TW436506B - Flame retardant polyester copolymers - Google Patents

Flame retardant polyester copolymers Download PDF

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Publication number
TW436506B
TW436506B TW084101943A TW84101943A TW436506B TW 436506 B TW436506 B TW 436506B TW 084101943 A TW084101943 A TW 084101943A TW 84101943 A TW84101943 A TW 84101943A TW 436506 B TW436506 B TW 436506B
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Taiwan
Prior art keywords
flame retardant
acid
item
phosphinic acid
polyester
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Application number
TW084101943A
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English (en)
Inventor
Jawed Asrar
Original Assignee
Solutia Inc
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Publication of TW436506B publication Critical patent/TW436506B/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • C08G63/6924—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6926—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Description

436506 六、申請專利範圍
6·根據申請專利範圍第5項之阻燃劑線形聚酷，其 酸雙-經烷酯的烷基取代基是選自包括 ^ , 具自1至6個碳原 于的烷基。 7·根據申請專利範圍第6項之阻燃劑線形聚醋，其中二苯 酸雙-羥烷酯是二苯酸雙-$ -羥乙酯。 ’、一奉 8.根據中請專利範圍第5項之阻燃劑線形聚醋，並中μ 次膦酸單體是選自包括2·致乙基（苯基）次鱗酸 甲基）次膦酸，2_羧乙基（苯基）次膦酸的環酸酐及1 Ik乙基（甲基）次膦酸的環酸酐。 9·根據申請專利範圍第8項之阻燃劑線形聚酯，其中羧基 次膦酸單體是2 -羧乙基（苯基）次膦酸。 " 1〇·根據申請專利範圍第8項之阻燃劑線形聚酯，其中羧基 次膦酸單體是2 -羧乙基（甲基）次膦酸。 比一種阻燃劑線形聚酯，其包含聚酯預聚物，萘酸雙-羥 烷酯和阻燃性羧基次膦酸單體的產物，其中聚酯預聚物 係各別於範圍⑴丨至”』。/。；莕酸雙羥烷酯係各別於範圍 〇.1%至99.8%;且羧基次膦酸單體的存量自〇.1%至1〇% 重量比，以聚醋之總重量為基準丄羧基次騰龄且有下 式：
0 0 II II HO—P—R—C—0H Ri 飽和的開鏈或環狀亞烴某其具自1 $ 具1至1〇個碳原子的次芳和苦释焯甚 本紙張尺度it财國國家標準(CNS) A4規格(210 X 2^公爱)
43
Jin K 一 定某，芳基和烷 12. 根據中請專㈣圍第"項之阻燃劑線形&，其中茶酸 雙-超垸醋的燒基取代基是選自包括具自⑴個碳原子 的烷基。 13. 根據申請專利範圍第12項之阻燃劑線形聚醋，其中苔酸 雙-每坑酯是莕酸雙-冷-經乙酯。 14·根據申請專利範目第i i項之阻燃劑線形$醋，其中叛基 人膦g又單f豆是選自包括2 _羧乙基（苯基）次膦酸，2 _羧乙 基（甲基）次膦酸，2-羧乙基（苯基）次膦酸之環酸酐及八 幾乙基（甲基）次膦酸之環酸酐。 b·根據申請專利範圍第丨4項之阻燃劑線形聚酯，其中羧 基次膦酸單體是2 -羧乙基（苯基）次膦酸。 16. 根據申請專利範圍第丨4項之阻燃劑線形聚酯，其中羧 基次膦酸單體是羧乙基（甲基）次膦酸。 17. —種製造阻燃劑線形聚酯之方法，其包含在溫度介於 250°C和293 °C下於存有觸媒中縮合聚酯預聚物，二苯酸 雙-燒醋與阻燃量之羧基次膦酸單體的混合物，基^ 羧基次膦酸具右: 〇 〇
II II
H〇_P_R_c_〇H
Ri I.中R是選自包和的開鏈或環狀亞烴基其具自1至 侗碳原子，丛i具1至丨〇個碳原子的次芳和芬亞烴基 本紙張尺歧财s ®家料(CNS) ^^1() x
436506 A8 B8
;:二各別於範圍。.1%至99 8 %;且羧基次膦酸單體 二於嫩1%至15%’條件為此三组份之總量為 18=據申請專利範圍第17項之阻燃劑線形聚酉旨的製法，其 聚醋預聚物是選自包括聚fm酸乙二§旨預聚物，聚對 酉太紅丁二酿預聚物和聚_乙二g旨預聚物。 α根據申請專利範圍第18項之阻燃劑線形聚醋的製法，其 中聚酿預聚物是聚對酞酸乙二酯。 2〇·根據申請專利範圍第17項之阻燃劑線形聚酯的製法’其 中二苯酸雙-羥烷酯的烷基取代基是選自包括具自】至6 個碳原子的烷基。 21·根據申請專利範圍第20項之阻燃劑線形聚醋的製法，其 中二苯酸雙·羥烷酯是二苯酸雙-羥乙醋。 22·根據申請專利範圍第17項之阻燃劑線形聚醋的製法，其 中幾基次膦酸單體是選自包括2-羧乙基（苯基）次膦酸， 叛乙基（甲基）次膦酸’ 2 -幾乙基（笨基）次膦酸之環酸 酐和2 -羧乙基（甲基）次膦酸之環酸酐。 23·根據申請專利範圍第π項之阻燃劑線形聚醋的製法，其 中羧基次膦酸單體是2 -羧乙基（苯基）次鱗酸。 24. —種阻燃劑線形聚酯之製法，其包含在溫度介於25(rc 和2 9 3 °C下於存有觸媒中縮合聚醋預聚物，二苯酸雙-經 本紙張尺度通用中國國家標準(CNS) A4規格(210 X 公釐) 436506 A8 B8 C8 申請專利範圍 烷知及阻燃性羧基次膦酸單體的混合物，真中羧基次膦
IliJlXj： 〇 〇 II ||
HO—P—R—C—OH
Ri 甚^-^AJiJi包括飽和的開錘或環狀亞烴某其具自1至 以及具1至丨0個磁原子的次菩和芳亞烴某 具高it至6個碳原+的抆其，芳基和烷 ~-~甚_ .中纪基取代基具自1至6個端原子，且其中聚 酉旨類預聚物係各別於範圍〇·丨至99.8 % ;二苯酸雙羥烷酯 係各別於範圍〇 · 1 %至9 9.8 % ; 而羧基次膦酸單體的存量為自〇· 1 %至丨〇%重量比，以聚 酯之總重量為基準。 25.根據申請專利範圍第24項之方法，其中二苯酸雙經燒酯 之燒基取代基是選自包括具自1至6個碳原子的烷基。 26·根據申請專利範圍第25項之方法，其中二苯酸雙羥烷酯 疋一冬雙-占-輕乙g旨。 27·根據申請專利範圍第24項之方法，其中羥基次膦酸單體 是選自包括2 -羥乙基（苯基）次膦酸，2 -羧乙基（甲基）次 膦酸，2 -羧乙基（苯基）次膦酸的環酸酐與2 -羧乙基（苯 基）次膦酸的環酸酐。 28·根據申請專利範圍第27項之方法’其中羧基次膦酸單體 疋2-幾乙基（苯基）次鱗酸。 29·根據申請專利範圍第27項之方法’其中羧基次膦酸單體 本紙張尺度國國家標準(CNS) A4規格(210X29宁公ί了
訂
8 8 8 8 A B c D 436506 六、申請專利範圍 是2 -羧乙基（甲基）次膦酸。 30. 根據申請專利範圍第1項之阻燃劑線形聚酯，其係呈成 型物件的形式。 31. 根據申請專利範圍第1項之阻燃劑線形聚酯，其係呈纖 維形式。 本紙張尺度適用中國國家標準(CNS) A4規格(21〇x 29^公釐）
TW084101943A 1994-03-11 1995-03-02 Flame retardant polyester copolymers TW436506B (en)

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US08/209,340 US5399428A (en) 1994-03-11 1994-03-11 Flame retardant polyester copolymers

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US (1) US5399428A (zh)
EP (1) EP0749451B1 (zh)
JP (1) JPH09510240A (zh)
KR (1) KR100404666B1 (zh)
AT (1) ATE195135T1 (zh)
CA (1) CA2183640A1 (zh)
DE (1) DE69518231T2 (zh)
ES (1) ES2149972T3 (zh)
PT (1) PT749451E (zh)
TW (1) TW436506B (zh)
WO (1) WO1995024434A1 (zh)

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ES2149972T3 (es) 2000-11-16
ATE195135T1 (de) 2000-08-15
WO1995024434A1 (en) 1995-09-14
EP0749451A1 (en) 1996-12-27
DE69518231D1 (de) 2000-09-07
DE69518231T2 (de) 2001-03-22
US5399428A (en) 1995-03-21
CA2183640A1 (en) 1995-09-14
MX9604005A (es) 1997-09-30
KR100404666B1 (ko) 2004-05-20
PT749451E (pt) 2000-12-29
EP0749451B1 (en) 2000-08-02
KR970701746A (ko) 1997-04-12
JPH09510240A (ja) 1997-10-14

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