US9597380B2 (en) | 2012-11-26 | 2017-03-21 | Modernatx, Inc. | Terminally modified RNA |
US10144254B2 (en) | 2013-03-12 | 2018-12-04 | Aperia Technologies, Inc. | Tire inflation system |
US9604157B2 (en) | 2013-03-12 | 2017-03-28 | Aperia Technologies, Inc. | Pump with water management |
US11453258B2 (en) | 2013-03-12 | 2022-09-27 | Aperia Technologies, Inc. | System for tire inflation |
US8980864B2 (en) | 2013-03-15 | 2015-03-17 | Moderna Therapeutics, Inc. | Compositions and methods of altering cholesterol levels |
EP3052521A1 (en) | 2013-10-03 | 2016-08-10 | Moderna Therapeutics, Inc. | Polynucleotides encoding low density lipoprotein receptor |
CA2926883C (en) * | 2013-12-04 | 2019-04-09 | F. Hoffmann-La Roche Ag | Improved process for producing magnetic monodisperse polymer particles |
ES2465715B1 (es) | 2014-02-14 | 2015-03-18 | Universitat Autónoma De Barcelona | Péptido, péptido magnético y método para detectar la enfermedad celíaca |
CN104072663B (zh) * | 2014-06-27 | 2016-02-24 | 西北工业大学 | 一种表面褶皱单分散固定化酶载体的制备方法 |
EP3557262B1 (en) | 2014-12-09 | 2022-08-10 | Life Technologies Corporation | High efficiency, small volume nucleic acid synthesis |
CN104788709A (zh) * | 2015-04-17 | 2015-07-22 | 张家港市山牧新材料技术开发有限公司 | 一种超大粒径复合橡胶改性聚苯乙烯树脂的制备方法 |
CN107922974B (zh) | 2015-07-02 | 2021-11-09 | 生命技术公司 | 羧基官能亲水微珠的偶合 |
US9868826B2 (en) | 2015-07-02 | 2018-01-16 | Life Technologies Corporation | Polymer substrates formed from carboxy functional acrylamide |
US10150992B2 (en) | 2015-07-06 | 2018-12-11 | Life Technologies Corporation | Substrates and methods useful in sequencing |
GB201512725D0 (en) * | 2015-07-20 | 2015-08-26 | Life Technologies As | Polymeric particles |
CN105131168A (zh) * | 2015-10-23 | 2015-12-09 | 蓝星(成都)新材料有限公司 | 一种大孔甲基丙烯酸羟乙酯树脂及其制备方法 |
CA3008679C (en) * | 2015-12-21 | 2023-03-21 | Dow Global Technologies Llc | Multistage aqueous emulsion polymer and aqueous coating composition formed therefrom |
CN109952237B (zh) | 2016-09-06 | 2022-08-26 | 阿佩利亚科技公司 | 用于轮胎充气的系统 |
CN106589222A (zh) * | 2016-12-05 | 2017-04-26 | 黄晖 | 一种单分散高分子微球及其制备方法 |
GB201700983D0 (en) | 2017-01-20 | 2017-03-08 | Life Tech As | Polymeric particles |
BR112019019338A2 (pt) * | 2017-03-27 | 2020-05-05 | Dow Global Technologies Llc | processo. |
US10406869B2 (en) | 2017-11-10 | 2019-09-10 | Aperia Technologies, Inc. | Inflation system |
US11851536B2 (en) * | 2018-10-02 | 2023-12-26 | Xerox Corporation | Precipitation process for preparing polystyrene microparticles |
US11642920B2 (en) | 2018-11-27 | 2023-05-09 | Aperia Technologies, Inc. | Hub-integrated inflation system |
CN110950989B (zh) | 2019-11-05 | 2023-01-10 | N科研中心私人投资有限公司 | 用于制备单分散颗粒的方法 |
CN111635551B (zh) * | 2020-06-23 | 2022-04-22 | 哈尔滨工程大学 | 一步法制备聚酰亚胺开孔泡沫的方法及产品 |
WO2023088864A1 (de) * | 2021-11-18 | 2023-05-25 | Lanxess Deutschland Gmbh | Verfahren zur herstellung von polymerisaten |
GB2620799A (en) | 2022-07-22 | 2024-01-24 | Life Tech As | Particles |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE483422A (zh) * | 1946-12-13 | |||
US4382124B1 (en) | 1958-07-18 | 1994-10-04 | Rohm & Haas | Process for preparing macroreticular resins, copolymers and products of said process |
NL241315A (zh) | 1958-07-18 | |||
DE1420830A1 (de) * | 1959-07-16 | 1968-10-31 | Wacker Chemie Gmbh | Verfahren zur Kondensation von Organosiloxanen |
DE1917090C3 (de) | 1968-04-06 | 1980-04-24 | Sekisui Kagaku Kogyo K.K., Osaka (Japan) | Verfahren zur Herstellung von Styrolpolymerteilchen mit einheitlichen Größen |
FR2238718A1 (en) | 1973-07-27 | 1975-02-21 | Sekisui Chemical Co Ltd | Polystyrene particles of uniform size, esp. for foams - by polymerising in suspension of fine polystyrene particles, contg. catalyst and polymn retarder |
NO141367C (no) | 1976-11-22 | 1980-02-27 | Sintef | Framgangsmaate for framstilling av findelte emulsjoner av et litt vannloeselig materiale |
AU530410B2 (en) | 1978-02-21 | 1983-07-14 | Sintef | Preparing aqueous emulsions |
JPS5829962B2 (ja) * | 1979-08-23 | 1983-06-25 | 東レ株式会社 | 親水性水不溶性微粒子の製造方法 |
NO149108C (no) | 1981-10-21 | 1984-02-15 | Sintef | Fremgangsmaate for fremstilling av vandige dispersjoner av organisk materiale og eventuelt videre omdannelse til en polymerdispersjon naar det organiske materiale er en polymeriserbar monomer |
US4564644A (en) | 1982-08-02 | 1986-01-14 | The Dow Chemical Company | Ion exchange resins prepared by sequential monomer addition |
JPS6126505A (ja) * | 1984-07-17 | 1986-02-05 | Toray Ind Inc | 黒色粒子 |
EP0326383B1 (en) * | 1988-01-29 | 1994-06-15 | Mita Industrial Co. Ltd. | Process for preparation of monodisperse polymer particles having increased particle size |
JPH03237105A (ja) | 1989-09-19 | 1991-10-23 | Mita Ind Co Ltd | 単分散重合体粒子の製造方法 |
JP3135262B2 (ja) | 1991-03-06 | 2001-02-13 | ガーヴァン インスティチュート オブ メディカル リサーチ | ヒトのガラニン、ヒトのガラニンをエンコードするcD NAクローンとヒトのガラニン製造方法 |
US5130343A (en) * | 1991-03-13 | 1992-07-14 | Cornell Research Foundation, Inc. | Process for producing uniform macroporous polymer beads |
US5231115A (en) * | 1991-12-19 | 1993-07-27 | The Dow Chemical Company | Seeded porous copolymers and ion-exchange resins prepared therefrom |
US5306561A (en) | 1992-02-20 | 1994-04-26 | Cornell Research Foundation, Inc. | Preparation of surface-functional polymer particles |
JP3166296B2 (ja) | 1992-05-20 | 2001-05-14 | 三菱化学株式会社 | 多孔性架橋共重合体粒子表面の付着微粒子の除去方法 |
US5366782A (en) * | 1992-08-25 | 1994-11-22 | The Procter & Gamble Company | Polymeric web having deformed sections which provide a substantially increased elasticity to the web |
CA2097630A1 (en) | 1992-12-29 | 1994-06-30 | Ann Louise Mccormack | Stretch-pillowed, bulked laminate |
JPH06256438A (ja) | 1993-03-09 | 1994-09-13 | Japan Synthetic Rubber Co Ltd | 重合体粒子の製造方法 |
JPH0727754A (ja) | 1993-07-09 | 1995-01-31 | Mitsubishi Chem Corp | カチオンクロマトグラフィー用充填剤及びその製造方法 |
NO308414B1 (no) | 1996-04-23 | 2000-09-11 | Polymers Holding As | Fremgangsmate for fremstilling av PVC-partikler, anvendelse av PVC-partiklene, samt PVC-partiklene som sadan |
JPH101561A (ja) | 1996-06-17 | 1998-01-06 | Dainippon Ink & Chem Inc | 発泡性スチレン系樹脂粒子 |
CA2262018C (en) | 1996-07-29 | 2007-10-02 | Nanosphere Llc | Nanoparticles having oligonucleotides attached thereto and uses therefor |
DE19634393A1 (de) | 1996-08-26 | 1998-03-05 | Bayer Ag | Verfahren zur Herstellung vernetzter Polymerisate |
JP3510089B2 (ja) | 1997-09-22 | 2004-03-22 | ユニ・チャーム株式会社 | 体液吸収性物品の透液性表面シートおよび該シートの製造方法 |
PL199101B1 (pl) * | 1997-10-10 | 2008-08-29 | Polymer Systems As | Sposoby wytwarzania polimerów w postaci cząstek |
EP1177231B1 (en) | 1999-04-09 | 2009-08-19 | Invitrogen Dynal AS | Process for the preparation of monodisperse polymer particles |
-
2000
- 2000-04-10 EP EP00919034A patent/EP1177231B1/en not_active Expired - Lifetime
- 2000-04-10 EP EP08162270.6A patent/EP1985639B1/en not_active Expired - Lifetime
- 2000-04-10 US US09/958,431 patent/US7217762B1/en not_active Expired - Lifetime
- 2000-04-10 AU AU39791/00A patent/AU777829B2/en not_active Expired
- 2000-04-10 CN CNB2005100038156A patent/CN1311005C/zh not_active Expired - Lifetime
- 2000-04-10 WO PCT/GB2000/001334 patent/WO2000061647A1/en active IP Right Grant
- 2000-04-10 CN CNB008070474A patent/CN1189495C/zh not_active Expired - Lifetime
- 2000-04-10 CA CA2369293A patent/CA2369293C/en not_active Expired - Lifetime
- 2000-04-20 TW TW089107457A patent/TW589330B/zh not_active IP Right Cessation
-
2001
- 2001-10-04 NO NO20014835A patent/NO332815B1/no not_active IP Right Cessation
-
2004
- 2004-10-18 AU AU2004222716A patent/AU2004222716B2/en not_active Expired
-
2007
- 2007-05-11 US US11/747,860 patent/US20070265390A1/en not_active Abandoned
-
2009
- 2009-12-21 US US12/644,003 patent/US20100099803A1/en not_active Abandoned
-
2012
- 2012-10-10 US US13/649,045 patent/US8658733B2/en not_active Expired - Fee Related
-
2014
- 2014-01-10 US US14/152,793 patent/US9309368B2/en not_active Expired - Fee Related
-
2015
- 2015-09-28 US US14/867,394 patent/US20160075800A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
NO20014835L (no) | 2001-12-07 |
US20070265390A1 (en) | 2007-11-15 |
AU2004222716B2 (en) | 2007-07-05 |
AU777829B2 (en) | 2004-11-04 |
CA2369293C (en) | 2010-06-08 |
EP1177231A1 (en) | 2002-02-06 |
AU2004222716A1 (en) | 2004-11-11 |
CA2369293A1 (en) | 2000-10-19 |
US20140256836A1 (en) | 2014-09-11 |
AU3979100A (en) | 2000-11-14 |
EP1985639A2 (en) | 2008-10-29 |
US20100099803A1 (en) | 2010-04-22 |
CN1189495C (zh) | 2005-02-16 |
WO2000061647A1 (en) | 2000-10-19 |
EP1985639A3 (en) | 2008-11-12 |
US7217762B1 (en) | 2007-05-15 |
NO20014835D0 (no) | 2001-10-04 |
NO332815B1 (no) | 2013-01-21 |
US20130035418A1 (en) | 2013-02-07 |
CN1362973A (zh) | 2002-08-07 |
US9309368B2 (en) | 2016-04-12 |
EP1177231B1 (en) | 2009-08-19 |
EP1985639B1 (en) | 2013-08-14 |
US8658733B2 (en) | 2014-02-25 |
US20160075800A1 (en) | 2016-03-17 |
CN1311005C (zh) | 2007-04-18 |
CN1644606A (zh) | 2005-07-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TW589330B (en) | Process for the preparation of monodisperse polymer particles | |
Cho et al. | Dispersion polymerization of acrylamide in aqueous solution of ammonium sulfate: Synthesis and characterization | |
TW589334B (en) | Emulsified functionalized polymers | |
JP5566152B2 (ja) | 単分散ポリマー粒子の製造法 | |
CN101434673A (zh) | 一种单分散多孔聚合物微球的制备方法 | |
CN102234343B (zh) | 单分散的表面功能化聚合物微球树脂及其制备方法 | |
JPH0688030A (ja) | 水溶性ポリマ一分散液 | |
JPH07258305A (ja) | 低粘度水溶性ポリマー分散液の製造方法、それからなる凝集剤、保持剤、増粘剤、添加剤、脱水剤および土壌改良剤 | |
CZ390289A3 (en) | Water-absorbing resins, and process for preparing thereof | |
JPH08504885A (ja) | 高い重合体含分を有する水溶性重合体分散液の製法 | |
CN105037626B (zh) | 一种大孔大粒径聚合物微球的制备方法 | |
JP2015512978A5 (zh) | ||
JP6986085B2 (ja) | エマルジョン粒子、これを含むエマルジョンおよびエマルジョンの製造方法 | |
EP0008213A1 (en) | The use of synthetic polymeric compositions as wallpaper adhesive | |
Capek et al. | Effects of the initiator type on the dispersion copolymerization of poly (ethylene glycol) macromonomer and styrene | |
JP2002542318A5 (zh) | ||
Laurienzo et al. | Novel alginate–acrylic polymers as a platform for drug delivery | |
JPS63289031A (ja) | アクリル樹脂外層を有する陰イオン交換樹脂 | |
CN110698583A (zh) | 一种环保型反应型乳化剂丙烯酸酯无皂乳液及其制备方法 | |
KR100729173B1 (ko) | 단분산 씨드 입자를 이용한 단분산성 가교 폴리머 비드의제조 방법 | |
JP2006137951A (ja) | 高分子粒子及びその製造方法 | |
Liu et al. | Preparation and characterization of a novel pH-sensitive ion exchange resin | |
JP2000135435A (ja) | 分離剤、エストロゲン化合物及びエストロゲン様物質の分離、並びにエストロゲン様物質のスクリ―ニング及び吸着除去方法 | |
JP6251978B2 (ja) | カラム用コアシェル型粒子及びその製造方法 | |
CN114478905B (zh) | 提高阳离子单体转化率的方法及聚合物微球乳液的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK4A | Expiration of patent term of an invention patent |