TW457271B - Thermoplastic elastomer composition with improved overmolding adhesion - Google Patents
Thermoplastic elastomer composition with improved overmolding adhesion Download PDFInfo
- Publication number
- TW457271B TW457271B TW086114065A TW86114065A TW457271B TW 457271 B TW457271 B TW 457271B TW 086114065 A TW086114065 A TW 086114065A TW 86114065 A TW86114065 A TW 86114065A TW 457271 B TW457271 B TW 457271B
- Authority
- TW
- Taiwan
- Prior art keywords
- ethylene
- thermoplastic elastomer
- patent application
- elastomer composition
- acrylate
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 26
- 229920001400 block copolymer Polymers 0.000 claims abstract description 26
- 229920006112 polar polymer Polymers 0.000 claims abstract description 22
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 13
- 239000004014 plasticizer Substances 0.000 claims abstract description 10
- 150000001993 dienes Chemical class 0.000 claims abstract description 7
- 150000001491 aromatic compounds Chemical class 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 5
- 229920001577 copolymer Polymers 0.000 claims description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 11
- -1 polypropylene Polymers 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 229920001897 terpolymer Polymers 0.000 claims description 10
- 230000002079 cooperative effect Effects 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000010775 animal oil Substances 0.000 claims description 3
- 239000005043 ethylene-methyl acrylate Substances 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- 229920001038 ethylene copolymer Polymers 0.000 claims description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical group C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 2
- 239000005662 Paraffin oil Substances 0.000 claims 2
- 239000001273 butane Substances 0.000 claims 2
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 claims 2
- 229920006245 ethylene-butyl acrylate Polymers 0.000 claims 2
- 238000002309 gasification Methods 0.000 claims 2
- 235000019198 oils Nutrition 0.000 claims 2
- 239000008158 vegetable oil Substances 0.000 claims 2
- PZWQOGNTADJZGH-SNAWJCMRSA-N (2e)-2-methylpenta-2,4-dienoic acid Chemical compound OC(=O)C(/C)=C/C=C PZWQOGNTADJZGH-SNAWJCMRSA-N 0.000 claims 1
- JJYWRQLLQAKNAD-UHFFFAOYSA-N 2-methylpent-2-enoic acid Chemical compound CCC=C(C)C(O)=O JJYWRQLLQAKNAD-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 1
- OUGJKAQEYOUGKG-UHFFFAOYSA-N ethyl 2-methylidenebutanoate Chemical compound CCOC(=O)C(=C)CC OUGJKAQEYOUGKG-UHFFFAOYSA-N 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 235000013311 vegetables Nutrition 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 13
- 229920001971 elastomer Polymers 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 239000000806 elastomer Substances 0.000 description 9
- 239000004417 polycarbonate Substances 0.000 description 7
- 229920000515 polycarbonate Polymers 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000052 vinegar Substances 0.000 description 4
- 235000021419 vinegar Nutrition 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920002633 Kraton (polymer) Polymers 0.000 description 3
- 150000001875 compounds Chemical group 0.000 description 3
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 2
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229920005684 linear copolymer Polymers 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229940017219 methyl propionate Drugs 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical compound C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BSKSLFYYCQNVQZ-UHFFFAOYSA-N C1=CC=CC=2C3=CC=CC=C3CC12.C1=CC=CC=2C3=CC=CC=C3CC12.C=CC(C)=C Chemical compound C1=CC=CC=2C3=CC=CC=C3CC12.C1=CC=CC=2C3=CC=CC=C3CC12.C=CC(C)=C BSKSLFYYCQNVQZ-UHFFFAOYSA-N 0.000 description 1
- LIRABMAXNCXREP-UHFFFAOYSA-N CC(=N)N.C(C=C)(=O)O Chemical compound CC(=N)N.C(C=C)(=O)O LIRABMAXNCXREP-UHFFFAOYSA-N 0.000 description 1
- WYLWVBPPOCKIDY-UHFFFAOYSA-N CCOC(C)=O.CCCCOC(=O)C=C Chemical compound CCOC(C)=O.CCCCOC(=O)C=C WYLWVBPPOCKIDY-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 235000011511 Diospyros Nutrition 0.000 description 1
- 244000236655 Diospyros kaki Species 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229920001890 Novodur Polymers 0.000 description 1
- 229920003302 Optema™ Polymers 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- WRVRNZNDLRUXSW-UHFFFAOYSA-N acetic acid;prop-2-enoic acid Chemical compound CC(O)=O.OC(=O)C=C WRVRNZNDLRUXSW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000010073 coating (rubber) Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- OGBBGGRANWCZGA-UHFFFAOYSA-N ethyl acetate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(C)=O OGBBGGRANWCZGA-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 229920005680 ethylene-methyl methacrylate copolymer Polymers 0.000 description 1
- OJCSPXHYDFONPU-UHFFFAOYSA-N etoac etoac Chemical compound CCOC(C)=O.CCOC(C)=O OJCSPXHYDFONPU-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0884—Epoxide-containing esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/16—Homopolymers or copolymers of alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/721,128 US5723543A (en) | 1996-09-26 | 1996-09-26 | Block copolymers with improved overmolding adhesion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW457271B true TW457271B (en) | 2001-10-01 |
Family
ID=24896652
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086114065A TW457271B (en) | 1996-09-26 | 1997-09-26 | Thermoplastic elastomer composition with improved overmolding adhesion |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5723543A (enExample) |
| EP (1) | EP0832930B1 (enExample) |
| JP (1) | JPH10130453A (enExample) |
| KR (1) | KR100515873B1 (enExample) |
| CN (1) | CN1117813C (enExample) |
| DE (1) | DE69704597T2 (enExample) |
| ES (1) | ES2158444T3 (enExample) |
| TR (1) | TR199701044A3 (enExample) |
| TW (1) | TW457271B (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5987688A (en) * | 1995-11-09 | 1999-11-23 | Gillette Canada Inc. | Gum-massaging oral brush |
| US5911676A (en) * | 1996-09-12 | 1999-06-15 | Anthony; Phillip K. | Low-speed trash belt for open-end spinning machine and method |
| US6886207B1 (en) * | 1999-06-14 | 2005-05-03 | The Procter & Gamble Company | Toothbrush |
| FR2799199B1 (fr) * | 1999-09-23 | 2005-02-25 | Thermoplastiques Cousin Tessie | Materiau polymerique thermoplastique presentant une memoire de forme, sans qu'il soit necessaire de le reticuler, article presentant une memoire de forme realise en ce materiau et procede de fabrication dudit article |
| JP2001261922A (ja) * | 2000-03-14 | 2001-09-26 | Tokai Rubber Ind Ltd | 高減衰エラストマー組成物 |
| US6553604B1 (en) | 2000-03-16 | 2003-04-29 | Gillette Canada Company | Toothbrush |
| US6846571B1 (en) * | 2002-10-03 | 2005-01-25 | Raj K. Agrawal | Polymer blend for automotive flooring applications |
| US20040177462A1 (en) * | 2003-03-14 | 2004-09-16 | The Gillette Company | Toothbrush head |
| US20060272112A9 (en) * | 2003-03-14 | 2006-12-07 | The Gillette Company | Toothbrush |
| MXPA05011363A (es) | 2003-04-23 | 2005-11-28 | Procter & Gamble | Cepillos dentales electricos. |
| US20090044357A1 (en) * | 2007-08-16 | 2009-02-19 | The Procter & Gamble Company | Electric toothbrushes |
| US7941886B2 (en) | 2003-09-19 | 2011-05-17 | Braun Gmbh | Toothbrushes |
| EP1582563A1 (en) * | 2004-03-31 | 2005-10-05 | KRATON Polymers Research B.V. | Hydrogenated styrenic block copolymer compositions with improved high temperature overmolding properties |
| US20070129454A1 (en) * | 2005-12-05 | 2007-06-07 | Tsrc Corporation | Thermoplastic elastomer foaming material and the manufacturing method thereof |
| US9260578B2 (en) * | 2005-11-30 | 2016-02-16 | Tsrc Corporation | Thermoplastic elastomer foaming material |
| JP5543805B2 (ja) * | 2010-03-04 | 2014-07-09 | 旭化成ケミカルズ株式会社 | 水性インク印刷性に優れた樹脂組成物 |
| GB201007796D0 (en) | 2010-05-10 | 2010-06-23 | Bielskis Linas | Motorcycle stand |
| KR20130043677A (ko) * | 2010-07-30 | 2013-04-30 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 플루오르화된 공중합체 수지 층 및 봉지제 층을 함유하는 다층 필름 |
| US20170174001A1 (en) * | 2014-07-02 | 2017-06-22 | Sumitomo Rubber Industries, Ltd. | Tread rubber composition and pneumatic tire |
| CA3028958C (en) | 2016-06-23 | 2024-10-01 | Dow Global Technologies Llc | OVERMOLDING MATERIAL FOR POLYCARBONATE |
| JP2018012818A (ja) * | 2016-07-22 | 2018-01-25 | 横浜ゴム株式会社 | タイヤ用ゴム組成物 |
| CN106700247A (zh) * | 2016-12-02 | 2017-05-24 | 芜湖天鸿汽车零部件有限公司 | 一种汽车把手注塑成型的模具材料及其制备方法 |
| WO2019068056A1 (en) * | 2017-09-29 | 2019-04-04 | Kraton Polymers Llc | ELASTOMERIC COMPOSITIONS PROVIDING ENHANCED WET ADHESION |
| KR102570571B1 (ko) * | 2018-10-31 | 2023-08-23 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 이용한 성형품 |
| CN114573939B (zh) * | 2022-03-08 | 2023-09-26 | 金发科技股份有限公司 | 一种热塑性弹性体组合物及其制备方法与应用 |
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|---|---|---|---|---|
| UST962011I4 (en) * | 1977-04-25 | 1977-09-06 | Shell Oil Company | Coextruded laminate |
| US4397987A (en) * | 1980-07-14 | 1983-08-09 | Uniroyal, Inc. | Nitrile rubber/EPDM graft blends |
| WO1983000158A1 (en) * | 1981-06-29 | 1983-01-20 | Abbott Lab | Clear, autoclavable thermoplastic formulation for medical liquid containers |
| US4391863A (en) * | 1981-10-23 | 1983-07-05 | Composite Container Corporation | Peel resistant coextruded sheet |
| EP0096301A2 (de) * | 1982-06-08 | 1983-12-21 | Bayer Ag | Einphasige Polymermischungen |
| US4444840A (en) * | 1982-08-09 | 1984-04-24 | Uniroyal, Inc. | Calendered AES film |
| US4493921A (en) * | 1982-09-24 | 1985-01-15 | Uniroyal, Inc. | Impact resistant blend |
| EP0107303B1 (en) * | 1982-09-24 | 1988-07-06 | UNIROYAL CHEMICAL COMPANY, Inc. | Impact resistant blend and method for making it |
| JPS5974153A (ja) * | 1982-10-21 | 1984-04-26 | Dainippon Plastics Co Ltd | 樹脂組成物 |
| US4476283A (en) * | 1982-11-12 | 1984-10-09 | Uniroyal, Inc. | Graft copolymerization process |
| USRE32217E (en) * | 1982-11-12 | 1986-07-29 | The Dow Chemical Company | Graft copolymerization process |
| US4550138A (en) * | 1984-04-23 | 1985-10-29 | Uniroyal, Inc. | Polycarbonate compositions with improved low temperature impact strength |
| DE3429523A1 (de) * | 1984-08-10 | 1986-02-20 | Alkor GmbH Kunststoffe, 8000 München | Schaumlaminatfolie oder -bahn |
| CA1238439A (en) * | 1984-11-20 | 1988-06-21 | Hiroshi Kawasaki | Thermoplastic resin composition |
| EP0203425A1 (en) * | 1985-05-13 | 1986-12-03 | General Electric Company | Composition of a copolymer of an olefin and an acrylate monomer and a block copolymer of vinylaromatic and aliphatic diene |
| US4638033A (en) * | 1985-12-23 | 1987-01-20 | General Electric Company | Resinous composition of a carbonate resin and a grafted derivative of ethylene-propylene-diene terpolymer exhibiting improved resistance to organic solvents |
| US4814381A (en) * | 1987-04-16 | 1989-03-21 | Uniroyal Chemical Company, Inc. | Impact resistant polyethylene terephthalate/polycarbonate blends |
| US4780506A (en) * | 1987-04-16 | 1988-10-25 | Uniroyal Chemical Company, Inc. | Impact resistant polyethylene terephthalate/polycarbonate blends |
| US4822653A (en) * | 1987-08-05 | 1989-04-18 | National Starch And Chemical Corporation | Recyclable hot melt adhesive compositions |
| GB2210047A (en) * | 1987-09-18 | 1989-06-01 | Evode Ltd | Thermoplastic elastomers |
| US4895899A (en) * | 1987-12-23 | 1990-01-23 | Uniroyal Chemical Company, Inc. | Impact resistant polyethylene terephthalate/polycarbonate/polyethylene graft copolymer blends |
| EP0330151A3 (en) * | 1988-02-23 | 1991-07-03 | Nissho Corporation | Bag for the storage of blood platelets |
| JPH0783758B2 (ja) * | 1989-07-20 | 1995-09-13 | 株式会社ニッショー | 血小板保存用バッグおよびそれを用いた複合バッグ |
| USH1022H (en) * | 1991-01-09 | 1992-02-04 | Shell Oil Company | Soft paintable polymer composition |
| US5356705A (en) * | 1992-01-09 | 1994-10-18 | The Dow Chemical Company | Laminated, weatherable film-capped siding structure |
-
1996
- 1996-09-26 US US08/721,128 patent/US5723543A/en not_active Expired - Lifetime
-
1997
- 1997-09-23 EP EP97202911A patent/EP0832930B1/en not_active Expired - Lifetime
- 1997-09-23 ES ES97202911T patent/ES2158444T3/es not_active Expired - Lifetime
- 1997-09-23 DE DE69704597T patent/DE69704597T2/de not_active Expired - Lifetime
- 1997-09-24 CN CN97121420A patent/CN1117813C/zh not_active Expired - Fee Related
- 1997-09-24 JP JP9259038A patent/JPH10130453A/ja active Pending
- 1997-09-24 KR KR1019970048451A patent/KR100515873B1/ko not_active Expired - Fee Related
- 1997-09-26 TW TW086114065A patent/TW457271B/zh not_active IP Right Cessation
- 1997-09-26 TR TR97/01044A patent/TR199701044A3/tr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1117813C (zh) | 2003-08-13 |
| TR199701044A2 (xx) | 1998-04-21 |
| JPH10130453A (ja) | 1998-05-19 |
| US5723543A (en) | 1998-03-03 |
| ES2158444T3 (es) | 2001-09-01 |
| DE69704597T2 (de) | 2001-10-18 |
| KR100515873B1 (ko) | 2006-01-12 |
| KR19980024907A (ko) | 1998-07-06 |
| CN1178810A (zh) | 1998-04-15 |
| EP0832930B1 (en) | 2001-04-18 |
| DE69704597D1 (de) | 2001-05-23 |
| TR199701044A3 (tr) | 1998-04-21 |
| EP0832930A1 (en) | 1998-04-01 |
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