TW202022143A - Deposition apparatus and deposition method - Google Patents

Deposition apparatus and deposition method Download PDF

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TW202022143A
TW202022143A TW108133980A TW108133980A TW202022143A TW 202022143 A TW202022143 A TW 202022143A TW 108133980 A TW108133980 A TW 108133980A TW 108133980 A TW108133980 A TW 108133980A TW 202022143 A TW202022143 A TW 202022143A
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substrate
gap
aforementioned
film forming
gas
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TWI773926B (en
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加藤裕子
矢島貴浩
中村文生
植喜信
小倉祥吾
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日商愛發科股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/12Organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/10Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C9/00Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
    • B05C9/08Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation
    • B05C9/12Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation the auxiliary operation being performed after the application
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/60Deposition of organic layers from vapour phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065After-treatment
    • B05D3/067Curing or cross-linking the coating
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/50Substrate holders
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment

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Abstract

Subject of this invention is to form resin layer with good film thickness distribution on a substrate. In a deposition apparatus, a cooling stage has a supporting surface which supports a substrate and a side surface portion connected to the supporting surface, and is configured so that an outer peripheral end of the substrate supported by the supporting surface protrudes outward from the side surface portion. A deposition-preventing frame portion is annular, is disposed so as to surround the side surface portion of the cooling stage, a recess portion is provided at a position facing the outer peripheral end of the substrate, and the side surface portion is surrounded by the recess portion. A gas supply unit supplies raw material gas including energy beam curable resin toward the supporting surface. An irradiation source faces the supporting surface and irradiates energy beam which cures the energy beam curable resin toward the supporting surface. A vacuum tank stores the cooling stage, the deposition-preventing frame portion, the gas supply unit, and the irradiation source.

Description

成膜裝置以及成膜方法Film forming device and film forming method

本發明係關於一種成膜裝置以及成膜方法。The present invention relates to a film forming device and a film forming method.

當使紫外線硬化樹脂等能量線硬化樹脂硬化而在基板上形成樹脂層時,通常來說,要進行以下兩個步驟。亦即,由冷卻台(cooling stage)來支持基板並將包含該樹脂之原料氣體供給至支持於冷卻台之基板上的步驟,以及將紫外線等光照射至基板上並在基板上形成已硬化之樹脂層的步驟。When an energy ray hardening resin such as an ultraviolet hardening resin is hardened to form a resin layer on a substrate, generally, the following two steps are required. That is, the step of supporting the substrate by a cooling stage and supplying the raw material gas containing the resin to the substrate supported on the cooling stage, and irradiating light such as ultraviolet rays on the substrate to form a hardened substrate on the substrate Resin layer steps.

尤其最近提供一種如下的成膜裝置:並非將這些複數個步驟分別在不同的真空腔室內進行,而是在一個真空腔室內進行將原料氣體供給至基板上的步驟以及藉由紫外線等在基板上形成已硬化的樹脂層的步驟(例如參照專利文獻1)。 [先前技術文獻] [專利文獻]Especially recently, a film forming apparatus is provided that does not perform these plural steps separately in different vacuum chambers, but performs the step of supplying the raw material gas onto the substrate in one vacuum chamber and the step of applying ultraviolet rays on the substrate. A step of forming a hardened resin layer (for example, refer to Patent Document 1). [Prior Technical Literature] [Patent Literature]

專利文獻1:日本特開2013-064187號公報。Patent Document 1: JP 2013-064187 A.

[發明所欲解決之課題][Problems to be solved by the invention]

然而,在減壓環境氣體下,原料氣體容易附著於相當於基板的側部(從基板的外周端起的前端的部分)之冷卻台。當該原料氣體硬化而作為樹脂層堆積得較厚時,會發生基板爬到該樹脂層之現象。藉此,冷卻台對基板造成的冷卻效果降低,基板的面內溫度分佈變得不均勻,陷入無法獲得所需的膜厚分佈之狀況。However, under a reduced pressure atmosphere, the raw material gas easily adheres to the cooling table corresponding to the side portion of the substrate (the part of the front end from the outer peripheral end of the substrate). When the raw material gas hardens and becomes thicker as a resin layer, a phenomenon in which the substrate climbs onto the resin layer may occur. As a result, the cooling effect of the cooling table on the substrate is reduced, and the in-plane temperature distribution of the substrate becomes non-uniform, and the desired film thickness distribution cannot be obtained.

作為解決該問題的手段,有在冷卻台的周圍安裝包圍冷卻台的側面部之防著板的方法。然而,即便設置這種防著板,樹脂層亦會堆積於基板的側部處的防著板,結果可能發生相同的現象。As a means to solve this problem, there is a method of installing an anti-blocking plate surrounding the side of the cooling table around the cooling table. However, even if such an anti-impact plate is provided, the resin layer will be deposited on the anti-impact plate at the side of the substrate, and as a result, the same phenomenon may occur.

鑒於以上情況,本發明的目的在於提供在基板上以良好的膜厚分佈形成樹脂層之成膜裝置以及成膜方法。 [用以解決課題的手段]In view of the above circumstances, the object of the present invention is to provide a film forming apparatus and a film forming method for forming a resin layer on a substrate with a good film thickness distribution. [Means to solve the problem]

為了達成上述目的,本發明的一形態的成膜裝置具備冷卻台、防著框部、氣體供給部、照射源以及真空槽。上述冷卻台具有將基板予以支持之支持面以及與上述支持面相連之側面部,且構成為由上述支持面所支持之上述基板的外周端從上述側面部突出。上述防著框部為環狀,以包圍上述冷卻台的上述側面部之方式配置,於與上述基板的上述外周端對向之位置處設置有凹部,由上述凹部包圍上述側面部。上述氣體供給部朝上述支持面供給包含能量線硬化樹脂之原料氣體。上述照射源與上述支持面對向,朝上述支持面照射使上述能量線硬化樹脂硬化之能量線。上述真空槽收容上述冷卻台、上述防著框部、上述氣體供給部以及上述照射源。In order to achieve the above-mentioned object, a film forming apparatus according to an aspect of the present invention includes a cooling table, an anti-sticking frame, a gas supply part, an irradiation source, and a vacuum chamber. The cooling stage has a support surface for supporting the substrate and a side surface connected to the support surface, and is configured such that the outer peripheral end of the substrate supported by the support surface protrudes from the side surface. The anti-blocking frame has a ring shape and is arranged to surround the side surface of the cooling stage. A recess is provided at a position facing the outer peripheral end of the substrate, and the side surface is surrounded by the recess. The gas supply part supplies a raw material gas containing an energy ray curable resin to the support surface. The irradiation source faces the support surface, and irradiates the support surface with energy rays that harden the energy ray hardening resin. The vacuum chamber accommodates the cooling table, the anti-blocking frame portion, the gas supply portion, and the irradiation source.

根據這種成膜裝置,因以包圍冷卻台的側面部之方式配置有防著框部,故樹脂層不易堆積於冷卻台。進而,因於防著框部中與基板的外周端對向之位置處設置有凹部,故即便樹脂層堆積於防著框部,樹脂層亦不會到達基板,基板不易從冷卻台離開。藉此,基板的面內溫度分佈變得均勻,能夠在基板上以良好的膜厚分佈形成樹脂層。According to this film forming apparatus, since the anti-sticking frame is arranged so as to surround the side surface of the cooling table, the resin layer is not easily deposited on the cooling table. Furthermore, since the recessed portion is provided at the position facing the outer peripheral end of the substrate in the anti-sticking frame portion, even if the resin layer is deposited on the anti-sticking frame portion, the resin layer does not reach the substrate and the substrate is not easily separated from the cooling table. Thereby, the in-plane temperature distribution of the substrate becomes uniform, and the resin layer can be formed on the substrate with a good film thickness distribution.

成膜裝置中,於上述冷卻台的上述側面部與上述防著框部之間設置有第一間隙;於上述防著框部與上述基板之間設置有第二間隙;於上述冷卻台設置有:氣體噴射機構,係經由上述第一間隙從上述第二間隙朝上述真空槽的側壁噴射惰性氣體。In the film forming apparatus, a first gap is provided between the side portion of the cooling table and the anti-sticking frame portion; a second gap is provided between the anti-sticking frame portion and the substrate; and the cooling table is provided with : A gas injection mechanism that injects an inert gas from the second gap to the side wall of the vacuum chamber through the first gap.

根據這種成膜裝置,藉由從防著框部與基板之間的第一間隙噴射之惰性氣體,將原料氣體於從台(stage)朝真空槽的側壁之方向推回。藉此,第一間隙中不易形成有樹脂層,基板更確實地不易從冷卻台離開。According to this film forming apparatus, the source gas is pushed back from the stage toward the side wall of the vacuum chamber by the inert gas injected from the first gap between the stop frame and the substrate. Thereby, the resin layer is not easily formed in the first gap, and the substrate is not easily separated from the cooling table more reliably.

成膜裝置中,設置於上述防著框部之上述凹部係藉由如下構件所構成:底面部;側壁部,與上述底面部連接設置,且與上述冷卻台的上述側面部對向;以及外周部,與上述底面部連接設置,且包圍上述底面部以及上述側壁部;於上述凹部係附設有與上述側壁部對向且包圍上述冷卻台之隔斷部;於上述隔斷部與上述側壁部之間設置有與上述第一間隙並排設置之第三間隙;於上述隔斷部與上述基板之間設置有第四間隙;上述氣體噴射機構係經由上述第一間隙而從上述第二間隙以及上述第四間隙朝上述真空槽的上述側壁噴射上述惰性氣體,並且經由上述第三間隙從上述第四間隙朝上述側壁噴射上述惰性氣體。In the film forming apparatus, the concave portion provided in the anti-sticking frame portion is constituted by the following members: a bottom surface portion; a side wall portion connected to the bottom surface portion and opposed to the side surface portion of the cooling table; and an outer periphery Part, which is connected to the bottom face part and surrounds the bottom face part and the side wall part; a partition part facing the side wall part and surrounding the cooling platform is attached to the recess part; between the partition part and the side wall part A third gap is provided side by side with the first gap; a fourth gap is provided between the partition portion and the substrate; the gas injection mechanism is moved from the second gap and the fourth gap through the first gap The inert gas is sprayed toward the side wall of the vacuum chamber, and the inert gas is sprayed toward the side wall from the fourth gap through the third gap.

根據這種成膜裝置,不僅向第一間隙,亦向第三間隙導入惰性氣體。藉此,原料氣體不易附著於構成凹部之側壁部,樹脂層不易形成於該側壁部。結果,基板更確實地不易從冷卻台離開。According to this film forming apparatus, the inert gas is introduced not only into the first gap but also into the third gap. Thereby, it is difficult for the raw material gas to adhere to the side wall constituting the recess, and the resin layer is difficult to form on the side wall. As a result, the substrate cannot be easily separated from the cooling table more reliably.

成膜裝置中,上述第四間隙的寬度可比上述第二間隙的寬度更寬。In the film forming apparatus, the width of the fourth gap may be wider than the width of the second gap.

根據這種成膜裝置,因構成為第四間隙的寬度比第二間隙的寬度更寬,故即便樹脂層形成於隔斷部的上部,該樹脂層亦不易到達基板。結果,基板更確實地不易從冷卻台離開。According to this film forming apparatus, since the width of the fourth gap is wider than the width of the second gap, even if the resin layer is formed on the upper part of the partition, the resin layer cannot easily reach the substrate. As a result, the substrate cannot be easily separated from the cooling table more reliably.

成膜裝置中,上述冷卻台的上述支持面為矩形;上述氣體噴射機構可獨立地控制在與上述支持面的角部對向之上述第三間隙流動之上述惰性氣體的流量、以及在與上述角部以外的上述支持面的邊部對向之上述第三間隙流動之上述惰性氣體的流量。In the film forming apparatus, the supporting surface of the cooling table is rectangular; the gas injection mechanism can independently control the flow rate of the inert gas flowing in the third gap opposite to the corner of the supporting surface, and The flow rate of the inert gas flowing in the third gap facing the side of the support surface other than the corner.

根據這種成膜裝置,即便存在於冷卻台的角部附近之原料氣體的濃度與存在於冷卻台的邊部附近之原料氣體的濃度不同,亦能夠獨立地控制分別在角部附近以及邊部附近之第三間隙流動之惰性氣體的流量。藉此,能夠均勻地控制分別於角部附近以及邊部附近之凹部處堆積之樹脂層的厚度。結果,基板更確實地不易從冷卻台離開。According to this film forming apparatus, even if the concentration of the source gas existing near the corner of the cooling table is different from the concentration of the source gas existing near the edge of the cooling table, it is possible to independently control the concentration of the source gas near the corner and the edge. The flow of inert gas flowing in the third gap nearby. Thereby, it is possible to uniformly control the thickness of the resin layer deposited in the recesses near the corners and the sides, respectively. As a result, the substrate cannot be easily separated from the cooling table more reliably.

本發明的一形態的成膜方法中,在具有將基板予以支持之支持面以及與上述支持面相連之側面部之冷卻台的上述支持面,以上述基板的外周端從上述側面部突出的方式支持上述基板;包圍上述冷卻台的上述側面部之環狀的防著框部係在與上述基板的上述外周端對向之位置處設置有凹部,且將上述側面部由上述凹部所包圍之上述防著框部配置於上述冷卻台的周圍;朝上述基板供給包含能量線硬化樹脂之原料氣體;朝上述基板照射使上述能量線硬化樹脂硬化之能量線,藉此於上述基板上形成樹脂層。In the film forming method according to an aspect of the present invention, the support surface of the cooling table having a support surface for supporting a substrate and a side surface connected to the support surface is such that the outer peripheral end of the substrate protrudes from the side surface. Supports the substrate; the ring-shaped adhesion prevention frame surrounding the side surface of the cooling table is provided with a recessed portion at a position opposite to the outer peripheral end of the substrate, and the side surface portion is surrounded by the recessed portion The protective frame is arranged around the cooling stage; supplying a raw material gas containing energy ray hardening resin to the substrate; irradiating the substrate with energy rays that harden the energy ray hardening resin, thereby forming a resin layer on the substrate.

根據這種成膜方法,以包圍冷卻台的側面部之方式配置有防著框部,因此樹脂層不易堆積於冷卻台。進而,因於防著框部中與基板的外周端對向之位置處設置有凹部,故即便樹脂層堆積於防著框部,樹脂層亦不會到達基板,基板不易從冷卻台離開。藉此,基板的面內溫度分佈變得均勻,能夠在基板上以良好的膜厚分佈形成樹脂層。 [發明功效]According to this film forming method, the anti-sticking frame is arranged so as to surround the side surface of the cooling table, so that the resin layer is not easily deposited on the cooling table. Furthermore, since the recessed portion is provided at the position facing the outer peripheral end of the substrate in the anti-sticking frame portion, even if the resin layer is deposited on the anti-sticking frame portion, the resin layer does not reach the substrate and the substrate is not easily separated from the cooling table. Thereby, the in-plane temperature distribution of the substrate becomes uniform, and the resin layer can be formed on the substrate with a good film thickness distribution. [Effect of invention]

如以上所述,根據本發明,提供能夠以良好的膜厚分佈在基板上形成樹脂層之成膜裝置以及成膜方法。As described above, according to the present invention, a film forming apparatus and a film forming method capable of forming a resin layer on a substrate with a good film thickness distribution are provided.

以下,參照圖式對本發明的實施形態進行說明。各圖式中有時導入XYZ軸坐標。例如,圖中X軸方向與Y軸方向表示相互正交之方向,這些方向在實施形態中表示水平方向。Z軸方向表示與X軸方向以及Y軸方向正交之方向,且表示鉛直方向(重力方向)。Hereinafter, an embodiment of the present invention will be described with reference to the drawings. XYZ axis coordinates are sometimes imported into each drawing. For example, the X-axis direction and the Y-axis direction in the figure indicate directions orthogonal to each other, and these directions indicate the horizontal direction in the embodiment. The Z-axis direction indicates a direction orthogonal to the X-axis direction and the Y-axis direction, and indicates the vertical direction (gravity direction).

而且,有時對相同的構件或具有相同的功能之構件附上相同的符號,且有時會在說明該構件後適當地省略說明。In addition, the same member or member having the same function may be given the same reference numeral, and the description may be appropriately omitted after the member is described.

(成膜裝置)(Film forming device)

圖1是本實施形態的成膜裝置之示意性剖視圖。圖2中的(a)是從鉛直方向俯視圖1的第一區域S1之示意性俯視圖。圖2中的(b)是沿著圖2中的(a)的A-A線之示意性剖視圖。Fig. 1 is a schematic cross-sectional view of the film forming apparatus of this embodiment. Fig. 2(a) is a schematic plan view of the first region S1 of Fig. 1 viewed from a vertical direction. Fig. 2(b) is a schematic cross-sectional view taken along line A-A in Fig. 2(a).

成膜裝置1是用以於基板W上形成作為能量線硬化樹脂之紫外線硬化樹脂層的成膜裝置。成膜裝置1具備真空槽10、冷卻台15、防著框部18、間隔壁16、氣體供給部13、照射源14以及氣體供給管線100。基板W例如為玻璃基板、半導體基板等,基板W的平面形狀例如可為矩形,亦可為圓形。The film forming apparatus 1 is a film forming apparatus for forming an ultraviolet curable resin layer as an energy ray curable resin on a substrate W. The film forming apparatus 1 includes a vacuum chamber 10, a cooling table 15, a blocking frame portion 18, a partition wall 16, a gas supply portion 13, an irradiation source 14, and a gas supply line 100. The substrate W is, for example, a glass substrate, a semiconductor substrate, etc., and the planar shape of the substrate W may be, for example, a rectangle or a circle.

真空槽10是上部為大氣且下部能夠維持減壓狀態之真空容器。真空槽10具有:第一腔室本體11;以及第二腔室本體12,係配置於第一腔室本體11之上。真空槽10收容冷卻台15、防著框部18、氣體供給部13、照射源14以及間隔壁16。The vacuum chamber 10 is a vacuum container whose upper part is atmospheric and the lower part can maintain a reduced pressure state. The vacuum chamber 10 has a first chamber body 11 and a second chamber body 12, which is disposed on the first chamber body 11. The vacuum tank 10 accommodates the cooling table 15, the anti-blocking frame part 18, the gas supply part 13, the irradiation source 14 and the partition wall 16.

真空槽10中,第一腔室本體11與第二腔室本體12藉由間隔壁16而劃分。第一腔室本體11的內部構成第一區域S1。第二腔室本體12的內部構成第二區域S2。In the vacuum chamber 10, the first chamber body 11 and the second chamber body 12 are divided by a partition wall 16. The inside of the first chamber body 11 constitutes a first area S1. The inside of the second chamber body 12 constitutes a second area S2.

第一區域S1藉由真空排氣系統19調壓至預定的真空度。調壓時的真空度無特別限制,但通常設定為1×10-3 Pa以上至500Pa以下。而且,於第一區域S1配置有氣體供給部13。第二區域S2係維持為例如大氣環境氣體。於第二區域S2係以與冷卻台15對向之方式配置有作為紫外線光源之照射源14。The pressure of the first region S1 is adjusted to a predetermined vacuum degree by the vacuum exhaust system 19. The degree of vacuum during pressure adjustment is not particularly limited, but is usually set to 1×10 -3 Pa or more and 500 Pa or less. Furthermore, a gas supply unit 13 is arranged in the first region S1. The second area S2 is maintained in, for example, atmospheric gas. In the second area S2, an irradiation source 14 serving as an ultraviolet light source is arranged opposite to the cooling table 15.

從Z軸方向觀察真空槽10之外形係被設計為例如與冷卻台15的外形相稱。例如,真空槽10的外形為矩形狀。然而,該外形不限於矩形。The external shape of the vacuum chamber 10 when viewed from the Z-axis direction is designed to match the external shape of the cooling table 15, for example. For example, the external shape of the vacuum chamber 10 is rectangular. However, the outer shape is not limited to rectangular.

冷卻台15經由未圖示的密封機構等安裝於第一腔室本體11,且設置於第一區域S1。冷卻台15具有用以配置基板W的基板支持台151。冷卻台15中,基板支持台151配置於第一區域S1的大致中央,且具有將作為處理對象之基板W予以支持之支持面151a。The cooling table 15 is attached to the first chamber body 11 via a sealing mechanism not shown or the like, and is installed in the first region S1. The cooling table 15 has a substrate support table 151 for arranging the substrate W. In the cooling stage 15, the substrate support stage 151 is arranged in the approximate center of the first region S1, and has a support surface 151a that supports the substrate W as the processing target.

支持面151a於與Z軸方向正交之X-Y軸平面中,形狀無特別限制,成為矩形狀。冷卻台15除具有支持面151a外,亦具有與支持面151a相連之側面部151w。而且,冷卻台15構成為當基板W被支持於支持面151a時,基板W的外周端E從側面部151w突出。換言之,支持面151a的面積小於基板W的面積。The supporting surface 151a is in the X-Y axis plane orthogonal to the Z axis direction, and the shape is not particularly limited, and is rectangular. In addition to the supporting surface 151a, the cooling table 15 also has a side surface 151w connected to the supporting surface 151a. Furthermore, the cooling stage 15 is configured such that when the substrate W is supported on the support surface 151a, the outer peripheral end E of the substrate W protrudes from the side surface 151w. In other words, the area of the support surface 151a is smaller than the area of the substrate W.

進而,基板支持台151內建用以將基板W冷卻至預定溫度之未圖示的冷卻機構(溫度:-30℃以上至0℃以下)。藉此,基板W藉由冷卻台15而冷卻至預定的溫度,原料氣體中的紫外線硬化樹脂於基板W上冷卻並冷凝。結果,於基板W上係能夠形成紫外線硬化樹脂層。為了於基板W形成均勻膜厚的紫外線硬化樹脂層,期望被支持於冷卻台15時的基板W的面內溫度分佈儘量無不均。Furthermore, the substrate support table 151 has a built-in cooling mechanism (temperature: -30°C or higher to 0°C or lower), not shown, for cooling the substrate W to a predetermined temperature. Thereby, the substrate W is cooled to a predetermined temperature by the cooling stage 15, and the ultraviolet curable resin in the raw material gas is cooled and condensed on the substrate W. As a result, an ultraviolet curable resin layer can be formed on the substrate W. In order to form an ultraviolet curable resin layer with a uniform film thickness on the substrate W, it is desirable that the in-plane temperature distribution of the substrate W when it is supported on the cooling table 15 is as uniform as possible.

而且,冷卻台15可藉由未圖示的驅動機構來使基板支持台151於Z軸方向升降。而且,冷卻台15亦可具備使支持面151a於X-Y軸平面內旋轉之旋轉機構。In addition, the cooling table 15 can raise and lower the substrate support table 151 in the Z-axis direction by a driving mechanism not shown. Moreover, the cooling table 15 may also be equipped with the rotation mechanism which rotates the support surface 151a in the X-Y axis plane.

防著框部18以包圍冷卻台15的側面部151w之方式配置。亦即,防著框部18是於X-Y軸平面中為環狀的構件。防著框部18的X-Y軸平面中之外形例如為矩形。於該防著框部18中與基板W的外周端E對向之位置處設置有凹部181h。凹部181h由底面部181b、側壁部181w及外周部181e所構成。The anti-sticking frame 18 is arranged so as to surround the side surface 151w of the cooling table 15. That is, the anti-sticking frame portion 18 is a ring-shaped member in the X-Y axis plane. The outer shape in the X-Y axis plane of the anti-stroke frame portion 18 is, for example, a rectangle. A recessed portion 181h is provided at a position opposed to the outer peripheral end E of the substrate W in the blocking frame portion 18. The recessed portion 181h is composed of a bottom surface portion 181b, a side wall portion 181w, and an outer peripheral portion 181e.

底面部181b係凹部181h中之成為基底之部分。側壁部181w係與底面部181b連接設置且是與冷卻台15的側面部151w對向之隔斷部。外周部181e係與底面部181b連接設置且包圍底面部181b以及側壁部181w之厚壁部分。由於防著框部18於X-Y軸平面中為環狀,因此凹部181h亦於X-Y軸平面中構成為環狀。藉此,冷卻台15的側面部151w成為由凹部181h所包圍之構成。The bottom portion 181b is a portion of the recess 181h that becomes the base. The side wall portion 181w is connected to the bottom surface portion 181b and is a partition portion facing the side surface portion 151w of the cooling table 15. The outer peripheral portion 181e is connected to the bottom surface portion 181b and surrounds the thick portion of the bottom surface portion 181b and the side wall portion 181w. Since the anti-sticking frame portion 18 is ring-shaped in the X-Y axis plane, the recessed portion 181h is also configured as a ring shape in the X-Y axis plane. Thereby, the side surface part 151w of the cooling table 15 becomes the structure enclosed by the recessed part 181h.

而且,防著框部18與冷卻台15的側面部151w不密接,於冷卻台15的側面部151w與防著框部18(側壁部181w)之間係設置有例如間隙寬度為0.01mm以上至0.5mm以下的第一間隙C1。防著框部18與基板W不密接,於防著框部18(側壁部181w)與基板W之間係設置有例如間隙寬度為0.01mm以上至0.2mm以下的第二間隙C2。第二間隙C2與第一間隙C1連通。另外,第二間隙C2亦是側壁部181w與支持面151a的高度之差。Furthermore, the anti-sticking frame portion 18 is not in close contact with the side surface 151w of the cooling table 15, and a gap width of 0.01 mm or more is provided between the side portion 151w of the cooling table 15 and the anti-sticking frame portion 18 (side wall portion 181w). The first gap C1 is 0.5mm or less. The adhesion prevention frame portion 18 and the substrate W are not in close contact, and a second gap C2 having a gap width of 0.01 mm or more and 0.2 mm or less is provided between the adhesion prevention frame portion 18 (side wall portion 181w) and the substrate W. The second gap C2 communicates with the first gap C1. In addition, the second gap C2 is also the difference in height between the side wall portion 181w and the supporting surface 151a.

外框構件20以包圍冷卻台15以及防著框部18之方式配置。亦即,外框構件20於X-Y軸平面中為環狀。外框構件20的X-Y軸平面中之外形例如為矩形。於外框構件20設置有包圍冷卻台15以及防著框部18之排氣槽201。排氣槽201係與第一區域S1連通,且將存在於第一區域S1之氣體予以抽吸。然後,存在於第一區域S1之氣體係藉由真空排氣系統19,經由排氣槽201而排出至真空槽10外。The outer frame member 20 is arranged so as to surround the cooling table 15 and the anti-sticking frame 18. That is, the outer frame member 20 has a ring shape in the X-Y axis plane. The outer shape in the X-Y axis plane of the outer frame member 20 is, for example, a rectangle. The outer frame member 20 is provided with an exhaust groove 201 surrounding the cooling table 15 and the anti-sticking frame 18. The exhaust groove 201 communicates with the first area S1 and sucks the gas existing in the first area S1. Then, the gas system existing in the first region S1 is exhausted to the outside of the vacuum chamber 10 through the exhaust groove 201 by the vacuum exhaust system 19.

氣體供給部13連接於:氣體供給管線100,係生成包含紫外線硬化樹脂之原料氣體。氣體供給部13具有複數個分支配管部131。氣體供給部13亦可為後述的簇射板(shower plate)。照射源14朝支持面151a照射作為能量線之紫外線UV。藉此,塗佈於基板W上之紫外線硬化樹脂硬化。照射源14配置於第二區域S2。反射板17使從照射源14照射之紫外線UV高效地聚集於基板W。The gas supply part 13 is connected to the gas supply line 100 and generates a raw material gas containing ultraviolet curable resin. The gas supply part 13 has a plurality of branch pipe parts 131. The gas supply part 13 may be a shower plate (shower plate) mentioned later. The irradiation source 14 irradiates ultraviolet rays UV as energy rays toward the support surface 151a. Thereby, the ultraviolet curable resin coated on the substrate W is cured. The irradiation source 14 is arranged in the second area S2. The reflection plate 17 collects the ultraviolet rays UV irradiated from the irradiation source 14 on the substrate W efficiently.

間隔壁16位於第一腔室本體11與第二腔室本體12之間。間隔壁16劃分真空槽10的內部,具有包含與Z軸方向正交之X-Y軸平面之板狀構造。間隔壁16具有透過紫外線UV之透過部161。透過部161可為整個間隔壁16,亦可為間隔壁16的一部分。透過部161例如由設置於四個部位之矩形狀的窗部所構成。而且,構成透過部161之材料只要是透過紫外線UV之材料即可,無特別限制,例如採用石英玻璃。藉由這種間隔壁16能夠阻斷第一區域S1與第二區域S2的環境氣體,且從照射源14照射之紫外線UV能夠透過。The partition wall 16 is located between the first chamber body 11 and the second chamber body 12. The partition wall 16 partitions the inside of the vacuum chamber 10, and has a plate-like structure including an X-Y axis plane orthogonal to the Z axis direction. The partition wall 16 has a transmission portion 161 that transmits ultraviolet rays UV. The transparent portion 161 may be the entire partition wall 16 or a part of the partition wall 16. The transparent portion 161 is constituted by, for example, rectangular windows provided at four locations. Furthermore, the material constituting the transmission portion 161 is not particularly limited as long as it is a material that transmits ultraviolet rays. For example, quartz glass is used. The partition wall 16 can block the ambient gas in the first area S1 and the second area S2, and the ultraviolet rays UV irradiated from the irradiation source 14 can be transmitted.

紫外線硬化樹脂材料能夠使用例如丙烯酸系樹脂。而且,上述樹脂中亦能夠添加並使用聚合起始劑等。包含這種樹脂之原料氣體係藉由設置於真空槽10的外部之氣體供給管線100所生成。氣體供給管線100連接於氣體供給部13,向真空槽10內供給包含上述樹脂之原料氣體。As the ultraviolet curable resin material, for example, acrylic resin can be used. Moreover, a polymerization initiator etc. can also be added and used for the said resin. The raw material gas system containing this resin is generated by the gas supply line 100 provided outside the vacuum chamber 10. The gas supply line 100 is connected to the gas supply unit 13 and supplies the raw material gas containing the above-mentioned resin into the vacuum chamber 10.

氣體供給管線100具有樹脂材料供給管線110、氣化器120以及配管130。The gas supply line 100 has a resin material supply line 110, a vaporizer 120 and a pipe 130.

樹脂材料供給管線110係由填充有液狀的樹脂材料之箱111、以及將樹脂材料從箱111向氣化器120輸送之配管112所構成。作為將樹脂材料從箱111向氣化器120輸送之方法,例如可列舉使用由惰性氣體所構成之載氣(carrier gas)的方法。而且,配管112中亦能夠安裝閥V1或未圖示的液體流量控制器等。The resin material supply line 110 is composed of a tank 111 filled with a liquid resin material, and a pipe 112 that transports the resin material from the tank 111 to the vaporizer 120. As a method of transferring the resin material from the tank 111 to the vaporizer 120, for example, a method of using a carrier gas composed of an inert gas can be cited. Furthermore, a valve V1, a liquid flow controller not shown, or the like can also be installed in the pipe 112.

配管112的一端部配置於氣化器120的內部。氣化器120藉由生成從配管112所輸送之樹脂材料的霧,來生成原料氣體。此處,生成樹脂材料的霧意味著使樹脂材料氣化。氣化器120係構成為:利用未圖示的加熱機構加熱,藉此能夠維持樹脂材料的氣化的狀態。One end of the pipe 112 is arranged inside the vaporizer 120. The vaporizer 120 generates a raw material gas by generating mist of the resin material conveyed from the pipe 112. Here, generating mist of the resin material means vaporizing the resin material. The vaporizer 120 is configured to be heated by a heating mechanism (not shown) to maintain the vaporized state of the resin material.

氣化器120連接於配管130。由氣化器120生成之原料氣體係經由配管130供給至氣體供給部13。此時,亦能夠將閥V2安裝於配管130,調節氣體向氣體供給部13的流入。進而,藉由安裝未圖示的流量控制器,能夠控制向氣體供給部13流入之氣體的流量。另外,配管130亦藉由未圖示的加熱機構而被加熱至能夠維持原料氣體的氣化狀態之溫度。The vaporizer 120 is connected to the pipe 130. The raw material gas system generated by the vaporizer 120 is supplied to the gas supply unit 13 via the pipe 130. At this time, the valve V2 can also be attached to the pipe 130 to regulate the inflow of gas into the gas supply unit 13. Furthermore, by installing a flow controller (not shown), the flow rate of the gas flowing into the gas supply unit 13 can be controlled. In addition, the pipe 130 is also heated to a temperature capable of maintaining the vaporized state of the source gas by a heating mechanism not shown.

(成膜方法)(Film forming method)

使用成膜裝置1之成膜方法主要具有以下的兩個步驟。亦即,將包含紫外線硬化樹脂之原料氣體從氣體供給部13供給至基板W上,藉此在基板W上形成紫外線硬化樹脂層之步驟;以及藉由從照射源14照射紫外線UV而將紫外線硬化樹脂層硬化之步驟。The film forming method using the film forming apparatus 1 mainly has the following two steps. That is, a step of supplying a raw material gas containing an ultraviolet curable resin from the gas supply part 13 to the substrate W, thereby forming an ultraviolet curable resin layer on the substrate W; and curing the ultraviolet by irradiating ultraviolet UV from the irradiation source 14 The step of hardening the resin layer.

(紫外線硬化樹脂層的形成步驟)(Steps of forming the UV-curable resin layer)

首先,如圖1般,將基板W配置於支持面151a上。此處,於支持面151a係以基板W的外周端E從側面部151w突出的方式支持基板W。而且,將環狀的防著框部18配置於冷卻台15的周圍。First, as shown in FIG. 1, the substrate W is arranged on the support surface 151a. Here, the substrate W is supported on the support surface 151a so that the outer peripheral end E of the substrate W protrudes from the side surface 151w. In addition, the ring-shaped anti-blocking frame 18 is arranged around the cooling table 15.

接下來,藉由真空排氣系統19將第一區域S1調壓至預定的真空度。此處,可將能夠遮蔽非成膜部分之遮罩等配置於基板W上,藉此能夠容易地進行紫外線硬化樹脂層的圖案形成。Next, the first region S1 is adjusted to a predetermined vacuum degree by the vacuum exhaust system 19. Here, a mask or the like capable of shielding the non-film-forming portion can be arranged on the substrate W, thereby making it possible to easily pattern the ultraviolet-curable resin layer.

氣體供給管線100由樹脂材料生成原料氣體,並經由氣體供給部13將原料氣體供給至真空槽10內。氣化器120使樹脂材料氣化,生成包含紫外線硬化樹脂之原料氣體。所生成之原料氣體經由配管130供給至氣體供給部13,從氣體供給部13朝基板W噴出原料氣體。當原料氣體到達基板W上時,原料氣體中的樹脂在基板W上冷凝,形成紫外線硬化樹脂層。The gas supply line 100 generates a raw material gas from a resin material, and supplies the raw material gas into the vacuum chamber 10 via the gas supply unit 13. The vaporizer 120 vaporizes the resin material to generate a raw material gas containing the ultraviolet curable resin. The generated source gas is supplied to the gas supply unit 13 via the pipe 130, and the source gas is ejected from the gas supply unit 13 toward the substrate W. When the raw material gas reaches the substrate W, the resin in the raw material gas condenses on the substrate W to form an ultraviolet-curing resin layer.

(紫外線硬化樹脂層的硬化步驟)(The curing step of the UV-curable resin layer)

接下來,於將第一腔室本體11維持為預定的真空度的狀態下,將紫外線UV從照射源14照射至基板W上,使紫外線硬化樹脂層硬化。從照射源14照射之紫外線UV透過間隔壁16的透過部161。已透過透過部161之紫外線UV經由分支配管部131間的間隙而照射至基板W上。而且,向第二腔室本體12的側壁的方向照射之一部分的紫外線UV係由反射板17反射,聚集至被配置於支持面151a之基板W上。Next, while maintaining the first chamber body 11 at a predetermined degree of vacuum, ultraviolet rays are irradiated onto the substrate W from the irradiation source 14 to harden the ultraviolet curable resin layer. The ultraviolet rays UV irradiated from the irradiation source 14 pass through the transmission portion 161 of the partition wall 16. The ultraviolet rays UV that have passed through the transmission portion 161 are irradiated onto the substrate W through the gap between the branch pipe portions 131. In addition, a part of the ultraviolet rays UV irradiated in the direction of the side wall of the second chamber body 12 is reflected by the reflecting plate 17 and collected on the substrate W arranged on the supporting surface 151a.

因氣體供給部13由相互地隔開間隔排列之複數個分支配管部131所構成,故能夠使從照射源14所照射之紫外線UV不被遮蔽地到達基板W上。藉此,能夠高效地使紫外線硬化樹脂層硬化。Since the gas supply section 13 is composed of a plurality of branch pipe sections 131 arranged at intervals, the ultraviolet rays UV irradiated from the irradiation source 14 can reach the substrate W without being shielded. Thereby, the ultraviolet curable resin layer can be cured efficiently.

(作用)(effect)

圖3是表示本實施形態的作用之示意圖。Fig. 3 is a schematic diagram showing the effect of this embodiment.

如圖3所示,藉由紫外線UV的照射所形成之紫外線硬化樹脂層30不僅堆積於基板W上,亦堆積於配置在基板W的外周之防著框部18上。尤其,隨著連續成膜的繼續,紫外線硬化樹脂層30的堆積變得顯著。As shown in FIG. 3, the ultraviolet curable resin layer 30 formed by ultraviolet UV irradiation is not only deposited on the substrate W, but also deposited on the anti-blocking frame portion 18 arranged on the outer periphery of the substrate W. In particular, as the continuous film formation continues, the accumulation of the ultraviolet curable resin layer 30 becomes remarkable.

這種情況下,由形成有凹部181h之防著框部18包圍冷卻台15的周圍,藉此於基板W的外周附近產生冷卻台15與防著框部18之間的高度偏移,抑制了紫外線硬化樹脂層30在側面部151w上的堆積(圖3)。In this case, the surrounding of the cooling table 15 is surrounded by the anti-blocking frame portion 18 in which the recessed portion 181h is formed, thereby generating a height shift between the cooling table 15 and the anti-blocking frame portion 18 near the outer periphery of the substrate W, thereby suppressing The ultraviolet curing resin layer 30 is deposited on the side surface 151w (FIG. 3).

假如沒有凹部181h,則藉由基板W的搬送偏離(基板W載置於支持面151a時的支持位置的偏差),紫外線硬化樹脂層30堆積於基板W的外周端W的下方。若紫外線硬化樹脂層30堆積於基板W的外周端W的下方,則基板W爬到紫外線硬化樹脂層30,產生基板W從支持面151a離開之現象。If there is no concave portion 181h, the ultraviolet curable resin layer 30 is deposited under the outer peripheral end W of the substrate W due to the deviation of the conveyance of the substrate W (the deviation of the supporting position when the substrate W is placed on the supporting surface 151a). When the ultraviolet curable resin layer 30 is deposited under the outer peripheral end W of the substrate W, the substrate W climbs up to the ultraviolet curable resin layer 30, and a phenomenon in which the substrate W separates from the support surface 151a occurs.

若產生這種現象,則基板W從支持面151a離開,冷卻台15的冷卻效率下降。因此,基板W的面內溫度分佈變得不均勻,形成於基板W上之紫外線硬化樹脂層30的膜厚分佈變得不均勻。If this phenomenon occurs, the substrate W will be separated from the support surface 151a, and the cooling efficiency of the cooling table 15 will decrease. Therefore, the in-plane temperature distribution of the substrate W becomes non-uniform, and the film thickness distribution of the ultraviolet curable resin layer 30 formed on the substrate W becomes non-uniform.

然而,如本實施形態般,藉由於防著框部18形成凹部181h,抑制了基板W因爬到紫外線硬化樹脂層30而從支持面151a離開之現象,基板W與支持面151a的整個面接觸。藉此,藉由冷卻台15的冷卻效果,基板W的面內溫度分佈變得均勻。結果,在基板W上以良好的膜厚分佈形成有紫外線硬化樹脂層30。However, as in the present embodiment, the recessed portion 181h is formed due to the frame portion 18 to prevent the substrate W from being separated from the support surface 151a by climbing onto the ultraviolet curable resin layer 30, and the substrate W contacts the entire surface of the support surface 151a. . Thereby, the in-plane temperature distribution of the substrate W becomes uniform due to the cooling effect of the cooling stage 15. As a result, the ultraviolet curable resin layer 30 is formed on the substrate W with a good film thickness distribution.

然而,因第二間隙C2未封閉,故長時間驅動時,紫外線硬化樹脂層30可能會堆積於第二間隙C2。However, since the second gap C2 is not closed, the ultraviolet curable resin layer 30 may accumulate in the second gap C2 during long-term driving.

(變形例1)(Modification 1)

在上述可能產生之現象係藉由變形例1來解決。The above-mentioned possible phenomenon is solved by Modification 1.

圖4是表示本實施形態的變形例1的成膜裝置之示意性剖視圖。圖4與沿著圖2中的(a)的A-A線之位置處的剖視圖對應。Fig. 4 is a schematic cross-sectional view showing a film forming apparatus according to Modification 1 of the present embodiment. Fig. 4 corresponds to a cross-sectional view taken along the line A-A in Fig. 2 (a).

如圖4所示,於冷卻台15係設置有:氣體噴射機構153,係從第二間隙C2經由第一間隙C1朝真空槽10的側壁噴射惰性氣體G。惰性氣體G例如為N2 、Ar等。氣體噴射機構153例如由附設於冷卻台15之氣體導入管153a、與第一間隙C1連通之流路153b、第一間隙C1以及第二間隙C2所構成。流路153b設置於氣體導入管153a內以及冷卻台15內。氣體導入管153a以及流路153b無特別限定,例如可沿著第一間隙C1配置複數個。而且,導入至流動之第一區域S1之惰性氣體G的總流量例如為0.01slm以上至1slm以下。As shown in FIG. 4, the cooling table 15 is provided with a gas injection mechanism 153 that injects the inert gas G toward the side wall of the vacuum chamber 10 from the second gap C2 through the first gap C1. The inert gas G is, for example, N 2 , Ar, or the like. The gas injection mechanism 153 is composed of, for example, a gas introduction pipe 153a attached to the cooling table 15, a flow path 153b communicating with the first gap C1, the first gap C1, and the second gap C2. The flow path 153b is provided in the gas introduction pipe 153a and the cooling stage 15. The gas introduction pipe 153a and the flow path 153b are not particularly limited, and for example, a plurality of them may be arranged along the first gap C1. In addition, the total flow rate of the inert gas G introduced into the first flow region S1 is, for example, 0.01 slm or more and 1 slm or less.

當惰性氣體G藉由氣體噴射機構153而從第二間隙C2朝向真空槽10的側壁噴射時,惰性氣體G由排氣槽201抽吸,並藉由真空排氣系統19排出至真空槽10外。亦即,於冷卻台15的外周係形成有從第二間隙C2朝向真空槽10的側壁之惰性氣體G的氣流。When the inert gas G is ejected from the second gap C2 toward the side wall of the vacuum chamber 10 by the gas ejection mechanism 153, the inert gas G is sucked by the exhaust groove 201, and is discharged out of the vacuum chamber 10 by the vacuum exhaust system 19 . That is, a flow of inert gas G from the second gap C2 toward the side wall of the vacuum chamber 10 is formed on the outer periphery of the cooling table 15.

藉此,存在於凹部181h附近之原料氣體係被惰性氣體G從冷卻台15朝真空槽10的側壁推回。因此,原料氣體不易進入第一間隙C1中,紫外線硬化樹脂層30更不易於第一間隙C1形成。結果,能夠更確實地防止基板W爬到紫外線硬化樹脂層30的現象,基板W不易從冷卻台15離開。Thereby, the raw material gas system existing in the vicinity of the recess 181h is pushed back by the inert gas G from the cooling table 15 toward the side wall of the vacuum chamber 10. Therefore, the raw material gas is less likely to enter the first gap C1, and the ultraviolet curable resin layer 30 is less likely to be formed in the first gap C1. As a result, it is possible to more reliably prevent the phenomenon that the substrate W climbs onto the ultraviolet curable resin layer 30, and it is difficult for the substrate W to leave the cooling stage 15.

然而,變形例1的構成中,儘管防止了在第一間隙C1中形成紫外線硬化樹脂層30,但在凹部181h中會發生紫外線硬化樹脂層30堆積於側壁部181w之現象(圖3)。這是因為,在減壓環境氣體下,惰性氣體G愈遠離第一間隙C1則惰性氣體G的濃度變得稀薄,排斥原料氣體之效果降低。若堆積於側壁部181w之紫外線硬化樹脂層30繼續生長,則可能發生由該紫外線硬化樹脂層30抬起基板W之現象。尤其,當長時間嘗試連續成膜時,側壁部181w中之紫外線硬化樹脂層30的生長變得顯著。However, in the configuration of Modification 1, although the ultraviolet curable resin layer 30 is prevented from being formed in the first gap C1, a phenomenon in which the ultraviolet curable resin layer 30 is deposited on the side wall 181w occurs in the recess 181h (FIG. 3 ). This is because, under a reduced pressure atmosphere, the farther the inert gas G is away from the first gap C1, the concentration of the inert gas G becomes thinner, and the effect of repelling the raw gas is reduced. If the ultraviolet-curable resin layer 30 deposited on the side wall portion 181w continues to grow, a phenomenon in which the substrate W is lifted by the ultraviolet-curable resin layer 30 may occur. In particular, when continuous film formation is attempted for a long time, the growth of the ultraviolet curable resin layer 30 in the side wall portion 181w becomes remarkable.

(變形例2)(Modification 2)

變形例1中可能產生之現象係藉由變形例2解決。The phenomenon that may occur in Modification 1 is solved by Modification 2.

圖5中的(a)、圖5中的(b)是本實施形態的變形例2的成膜裝置之示意性剖視圖。圖5中的(a)係與沿著圖2中的(a)的A-A線之位置處的剖視圖對應。圖5中的(b)是圖5中的(a)的放大圖。Fig. 5(a) and Fig. 5(b) are schematic cross-sectional views of a film forming apparatus according to Modification 2 of this embodiment. (A) in FIG. 5 corresponds to a cross-sectional view taken along the line A-A in (a) in FIG. 2. (B) in FIG. 5 is an enlarged view of (a) in FIG. 5.

如圖5中的(a)所示,於防著框部18中,於凹部181h附設有與側壁部181w對向之隔斷部181p。隔斷部181p為環狀,包圍冷卻台15。於隔斷部181p與側壁部181w之間設置有與第一間隙C1並排設置之第三間隙C3。第三間隙C3的間隙寬度為0.01mm以上至0.5mm以下。As shown in FIG. 5(a), in the anti-blocking frame portion 18, a partition portion 181p facing the side wall portion 181w is attached to the recess 181h. The partition part 181p has a ring shape and surrounds the cooling stage 15. A third gap C3 arranged side by side with the first gap C1 is provided between the partition portion 181p and the side wall portion 181w. The gap width of the third gap C3 is 0.01 mm or more and 0.5 mm or less.

於隔斷部181p與基板W之間係設置有:第四間隙C4,係與第二間隙C2以及第三間隙C3連通。流路153b不僅與第一間隙C1連通,且與第三間隙C3連通。換言之,流路153b的下游藉由第一間隙C1與第三間隙C3而分叉。而且,第四間隙C4的寬度比第二間隙C2的寬度更寬。另外,第四間隙C4亦是隔斷部181p與支持面151a的高度之差。第四間隙C4的間隙寬度為0.01mm以上至1mm以下。A fourth gap C4 is provided between the partition portion 181p and the substrate W, which communicates with the second gap C2 and the third gap C3. The flow path 153b communicates not only with the first gap C1 but also with the third gap C3. In other words, the downstream of the flow path 153b is branched by the first gap C1 and the third gap C3. Moreover, the width of the fourth gap C4 is wider than the width of the second gap C2. In addition, the fourth gap C4 is also the difference in height between the partition portion 181p and the support surface 151a. The gap width of the fourth gap C4 is 0.01 mm or more and 1 mm or less.

氣體噴射機構153例如由以下所構成:氣體導入管153a;流路153b;第一間隙C1;第二間隙C2;第三間隙C3,係與流路153b連通;以及第四間隙。氣體噴射機構153係經由第一間隙C1而從第二間隙C2以及第四間隙C4朝真空槽10的側壁噴射惰性氣體G,並且經由第三間隙C3從第四間隙C4朝該側壁噴射惰性氣體G。The gas injection mechanism 153 is composed of, for example, a gas introduction pipe 153a; a flow path 153b; a first gap C1; a second gap C2; a third gap C3 communicating with the flow path 153b; and a fourth gap. The gas injection mechanism 153 injects the inert gas G from the second gap C2 and the fourth gap C4 toward the side wall of the vacuum chamber 10 through the first gap C1, and injects the inert gas G toward the side wall from the fourth gap C4 through the third gap C3. .

根據這種構成,不僅向第一間隙C1,亦向第三間隙C3導入惰性氣體。藉此,原料氣體不易附著於構成凹部181h之側壁部181w,紫外線硬化樹脂層30不易形成於該側壁部181w。進而,因第四間隙C4的間隙寬度構成得比第二間隙C2的間隙寬度更寬,故如圖5中的(b)所示,即便於隔斷部181p的上部形成有紫外線硬化樹脂層30,因間隙的距離延長,紫外線硬化樹脂層30不易到達基板W。結果,基板W更確實地不易從支持面151a離開。According to this configuration, the inert gas is introduced not only into the first gap C1 but also into the third gap C3. Thereby, it is difficult for the raw material gas to adhere to the side wall part 181w constituting the recess 181h, and the ultraviolet curable resin layer 30 is not easily formed on the side wall part 181w. Furthermore, since the gap width of the fourth gap C4 is configured to be wider than the gap width of the second gap C2, as shown in FIG. 5(b), even if the ultraviolet curable resin layer 30 is formed on the upper portion of the partition portion 181p, Since the distance of the gap is extended, the ultraviolet curable resin layer 30 cannot easily reach the substrate W. As a result, the substrate W cannot be easily separated from the support surface 151a more reliably.

而且,當在與側壁部181w為相反側的隔斷部181p的上部角設置錐形部181t時,使紫外線硬化樹脂層30到達基板W之時間延遲之效果會增加。結果,基板W更確實地不易從支持面151a離開。Moreover, when the tapered portion 181t is provided at the upper corner of the partition portion 181p on the opposite side to the side wall portion 181w, the effect of delaying the time for the ultraviolet curable resin layer 30 to reach the substrate W increases. As a result, the substrate W cannot be easily separated from the support surface 151a more reliably.

(變形例3)(Modification 3)

圖6是本實施形態的變形例3的成膜裝置之示意性俯視圖。圖6中顯示從鉛直方向俯視第一區域S1之平面。Fig. 6 is a schematic plan view of a film forming apparatus according to Modification 3 of the present embodiment. FIG. 6 shows the plane of the first region S1 viewed from the vertical direction.

變形例3中,氣體噴射機構153獨立地控制:在與支持面151a的角部151c對向之第三間隙C3流動之惰性氣體G的流量、以及在與角部151c以外的支持面151a的邊部151s對向之第三間隙C3流動之惰性氣體G的流量。該情形下,上述圖5中例示之氣體噴射機構153獨立地控制:在與角部151c對向之第一間隙C1流動之惰性氣體G的流量、以及在與邊部151s對向之第一間隙C1流動之惰性氣體G的流量。In Modification 3, the gas injection mechanism 153 independently controls: the flow rate of the inert gas G flowing in the third gap C3 facing the corner 151c of the support surface 151a, and the flow rate of the inert gas G flowing on the side of the support surface 151a other than the corner 151c. The flow rate of the inert gas G flowing in the third gap C3 opposite to the portion 151s. In this case, the gas injection mechanism 153 illustrated in FIG. 5 independently controls: the flow rate of the inert gas G flowing in the first gap C1 facing the corner 151c, and the first gap facing the side 151s The flow rate of the inert gas G flowing through C1.

藉此,在上述第四間隙C4中,獨立地控制:從與角部151c對向之第四間隙C4噴射之惰性氣體G的流量、以及從與邊部151s對向之第四間隙C4噴射之惰性氣體G的流量。Thereby, in the fourth gap C4, the flow rate of the inert gas G injected from the fourth gap C4 opposite to the corner portion 151c and the flow rate of the inert gas G injected from the fourth gap C4 opposite to the side portion 151s are independently controlled. Flow rate of inert gas G.

藉此,即便於支持面151a的周邊,在原料氣體的濃度產生偏差,原料氣體亦以與在該周邊中之各個區域的濃度對應之惰性氣體G的流量從冷卻台15被朝向真空槽10的側壁推回。結果,避免了以下的現象:紫外線硬化樹脂層30比起邊部151s附近的凹部181h而優先堆積於角部151c附近的凹部181h。Thereby, even if there is a deviation in the concentration of the raw material gas in the periphery of the support surface 151a, the raw material gas is directed from the cooling stage 15 toward the vacuum chamber 10 at the flow rate of the inert gas G corresponding to the concentration of each area in the periphery Push back the side wall. As a result, the following phenomenon is avoided in which the ultraviolet curable resin layer 30 is preferentially deposited in the recess 181h near the corner portion 151c than the recess 181h near the side portion 151s.

(變形例4)(Modification 4)

圖7是本實施形態的變形例4的成膜裝置之示意性剖視圖。Fig. 7 is a schematic cross-sectional view of a film forming apparatus according to Modification 4 of the present embodiment.

複數個分支配管部可置換為簇射板。氣體供給部13B具有簇射板部1332以及空間部1330。簇射板部1332係構成如下的板狀的簇射板:配置於間隔壁16與支持面151a之間,具有在厚度方向貫通之複數個氣體供給孔1331,且整體具有紫外線透過性。空間部1330係由間隔壁16與簇射板部1332的間隙所構成,且是由它們與第一腔室本體11所劃分之空間。Multiple branch piping parts can be replaced with shower plates. The gas supply part 13B has a shower plate part 1332 and a space part 1330. The shower plate portion 1332 is configured as a plate-shaped shower plate arranged between the partition wall 16 and the support surface 151a, having a plurality of gas supply holes 1331 penetrating in the thickness direction, and having ultraviolet light permeability as a whole. The space portion 1330 is formed by the gap between the partition wall 16 and the shower plate portion 1332, and is a space partitioned by the partition wall 16 and the first chamber body 11.

以上,對本發明的實施形態進行了說明,但本發明不僅限於上述實施形態,當然可添加各種變更。各實施形態不限於獨立的形態,能夠在技術上盡可能地組合。As mentioned above, the embodiment of the present invention has been described, but the present invention is not limited to the above-mentioned embodiment, and of course various changes can be added. The respective embodiments are not limited to independent forms, and can be combined as technically as possible.

1:成膜裝置 10:真空槽 11:第一腔室本體 11c:角部 12:第二腔室本體 13,13B:氣體供給部 14:照射源 15:冷卻台 16:間隔壁 17:反射板 18:防著框部 19:真空排氣系統 20:外框構件 30:紫外線硬化樹脂層 100:氣體供給管線 110:樹脂材料供給管線 111:箱 112:配管 120:氣化器 130:配管 131:分支配管部 151:基板支持台 151a:支持面 151c:角部 151s:邊部 151w:側面部 153:氣體噴射機構 153a:氣體導入管 153b:流路 161:透過部 181b:底面部 181e:外周部 181h:凹部 181p:隔斷部 181t:錐形部 181w:側壁部 201:排氣槽 1330:空間部 1331:氣體供給孔 1332:簇射板部 C1:第一間隙 C2:第二間隙 C3:第三間隙 C4:第四間隙 E:外周端 G:惰性氣體 S1:第一區域 S2:第二區域 UV:紫外線 V1,V2:閥 W:基板1: Film forming device 10: Vacuum tank 11: The first chamber body 11c: corner 12: The second chamber body 13, 13B: Gas supply section 14: Irradiation source 15: Cooling table 16: next door 17: reflector 18: Anti-stroke frame 19: Vacuum exhaust system 20: Outer frame member 30: UV curable resin layer 100: Gas supply line 110: Resin material supply line 111: box 112: Piping 120: Vaporizer 130: Piping 131: Branch piping 151: substrate support table 151a: Support surface 151c: corner 151s: edge 151w: side 153: Gas injection mechanism 153a: Gas inlet pipe 153b: Flow path 161: Through Department 181b: bottom face 181e: Peripheral 181h: recess 181p: Partition 181t: tapered part 181w: side wall 201: Exhaust slot 1330: Ministry of Space 1331: Gas supply hole 1332: shower plate C1: first gap C2: Second clearance C3: third gap C4: The fourth gap E: peripheral end G: inert gas S1: The first area S2: second area UV: Ultraviolet V1, V2: Valve W: substrate

[圖1]是本實施形態的成膜裝置之示意性剖視圖。 [圖2]中,(a)是從鉛直方向俯視圖1的第一區域S1之示意性俯視圖,(b)是沿著(a)的A-A線之示意性剖視圖。 [圖3]是表示本實施形態的作用之示意圖。 [圖4]是本實施形態的變形例1的成膜裝置之示意性剖視圖。 [圖5]是本實施形態的變形例2的成膜裝置之示意性剖視圖。 [圖6]是本實施形態的變形例3的成膜裝置的示意性俯視圖。 [圖7]是本實施形態的變形例4的成膜裝置之示意性剖視圖。Fig. 1 is a schematic cross-sectional view of the film forming apparatus of the present embodiment. In [FIG. 2], (a) is a schematic plan view of the first region S1 of FIG. 1 viewed from a vertical direction, and (b) is a schematic cross-sectional view taken along the line A-A of (a). Fig. 3 is a schematic diagram showing the effect of this embodiment. Fig. 4 is a schematic cross-sectional view of a film forming apparatus according to Modification 1 of the present embodiment. Fig. 5 is a schematic cross-sectional view of a film forming apparatus according to Modification 2 of this embodiment. [Fig. 6] Fig. 6 is a schematic plan view of a film forming apparatus according to Modification 3 of this embodiment. Fig. 7 is a schematic cross-sectional view of a film forming apparatus according to Modification 4 of this embodiment.

1:成膜裝置 1: Film forming device

10:真空槽 10: Vacuum tank

11:第一腔室本體 11: The first chamber body

12:第二腔室本體 12: The second chamber body

13:氣體供給部 13: Gas supply department

14:照射源 14: Irradiation source

15:冷卻台 15: Cooling table

16:間隔壁 16: next door

17:反射板 17: reflector

18:防著框部 18: Anti-stroke frame

19:真空排氣系統 19: Vacuum exhaust system

20:外框構件 20: Outer frame member

100:氣體供給管線 100: Gas supply line

110:樹脂材料供給管線 110: Resin material supply line

111:箱 111: box

112:配管 112: Piping

120:氣化器 120: Vaporizer

130:配管 130: Piping

131:分支配管部 131: Branch piping

151:基板支持台 151: substrate support table

151a:支持面 151a: Support surface

151w:側面部 151w: side

161:透過部 161: Through Department

201:排氣槽 201: Exhaust slot

S1:第一區域 S1: First zone

S2:第二區域 S2: second area

UV:紫外線 UV: Ultraviolet

V1,V2:閥 V1, V2: Valve

W:基板 W: substrate

Claims (7)

一種成膜裝置,具備: 冷卻台,具有將基板予以支持之支持面以及與前述支持面相連之側面部,且構成為由前述支持面所支持之前述基板的外周端從前述側面部突出; 環狀的防著框部,以包圍前述冷卻台的前述側面部之方式配置,於與前述基板的前述外周端對向之位置處設置有凹部,由前述凹部包圍前述側面部; 氣體供給部,朝前述支持面供給包含能量線硬化樹脂之原料氣體; 照射源,與前述支持面對向,朝前述支持面照射使前述能量線硬化樹脂硬化之能量線;以及 真空槽,收容前述冷卻台、前述防著框部、前述氣體供給部以及前述照射源。A film forming device including: The cooling table has a supporting surface for supporting the substrate and a side surface connected to the supporting surface, and is configured such that the outer peripheral end of the substrate supported by the supporting surface protrudes from the side surface; The ring-shaped anti-blocking frame is arranged to surround the side surface of the cooling table, a recess is provided at a position opposite to the outer peripheral end of the substrate, and the side surface is surrounded by the recess; The gas supply part supplies the raw material gas containing the energy ray hardening resin toward the support surface; An irradiation source, facing the support surface, irradiates the support surface with energy rays that harden the energy ray hardening resin; and The vacuum tank accommodates the cooling table, the anti-blocking frame, the gas supply part, and the irradiation source. 如請求項1所記載之成膜裝置,其中於前述冷卻台的前述側面部與前述防著框部之間設置有第一間隙; 於前述防著框部與前述基板之間設置有第二間隙; 於前述冷卻台設置有:氣體噴射機構,係經由前述第一間隙從前述第二間隙朝前述真空槽的側壁噴射惰性氣體。The film forming apparatus as recited in claim 1, wherein a first gap is provided between the side surface portion of the cooling table and the blocking frame portion; A second gap is provided between the anti-sticking frame portion and the substrate; The cooling stage is provided with a gas injection mechanism which injects an inert gas from the second gap to the side wall of the vacuum tank through the first gap. 如請求項2所記載之成膜裝置,其中設置於前述防著框部之前述凹部係藉由如下構件所構成: 底面部; 側壁部,與前述底面部連接設置,且與前述冷卻台的前述側面部對向;以及 外周部,與前述底面部連接設置,且包圍前述底面部以及前述側壁部; 於前述凹部係附設有與前述側壁部對向且包圍前述冷卻台之隔斷部; 於前述隔斷部與前述側壁部之間設置有與前述第一間隙並排設置之第三間隙; 於前述隔斷部與前述基板之間設置有第四間隙; 前述氣體噴射機構係經由前述第一間隙而從前述第二間隙以及前述第四間隙朝前述真空槽的前述側壁噴射前述惰性氣體,並且經由前述第三間隙從前述第四間隙朝前述側壁噴射前述惰性氣體。The film forming apparatus described in claim 2, wherein the concave portion provided in the anti-sticking frame portion is composed of the following members: Bottom face The side wall is connected to the bottom surface and is opposite to the side surface of the cooling platform; and The outer peripheral portion is connected to the aforementioned bottom portion and surrounds the aforementioned bottom portion and the aforementioned side wall portion; The aforementioned recessed portion is attached with a partition portion facing the aforementioned side wall portion and surrounding the aforementioned cooling platform; A third gap arranged side by side with the first gap is provided between the partition portion and the side wall portion; A fourth gap is provided between the aforementioned partition and the aforementioned substrate; The gas ejection mechanism ejects the inert gas from the second gap and the fourth gap to the side wall of the vacuum chamber through the first gap, and ejects the inert gas from the fourth gap to the side wall through the third gap. gas. 如請求項2或3所記載之成膜裝置,其中前述第四間隙的寬度比前述第二間隙的寬度更寬。The film forming apparatus according to claim 2 or 3, wherein the width of the fourth gap is wider than the width of the second gap. 如請求項2或3所記載之成膜裝置,其中前述冷卻台的前述支持面為矩形; 前述氣體噴射機構係獨立地控制在與前述支持面的角部對向之前述第三間隙流動之前述惰性氣體的流量、以及在與前述角部以外的前述支持面的邊部對向之前述第三間隙流動之前述惰性氣體的流量。The film forming device as described in claim 2 or 3, wherein the supporting surface of the cooling table is rectangular; The gas injection mechanism independently controls the flow rate of the inert gas flowing in the third gap facing the corner portion of the support surface, and the first step facing the edge portion of the support surface other than the corner portion. The flow rate of the aforementioned inert gas flowing in three gaps. 如請求項4所記載之成膜裝置,其中前述冷卻台的前述支持面為矩形; 前述氣體噴射機構係獨立地控制在與前述支持面的角部對向之前述第三間隙流動之前述惰性氣體的流量、以及在與前述角部以外的前述支持面的邊部對向之前述第三間隙流動之前述惰性氣體的流量。The film forming apparatus described in claim 4, wherein the supporting surface of the cooling table is rectangular; The gas injection mechanism independently controls the flow rate of the inert gas flowing in the third gap facing the corner portion of the support surface, and the first step facing the edge portion of the support surface other than the corner portion. The flow rate of the aforementioned inert gas flowing in three gaps. 一種成膜方法,係具備以下步驟: 在具有將基板予以支持之支持面以及與前述支持面相連之側面部之冷卻台的前述支持面,以前述基板的外周端從前述側面部突出的方式支持前述基板; 包圍前述冷卻台的前述側面部之環狀的防著框部係在與前述基板的前述外周端對向之位置處設置有凹部,且將前述側面部由前述凹部所包圍之前述防著框部配置於前述冷卻台的周圍; 朝前述基板供給包含能量線硬化樹脂之原料氣體; 朝前述基板照射使前述能量線硬化樹脂硬化之能量線,藉此於前述基板上形成樹脂層。A film forming method has the following steps: On the supporting surface of the cooling table having a supporting surface for supporting the substrate and a side surface connected to the supporting surface, the substrate is supported in such a manner that the outer peripheral end of the substrate protrudes from the side surface; The ring-shaped anti-blocking frame portion surrounding the side surface of the cooling stage is provided with a recessed portion at a position opposite to the outer peripheral end of the substrate, and the anti-blocking frame portion that surrounds the side surface portion by the recessed portion Arranged around the aforementioned cooling table; Supply raw material gas containing energy ray hardening resin to the aforementioned substrate; The substrate is irradiated with energy rays that harden the energy ray hardening resin, thereby forming a resin layer on the substrate.
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