TW440577B - Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and faom prepared therewith - Google Patents
Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and faom prepared therewith Download PDFInfo
- Publication number
- TW440577B TW440577B TW086100729A TW86100729A TW440577B TW 440577 B TW440577 B TW 440577B TW 086100729 A TW086100729 A TW 086100729A TW 86100729 A TW86100729 A TW 86100729A TW 440577 B TW440577 B TW 440577B
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- Taiwan
- Prior art keywords
- polyol
- polyols
- weight
- polyoxyalkylene
- polymer
- Prior art date
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- 229920005862 polyol Polymers 0.000 title claims abstract description 347
- 150000003077 polyols Chemical class 0.000 title claims abstract description 336
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 125000006353 oxyethylene group Chemical group 0.000 title claims abstract description 25
- 239000006260 foam Substances 0.000 title claims description 105
- 239000003054 catalyst Substances 0.000 claims abstract description 87
- -1 polyoxypropylene Polymers 0.000 claims abstract description 78
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 12
- 229920005830 Polyurethane Foam Polymers 0.000 claims abstract description 7
- 239000011496 polyurethane foam Substances 0.000 claims abstract description 7
- 239000005977 Ethylene Substances 0.000 claims abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 76
- 229920000642 polymer Polymers 0.000 claims description 58
- 239000000203 mixture Substances 0.000 claims description 57
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 43
- 238000006243 chemical reaction Methods 0.000 claims description 37
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 35
- 238000011049 filling Methods 0.000 claims description 30
- 238000006116 polymerization reaction Methods 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000004815 dispersion polymer Substances 0.000 claims description 23
- 239000007787 solid Substances 0.000 claims description 23
- 230000002079 cooperative effect Effects 0.000 claims description 17
- 239000012948 isocyanate Substances 0.000 claims description 17
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 15
- 150000002513 isocyanates Chemical class 0.000 claims description 15
- 229920000570 polyether Polymers 0.000 claims description 15
- 150000001412 amines Chemical class 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000012545 processing Methods 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 238000011065 in-situ storage Methods 0.000 claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 11
- 150000005846 sugar alcohols Polymers 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 9
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 9
- 239000000600 sorbitol Substances 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 8
- 238000006555 catalytic reaction Methods 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 239000003063 flame retardant Substances 0.000 claims description 7
- 238000005187 foaming Methods 0.000 claims description 7
- 229920001228 polyisocyanate Polymers 0.000 claims description 7
- 239000005056 polyisocyanate Substances 0.000 claims description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000012974 tin catalyst Substances 0.000 claims description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 5
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 claims description 4
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004604 Blowing Agent Substances 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 4
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 4
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004970 Chain extender Substances 0.000 claims description 3
- 239000004971 Cross linker Substances 0.000 claims description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 238000007796 conventional method Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910001512 metal fluoride Inorganic materials 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 241000894007 species Species 0.000 claims description 3
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 3
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 claims description 2
- NDKGUMMLYBINOC-UHFFFAOYSA-N 1,2-dichloro-1-fluoroethane Chemical compound FC(Cl)CCl NDKGUMMLYBINOC-UHFFFAOYSA-N 0.000 claims description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 241001425800 Pipa Species 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims description 2
- SKSIVTKFQMBQLL-UHFFFAOYSA-N [Sn].CCCCCCCCCCCC(=O)OCCCC.CCCCCCCCCCCC(=O)OCCCC Chemical compound [Sn].CCCCCCCCCCCC(=O)OCCCC.CCCCCCCCCCCC(=O)OCCCC SKSIVTKFQMBQLL-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 150000004985 diamines Chemical class 0.000 claims description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 claims description 2
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- JXDYKVIHCLTXOP-UHFFFAOYSA-N isatin Chemical compound C1=CC=C2C(=O)C(=O)NC2=C1 JXDYKVIHCLTXOP-UHFFFAOYSA-N 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 238000011068 loading method Methods 0.000 claims description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920013730 reactive polymer Polymers 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000052 vinegar Substances 0.000 claims description 2
- 235000021419 vinegar Nutrition 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims 2
- 238000010304 firing Methods 0.000 claims 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims 1
- 238000006213 oxygenation reaction Methods 0.000 claims 1
- 229920001281 polyalkylene Polymers 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000003999 initiator Substances 0.000 description 26
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 23
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 21
- 235000011187 glycerol Nutrition 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 7
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 238000010422 painting Methods 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 210000003625 skull Anatomy 0.000 description 4
- 238000011179 visual inspection Methods 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 229910052702 rhenium Inorganic materials 0.000 description 3
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- 239000002002 slurry Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 229920000638 styrene acrylonitrile Polymers 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
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- 150000001875 compounds Chemical class 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000005309 metal halides Chemical class 0.000 description 2
- 239000013518 molded foam Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
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- 230000000007 visual effect Effects 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
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- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
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- BRDOPVMUMDUXEX-UHFFFAOYSA-N C1=CC=CC=2C3=CC=CC=C3CC12.[Au] Chemical compound C1=CC=CC=2C3=CC=CC=C3CC12.[Au] BRDOPVMUMDUXEX-UHFFFAOYSA-N 0.000 description 1
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- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 208000001613 Gambling Diseases 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001395537 Ia io Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 229920002675 Polyoxyl Polymers 0.000 description 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- QMNOIORHZMRPLS-UHFFFAOYSA-N butan-1-ol;ethane-1,2-diol;propane-1,2-diol Chemical compound OCCO.CCCCO.CC(O)CO QMNOIORHZMRPLS-UHFFFAOYSA-N 0.000 description 1
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- RKBAPHPQTADBIK-UHFFFAOYSA-N cobalt;hexacyanide Chemical compound [Co].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] RKBAPHPQTADBIK-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- JQZRVMZHTADUSY-UHFFFAOYSA-L di(octanoyloxy)tin Chemical compound [Sn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O JQZRVMZHTADUSY-UHFFFAOYSA-L 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- IZLAVFWQHMDDGK-UHFFFAOYSA-N gold(1+);cyanide Chemical compound [Au+].N#[C-] IZLAVFWQHMDDGK-UHFFFAOYSA-N 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- HOVAGTYPODGVJG-ZFYZTMLRSA-N methyl alpha-D-glucopyranoside Chemical compound CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HOVAGTYPODGVJG-ZFYZTMLRSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920002098 polyfluorene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 230000003319 supportive effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- IPCXNCATNBAPKW-UHFFFAOYSA-N zinc;hydrate Chemical compound O.[Zn] IPCXNCATNBAPKW-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyethers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/592,087 US5605939A (en) | 1996-01-26 | 1996-01-26 | Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and foam prepared therewith |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW440577B true TW440577B (en) | 2001-06-16 |
Family
ID=24369232
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086100729A TW440577B (en) | 1996-01-26 | 1997-01-23 | Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and faom prepared therewith |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US5605939A (OSRAM) |
| EP (1) | EP0876416B1 (OSRAM) |
| JP (1) | JP3895385B2 (OSRAM) |
| CN (1) | CN1114640C (OSRAM) |
| AR (1) | AR005528A1 (OSRAM) |
| AU (1) | AU1544897A (OSRAM) |
| BR (1) | BR9706974A (OSRAM) |
| CA (1) | CA2241627C (OSRAM) |
| DE (1) | DE69700406T2 (OSRAM) |
| ES (1) | ES2135287T3 (OSRAM) |
| TW (1) | TW440577B (OSRAM) |
| WO (1) | WO1997027236A1 (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015111583A1 (de) | 2014-08-26 | 2016-03-03 | Yuan-Hung WEN | Hydraulische Fahrradbremse |
Families Citing this family (85)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5670601A (en) * | 1995-06-15 | 1997-09-23 | Arco Chemical Technology, L.P. | Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation |
| US5700847A (en) * | 1995-12-04 | 1997-12-23 | Arco Chemical Technology, L.P. | Molded polyurethane foam with enhanced physical properties |
| US5668191A (en) * | 1995-12-21 | 1997-09-16 | Arco Chemical Technology, L.P. | One-shot cold molded flexible polyurethane foam from low primary hydroxyl polyols and process for the preparation thereof |
| US5958994A (en) * | 1997-02-25 | 1999-09-28 | Arco Chemical Technology, L.P. | Method for decreasing the propensity for phase-out of the high molecular weight component of double metal cyanide-catalyzed high secondary hydroxyl polyoxypropylene polyols |
| US6066683A (en) * | 1998-04-03 | 2000-05-23 | Lyondell Chemical Worldwide, Inc. | Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof |
| US6008263A (en) * | 1998-04-03 | 1999-12-28 | Lyondell Chemical Worldwide, Inc. | Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof |
| DE19840585A1 (de) † | 1998-09-05 | 2000-03-09 | Basf Ag | Verfahren zur Herstellung von Polyetherolen durch ringöffnende Polymerisation von Alkylenoxiden |
| WO2000039178A1 (en) * | 1998-12-29 | 2000-07-06 | The Dow Chemical Company | Polyurethane foams prepared from mechanically frothed polyurethane dispersions |
| JO2132B1 (en) * | 1999-01-19 | 2002-08-07 | شل انترناشونال ريسيرتش ماتستشابيج بي في | Method for preparing flexible polyurethane foams |
| DE19917897A1 (de) | 1999-04-20 | 2000-10-26 | Basf Ag | Verfahren zur Herstellung von Polyurethanen |
| DE19918727A1 (de) | 1999-04-24 | 2000-10-26 | Bayer Ag | Langkettige Polyetherpolyole mit hohem Anteil primärer OH-Gruppen |
| DE19928156A1 (de) * | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
| DE19944762A1 (de) * | 1999-09-17 | 2001-03-22 | Basf Ag | Verfahren zur Herstellung von Blockweichschaumpolyolen |
| DE19960148A1 (de) * | 1999-12-14 | 2001-06-21 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| DE60120390T2 (de) | 2000-04-14 | 2007-05-16 | Asahi Glass Co., Ltd. | Verfahren zur herstellung von flexiblem polyurethanschaum |
| US6642171B2 (en) | 2000-04-28 | 2003-11-04 | Synuthane International, Inc. | Double metal cyanide catalysts containing polyglycol ether complexing agents |
| US6201035B1 (en) * | 2000-05-24 | 2001-03-13 | Basf Corporation | Use of low unsaturated polyether polyols in high resilience slabstock foam applications |
| US6344494B1 (en) * | 2000-05-24 | 2002-02-05 | Basf Corporation | Use of low unsaturated polyether polyols in slabstock foam applications |
| US6372812B1 (en) * | 2001-02-20 | 2002-04-16 | Foamex L.P. | Higher support, lower density cushioning foams |
| DE10111823A1 (de) * | 2001-03-13 | 2002-09-26 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen |
| CN1208364C (zh) * | 2001-05-24 | 2005-06-29 | 三井武田化学株式会社 | 生产软聚氨酯泡沫的方法 |
| JP4122874B2 (ja) * | 2001-07-18 | 2008-07-23 | 旭硝子株式会社 | ポリオールおよびポリマー分散ポリオールの製造方法 |
| KR100873594B1 (ko) * | 2001-07-18 | 2008-12-11 | 아사히 가라스 가부시키가이샤 | 폴리올 및 폴리머 분산 폴리올의 제조방법 |
| JP2008095122A (ja) * | 2001-08-06 | 2008-04-24 | Asahi Glass Co Ltd | 軟質ポリウレタンフォーム、その製造方法およびその製造用原料システム液 |
| JP4601894B2 (ja) * | 2001-08-06 | 2010-12-22 | 旭硝子株式会社 | 自動車シート用軟質ポリウレタンフォーム |
| KR100930000B1 (ko) * | 2001-12-21 | 2009-12-07 | 아사히 가라스 가부시키가이샤 | 저반발 연질 폴리우레탄 폼 및 그 제조방법 |
| EP1329469A1 (de) * | 2002-01-18 | 2003-07-23 | Sika Schweiz AG | Polyurethanzusammensetzung |
| DE10226415A1 (de) * | 2002-06-13 | 2003-12-24 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| US6740687B2 (en) * | 2002-08-14 | 2004-05-25 | Foamex L.P. | Latex replacement polyurethane foams with improved flame retardancy |
| US20040064001A1 (en) * | 2002-09-30 | 2004-04-01 | Stephan Ehlers | Processes for preparing ethylene oxide-capped polyols |
| US7094811B2 (en) * | 2002-10-03 | 2006-08-22 | Bayer Corporation | Energy absorbing flexible foams produced in part with a double metal cyanide catalyzed polyol |
| US6855742B2 (en) * | 2003-01-28 | 2005-02-15 | Bayer Antwerp, N.V. | Agents for reducing the force-to-crush (FTC) of high support flexible foams |
| US6716890B1 (en) | 2003-01-30 | 2004-04-06 | Foamex L.P. | Polyurethane foams with fine cell size |
| US20040154718A1 (en) * | 2003-02-06 | 2004-08-12 | Doesburg Van I. | Polyurethane filled tire and method of making same |
| US20050038132A1 (en) * | 2003-03-19 | 2005-02-17 | Raghuram Gummaraju | Composition for forming a foamed article and an article of furniture having the foamed article disposed therein |
| US6784218B1 (en) * | 2003-03-19 | 2004-08-31 | Basf Corporation | Method of forming high resilience slabstock polyurethane foam displaying latex-like characteristics |
| US6797736B1 (en) * | 2003-03-19 | 2004-09-28 | Basf Corporation | Method of forming high resilience slabstock polyurethane foam |
| US7005552B2 (en) * | 2003-11-03 | 2006-02-28 | Bayer Materialscience Llc | Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates |
| US20050101681A1 (en) * | 2003-11-07 | 2005-05-12 | Kaushiva Bryan D. | Molded polyurethane foam with property enhancements for improved comfort and greater durability |
| US20060029788A1 (en) * | 2004-08-04 | 2006-02-09 | Foamex L.P. | Lower density, thermoformable, sound absorbing polyurethane foams |
| DE102004047524A1 (de) * | 2004-09-28 | 2006-03-30 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen |
| DE102004047406A1 (de) * | 2004-09-28 | 2006-03-30 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen |
| AU2005299519B2 (en) * | 2004-10-25 | 2012-02-02 | Dow Global Technologies Llc | Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids |
| MX2007004933A (es) * | 2004-10-25 | 2007-06-12 | Dow Global Technologies Inc | Prepolimeros preparados a partir de poliester polioles que contienen hidroximetilo derivados de acidos grasos. |
| EP1807460B1 (en) * | 2004-10-25 | 2013-02-13 | Dow Global Technologies LLC | Polyurethane carpet backings made using hydroxymethylated polyester polyols |
| MY148439A (en) * | 2004-10-25 | 2013-04-30 | Dow Global Technologies Inc | Polymer polyols and polymer dispersions made from vegetable oil-based hydroxyl-containing materials |
| CA2580567A1 (en) * | 2004-10-25 | 2006-05-04 | Dow Global Technologies Inc. | Aqueous polyurethane dispersions made from hydroxymethyl containing polyester polyols derived from fatty acids |
| EP1813632B1 (en) | 2004-11-18 | 2012-05-23 | Asahi Glass Company, Limited | Process for producing flexible polyurethane foam |
| JP5266757B2 (ja) * | 2005-05-25 | 2013-08-21 | 旭硝子株式会社 | 軟質ポリウレタンフォームの製造方法 |
| DE102005041142A1 (de) * | 2005-08-30 | 2007-03-01 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| TW200801060A (en) * | 2006-02-28 | 2008-01-01 | Asahi Glass Co Ltd | Flexible polyurethane foam and process for producing the same |
| WO2007147780A1 (de) * | 2006-06-23 | 2007-12-27 | Basf Se | Verfahren zur kontinuierlichen herstellung von polyetheralkoholen |
| US20070299153A1 (en) * | 2006-06-23 | 2007-12-27 | Hager Stanley L | Viscoelastic foams with slower recovery and improved tear |
| CN100588668C (zh) * | 2006-11-28 | 2010-02-10 | 王伟松 | 甘油聚醚的合成方法 |
| CN100588669C (zh) * | 2006-11-28 | 2010-02-10 | 王伟松 | 烯丙醇无规聚醚的制备方法 |
| CN100588671C (zh) * | 2006-11-28 | 2010-02-10 | 王伟松 | 丁醇聚醚的合成方法 |
| CN100588672C (zh) * | 2006-11-28 | 2010-02-10 | 王伟松 | 烯丙醇无规聚醚的合成方法 |
| US20090012195A1 (en) * | 2007-07-05 | 2009-01-08 | Neff Raymond A | Resin composition for use in forming a polyurethane article with increased comfort |
| JP5303885B2 (ja) | 2007-09-18 | 2013-10-02 | 旭硝子株式会社 | 軟質ポリウレタンフォームの製造方法および軟質ポリウレタンフォーム |
| EP2095832A1 (de) * | 2008-02-28 | 2009-09-02 | Bayer MaterialScience AG | Polyharnstoff-Systeme und deren Anwendung als postoperative Adhäsionsbarrieren, Filme und Verbundteile. |
| ES2526558T3 (es) * | 2009-03-17 | 2015-01-13 | Basf Se | Cuerpos moldeados de poliuretano con resistencia al desgarre progresivo mejorada y comportamiento de fatiga por flexión mejorado |
| DE102009033710A1 (de) | 2009-07-18 | 2011-01-20 | Evonik Goldschmidt Gmbh | Verwendung von Metallsalzen einer Carbonsäure bei der Herstellung von Polyurethansystemen |
| CN102725330B (zh) * | 2009-12-29 | 2014-10-29 | 陶氏环球技术有限责任公司 | 用于吸收声音和振动的低密度聚氨酯泡沫的制造方法 |
| US9115246B2 (en) | 2010-04-30 | 2015-08-25 | Basf Se | Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes |
| JP5956979B2 (ja) | 2010-04-30 | 2016-07-27 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ポリエーテルポリオール、ポリエーテルポリオールを製造するための方法、及びポリウレタンを製造するために、このポリエーテルポリオールを使用する方法 |
| MX2013009361A (es) * | 2011-02-14 | 2013-09-26 | Dow Brasil Sudeste Ind Ltda | Espumas de poliuretano de baja densidad. |
| US10066047B2 (en) | 2012-02-02 | 2018-09-04 | Covestro Llc | Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams |
| CN104781299A (zh) | 2012-10-10 | 2015-07-15 | 巴斯夫欧洲公司 | 粘弹性聚氨酯泡沫体 |
| CN103087292B (zh) * | 2013-02-04 | 2015-01-07 | 苏州井上高分子新材料有限公司 | 一种用于校车挡板的聚氨酯高回弹泡沫组合物 |
| AU2014318646B2 (en) * | 2013-09-13 | 2017-10-12 | Dow Global Technologies Llc | PIPA polyol based conventional flexible foam |
| CN107406571A (zh) * | 2015-04-08 | 2017-11-28 | 国际壳牌研究有限公司 | 关于多元醇和聚氨基甲酸酯的改进 |
| US10301419B2 (en) | 2015-06-30 | 2019-05-28 | Dow Global Technologies Llc | Method for making propylene oxide/ethylene oxide copolymers using double metal cyanide catalysts, and copolymers so made |
| MX2018004006A (es) * | 2015-09-29 | 2018-05-23 | Basf Se | Espuma de poliuretano de alta resiliencia. |
| JP6872536B2 (ja) * | 2015-10-08 | 2021-05-19 | ダウ グローバル テクノロジーズ エルエルシー | 主に二級ヒドロキシル基を有する、高官能価、高当量のポリオールで製造された高弾性ポリウレタン発泡体 |
| CN108368230B (zh) * | 2015-12-21 | 2021-08-20 | 国际壳牌研究有限公司 | 用于制造聚氨基甲酸酯泡沫的方法 |
| US11312811B2 (en) | 2016-04-26 | 2022-04-26 | Covestro Llc | Flexible foam using polymer polyols produced via DMC catalyzed polyols |
| WO2018022368A1 (en) | 2016-07-29 | 2018-02-01 | Resinate Materials Group, Inc. | Sustainable polyester polyol compositions |
| US10155837B2 (en) | 2016-07-29 | 2018-12-18 | Resinate Materials Group, Inc. | Sustainable polyester polyol compositions |
| EP3707192B1 (en) | 2017-11-06 | 2023-06-07 | Shell Internationale Research Maatschappij B.V. | Process for preparing a polyether polyol with a high ethylene oxide content |
| US10766998B2 (en) * | 2017-11-21 | 2020-09-08 | Covestro Llc | Flexible polyurethane foams |
| JP7158903B2 (ja) * | 2018-06-13 | 2022-10-24 | シーカ・ハマタイト株式会社 | ２液ウレタン系接着剤組成物 |
| US11572433B2 (en) | 2021-03-12 | 2023-02-07 | Covestro Llc | In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation |
| CN115232257B (zh) * | 2021-04-22 | 2023-09-29 | 中国石油化工股份有限公司 | 一种低粘度聚合物多元醇的制备方法及得到的聚合物多元醇与应用 |
| US11718705B2 (en) | 2021-07-28 | 2023-08-08 | Covestro Llc | In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams |
| WO2025128192A1 (en) * | 2023-12-15 | 2025-06-19 | Dow Global Technologies Llc | High-resiliency polyurethane foam and method of making |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3461086A (en) * | 1964-03-05 | 1969-08-12 | Dow Chemical Co | Polyether urethane foams from certain heteric polyethers |
| US3829505A (en) * | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US4143004A (en) * | 1974-10-02 | 1979-03-06 | Berol Kemi Ab | Process for the preparation of polyurethane foam |
| US4690955A (en) * | 1986-06-30 | 1987-09-01 | Union Carbide Corporation | Polyether silicone copolymers with mixed hydroxy alkoxy capping for stabilizing high solid content, molded, flexible urethane foam |
| US5171759A (en) * | 1988-07-12 | 1992-12-15 | Arco Chemical Technology, L.P. | Polymer polyol compositions and their use in the preparation of polyurethane foams |
| WO1990004613A1 (fr) * | 1988-10-25 | 1990-05-03 | Asahi Glass Company Ltd. | Mousse de polyurethane elastique et procede de production |
| US5114619A (en) * | 1989-07-14 | 1992-05-19 | The Dow Chemical Company | Production of polyether polyols with reduced unsaturation |
| CN1033093C (zh) * | 1988-11-18 | 1996-10-23 | 陶氏化学公司 | 一种制备聚氨酯聚合物的方法 |
| US5010117A (en) * | 1989-06-16 | 1991-04-23 | Dow Chemical Company | Flexible polyurethane foams prepared using low unsaturation polyether polyols |
| US5391722A (en) * | 1990-03-30 | 1995-02-21 | Olin Corporation | Acid-catalyzed fabrication of precursors for use in making polyols using double metal cyanide catalysts |
| US5177119A (en) * | 1990-04-25 | 1993-01-05 | Arco Chemical Technology, L.P. | Polyurethane foams blown only with water |
| US5144093A (en) * | 1991-04-29 | 1992-09-01 | Olin Corporation | Process for purifying and end-capping polyols made using double metal cyanide catalysts |
| US5235114A (en) * | 1991-04-29 | 1993-08-10 | Olin Corporation | Process for purifying and end-capping polyols made using double metal cyanide catalysts |
| US5157056A (en) * | 1991-07-17 | 1992-10-20 | Arco Chemical Technology, L.P. | High resiliency polyurethane foams with improved static fatigue properties |
| US5158922A (en) * | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5357038A (en) * | 1992-08-03 | 1994-10-18 | Olin Corporation | Process and composition for providing double metal cyanide catalyzed polyols having enhanced reactivity |
| GB9301995D0 (en) * | 1993-02-02 | 1993-03-17 | Ici Plc | Process for making flexible foams |
| US5364906A (en) * | 1993-08-20 | 1994-11-15 | Arco Chemical Technology, L.P. | Low viscosity polymer polyols with improved dispersion stability |
-
1996
- 1996-01-26 US US08/592,087 patent/US5605939A/en not_active Expired - Lifetime
- 1996-10-21 US US08/734,561 patent/US5648559A/en not_active Expired - Lifetime
-
1997
- 1997-01-23 EP EP97901596A patent/EP0876416B1/en not_active Expired - Lifetime
- 1997-01-23 BR BR9706974A patent/BR9706974A/pt not_active IP Right Cessation
- 1997-01-23 AU AU15448/97A patent/AU1544897A/en not_active Abandoned
- 1997-01-23 CN CN97191859A patent/CN1114640C/zh not_active Expired - Lifetime
- 1997-01-23 CA CA002241627A patent/CA2241627C/en not_active Expired - Fee Related
- 1997-01-23 DE DE69700406T patent/DE69700406T2/de not_active Expired - Lifetime
- 1997-01-23 WO PCT/EP1997/000306 patent/WO1997027236A1/en not_active Ceased
- 1997-01-23 JP JP52654297A patent/JP3895385B2/ja not_active Expired - Fee Related
- 1997-01-23 ES ES97901596T patent/ES2135287T3/es not_active Expired - Lifetime
- 1997-01-23 TW TW086100729A patent/TW440577B/zh active
- 1997-01-23 AR ARP970100271A patent/AR005528A1/es unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015111583A1 (de) | 2014-08-26 | 2016-03-03 | Yuan-Hung WEN | Hydraulische Fahrradbremse |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1544897A (en) | 1997-08-20 |
| DE69700406T2 (de) | 2000-03-23 |
| JP2000517347A (ja) | 2000-12-26 |
| BR9706974A (pt) | 1999-04-06 |
| US5605939A (en) | 1997-02-25 |
| WO1997027236A1 (en) | 1997-07-31 |
| DE69700406D1 (de) | 1999-09-16 |
| EP0876416A1 (en) | 1998-11-11 |
| CA2241627A1 (en) | 1997-07-31 |
| CA2241627C (en) | 2006-08-29 |
| AR005528A1 (es) | 1999-06-23 |
| ES2135287T3 (es) | 1999-10-16 |
| US5648559A (en) | 1997-07-15 |
| EP0876416B1 (en) | 1999-08-11 |
| CN1209820A (zh) | 1999-03-03 |
| CN1114640C (zh) | 2003-07-16 |
| JP3895385B2 (ja) | 2007-03-22 |
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