BR112013009345A2 - Composição de resina epóxi, prepreg, material compósito reforçado com fibra e método de fabricação. - Google Patents

Composição de resina epóxi, prepreg, material compósito reforçado com fibra e método de fabricação.

Info

Publication number
BR112013009345A2
BR112013009345A2 BR112013009345A BR112013009345A BR112013009345A2 BR 112013009345 A2 BR112013009345 A2 BR 112013009345A2 BR 112013009345 A BR112013009345 A BR 112013009345A BR 112013009345 A BR112013009345 A BR 112013009345A BR 112013009345 A2 BR112013009345 A2 BR 112013009345A2
Authority
BR
Brazil
Prior art keywords
prepreg
manufacturing
resin composition
epoxy resin
composite material
Prior art date
Application number
BR112013009345A
Other languages
English (en)
Portuguese (pt)
Inventor
Nobuyuki Arai
Jonathan C Hughes
Norimitsu Natsume
Alfred P Haro
Original Assignee
Toray Industries
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries filed Critical Toray Industries
Publication of BR112013009345A2 publication Critical patent/BR112013009345A2/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/28Di-epoxy compounds containing acyclic nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/04Epoxynovolacs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0007Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
    • B32B37/003Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid air inclusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/3227Compounds containing acyclic nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014Nitrogen containing compounds
    • C08G59/4021Ureas; Thioureas; Guanidines; Dicyandiamides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/504Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/21Urea; Derivatives thereof, e.g. biuret
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/315Compounds containing carbon-to-nitrogen triple bonds
    • C08K5/3155Dicyandiamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Quality & Reliability (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
BR112013009345A 2010-11-08 2011-11-07 Composição de resina epóxi, prepreg, material compósito reforçado com fibra e método de fabricação. BR112013009345A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US41123110P 2010-11-08 2010-11-08
US201161530173P 2011-09-01 2011-09-01
PCT/US2011/059610 WO2012064662A1 (en) 2010-11-08 2011-11-07 Epoxy resin composition for fiber reinforced composite material, prepreg, and fiber reinforced composite material

Publications (1)

Publication Number Publication Date
BR112013009345A2 true BR112013009345A2 (pt) 2015-04-22

Family

ID=46051258

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013009345A BR112013009345A2 (pt) 2010-11-08 2011-11-07 Composição de resina epóxi, prepreg, material compósito reforçado com fibra e método de fabricação.

Country Status (10)

Country Link
US (1) US9957387B2 (enExample)
EP (1) EP2637860B1 (enExample)
JP (1) JP6007914B2 (enExample)
KR (1) KR101825247B1 (enExample)
CN (1) CN103201102B (enExample)
BR (1) BR112013009345A2 (enExample)
CA (1) CA2810709A1 (enExample)
RU (1) RU2013126414A (enExample)
TW (1) TW201229084A (enExample)
WO (1) WO2012064662A1 (enExample)

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GB201217210D0 (en) * 2012-09-26 2012-11-07 Blade Dynamics Ltd A metod of forming a structural connection between a spar cap fairing for a wind turbine blade
TWI621639B (zh) 2013-01-07 2018-04-21 東麗股份有限公司 環氧樹脂組成物及預浸漬物
CN104119639B (zh) * 2013-04-24 2016-08-03 台光电子材料(昆山)有限公司 无卤素树脂组合物及应用其的铜箔基板及印刷电路板
WO2014195799A2 (en) * 2013-06-07 2014-12-11 Toray Industries, Inc. Fiber reinforced polymer composition enabling rapid-cycle void-free composite manufacturing
US9309353B2 (en) * 2013-08-09 2016-04-12 The Boeing Company Formulation methodology for distortional thermosets
GB201411586D0 (en) * 2014-06-30 2014-08-13 Hexcel Composites Ltd Adhesive composition
EP3002304B1 (en) 2014-10-03 2017-08-02 Tokyo Ohka Kogyo Co., Ltd. Curable composition
CN104388028A (zh) * 2014-12-01 2015-03-04 南京大学 一种韧性耐高温环氧树脂粘合剂
JP6511071B2 (ja) 2014-12-09 2019-05-15 東京応化工業株式会社 硬化性組成物
KR20170124545A (ko) * 2015-02-27 2017-11-10 도레이 카부시키가이샤 수지 공급 재료, 프리폼, 및 섬유 강화 수지의 제조 방법
EP3333212B1 (en) * 2015-09-17 2019-08-28 Toray Industries, Inc. Epoxy resin composition, prepreg, and fiber-reinforced composite material
KR20180095502A (ko) 2015-12-16 2018-08-27 도레이 카부시키가이샤 프리프레그, 적층체, 섬유 강화 복합 재료, 및 섬유 강화 복합 재료의 제조 방법
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US11168189B2 (en) 2016-06-27 2021-11-09 Dow Global Technologies Llc Storage stable epoxy prepregs from dicyandiamide solutions and methods for making the same
US20190169356A1 (en) * 2016-08-26 2019-06-06 Toray Industries, Inc. Epoxy resin composition, prepreg, and fiber reinforced plastic material
US20200079917A1 (en) * 2017-05-10 2020-03-12 Toray Industries, Inc. Method for producing fiber-reinforced composite material
KR102341161B1 (ko) * 2017-08-10 2021-12-20 도레이첨단소재 주식회사 저밀도 프리프레그 및 이를 포함하는 샌드위치 복합 성형품
RU2655805C1 (ru) * 2017-08-31 2018-05-29 Акционерное общество "Препрег-Современные Композиционные Материалы" (АО "Препрег-СКМ") Эпоксидное связующее, препрег на его основе и изделие, выполненное из него
US20210371612A1 (en) * 2018-01-31 2021-12-02 Toray Industries, Inc. Prepreg sheets and prepreg stacks useful for preparing low void content fiber-reinforced composite materials
JP7209470B2 (ja) * 2018-03-13 2023-01-20 帝人株式会社 プリプレグ及び炭素繊維強化複合材料
KR102562027B1 (ko) * 2018-07-05 2023-07-31 도레이첨단소재 주식회사 섬유강화 복합재료용 에폭시 수지 조성물 및 이를 이용한 프리프레그
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Also Published As

Publication number Publication date
CN103201102B (zh) 2015-07-01
JP6007914B2 (ja) 2016-10-19
EP2637860A1 (en) 2013-09-18
CN103201102A (zh) 2013-07-10
CA2810709A1 (en) 2012-05-18
US9957387B2 (en) 2018-05-01
JP2013543035A (ja) 2013-11-28
EP2637860B1 (en) 2017-08-16
KR101825247B1 (ko) 2018-02-02
EP2637860A4 (en) 2014-09-17
TW201229084A (en) 2012-07-16
US20130217283A1 (en) 2013-08-22
RU2013126414A (ru) 2014-12-20
KR20130141491A (ko) 2013-12-26
WO2012064662A1 (en) 2012-05-18

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