TW201124084A - Noxious organism controlling composition and method for controlling the noxious organism - Google Patents
Noxious organism controlling composition and method for controlling the noxious organism Download PDFInfo
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- A—HUMAN NECESSITIES
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- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
Abstract
Description
201124084 六、發明說明： 【發明所屬之技術領域】 本發明係關於有效地同時防除各種害蟲與 害之有害生物防除組成物。 【先前技術】 硫代仲丁基氧-乙基 2 -羰基· 1 , 3 -噻唑啶 酸酯係專利文獻1所揭示之化合物。氧-乙基-硫 2-氰亞胺基-3-甲基-咪唑啶-1-基）硫磷酸酯{ 所揭示之化合物。S , S -二仲丁基氧-乙基二 專利文獻3所揭示之化合物。此等係作爲殺蟲 線蟲劑有效成份之已知有機磷系化合物。然而 特定的有機磷系化合物與特定的殺菌劑時，關 於土壤及/或種子中的害蟲，及土壤及/或種子 病害雙方，發揮相乘的效果。 專利文獻1 :美國專利第4590182號 專利文獻2:美國專利第5405961號 專利文獻3 :美國專利第4 5 3 5 0 7 7號 【發明內容】 發明所欲解決的課題 要求可防除線蟲類、根蟎等之棲息於土 i 中的害蟲，及土壤及/或種子傳染性植物病害 比單獨個別防除，更相乘地強化防除雙方效果 各種植物病 -3-基硫代膦 :代正丙基（ 系專利文獻2 硫代磷酸係 、殺蟎、殺 並未知組合 於防除棲息 傳染性植物 s及/或種子 雙方，而且 之有害生物 -5- 201124084 防除劑。 課題之解決手段 本發明者等爲解決此等課題而努力檢討的結果，由組 合特定的有機磷系化合物與特定的殺菌劑時，發現可得到 預期以上的效果，而完成本發明。 本發明係由下述要點而成者。 1、 以含有至少1種選自硫代仲丁基氧-乙基 2-羰基_ 1,3-噻唑啶-3-基硫代膦酸酯、氧-乙基-硫代正丙基（2-氰 亞胺基-3-甲基-咪唑啶-1-基）硫磷酸酯及S,S-二仲丁基 氧-乙基二硫代磷酸所成群之有機磷系化合物，以及至少 1種選自扶吉胺（Fluazinam)、免賴得（Benomyl)、甲 基立枯磷（Tolclofos-methyl )、滅達樂（Metalaxyl ) ' 蓋普丹（Captan )、依普同（Iprodione )、四氣異苯（ Chlorothalonil )、邁隆（Dazomet )、殺紋寧（ Hymexazole )、福多寧（Flutolanil )及維利黴素（ Validamycin)所成群之殺菌劑爲有效成份爲特徵之有害生 物防除組成物》 2、 上述1記載之有害生物防除組成物中，上述有機磷 系化合物與上述殺菌劑之含有比率係重量比爲1 : 1 0000至 10000 ：卜 3、 以含有至少1種選自硫代仲丁基氧-乙基 2_羰基-1，3 -噻唑啶-3 -基硫代膦酸酯、氧-乙基·硫代正丙基（2 -氰 亞胺基-3-甲基-咪唑啶-1-基）硫磷酸酯及S，S-二仲丁基 -6 - 201124084 氧-乙基二硫代磷酸所成群之有機磷系化合物，以及至少 1種選自扶吉胺（Fluazinam)、免賴得（Benomyl)、甲 基立枯磷（Tolclofos-methyl) '滅達樂（Metalaxyi)、 蓋普丹（Captan)、依普同（Iprodione)、四氯異苯（ Chlorothalonil )、邁隆（Dazomet )、殺紋寧（ Hymexazole )、福多寧（Flutolanil)及維利黴素（ Validamycin )所成群之殺菌劑爲有效成份而作用於有害生 物爲特徵之有害生物之防除方法。 4、 上述3記載之有害生物之防除方法，其中使上述有 機磷系化合物與上述殺菌劑同時作用，或使上述有機磷系 化合物與上述殺菌劑中之某一種作用，接著再使另一種作 用。 5、 上述3或4記載之有害生物之防除方法中，使上述 有機磷系化合物與上述殺菌劑之比率係重量比成1 : 1 0000 至1 0000 : 1而作用。 6、 上述3至5中任一項記載之有害生物之防除方法係 使上述有效成份之濃度成0.1至lOOOOppm而作用。 7、 上述3至6中任一項記載之有害生物之防除方法中 ’有害生物係棲息於土壤及/或種子中的有害生物。 8、 上述3至6中任一項記載之有害生物之防除方法中 ’有害生物係棲息於土壤及/或種子中的害蟲。 9、 上述3至9中任一項記載之有害生物之防除方法中 ’有害生物係植物寄生性線蟲類》 1〇、上述3至6中任一項記載之有害生物之防除方法， 201124084 植物寄生性線蟲類係至少1種選自根瘤線蟲類、黃金線蟲 類、根腐線蟲類、稻心枯線蟲、莓芽線蟲（ Nothotylenchus acris，Strawberry bud nematodes )及松材 線蟲(Pine wood nemotode )。 11、上述3至10中任一項記載之有害生物之防除方法 中，處理上述有機磷系化合物與上述殺菌劑於土壤及/或 種子。 發明之功效 、 依據本發明，提供同時提高防除棲息於土壤及/或種 子中的害蟲之效果，及防除土壤及/或種子傳染性病害之 效果之嶄新的有害生物防除組成物及防除方法。 用以實施發明之最佳型態 對於硫代仲丁基氧-乙基 2-羰基-1，3-噻唑啶-3-基硫 代膦酸酯，存在光學異構物，除了消旋體以外，包含（· )體及（+)體。消旋體之（R，S)·硫代仲丁基氧-乙基 2-羰基-1，3-噻唑啶-3-基硫代膦酸酯係已知一般名爲福賽絕 (Fosthiazate)之化合物。 氧-乙基-硫代正丙基（2-氰亞胺基-3-甲基-咪唑啶-1-基）硫磷酸酯亦存在光學異構物，除了消旋體以外，包含 (-)體及（+)體。 S，S-二仲丁基氧-乙基二硫代磷酸酯係已知一般名 爲克線丹（cadusafos)之化合物。 201124084 扶吉胺（Fluazinam )、免賴得（Benomyl )、甲基立 枯磷（Tolclofos-methyl )、滅達樂（Meta 1 axy丨）、芸普 丹（Captan )、依普同（Ipro di οne )、四氯異苯（ Chlorothalonil )、邁隆（Dazomet )、殺紋寧（ Hymexazole )、福多寧（F 1 utο 1 ani 1 )、維利徽素（ Validamycin)之任一種皆爲殺蟲劑，記載於The pesticide Manual (第 13 版；BRITISH CROP PROTECTION COUNCIL )之化合物。 上述有機磷系化合物及殺菌劑之混合比率，通常重量 比爲 1: 10000 至 10000: 1，以 1: 1000 至 1000: i 爲宜。 本發明組成物係含有效成份以外之補助劑。有效成份 之配合比率係0 · 0 5至7 5重量％即可。作爲補助劑，可舉例 如載體、乳化劑、懸濁劑、分散劑 '展開劑、滲透劑、濕 潤劑、增黏劑、安定劑等，因應需要而可適當地添加。作 爲載體，可分爲固體載體及液體載體，作爲固體載體，可 舉例如澱粉、活性碳、大豆粉、小麥粉、木粉、魚粉及乳 粉等之動植物粉末、滑石、陶土、膨潤土、碳酸鈣、沸石 、矽藻土、碳白、黏土、氧化鋁及硫黃粉末等之礦物性粉 末等，作爲液體載體，可舉例如水、甲醇及乙醇等之醇類 、丙酮、甲基乙基甲酮等之酮類、二nf烷及四氫呋喃等之 醚類、煤油及燈油等之脂肪族烴類、及二甲苯、三甲苯、 四甲苯、環己烷及溶劑石腦油等之芳香族烴類、氯仿、氯 苯等之鹵素化烴類、二甲基甲醯胺等之酸醯胺類、乙酸乙 酯、脂肪酸之甘油酯等之酯類、乙腈等之腈類、二甲亞硕 -9- 201124084 等之含硫化合物類。可使用各種界面活性劑爲乳化劑、懸 濁劑、分散劑、展開劑、滲透劑及濕潤劑等。另外，因應 需要，可混用、倂用其他農藥，例如殺蟲劑、殺蟎劑、殺 線蟲劑、殺菌劑、抗病毒劑、引誘劑、除草劑及植物成長 調整劑等，此時亦顯示更優異的效果。 本發明組成物係可製劑成乳劑、粉劑、微粒劑、粒劑 、錠劑、水合劑、液劑、氣溶膠劑、糊劑、懸浮劑、乾懸 浮劑及微膠囊劑等之各種型態。其中係以乳劑、微粒劑' 水合劑、液劑粉劑、粒劑及錠劑等之型態爲宜，以乳劑、 微粒劑、水合劑及液劑等之型態最佳。乳劑中之適合配合 比率係有效成份爲5至75重量份，載體爲90至10重量份及 界面活性劑爲5至15重量份。另外，粉劑、粒劑及錠劑中 之適合配合比率係有效成份爲0.1至10重量份，載體爲85 至99重量份及界面活性劑爲0.5至5重量份。實際上使用此 等製劑時，可直接使用，或以水等之稀釋劑稀釋成所定濃 度而使用。 實施本發明組成物之有效濃度一般係以0.1至 lOOOOppm爲宜，以1至lOOOppm尤佳。此等有效成份濃度 係依製劑的型態及使用方法、目的、時期、場所及害蟲的 發生狀況等而可適當地改變，每單位面積的使用量係每 l〇a，使用有效成份化合物約爲1至5000g，以10至1 000g爲 宜。然而，特別情況下，亦可超出此等範圍。作爲本發明 組成物之使用方法，可舉例如土壤混合處理、植穴處理、 植溝處理或灌注處理，或對種子等之浸漬處理、粉衣處理 -10- 201124084 等。 本發明中，處理本發明組成物於有害生物之方法外， 包含同時處理上述有機磷系化合物及殺菌劑於有害生物之 方法、處理有機磷系化合物及殺菌劑中之某一種於有害生 物後，再處理另一種藥劑於有害生物之方法。 作爲可適用本發明之有害生物，可舉例如植物寄生性 線蟲類、等足類'鞘翅目害蟲、鱗翅目害蟲、腹足類、直 翅目害蟲、植物寄生性蟎類、薊馬目害蟲、雙翅目害蟲、 膜翅目害蟲、隱翅目害蟲、虱目害蟲及等翅目害蟲等之各 種害蟲或各種植物病害。尤其本發明係對於防除棲息於土 壤及/或種子中之有害生物有效。作爲棲息於土壤及/或種 子中之害蟲，可舉例如於土壤中加害農園藝作物及樹木等 之害蟲或加害農園藝作物或樹木的種子之害蟲等。可舉例 如上述之植物寄生性線蟲類、等足類、鞘翅目害蟲、鱗翅 目害蟲、腹足類、直翅目害蟲及植物寄生性蟎類等。其中 ’本發明係對於防除植物寄生性線蟲類最有效。 本發明可適用之各種害蟲之具體例如下所示。 作爲植物寄生性線蟲類，可舉例如蕃薯根瘤線蟲（ Meloidogyne inc〇gnita)等之根瘤線蟲類；馬鈴薯黃金線 蟲（Globoderarostochiensis)等之黃金線蟲類；北方根腐 線蟲（P r a t y 1 e n c h u s p e n e t r a n s )等之根腐線蟲類；稻心枯 線蟲；每芽線蟲（Nothotylenchus acris，Strawberry bud nematodes)及松材線蟲（Pine wood nemotode)等。另外 ’等足類係可舉例如土鱉、草鞋蟲等。 -11 - 201124084 作爲鞘翅目害蟲，可舉例如西方玉米根蟲、南方玉米 根蟲等之玉米根蟲類：金銅金龜、姬金龜等之金龜子類； 玉米象鼻蟲（maize weevil )、水稻水象鼻蟲、苜蓿葉象 鼻蟲、綠豆象鼻蟲等之象鼻蟲類；黃粉蟲、擬穀盜等之黑 粉蟲類、黃守瓜、黃條葉蚤、馬鈴薯甲蟲（Leptinotarsa decemlineata)等之金花蟲類：竊蠢類；茄二十八星瓢蟲 等之瓢蟲類；褐粉蠢類；大谷蠢類；長蠢類；褐毒隱翅蟲 等》 作爲鱗翅目害蟲，可舉例如斜紋夜蛾、黏蟲、大螟、 甜菜夜蛾、甘藍夜蛾等之夜蛾類；切根蟲、蕪菁夜蛾、擬 尺蠖屬、菸芽夜蛾屬及番茄夜蛾屬等之夜蛾類；二化螟蟲 、水稻縱捲葉蟲、歐洲玉米螺、Parapediasia teterrella、 Notarcha derogata、Plodia interpunctella等之螟蛾類；紋 白蝶等之粉蝶類；茶姬捲葉蛾屬、桃折心蟲及蘋果蛾等 之捲葉蛾類；桃蛀果蛾等之蛀果蛾類；桃葉潛蛾屬等之潛 蛾類；舞毒蛾屬、黃毒蛾屬等之毒蛾類；小菜蛾等之巢蛾 類。 作爲腹足類，可舉例如蝸牛、蛞蝓等。 作爲直翅目害蟲，可舉例如螻蛄、蚱蜢、德國姬蠊、 黑褐家蠊、美洲蜚蠊、棕色蜚蠊及東方蜚蠊等。 作爲植物寄生性蟎類，可舉例如二點葉蟎、赤葉瞞' 柑桔葉蟎及根蟎等。 作爲薊馬目害蟲，可舉例如南黃薊馬、蔥薊馬、花薊 馬等。 -12- 201124084 作爲雙翅目害蟲，可舉例如淡色庫蚊、三帶喙庫蚊等 之庫蚊類、搖蚊類、家蠅、大家蠅等之家蠅類、麗蠅類、 肉蠅類、夏廁蠅類、種蠅類及洋蔥種蠅等之花蠅類、果實 蠅類、果蠅類、蛾蚋類、蚋類、虻類、螫蠅類 '潛蠅類等 0 作爲膜翅目害蟲，可舉例如犠類、胡蜂類、蟻形蜂類 、黃翅菜葉蜂等之蜂類等。 作爲隱翅目害蟲，可舉例如人蚤等。 作爲虱目害蟲，可舉例如人虱及恥陰蝨等。 作爲等翅目害蟲，可舉例如黃胸散白犠、家白蟻等。 作爲本發明可適用之各種植物病害，可舉例如土壤及 /或種子傳染性之植物病害。具體上如下所述者。 由Rosellinia菌所引起之各種病害，例如草地之葉腐 病（Rhizoctonia solani);萵苣之据枯病（Rhizoctonia solani );鬱金香之葉腐病（Rhizoctonia solani );甜菜 、蕃前、前子、小黃瓜、青椒、鴨兒芽、蔷麥、飛燕草' 秋葵之苗立枯病（Rhizoctonia solani );鴨兒芹、高麗菜 之立枯病（Rhizoctonia solani) •，紅蘿蔔之根腐病（ Rhizoctonia solani);薛草之腰折病（Rhizoctonia solani );菠菜、高麗菜之株腐病（Rhizoctonia solani);牛蒡 之黑斑病（Rhizoctonia solani);蘿蔔之龜裂褐變症（根 腐病）（Rhizoctonia solani);201124084 VI. Description of the Invention: [Technical Field to Be Invented by the Invention] The present invention relates to a pest control composition which effectively simultaneously prevents various pests and pests. [Prior Art] Thio-sec-butyloxy-ethyl 2 -carbonyl· 1 , 3 -thiazolidinate is a compound disclosed in Patent Document 1. Oxy-ethyl-sulfury 2-cyanoimido-3-methyl-imidazolidine-1-yl)thiophosphate {The disclosed compound. S, S-di-sec-butyloxy-ethyl 2 The compound disclosed in Patent Document 3. These are known organophosphorus compounds which are active ingredients of insecticidal nematodes. However, when a specific organophosphorus compound and a specific bactericide are used, the effects of the multiplication of the pests in the soil and/or the seed, and the soil and/or the seed disease are exerted. Patent Document 1: U.S. Patent No. 4,590, 182, Patent Document 2: U.S. Patent No. 5,405, 591, Patent Document 3: U.S. Patent No. 4, 5,037, the disclosure of which is hereby incorporated by reference. Pests such as cockroaches infested in soil i, and soil and/or seed-infected plant diseases are more individually controlled than individual ones, and are more effective in controlling the effects of both sides of various plant diseases -3-yl thiophosphine: n-propyl ( Patent Document 2 thiophosphoric acid, killing, killing and unknown combination in the control of both invasive plants and/or seeds, and the harmful organisms-5-201124084 control agent. The solution of the problem is solved by the inventors As a result of the evaluation of the above-mentioned problems, it has been found that the above-described effects can be obtained by combining a specific organophosphorus compound with a specific bactericidal agent. The present invention has been made up of the following points. Containing at least one selected from the group consisting of thio-sec-butyloxy-ethyl 2-carbonyl-1,3-1,3-thiazolidin-3-ylthiophosphonate, oxy-ethyl-thio-n-propyl (2-cyanide) Imino-3-methyl-imidazolidin-1-yl) Phosphate esters and organophosphorus compounds in groups of S,S-di-sec-butyloxy-ethyl dithiophosphoric acid, and at least one selected from the group consisting of Fluazinam, Benomyl, and methyl Tolclofos-methyl, Metalaxyl 'Captan', Iprodione, Chlorothalonil, Dazomet, Hymexazole The bactericidal agent grouped by Flutolanil and Validamycin is a pest control composition characterized by an active ingredient. 2. The above-mentioned organophosphorus system is included in the pest control composition described in the above 1. The content ratio of the compound to the above bactericide is 1:1 to 10000: 3, and contains at least one selected from the group consisting of thio-sec-butyloxy-ethyl 2 carbonyl-1,3-thiazole pyridine-3 -ylthiophosphonate, oxy-ethyl thio-n-propyl (2-cyanoimido-3-methyl-imidazolidine-1-yl)thiophosphate and S,S-di-sec-butyl -6 - 201124084 Organophosphorus compounds in groups of oxy-ethyl dithiophosphoric acid, and at least one selected from the group consisting of Fuzinam (Benomyl), Tolclofos-methyl 'Metalaxyi, Captan, Iprodione, Chlorothalonil, Dazomet, A bactericide in which a group of Hymexazole, Flutolanil, and Validamycin are active ingredients acts as a pest control agent for harmful organisms. 4. The method for controlling a pest according to the above 3, wherein the organic phosphorus compound is allowed to act simultaneously with the sterilizing agent, or the organic phosphorus compound and the sterilizing agent are acted upon, and then another effect is applied. 5. The method for controlling pests according to the above 3 or 4, wherein the ratio of the ratio of the organophosphorus compound to the bactericide is from 1:10000 to 10,000:1. 6. The method for controlling a pest according to any one of the above 3 to 5, wherein the concentration of the active ingredient is from 0.1 to 1000 ppm. 7. The pest control method according to any one of the above 3 to 6, wherein the harmful organism is a pest inhabiting the soil and/or the seed. 8. The pest control method according to any one of the above 3 to 6, wherein the pest is a pest inhabiting the soil and/or the seed. 9. In the method for controlling a pest according to any one of the above 3 to 9, the "harmful plant parasitic nematode", the pest control method according to any one of the above 3 to 6, 201124084 At least one species of the nematode is selected from the group consisting of nodule nematodes, golden nematodes, root rot nematodes, Neisseria candida, Strawberry bud nematodes, and Pine wood nemotode. The method for controlling a pest according to any one of the items 3 to 10, wherein the organophosphorus compound and the bactericide are treated in soil and/or seed. EFFECT OF THE INVENTION According to the present invention, there is provided a novel pest control composition and a control method for simultaneously improving the effects of controlling pests inhabiting soils and/or seeds, and controlling the effects of soil and/or seed infectious diseases. BEST MODE FOR CARRYING OUT THE INVENTION For thio-sec-butyloxy-ethyl 2-carbonyl-1,3-thiazolidin-3-ylthiophosphonate, optical isomers exist, except for racemates. Contains (·) and (+) bodies. The (R,S)·thio sec-butyloxy-ethyl 2-carbonyl-1,3-thiazolidin-3-yl thiophosphonate of the racemate is known generally as Fosthiazate. Compound. Oxy-ethyl-thio-n-propyl (2-cyanoimido-3-methyl-imidazolidine-1-yl)thiophosphate is also present as an optical isomer, including (-) in addition to the racemate Body and (+) body. S,S-di-sec-butyloxy-ethyl dithiophosphate is a compound known generally as cadusafos. 201124084 Fluazinam, Benomyl, Tolclofos-methyl, Meta 1 axy丨, Captan, Ipro di οne ), Chlorothalonil, Dazomet, Hymexazole, F 1 utο 1 ani 1 , Validamycin are all pesticides , a compound described in The pesticide Manual (13th edition; BRITISH CROP PROTECTION COUNCIL). The mixing ratio of the above organophosphorus compound and the bactericide is usually 1: 10,000 to 10,000: 1, and preferably 1: 1000 to 1000: i. The composition of the present invention contains a supplement other than the active ingredient. The compounding ratio of the active ingredients is from 0. 5 to 75% by weight. The auxiliary agent may, for example, be a carrier, an emulsifier, a suspending agent, a dispersing agent, a developing agent, a penetrating agent, a wetting agent, a tackifier or a stabilizer, and may be appropriately added as needed. The carrier can be classified into a solid carrier and a liquid carrier, and examples of the solid carrier include animal and plant powders such as starch, activated carbon, soybean powder, wheat flour, wood flour, fish meal, and milk powder, talc, clay, bentonite, and calcium carbonate. And mineral powders such as zeolite, diatomaceous earth, carbon white, clay, alumina, and sulfur powder, and examples of the liquid carrier include alcohols such as water, methanol, and ethanol, acetone, methyl ethyl ketone, and the like. Ethers such as ketones, di ntan and tetrahydrofuran, aliphatic hydrocarbons such as kerosene and kerosene, and aromatic hydrocarbons such as xylene, trimethylbenzene, tetramethylbenzene, cyclohexane and solvent naphtha, and chloroform Halogenated hydrocarbons such as chlorobenzene, acid amides such as dimethylformamide, esters such as ethyl acetate and glycerides of fatty acids, nitriles such as acetonitrile, and dimethyl sulphide-9- 201124084 Such as sulfur compounds. Various surfactants can be used as emulsifiers, suspending agents, dispersing agents, developing agents, penetrating agents, and wetting agents. In addition, other pesticides such as insecticides, acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides and plant growth regulators can be mixed and used as needed. Excellent results. The composition of the present invention can be formulated into various types such as emulsions, powders, granules, granules, troches, hydrating agents, liquids, aerosols, pastes, suspensions, dry suspensions, and microcapsules. Among them, emulsions, microgranules, hydrating agents, liquid powders, granules, and lozenges are preferred, and emulsions, microgranules, hydrating agents, and liquids are preferred. A suitable compounding ratio in the emulsion is 5 to 75 parts by weight, the carrier is 90 to 10 parts by weight, and the surfactant is 5 to 15 parts by weight. Further, a suitable compounding ratio of the powder, the granules and the tablet is from 0.1 to 10 parts by weight, the carrier is from 85 to 99 parts by weight, and the surfactant is from 0.5 to 5 parts by weight. In practice, when such a preparation is used, it can be used as it is, or diluted with a diluent such as water to a predetermined concentration. The effective concentration of the composition of the present invention is generally from 0.1 to 1000 ppm, more preferably from 1 to 1000 ppm. The concentration of these active ingredients may be appropriately changed depending on the type of the preparation, the method of use, the purpose, the period, the place, and the occurrence state of the pest, etc., and the amount of use per unit area is about 1 〇a, and the active ingredient compound is used. From 1 to 5000 g, preferably from 10 to 1,000 g. However, in special cases, these ranges may also be exceeded. The method of using the composition of the present invention may, for example, be a soil mixing treatment, a planting treatment, a gutter treatment or a perfusion treatment, or an immersion treatment for seeds or the like, and a powder coating treatment -10-201124084. In the present invention, in addition to the method for treating the composition of the present invention to a pest, a method of simultaneously treating the organophosphorus compound and the bactericide to a pest, and treating one of the organophosphorus compound and the bactericide to the pest, Another method of treating another agent in a pest. Examples of the pest to which the present invention is applicable include plant parasitic nematodes, isopods, 'coleoptera pests, lepidopteran pests, gastropods, orthoptera pests, plant parasitic mites, damselfish pests, and double wings. Various pests or various plant diseases such as target pests, Hymenoptera pests, Hymenoptera pests, Odonata pests, and Isoptera pests. In particular, the present invention is effective for controlling pests inhabiting soils and/or seeds. Examples of the pests that inhabit the soil and/or the seed include pests such as agricultural horticultural crops and trees, pests such as agricultural horticultural crops or trees, and pests. For example, the above-mentioned plant parasitic nematodes, isopods, coleopteran pests, lepidopteran pests, gastropods, Orthoptera pests, and plant parasitic mites. Wherein the invention is most effective for controlling plant-parasitic nematodes. Specific examples of various pests to which the present invention is applicable are shown below. Examples of plant-parasitic nematodes include nodule nematodes such as Meloidogyne inc〇gnita; golden nematodes such as Globoderarostochiensis; and P raty 1 enchuspenetrans; Root rot nematodes; Neisseria candida; Nothotylenchus acris (Strawberry bud nematodes) and Pine wood nemotode (Pine wood nemotode). Further, the 'equipment type' may be, for example, a bandit, a grass worm, or the like. -11 - 201124084 As a coleopteran pest, for example, corn rootworms such as western corn rootworm and southern corn rootworm: golden chafers such as gold-copper tortoises and ginseng tortoises; maize weevil and rice water elephants Nematodes such as larvae, locust leaf weevil, mung bean weevil, etc.; black powderworms such as yellow mealworms and quarantine worms, yellow stalked melons, yellow stalks, and potato beetles (Leptinotarsa decemlineata) Golden flower worms: thief species; ladybugs such as the 28-star ladybug; brown powder stupid; big valley stupid; long stupid; brown poisoned worm, etc. As a lepidopteran pest, for example Noctuidae such as Spodoptera litura, Zygomycosis, Daphnia, Spodoptera exigua, and Brassica californica; nocturnal moths such as cutworm, budworm, genus, genus, and genus Classes; aphids, rice leafworms, European corn snails, Parapediasia teterrella, Notarcha derogata, Plodia interpunctella, etc.; butterfly species such as white butterfly; genus Corydalis, Peach worm, and apple moth Leaf moth, fruit moth, etc. Classes; the moths of the genus Peach genus; the genus Moths of the genus Gypsy, the genus Xanthophylls, and the genus Moth, such as the diamondback moth. Examples of the gastropods include snails, snails, and the like. Examples of the Orthoptera pests include cockroaches, cockroaches, German cockroaches, black brown cockroaches, American cockroaches, brown cockroaches, and oriental cockroaches. Examples of the plant parasitic mites include, for example, two-spotted spider mites, red stalks, citrus leaf mites, and root mites. Examples of the pests of the common horses include the southern yellow horse, the onion horse, and the flower horse. -12- 201124084 As a dipteran pest, for example, Culex pipiens, Culex pipiens pallens, house mosquitoes, house flies, flies, flies, flies, etc. Flower flies, fruit flies, fruit flies, moths, mites, mites, ticks, larvae, etc., in the summer flies, flies, and onion flies, etc. Examples of the pest include bees such as mites, wasps, ant bees, and yellow-winged bees. Examples of the cryptic wing pests include human mites and the like. Examples of the target insects include human lice and shame. Examples of the isofoptera pest include, for example, yellow-breasted white mites and house termites. As various plant diseases to which the present invention is applicable, for example, soil and/or seed infectious plant diseases can be mentioned. Specifically as described below. Various diseases caused by the Rosalinia bacterium, such as Rhizoctonia solani; Rhizoctonia solani; Rhizoctonia solani; Beet, Pre-former, Pre-branched, Gherkin , green pepper, duck bud, buckwheat, delphinium 'Ohki's seedling blight (Rhizoctonia solani); duck celery, Korean cabbage blight (Rhizoctonia solani) •, carrot root rot (Rizoctonia solani Rhizoctonia solani; spinach, cabbage rotani (Rhizoctonia solani); burdock black spot disease (Rhizoctonia solani); radish crack browning (root rot) (Rhizoctonia) Solani)
Uromyces菌所引起之百合之鱗莖銹症（Uromyces h ο 1 w a y i )； -13- 201124084Liromyces h ο 1 w a y i caused by Uromyces bacteria; -13- 201124084
Pythium菌所引起之各種病害，例如甜菜之苗立枯病 (Pythium debaryanum ):薛草之舞病（Pythium debaryanum);蕃前、小黃瓜、前子、青椒、哈密瓜、甜 瓜、西瓜、白瓜、南瓜之苗立枯病（Pythium vexans ): 草地之紅燒病（Pythium aphanidermatum):爾篛之根腐 病（Pythium aristosporum);薑、茗荷之根莖腐敗病（ Pythium ulitimum) ；Various diseases caused by Pythium bacteria, such as Pythium debaryanum: Pythium debaryanum; pilosula, cucumber, anterior, green pepper, cantaloupe, melon, watermelon, white melon, pumpkin Pythium vexans: Pythium aphanidermatum: Pythium aristosporum; Pythium ulitimum;
Fusarium菌所引起之各種病害，例如鬱金香之球根腐 敗病（Fusarium ox.ysporum);荷藉之乾腐病（Fusarium oxysporum);草莓之萎黃病（Fusarium oxysporum);馬 鈴薯、蕃節之萎调病（Fusarium oxysporum);小黃瓜、 蕃薯之蔓割病（Fusarium oxysporum);巴西利之立枯病 (Fusarium solani);洋憩、辣韭之乾腐病（Fusarium oxysporum ) ；Various diseases caused by Fusarium bacteria, such as tulip root rot (Fusarium ox. ysporum); Fusarium oxysporum; Fusarium oxysporum; potato, wilting disease (Fusarium oxysporum); cucumber, sweet potato vines (Fusarium oxysporum); Basil's disease (Fusarium solani); artichoke, hot rot (Fusarium oxysporum);
Phytophthora菌所引起之各種病害，例如鳳梨之心腐 病（Phytophthora cinnamomi):刺嫩芽之立枯疫病（ Phytophthora cactorum);青椒、巴西利、非洲菊、宿根 滿天星、海芋、非洲堇、薛草之疫病（Phytophthora capsici);草莓之根腐病（Phytophthora fragariae);Various diseases caused by Phytophthora bacteria, such as Phytophthora cinnamomi: Phytophthora cactorum; green pepper, Basili, gerbera, perennial star, sea otter, African cockroach, Phytophthora capsici; Phytophthora fragariae;
Verticillium菌所引起之各種病害，例如白菜之黃化病 (Verticillium dahliae );前子之半身萎调病 （ Verticillium dahliae);Various diseases caused by Verticillium bacteria, such as Verticillium dahliae; Verticillium dahliae;
Thanatephorus菌所引起之甜菜之根腐病 （Root rot of beet caused by Thanatephorus
Thanatephorus cucumeris )； -14- 201124084Thanatephorus cucumeris ); -14- 201124084
Rhizopu菌所引起之百合之莖腐病（Rhizopu necans) »Rhizopu necans caused by Rhizopu bacteria »
Penicillium菌所引起之鬱金香之青黴病（PeniciUium cyclopium ) ；Penicillium caused by penicillium (PeniciUium cyclopium);
Plasmodiophora菌所引起之高麗菜、白菜等之油菜科 蔬菜等之根瘤病（Plasmodiophorabrassicae);Plasmodiophorabrassicae of rapeseed vegetables such as cabbage, cabbage, etc. caused by Plasmodiophora;
Spongospora菌所引起之馬鈴薯之粉狀層化病（ Spongospora subterranea ) ;Spongospora subterranea caused by Spongospora bacteria;
Rosellinia菌所引起之果樹、花木、茶之白紋羽病（ Rosellinia necatrix) ；Rosellinia necatrix caused by rosellinia; fruit trees, flowers, and tea;
Sclerotium菌所引起之菌、韭菜、款冬、淘藉、大豆 、菊、青椒之白絹病（Sclerotiumrolfsii)；Sclerotiumrolfsii caused by bacteria, amaranth, coltsfoot, scouring, soybean, chrysanthemum, and green pepper caused by Sclerotium;
Colletotrichum菌所引起之草莓之炭疽病 （ Colletotrichum acutaum ) ;Colletotrichum acutaum caused by Colletotrichum bacteria;
Polymyxa菌所引起之甜菜之叢根病（Polymyxa betae 媒介）；Polysaccharosis of sugar beet caused by Polymyxa (Polymyxa betae medium);
Botritis菌所引起之蔥之小菌核腐敗病（Botritis squamosa ) ;Botritis squamosa caused by Botritis bacteria;
Helicobasidium菌所引起之果樹、花木、茶之紫紋羽 病(Helicobasidium mompa)；Helicobasidium disease caused by Helicobasidium bacteria (Helicobasidium mompa);
Ceratocystis菌所引起之蕃薯之黑斑病（Ceratocystis imbriata ) ；Ceratocystis imbriata caused by Ceratocystis;
Monosporascus菌所引起之哈密瓜之黑點根腐病（ Monosporascus cannonballus )； -15- 201124084Monosporascus cannonballus caused by Monosporascus; -15- 201124084
Thielaviopsis菌所引起之菸草之黑根病（ Thielaviopsis basicola)；Thielaviopsis basicola caused by Thielaviopsis;
Thantatporus菌所引起之馬鈴薯之黑斑病（ Thantatporus cucumeris ) ；Potato black spot (Thantatporus cucumeris ) caused by Thantatporus ;
Thanatephorus菌所引起之豌豆之莖腐病（ Thanatephorus cucumeris ) ；Thanatephorus cucumeris caused by Thanatephorus bacteria;
Gibberella菌所引起之水稻之徒長病（Gibberella fujikuroi) ；Gibberella fujikuroi caused by Gibberella bacteria;
Sterpomyces菌所引起之馬鈴薯之層化病 （ Sterpomyces scabies);及 Pyricularia菌所引起之水稻之 稻熱病（Pyricularia oryzae);等》 另外，本發明係適用於如例示以外之許多土壤傳染性 或種子傳染性之病害。 本發明組成物及方法係關於防除有害生物，具有協同 的作用。此作用係由各藥劑所具有防除各種病害蟲特性所 無法預測的效果。可說本發明之有效性係比單獨使用各藥 劑，明顯地增強防除有害生物的效果，尤其防除土壤中之 有害生物能力，並且具有賦予即效性的效果。 【實施方式】 實施例 其次係記載本發明之實施例 -16 - 201124084 〔表1〕 一般名或化學名 化合物 No. [I]有機磷系化合物 福賽絕 I-a 氧-乙基-硫代正丙基(2-氰亞胺基-3-甲基-咪唑啶-1-基)硫磷酸酯:美國專利第 I-b 5405961號所記載之化合物 克綠丹 I-c [Π]殺菌劑 扶吉胺 II-a 免懶得 Il-b 甲基立枯磷 II-c 滅達樂 Il-d 蓋普丹 Il-e 依普同 Il-f 四氯異苯 n-g 邁隆 Il-h 殺紋寧 Il-i 福多寧 n-,i 維利黴素 Il-kSterpomyces scabies caused by Sterpomyces bacteria; and rice leaf fever (Pyricularia oryzae) caused by Pyricularia bacteria; etc. In addition, the present invention is applicable to many soil infectious or seed infections as exemplified Sexual disease. The compositions and methods of the present invention have a synergistic effect in controlling pests. This effect is unpredictable by the respective agents to prevent the characteristics of various pests and diseases. It can be said that the effectiveness of the present invention significantly enhances the pest control effect, particularly the pest resistance in the soil, and has the effect of giving immediate effect, compared to the use of each of the medicines alone. [Embodiment] The following is a description of the present invention Example-16 - 201124084 [Table 1] General name or chemical name Compound No. [I] Organophosphorus compound Fozei Ia Oxygen-ethyl-thio-n-propyl (2-Cyminoimido-3-methyl-imidazolidine-1-yl)thiophosphate: a compound described in U.S. Patent No. Ib 5405961, chlorophyll Ic [Π] bactericide, gibberidine II-a Free lazy to Il-b methyl chlorpyrifos II-c halal Il-d cappdan Il-e yipu with Il-f tetrachloroisophthalene ng mailong Il-h killing lining Il-i Fudaning N-,i vilimycin Il-k
S -17- 201124084 試驗例1 調整所定濃度之藥液中，浸漬處理200至25 0隻蕃薯根 瘤線蟲2期幼蟲，於25 °C的恆溫室保存24小時。調查顯微 鏡下’藥液中之蕃薯根瘤線蟲總數（A )及藥液中1 5秒鐘 未活動的個數（B )。另外，調査使用蒸餾水以取代藥液 之對照區’調查總數（A’）及15秒鐘未活動的個數（B，） 。由此等値’依下式求取運動阻礙率。結果如第1表至第 12表所示。 運動阻礙率（％) = [1-{(1-Β/Α)/(Β，/Α，）}]χ1〇〇 另外’由Corby式計算運動阻礙率之理論値（％ )。運 動阻礙率（°/β )若比理論値（％ )高時，本發明之有害生 物防除組成物係具有關於防除線蟲之相乘效果。此時之理 論値（％) —倂表示於第1表至第12表之（）內。 〔表2〕 第1表蕃薯根瘤線蟲運動阻礙率（％) Π [-a] lOppm 5.Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [ΙΙ-e] lOOOppm 100.0 (98.0) 93.6 (92.5) 93.5 (84.3) 56.4 (37.9) 54.8 (37.9) 10.3 Oppm 97.8 91.6 82.5 30.8 30.8 0 -18- 201124084 〔表3〕 第2表蕃薯根瘤線蟲運動阻礙率（％) Γ] [-a] lOppm 5. Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [II-a] 500ppm 100.0 (97.8) 100.0 (91.6) 100.0 (82.5) 100.0 (30_8) 51.7 (30.8) 2.8 Oppm 97.8 91.6 82.5 30.8 30.8 0 〔表4〕 第3表蕃薯根瘤線蟲運動阻礙率（％) π [-a] lOppm 5· Oppm 2_5ppm 1.25ppm 0.63ppm Oppm [II-c] lOOOppm 100.0 (97.9) 100.0 (91.9) 100.0 (83.1) 100.0 (33_2) 77.1 (33.2) 3.4 Oppm 97.8 91.6 82.5 30.8 30.8 0 〔表5〕 第4表蕃薯根瘤線蟲運動阻礙率（％) Π _al lOppm 5. Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [Il-b] 2 5 Oppm 100.0 (92.7) 100.0 (88.5) 89.7 (78.8) 67.1 (52.4) 48.2 (449) 12.1 Oppm 91.7 86.9 75.9 45.8 37.3 0 -19- '*1 201124084 〔表6〕 第5表蕃薯根瘤線蟲運動阻礙率（％) ίΐ-bl lOppm 5. Oppm 2.5ppm Oppm [Π-c] lOOOppm 97.8 94.0 (93.5) 91.4 (70.9) 3.4 Oppm 100.0 93.3 69.9 0 〔表7〕 第6表蕃薯根瘤線蟲運動阻礙率（％) il-bl lOppm 5.Oppm 2.5ppm Oppm [II-c] 500ppm 100.0 (100.0) 100.0 (93.3) 92.1 (69.9) 0 Oppm 100.0 93.3 69.9 0 〔表8〕 第7表蕃薯根瘤線蟲運動阻礙率（％) Π [-bl lOppm 5.Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [Il-b] 250ppm 100.0 (85.5) 94.3 (84.5) 71.1 (49.3) 53.1 (43.4) 37.1 (28.5) 12.1 Oppm 83.5 82.4 42.3 35.6 18.7 0 -20- 201124084 〔表9〕 第8表蕃薯根瘤線蟲運動阻礙率（％) [I-c] lOppm 5.Oppm 2.5ppm 1.25ppm Oppm [II-b] 250ppm 100.0 (96.2) 97.0 (87.4) 70.6 73.5 (48.8) 12.1 Oppm 95.7 85.7 70.3 41.8 0 〔表 10〕 第9表蕃薯根瘤線蟲運動阻礙率（％) fi-cl lOppm 5.Oppm 2.5ppm 1.25ppm Oppm [Π-e] lOOOppm 100.0 (96.2) 90.1 (87.2) 72.9 49.4 (48.0) 10.6 Oppm 95.7 85.7 70.3 41.8 0 〔表 1 1〕 第10表蕃薯根瘤線蟲運動阻礙率（％) ri-ci lOppm 5. Oppm 2.5ppm 1.25ppm Oppm [II-c] lOOOppm 100.0 (96.4) 92.1 (88.1) 79.7 (75.3) 37.6 16.7 Oppm 95.7 85.7 70.3 41.8 0 Γ.；3 -21 - 201124084 〔表 1 2〕 第1 1表蕃薯根瘤線蟲運動阻礙率（％) η-d lOppm 5.Oppm 2.5ppm 1.25ppm Oppm [Π-a] 500ppm 100.0 (95.9) 100.0 (86.4) 75.9 (71.7) 60.1 (44.5) 4.7 Oppm 95.7 85.7 70.3 41.8 0 〔表 13〕 第12表蕃薯根瘤線蟲運動阻礙率（％) [I-c] 20ppm lOppm 5.0ppm 1.25ppm Oppm [Il-d] 25 Oppm 100.0 (100.0) 100.0 (96.5) 99.2 (90.5) 58.9 (48.3) 4.1 Oppm 100.0 96.3 90.1 46.1 0 試驗例2 於洋蔥粉末中，以1 : 1 〇的比率加入水，充份地攪拌 。將8cm的濾紙浸漬於粉末懸濁液而風乾後，重疊3張放入 8 cm培養皿，加入2ml之所定濃度之有機磷系化合物及/或 殺菌劑之藥劑。每個培養皿中接種5 0隻之根蟎雌成蟲後加 蓋，靜置25t之恆溫室。於48至72小時後，於實體顯微鏡 下觀察，進行生死判定，而求出死蟲率》 死蟲率（％)= {1-(生存數/放入蟲數）}xl〇〇 另外，可由Corby式計算死蟲率之理論値（％ )。死蟲 率之實驗値（％ )若比理論値（％ )高時，本發明之有害 生物防除組成物係具有關於防除根蟎有害生物之相乘效果 -22- 201124084 有機磷系化合物：殺菌劑=1: 100至100: 1之範圍內 ’顯示死蟲率之實驗値爲比理論値高之値。 試驗例3 作成混合壤土 3 :砂土 1 :腐植土 1之試驗土壤，各放 入200g之土壤於3 00ml之塑膠製容器，以所定濃度添加混 合有機磷系化合物及/或殺菌劑。各放入1 0隻剛孵化後之 金龜子幼蟲，於黑暗下之2 5 °c的恆溫室中靜置5至1 0天後 ，解體土壤，計數生存之幼蟲數，而求出死蟲率。 死蟲率（％) = {1-(生存數/放入蟲數）}X100 另外，可由Corby式計算死蟲率之理論値（％ )。死蟲 率（％ )若比理論値（％ )高時，本發明之有害生物防除 組成物係具有關於防除金龜子之有害生物之相乘效果。 有機磷系化合物··殺菌劑=1 : 1 0 0 0至1 : 6之範圍內 ，顯示死蟲率之實驗値爲比理論値高之値。 試驗例4 倒入調整含有機磷系化合物及/或殺菌劑至所定濃度 之P A S培養基於8 c m培養皿’將於其他培養基上所增殖之S -17- 201124084 Test Example 1 In the chemical solution of the specified concentration, 200 to 25 larvae of the second phase of the nematode, Nematode, were immersed and stored in a constant temperature room at 25 °C for 24 hours. Investigate the total number of A. tumefaciens (A) in the liquid medicine and the number of unactive activities (B) in the liquid for 15 seconds. In addition, the number of investigations (A') of the control area using distilled water instead of the drug solution and the number of unactive activities (B,) of 15 seconds were investigated. From this, 运动' is determined by the following equation. The results are shown in Tables 1 to 12. Movement inhibition rate (%) = [1-{(1-Β/Α)/(Β, /Α,)}]χ1〇〇 In addition, the theory of motion inhibition rate (%) is calculated by the Corby formula. When the exercise inhibition ratio (°/β) is higher than the theoretical 値 (%), the harmful biological control composition of the present invention has a synergistic effect on the control of nematodes. The theory at this time (%) - 倂 is expressed in (1) to (12). [Table 2] The obstruction rate of No. 2 elegans nematode (%) Π [-a] lOppm 5.Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [ΙΙ-e] lOOOOppm 100.0 (98.0) 93.6 (92.5) 93.5 (84.3 56.4 (37.9) 54.8 (37.9) 10.3 Oppm 97.8 91.6 82.5 30.8 30.8 0 -18- 201124084 [Table 3] The obstruction rate of the nodule nematode in the second table (%) Γ] [-a] lOppm 5. Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [II-a] 500ppm 100.0 (97.8) 100.0 (91.6) 100.0 (82.5) 100.0 (30_8) 51.7 (30.8) 2.8 Oppm 97.8 91.6 82.5 30.8 30.8 0 [Table 4] 3rd table potato root nodule nematode Movement inhibition rate (%) π [-a] lOppm 5· Oppm 2_5ppm 1.25ppm 0.63ppm Oppm [II-c] lOOOOppm 100.0 (97.9) 100.0 (91.9) 100.0 (83.1) 100.0 (33_2) 77.1 (33.2) 3.4 Oppm 97.8 91.6 82.5 30.8 30.8 0 [Table 5] Movement inhibition rate (%) of No. 4 sweet potato nodule nematode Π _al lOppm 5. Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [Il-b] 2 5 Oppm 100.0 (92.7) 100.0 (88.5 89.7 (78.8) 67.1 (52.4) 48.2 (449) 12.1 Oppm 91.7 86.9 75.9 45.8 37.3 0 -19- '*1 201124084 [Table 6] Movement inhibition rate of nematode nodules in the fifth table (%) Ϊ́-bl lOppm 5. Oppm 2.5ppm Oppm [Π-c] lOOOppm 97.8 94.0 (93.5) 91.4 (70.9) 3.4 Oppm 100.0 93.3 69.9 0 [Table 7] No. 6 table potato tuberculosis movement inhibition rate (%) il- Bl lOppm 5.Oppm 2.5ppm Oppm [II-c] 500ppm 100.0 (100.0) 100.0 (93.3) 92.1 (69.9) 0 Oppm 100.0 93.3 69.9 0 [Table 8] Table 7: Stem Nodule Nematode Movement Obstruction Rate (%) Π [-bl lOppm 5.Oppm 2.5ppm 1.25ppm 0.63ppm Oppm [Il-b] 250ppm 100.0 (85.5) 94.3 (84.5) 71.1 (49.3) 53.1 (43.4) 37.1 (28.5) 12.1 Oppm 83.5 82.4 42.3 35.6 18.7 0 -20 - 201124084 [Table 9] Movement inhibition rate of No. 8 tube nodule nematode (%) [Ic] lOppm 5.Oppm 2.5ppm 1.25ppm Oppm [II-b] 250ppm 100.0 (96.2) 97.0 (87.4) 70.6 73.5 (48.8) 12.1 Oppm 95.7 85.7 70.3 41.8 0 [Table 10] The hindrance rate of the No. 2 tube nodule nematode (%) fi-cl lOppm 5.Oppm 2.5ppm 1.25ppm Oppm [Π-e] lOOOOppm 100.0 (96.2) 90.1 (87.2) 72.9 49.4 (48.0) 10.6 Oppm 95.7 85.7 70.3 41.8 0 [Table 1 1] The inhibition rate of No. 4 sylvestre root nematode (%) ri-ci lOppm 5. Oppm 2.5ppm 1.25ppm O Ppm [II-c] lOOOOppm 100.0 (96.4) 92.1 (88.1) 79.7 (75.3) 37.6 16.7 Oppm 95.7 85.7 70.3 41.8 0 Γ.;3 -21 - 201124084 [Table 1 2] The 1st table of sweet potato nodule nematode movement hinder Rate (%) η-d lOppm 5.Oppm 2.5ppm 1.25ppm Oppm [Π-a] 500ppm 100.0 (95.9) 100.0 (86.4) 75.9 (71.7) 60.1 (44.5) 4.7 Oppm 95.7 85.7 70.3 41.8 0 [Table 13] 12 Insect blocking rate of Caesarean tuberculosis (%) [Ic] 20ppm lOppm 5.0ppm 1.25ppm Oppm [Il-d] 25 Oppm 100.0 (100.0) 100.0 (96.5) 99.2 (90.5) 58.9 (48.3) 4.1 Oppm 100.0 96.3 90.1 46.1 0 Test Example 2 Water was added to the onion powder at a ratio of 1: 1 Torr and stirred thoroughly. After immersing the 8 cm filter paper in a powder suspension and air-drying, three sheets were placed in an 8 cm culture dish, and 2 ml of a predetermined concentration of the organophosphorus compound and/or the bactericide was added. Each of the culture dishes was inoculated with 50 root female adult worms, and then placed in a constant temperature room of 25 t. After 48 to 72 hours, observe under a stereoscopic microscope, and judge the life and death, and determine the mortality rate. The mortality rate (%) = {1 (number of survival / number of insects)} xl 〇〇 Corby's theory of calculating the mortality rate (%). The experimental 値(%) of the dead worm rate is higher than the theoretical 値(%), and the pest control composition of the present invention has a multiplication effect on the pest control of the root mites-22-201124084 organophosphorus compound: bactericide =1: In the range of 100 to 100: 1 'the experiment showing the mortality rate is higher than the theoretical one. Test Example 3 A mixed loam 3: sand soil 1: humus soil 1 test soil was placed, and 200 g of soil was placed in a plastic container of 300 ml, and a mixed organic phosphorus compound and/or a bactericide was added at a predetermined concentration. Each of the newly hatched chafer larvae was placed in a thermostatic chamber at 25 ° C in the dark for 5 to 10 days, and the soil was disintegrated, and the number of larvae survived was counted to determine the mortality rate. Dead insect rate (%) = {1 - (number of survivors / number of insects)} X100 In addition, the theoretical 値 (%) of the mortality rate can be calculated by the Corby formula. When the mortality rate (%) is higher than the theoretical 値 (%), the pest control composition of the present invention has a synergistic effect on the pest controlling the chafer. In the range of organophosphorus compound··bactericide=1: 1 0 0 0 to 1:6, the experimental 显示 showing the mortality rate is higher than the theoretical 値. Test Example 4 Pour the P A S medium containing the organic phosphorus compound and/or the bactericide to a predetermined concentration in an 8 cm culture dish, which was propagated on other medium.
Rhizoctonia 菌、Pythium 菌及 Fusarium菌，以 6mm之打孔器 切取含有菌絲之培養基，移植於含藥劑之培養基。於25°C 之11溫室中，培養4至7天後’測定伸長之菌絲長度’求出 菌絲伸長阻礙率。 -23- 201124084 菌絲伸長阻礙率（％) = { 1 -(藥物處理區之菌絲伸長量/ 無處理之菌絲伸長量）} X 1 0 0 另外，可由Corby式計算菌絲伸長阻礙率之理論値（％ )。菌絲伸長阻礙率（％ )若比理論値（°/〇 )高時，本發 明之有害生物防除組成物係具有關於防除病害菌之相乘效 果。 有機磷系化合物：殺菌劑=1: 100至10000: 1之範圍 內，顯示菌絲伸長阻礙率之實驗値爲比理論値高之値。 試驗例5 將3公升之混合水田土 4:砂1之砂壤土，放入1/5 00 0a 缽中，以所定濃度添加混合有機磷系化合物及/或殺菌劑 。剛添加藥劑後，20天後及40天後，接種5 00cc之線蟲蕃 薯根瘤線蟲（Meloidogyne incognita)污染土壤於各個跡 中，充份地混合後，移植蕃茄（品種：強力米壽）苗。移 植51天後，調査線蟲之根瘤著生程度（0至100%著生）。 結果如第1 3表所示。另外，爲統一移植日，混和砂壤土及 藥劑係於由移植日反算之日預先進行。另外，由Corby式 計算根瘤著生程度之理論値（％ )。根瘤著生程度（％ ) 若比理論値（％ )低時，本發明之有害生物防除組成物係 具有關於防除線蟲之相乘效果。此時之理論値（％ ~倂 表示於第13表之（）內。 • 24- 201124084 〔表 14〕 第1 3表 根瘤著生程度（％ ) 供試藥劑 移植後之日數 (Kg a.i./ha) 0 20 40 I-a(3) 30 17 57 II-a(1.5) 100 100 100 I-a(3)+II-a(1.5) 20(30) 10(17) 50(57) II-c(1.5) 100 100 100 I-a(3)+II-c(1.5) 25(30) 10(17) 60 II-d(1.5) 100 100 100 I-a(3)+II-d(1.5) 30 7(17) 53(57) II-f(1.5) 100 100 100 I-a(3)+II-f(1.5) 20(30) 13(17) 40(57) II-gd.5) 100 100 100 I-a(3)+II-g(1.5) 20(30) 10(17) 50(57) II-i(1.5) 100 100 100 I-a(3 )+II-i(l.5) 17(30) 17 50(57) n-id.5) 100 100 100 I-a(3)+II-j(1.5) 20(30) 10(17) 47(57) II-k(1.5) 100 100 100 I-a(3)+II-k(1.5) 33 10(17) 50(57) 無處理 100 100 100 -25- 201124084 試驗例6 將蕃薯根瘤線蟲（Meloidogye incognita)及 Fusarium oxysoprum)所污染之土壤及所定量的 於1 /1 000a塑膠缽中，播種7粒小黃瓜（品種：北 。播種66天後，調査小黃瓜蔓割病發病株率，並 黃瓜的第2至第3節間的莖，導管的褐變程度係依 5階段評估，基於評估結果，算出受害指數。此 第1 4表所示。另外，試驗係以3連制進行。另外， 式計算發病株率及受害指數之理論値。發病株率 數若比理論値低時，本發明之有害生物防除組成 關於防除小黃瓜蔓割病之相乘效果。此時之理論 —倂表示於第表之（）內。 A :株全體枯死 B :導管之2/3以上褐變 C :導管之1/2程度褐變 D :導管之1/3以下褐變 E :導管無褐變 N:調査株數（本試驗中爲7) 受害指數={(4a + 3B + 2C+1D/4N)}x100 鐮胞菌（ 藥劑混合 進）種子 且切斷小 下述基準 等結果如 由 Corby 及受害指 物係具有 値（％ ) -26- 201124084 〔表 15〕 黃瓜蔓割病發病株率 供試藥劑 (Kg a.i./ha) 發病株率(〇/〇) 受害指數 I-a(3) 100 82 II-a(3) 100 100 I-a(3)+II-a(3) 81(100) 61(82) 無處理 100 100 試驗例7 (1) 將蕃薯根瘤線蟲（Meloidogye incognita)及鐮 胞菌（Fusarium 〇xySOprum )所污染之土壤及所定量的 Basamid微粒劑（有效成份^ -h )混合於1/1 〇〇〇a塑膠缽中 ’ 7天後及10天後進行土壤中氣體移除。 (2) (Ο之操作後，混合所定量之NematorinS粒劑 (有效成份I-a )於土壤中，再經4天後，播種7粒小黃瓜（ 品種：北進）種子。 (3) 播種61天後’調查小黃瓜蔓割病發病株率，並 且以與試驗例6同樣的方法，算出受害指數。並且調查線 蟲之根瘤著生程度（0至1 0 0 %著生）。此等結果如第1 5表 所示。試驗係以3連制進行。 爲進行比較，對於不進行（1 )之操作，以（2 )中之 所定量NematorinS粒劑（有效成份l-a)處理受污染之土壤 情況時，以及（1 )之操作後，（2 )之操作中，不混合所 定量之NematorinS粒劑（有效成份I-a )於土壤情況時’進 行相同的試驗。 -27- 201124084 〔表 1 6〕 第15表 複數病害防除試驗 供試藥劑 小黃瓜蔓割病 根瘤 (Kg a.i./ha) 發病株率(％) 受害指數 著生程度(％) I-a(3) 71 40 5 II-h(294) 79 53 2 I-a(3)+II-h(294) 41 23 0 無處理 89 60 25 製劑例1 98.3重量份 0.2重量份 1.0重量份 0 · 5重量份 作爲對於（1 )之 9 7.7重量份 1 .0重量份 1 .0重量份 〇. 3重量份 (1 )矽石細粒（東海工業製） (2) 扶吉胺（Fluazinam) (3) 福賽絕（Fosthiazate) (4 )環氧化亞麻籽油 將上述（2)至（4)加熱混合者 吹付粒劑。 製劑例2 (1) 矽石細粒（東海工業製） (2) 扶吉胺（Fluazinam) (3) 福賽絕（Fosthiazate) (4 )環氧化亞麻籽油 將上述（2)至（4)加熱混合者，作爲對於（1)之 吹付粒.劑。 -28 · 201124084 (1 )矽石細粒（東海工業製） (2) 扶吉胺（Fluazinam) (3) 福賽絕（Fosthiazate) (4 )環氧化亞麻籽油 98.3重量份 0-2重量份 1 · 0重量份 〇.5重量份 將上述（2)至（4)加熱混合者’作爲對於（1)之 吹付粒劑。 製劑例2 (1)扶吉胺（Fluazinam) 20重量份 (2 )福賽絕（Fosthiazate ) 10重量份 (3) Solpol3661S (東邦化學製） 1〇重量份 (4) Ipuzoll50(出光石油化學製）60重重份 將上述（1 )至（4 )混合溶解成乳劑。 另外，在此引用成爲本申請書之優先權主張基礎之曰 本特許願2004-015667號（2004年1月23日對日本特許廳提 出申請）之總說明書內容’作爲本發明之說明書之揭示所 採用者。 -29-Rhizoctonia, Pythium, and Fusarium were cultured in a medium containing a hyphal with a 6 mm punch. The mycelial elongation inhibition rate was determined by incubating for 4 to 7 days in a greenhouse at 25 ° C for 4 to 7 days. -23- 201124084 Mycelial elongation inhibition rate (%) = { 1 - (hyphal elongation in drug treatment area / untreated hyphae elongation)} X 1 0 0 In addition, the hyphal elongation inhibition rate can be calculated by Corby formula The theory 値 (%). When the mycelial elongation inhibition rate (%) is higher than the theoretical 値 (°/〇), the pest control composition of the present invention has a synergistic effect on the control of the disease-preventing bacteria. Organophosphorus compound: bactericide = 1: 100 to 10000: 1 The experimental enthalpy showing the mycelial elongation inhibition ratio is higher than the theoretical enthalpy. Test Example 5 3 liters of mixed paddy soil 4: Sand 1 loam was placed in a 1/5 00 0a crucible, and a mixed organophosphorus compound and/or a bactericide was added at a predetermined concentration. Immediately after the addition of the drug, after 500 days and 40 days, 500 cc of the larvae of Meloidogyne incognita was inoculated into the soil, and after thorough mixing, the tomato (variety: strong rice) seedling was transplanted. After 51 days of transplanting, the degree of root nodule of the nematode was investigated (0 to 100% of the birth). The results are shown in Table 13. In addition, for the unified transplant day, the mixed sandy loam and the chemical system are carried out in advance on the date of the calculation of the transplant date. In addition, the theoretical 値 (%) of the degree of root nodulation is calculated by the Corby formula. Root tumor degree (%) If the ratio is lower than the theoretical 値 (%), the pest control composition of the present invention has a synergistic effect on the control of nematodes. The theoretical 値 at this time (% ~ 倂 is shown in the table () of the 13th table. • 24- 201124084 [Table 14] The degree of root nodulation (%) The number of days after the test drug transplantation (Kg ai / Ha) 0 20 40 Ia(3) 30 17 57 II-a(1.5) 100 100 100 Ia(3)+II-a(1.5) 20(30) 10(17) 50(57) II-c(1.5) 100 100 100 Ia(3)+II-c(1.5) 25(30) 10(17) 60 II-d(1.5) 100 100 100 Ia(3)+II-d(1.5) 30 7(17) 53( 57) II-f(1.5) 100 100 100 Ia(3)+II-f(1.5) 20(30) 13(17) 40(57) II-gd.5) 100 100 100 Ia(3)+II- g(1.5) 20(30) 10(17) 50(57) II-i(1.5) 100 100 100 Ia(3 )+II-i(l.5) 17(30) 17 50(57) n-id .5) 100 100 100 Ia(3)+II-j(1.5) 20(30) 10(17) 47(57) II-k(1.5) 100 100 100 Ia(3)+II-k(1.5) 33 10(17) 50(57) No treatment 100 100 100 -25- 201124084 Test Example 6 Soil contaminated with Meloidogye incognita and Fusarium oxysoprum and quantified in 1 / 1 000a plastic mortar, Sowing 7 gherkins (variety: North. After 66 days of sowing, investigate the rate of diseased cucumbers, and the stems of the 2nd to 3rd sections of the cucumber, the catheter The degree of change is based on the five-stage evaluation, and the damage index is calculated based on the evaluation result. This is shown in Table 14. In addition, the test is carried out in a three-line system. In addition, the formula calculates the disease rate and the damage index. If the rate is lower than the theoretical one, the pest control composition of the present invention is related to the multiplication effect of controlling the cucumber cucumber disease. The theory at this time is shown in the table (A): A: The whole plant is dead B: 2/3 or more browning of the catheter C: 1/2 degree browning of the catheter D: browning of 1/3 or less of the catheter E: no browning of the catheter N: number of investigated plants (7 in this test) damage index = { (4a + 3B + 2C+1D/4N)}x100 Phytophthora (mixed with medicinal) seeds and cut off the following results, such as the Corby and the victim system, 値 (%) -26- 201124084 [Table 15 〕 Cucumber vine disease incidence rate test agent (Kg ai / ha) incidence rate (〇 / 〇) victim index Ia (3) 100 82 II-a (3) 100 100 Ia (3) + II-a ( 3) 81(100) 61(82) No treatment 100 100 Test Example 7 (1) Stained by Meloidogye incognita and Fusarium 〇xySOprum The soil and the quantitative Basamid granules (active ingredient ^ -h ) were mixed in 1/1 〇〇〇a plastic ‘ 7 days later and 10 days later, the soil gas was removed. (2) (After the operation, mix the quantified NematorinS granules (active ingredient Ia) in the soil, and after 4 days, sow 7 seeds of cucumber (variety: Beijin). (3) After sowing for 61 days 'Investigate the incidence rate of the cucumber cucumber disease, and calculate the damage index in the same manner as in Test Example 6. And investigate the degree of root nodule of the nematode (0 to 100% of the birth). These results are as shown in the first The table is shown in Table 3. For the comparison, for the case where the contaminated soil is treated with the quantified NematorinS granule (active ingredient la) in (2) without performing the operation (1), And after the operation of (1), in the operation of (2), the same test is carried out without mixing the quantified NematorinS granules (active ingredient Ia) in the soil condition. -27- 201124084 [Table 1 6] Table 15 Multi-disease control test test agent Ginkgo biloba root nodule (Kg ai/ha) Incidence rate (%) Degree of birth index (%) Ia(3) 71 40 5 II-h(294) 79 53 2 Ia (3) +II-h(294) 41 23 0 No treatment 89 60 25 Formulation Example 1 98.3 parts by weight 0.2 parts by weight 1.0 weight 0 parts by weight of 5 parts by weight of 7.7 parts by weight of (1), 1.0 parts by weight of 1.0 parts by weight of 〇. 3 parts by weight of (1) vermiculite fine particles (manufactured by Tokai Kogyo Co., Ltd.) (2) gibberidine ( Fluazinam) (3) Fosthiazate (4) Epoxidized linseed oil. The above-mentioned (2) to (4) heating mixture is blown into the granules. Formulation Example 2 (1) Vermiculite fine particles (made by Tokai Industrial Co., Ltd.) (2) Fluazinam (3) Fosthiazate (4) Epoxidized linseed oil The above (2) to (4) are heated and mixed as a blowing agent for (1). -28 · 201124084 (1) Vermiculite (made by Tokai) (2) Fuaginam (3) Fosthiazate (4) Epoxidized linseed oil 98.3 parts by weight 0-2 parts by weight 1 · 0 parts by weight of 〇. 5 parts by weight, the above (2) to (4) are heated to be mixed as a granule for (1). Formulation Example 2 (1) Fluazinam 20 parts by weight (2) ) Fosthiazate 10 parts by weight (3) Solpol3661S (manufactured by Toho Chemical Co., Ltd.) 1 part by weight (4) Ipuzoll 50 (manufactured by Idemitsu Petrochemical Co., Ltd.) 60 parts by weight The above (1) to (4) were mixed and dissolved into an emulsion. In addition, the contents of the general specification of the present application No. 2004-015667 (applied to the Japanese Patent Office on January 23, 2004), which is the basis of the priority of the present application, is hereby incorporated by reference. Adopter. -29-
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| CN101953341A (en) * | 2010-06-03 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Sterilizing composition |
| CN102258051B (en) * | 2011-05-25 | 2013-08-14 | 江苏龙灯化学有限公司 | Composition and method for preventing and removing pests |
| KR102015382B1 (en) * | 2012-07-03 | 2019-08-28 | 이시하라 산교 가부시끼가이샤 | Pesticidal composition and pest control method |
| JP2014097975A (en) * | 2012-10-16 | 2014-05-29 | Sumitomo Chemical Co Ltd | Method of controlling sweet potato fusarium wilt |
| CN103210955A (en) * | 2013-03-24 | 2013-07-24 | 广东中迅农科股份有限公司 | Thiazole phosphine and metalaxyl granule and preparation method thereof |
| CN103734176B (en) * | 2013-12-26 | 2015-06-10 | 山东康乔生物科技有限公司 | Insecticidal composition containing fipronil |
| CN103749529B (en) * | 2013-12-26 | 2016-04-13 | 山东康乔生物科技有限公司 | A kind of insecticidal and bactericidal composition |
| CN103734180B (en) * | 2013-12-30 | 2015-12-30 | 刘一平 | A kind of Fungicidal insecticidal composition containing sufluoxime |
| CN103704256A (en) * | 2013-12-30 | 2014-04-09 | 孙蒙蒙 | Sterilization insecticidal combination containing iprodione |
| CN103814947B (en) * | 2013-12-30 | 2016-08-17 | 青岛青知企业管理咨询有限公司 | A kind of Pesticidal combination containing chlorfenapyr |
| CN103749530B (en) * | 2013-12-30 | 2015-10-14 | 顾祥茂 | A kind of Pesticidal combination containing Avermectin |
| CN105851054A (en) * | 2016-04-16 | 2016-08-17 | 广东中迅农科股份有限公司 | Pesticide composition containing fluazinam and fosthiazate |
| CN105918346A (en) * | 2016-06-24 | 2016-09-07 | 江苏省绿盾植保农药实验有限公司 | Rice seed treating agent containing fluazinam and fosthiazate and application thereof |
| JP7280803B2 (en) | 2019-10-23 | 2023-05-24 | 日鉄神鋼建材株式会社 | Spill prevention device |
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| JPS60136590A (en) * | 1983-12-23 | 1985-07-20 | Ishihara Sangyo Kaisha Ltd | Organic phosphorous compound, insecticide, acaricide, and nematocide containing same |
| JPS60136500A (en) * | 1983-12-26 | 1985-07-19 | Hitachi Ltd | Control transmitter of remote supervisory and controlling device |
| JPH01238505A (en) * | 1988-03-18 | 1989-09-22 | Ishihara Sangyo Kaisha Ltd | Control agent of harmful animal |
| JPH0739430B2 (en) * | 1990-07-06 | 1995-05-01 | アグロカネショウ株式会社 | Organophosphorus compound, method for producing the same and insecticide, acaricide, nematicide containing the compound |
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