TW201229084A - Epoxy resin composition for fiber reinforced composite material prepreg, and fiber reinforced composite material - Google Patents
Epoxy resin composition for fiber reinforced composite material prepreg, and fiber reinforced composite material Download PDFInfo
- Publication number
- TW201229084A TW201229084A TW100140457A TW100140457A TW201229084A TW 201229084 A TW201229084 A TW 201229084A TW 100140457 A TW100140457 A TW 100140457A TW 100140457 A TW100140457 A TW 100140457A TW 201229084 A TW201229084 A TW 201229084A
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- Prior art keywords
- epoxy resin
- prepreg
- resin composition
- weight
- fiber
- Prior art date
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- 239000003822 epoxy resin Substances 0.000 title claims abstract description 153
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 153
- 239000000203 mixture Substances 0.000 title claims abstract description 107
- 239000000463 material Substances 0.000 title claims description 82
- 239000003733 fiber-reinforced composite Substances 0.000 title claims description 69
- -1 Urea compound Chemical class 0.000 claims abstract description 22
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims abstract description 14
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004202 carbamide Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims description 101
- 239000011347 resin Substances 0.000 claims description 101
- 239000000835 fiber Substances 0.000 claims description 31
- 239000012783 reinforcing fiber Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000004593 Epoxy Substances 0.000 claims description 18
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 230000009477 glass transition Effects 0.000 claims description 13
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- 239000000126 substance Substances 0.000 claims description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000007872 degassing Methods 0.000 claims description 4
- 238000005452 bending Methods 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- LNOLJFCCYQZFBQ-BUHFOSPRSA-N (ne)-n-[(4-nitrophenyl)-phenylmethylidene]hydroxylamine Chemical compound C=1C=C([N+]([O-])=O)C=CC=1C(=N/O)/C1=CC=CC=C1 LNOLJFCCYQZFBQ-BUHFOSPRSA-N 0.000 claims description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 claims description 2
- 229930185605 Bisphenol Natural products 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
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- 244000166124 Eucalyptus globulus Species 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- 230000035699 permeability Effects 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 150000001412 amines Chemical class 0.000 abstract description 5
- 239000011159 matrix material Substances 0.000 description 38
- 229920003319 Araldite® Polymers 0.000 description 24
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- 239000004917 carbon fiber Substances 0.000 description 18
- 239000011148 porous material Substances 0.000 description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 16
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- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- XGEGHDBEHXKFPX-UHFFFAOYSA-N N-methyl urea Chemical compound CNC(N)=O XGEGHDBEHXKFPX-UHFFFAOYSA-N 0.000 description 2
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- 229910052797 bismuth Inorganic materials 0.000 description 2
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- 238000006243 chemical reaction Methods 0.000 description 2
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
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- 230000002708 enhancing effect Effects 0.000 description 2
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- 238000012360 testing method Methods 0.000 description 2
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- LARNQUAWIRVQPK-UHFFFAOYSA-N 2-methyloxiran-2-amine Chemical compound NC1(CO1)C LARNQUAWIRVQPK-UHFFFAOYSA-N 0.000 description 1
- 240000001606 Adenanthera pavonina Species 0.000 description 1
- 235000011470 Adenanthera pavonina Nutrition 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
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- 101710178035 Chorismate synthase 2 Proteins 0.000 description 1
- 101710152694 Cysteine synthase 2 Proteins 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
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- 235000012633 Iberis amara Nutrition 0.000 description 1
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- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical group [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
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- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
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- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
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- JAYXSROKFZAHRQ-UHFFFAOYSA-N n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC=CC=1)CC1CO1 JAYXSROKFZAHRQ-UHFFFAOYSA-N 0.000 description 1
- AHNZVFVNAQKFBB-UHFFFAOYSA-N n-amino-n-(n-aminoanilino)aniline Chemical compound C=1C=CC=CC=1N(N)N(N)C1=CC=CC=C1 AHNZVFVNAQKFBB-UHFFFAOYSA-N 0.000 description 1
- CDZOGLJOFWFVOZ-UHFFFAOYSA-N n-propylaniline Chemical compound CCCNC1=CC=CC=C1 CDZOGLJOFWFVOZ-UHFFFAOYSA-N 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/04—Epoxynovolacs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0007—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
- B32B37/003—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid air inclusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/28—Di-epoxy compounds containing acyclic nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3227—Compounds containing acyclic nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/504—Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/21—Urea; Derivatives thereof, e.g. biuret
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
- C08K5/3155—Dicyandiamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Quality & Reliability (AREA)
- Reinforced Plastic Materials (AREA)
- Epoxy Resins (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41123110P | 2010-11-08 | 2010-11-08 | |
| US201161530173P | 2011-09-01 | 2011-09-01 |
Publications (1)
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| TW201229084A true TW201229084A (en) | 2012-07-16 |
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| TW100140457A TW201229084A (en) | 2010-11-08 | 2011-11-07 | Epoxy resin composition for fiber reinforced composite material prepreg, and fiber reinforced composite material |
Country Status (10)
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| US (1) | US9957387B2 (enExample) |
| EP (1) | EP2637860B1 (enExample) |
| JP (1) | JP6007914B2 (enExample) |
| KR (1) | KR101825247B1 (enExample) |
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| CA (1) | CA2810709A1 (enExample) |
| RU (1) | RU2013126414A (enExample) |
| TW (1) | TW201229084A (enExample) |
| WO (1) | WO2012064662A1 (enExample) |
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| WO2013164686A1 (en) * | 2012-05-02 | 2013-11-07 | Nexans | A light weight cable |
| US9574081B2 (en) * | 2012-08-20 | 2017-02-21 | Mitsubishi Rayon Co., Ltd. | Epoxy-resin composition, and film, prepreg and fiber-reinforced plastic using the same |
| GB201217210D0 (en) * | 2012-09-26 | 2012-11-07 | Blade Dynamics Ltd | A metod of forming a structural connection between a spar cap fairing for a wind turbine blade |
| TWI621639B (zh) * | 2013-01-07 | 2018-04-21 | 東麗股份有限公司 | 環氧樹脂組成物及預浸漬物 |
| CN104119639B (zh) * | 2013-04-24 | 2016-08-03 | 台光电子材料(昆山)有限公司 | 无卤素树脂组合物及应用其的铜箔基板及印刷电路板 |
| WO2014195799A2 (en) * | 2013-06-07 | 2014-12-11 | Toray Industries, Inc. | Fiber reinforced polymer composition enabling rapid-cycle void-free composite manufacturing |
| US9309353B2 (en) * | 2013-08-09 | 2016-04-12 | The Boeing Company | Formulation methodology for distortional thermosets |
| GB201411586D0 (en) * | 2014-06-30 | 2014-08-13 | Hexcel Composites Ltd | Adhesive composition |
| EP3002304B1 (en) | 2014-10-03 | 2017-08-02 | Tokyo Ohka Kogyo Co., Ltd. | Curable composition |
| CN104388028A (zh) * | 2014-12-01 | 2015-03-04 | 南京大学 | 一种韧性耐高温环氧树脂粘合剂 |
| JP6511071B2 (ja) | 2014-12-09 | 2019-05-15 | 東京応化工業株式会社 | 硬化性組成物 |
| KR20170124545A (ko) * | 2015-02-27 | 2017-11-10 | 도레이 카부시키가이샤 | 수지 공급 재료, 프리폼, 및 섬유 강화 수지의 제조 방법 |
| KR101878128B1 (ko) * | 2015-09-17 | 2018-07-12 | 도레이 카부시키가이샤 | 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료 |
| KR20180095502A (ko) | 2015-12-16 | 2018-08-27 | 도레이 카부시키가이샤 | 프리프레그, 적층체, 섬유 강화 복합 재료, 및 섬유 강화 복합 재료의 제조 방법 |
| WO2017163129A1 (en) * | 2016-03-24 | 2017-09-28 | Toray Industries, Inc. | Epoxy resin composition, prepreg, and fiber reinforced plastic material |
| KR101790112B1 (ko) * | 2016-03-29 | 2017-10-26 | 주식회사 한국카본 | 프레스 공법을 통한 차체부품 고속경화 프리프레그용 수지 조성물 및 이를 포함하는 프리프레그 제품 |
| EP3475348B1 (en) * | 2016-06-27 | 2021-03-24 | Dow Global Technologies LLC | Storage stable epoxy prepregs from dicyandiamide solutions and methods for making the same |
| CN109642019A (zh) * | 2016-08-26 | 2019-04-16 | 东丽株式会社 | 环氧树脂组合物、预浸料坯和纤维增强塑料材料 |
| US20200079917A1 (en) * | 2017-05-10 | 2020-03-12 | Toray Industries, Inc. | Method for producing fiber-reinforced composite material |
| KR102341161B1 (ko) * | 2017-08-10 | 2021-12-20 | 도레이첨단소재 주식회사 | 저밀도 프리프레그 및 이를 포함하는 샌드위치 복합 성형품 |
| RU2655805C1 (ru) * | 2017-08-31 | 2018-05-29 | Акционерное общество "Препрег-Современные Композиционные Материалы" (АО "Препрег-СКМ") | Эпоксидное связующее, препрег на его основе и изделие, выполненное из него |
| US20210371612A1 (en) * | 2018-01-31 | 2021-12-02 | Toray Industries, Inc. | Prepreg sheets and prepreg stacks useful for preparing low void content fiber-reinforced composite materials |
| JP7209470B2 (ja) * | 2018-03-13 | 2023-01-20 | 帝人株式会社 | プリプレグ及び炭素繊維強化複合材料 |
| KR102562027B1 (ko) * | 2018-07-05 | 2023-07-31 | 도레이첨단소재 주식회사 | 섬유강화 복합재료용 에폭시 수지 조성물 및 이를 이용한 프리프레그 |
| JP7206993B2 (ja) * | 2019-02-18 | 2023-01-18 | 三菱ケミカル株式会社 | 炭素繊維強化複合材料用エポキシ樹脂組成物、プリプレグおよび炭素繊維強化複合材料 |
| JP7415926B2 (ja) * | 2019-07-05 | 2024-01-17 | 東レ株式会社 | プリプレグおよび繊維強化複合材料 |
| JP7487865B2 (ja) * | 2020-02-27 | 2024-05-21 | 国立大学法人東海国立大学機構 | ホース、ホースの製造方法、および、油圧式ポンプ |
| CN114230974B (zh) * | 2021-12-14 | 2024-04-02 | 江苏兆鋆新材料股份有限公司 | 一种碳纤维环氧预浸料用增韧环氧树脂及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5230906A (en) * | 1986-11-24 | 1993-07-27 | Polytex Plastic Sa | Method of and apparatus for manufacturing fiber-reinforced plastics articles |
| JPH0362821A (ja) * | 1989-07-31 | 1991-03-18 | Tonen Corp | エポキシ樹脂組成物 |
| EP0825222B1 (en) * | 1996-02-21 | 2005-06-01 | Toray Industries, Inc. | Yarn preprared and fiber-reinforced composite material prepeared therefrom |
| ATE256550T1 (de) | 1998-05-20 | 2004-01-15 | Cytec Tech Corp | Herstellung von blasenfreien laminaten und deren anwendung |
| JP4544656B2 (ja) * | 1998-06-30 | 2010-09-15 | 東レ株式会社 | プリプレグおよび繊維強化複合材料 |
| WO2000053654A1 (fr) * | 1999-03-11 | 2000-09-14 | Toray Industries, Inc. | Composition de resine epoxy, composition de resine epoxy pour materiau composite a fibres, et materiau composite a fibres contenant ladite composition |
| EP1174250B1 (fr) * | 2000-07-17 | 2005-10-19 | Conception et Développement Michelin S.A. | Imprégnation en continu de fibres en grandes longueurs, par de la résine, pour la fabrication d'éléments composites longilignes |
| US20030082385A1 (en) * | 2001-07-13 | 2003-05-01 | Toray Composites (America), Inc. | Quick cure carbon fiber reinforced epoxy resin |
| JP4177041B2 (ja) | 2002-07-18 | 2008-11-05 | 三菱レイヨン株式会社 | 繊維強化複合材料の製造方法 |
| ES2302980T5 (es) * | 2002-11-28 | 2015-12-01 | Mitsubishi Rayon Co., Ltd. | Procedimientos para la producción de material compuesto reforzado con fibras |
| US7208228B2 (en) * | 2003-04-23 | 2007-04-24 | Toray Composites (America), Inc. | Epoxy resin for fiber reinforced composite materials |
| US20050095415A1 (en) * | 2003-10-30 | 2005-05-05 | Raghavendran Venkat K. | Glass mat thermoplastic composite |
| JP2006028274A (ja) * | 2004-07-14 | 2006-02-02 | Tokai Rubber Ind Ltd | エポキシ樹脂組成物およびこれを用いたプリプレグ |
| JP5090701B2 (ja) | 2006-09-30 | 2012-12-05 | 東邦テナックス株式会社 | 部分含浸プリプレグとそれを用いた繊維強化複合材料の製造方法 |
| JP2009292976A (ja) | 2008-06-06 | 2009-12-17 | Mitsubishi Rayon Co Ltd | プレス成形用プリプレグ及び成形品の製造方法 |
| ES2755105T3 (es) * | 2008-07-31 | 2020-04-21 | Toray Industries | Preimpregnado, preforma, producto moldeado y procedimiento de fabricación de un preimpregnado |
| JP5326435B2 (ja) * | 2008-08-29 | 2013-10-30 | 東レ株式会社 | エポキシ樹脂組成物、プリプレグ、および、繊維強化複合材料、ならびに、繊維強化複合材料の製造方法 |
| JP5668329B2 (ja) * | 2009-06-08 | 2015-02-12 | 三菱レイヨン株式会社 | エポキシ樹脂組成物およびそれを用いた繊維強化複合材料 |
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2011
- 2011-11-07 TW TW100140457A patent/TW201229084A/zh unknown
- 2011-11-07 EP EP11839752.0A patent/EP2637860B1/en active Active
- 2011-11-07 RU RU2013126414/05A patent/RU2013126414A/ru not_active Application Discontinuation
- 2011-11-07 JP JP2013537913A patent/JP6007914B2/ja active Active
- 2011-11-07 BR BR112013009345A patent/BR112013009345A2/pt not_active IP Right Cessation
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- 2011-11-07 CA CA 2810709 patent/CA2810709A1/en not_active Abandoned
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- 2011-11-07 US US13/881,790 patent/US9957387B2/en active Active
- 2011-11-07 CN CN201180053710.5A patent/CN103201102B/zh active Active
Also Published As
| Publication number | Publication date |
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| KR20130141491A (ko) | 2013-12-26 |
| JP6007914B2 (ja) | 2016-10-19 |
| BR112013009345A2 (pt) | 2015-04-22 |
| EP2637860A4 (en) | 2014-09-17 |
| CN103201102A (zh) | 2013-07-10 |
| RU2013126414A (ru) | 2014-12-20 |
| US20130217283A1 (en) | 2013-08-22 |
| WO2012064662A1 (en) | 2012-05-18 |
| EP2637860A1 (en) | 2013-09-18 |
| CA2810709A1 (en) | 2012-05-18 |
| CN103201102B (zh) | 2015-07-01 |
| KR101825247B1 (ko) | 2018-02-02 |
| EP2637860B1 (en) | 2017-08-16 |
| JP2013543035A (ja) | 2013-11-28 |
| US9957387B2 (en) | 2018-05-01 |
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