CN101810194A - The method of control of Pesticidal composition and pest - Google Patents
The method of control of Pesticidal composition and pest Download PDFInfo
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- CN101810194A CN101810194A CN201010161962A CN201010161962A CN101810194A CN 101810194 A CN101810194 A CN 101810194A CN 201010161962 A CN201010161962 A CN 201010161962A CN 201010161962 A CN201010161962 A CN 201010161962A CN 101810194 A CN101810194 A CN 101810194A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
Abstract
The invention provides to improve simultaneously and prevent and kill off the effect of living in the insect in soil and/or the seed and prevent and kill off soil and/or the Pesticidal composition and the method for control of the effect of seed transmission venereal disease evil.That is, provide and contain O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate, and fluazinam and/or benomyl are as the Pesticidal composition of active ingredient and use the method for control of said composition.
Description
The application is to be on January 20th, 2005 applying date, and application number is 200580003066.5, and denomination of invention is divided an application for the Chinese patent application of " the method for control of Pesticidal composition and pest ".
Technical field
The present invention relates to prevent and kill off the Pesticidal composition of various insects and various plant diseases effectively simultaneously.
Background technology
S-sec-butyl O-ethyl 2-oxo-1,3-thiazoles alkane-3-base thiophosphate is by patent documentation 1 disclosed compound.O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate is by patent documentation 2 disclosed compounds.S, S-two sec-butyl O-diethyldithioposphoric acid esters are by patent documentation 3 disclosed compounds.These compounds all be as desinsection, kill mite, nematocide active ingredient and known organophosphorus compound.But when still not knowing to make up specific organophosphorus compound and specific bactericide, the two all can bring into play synergistic effect for preventing and kill off the insect that lives in soil and/or the seed and soil and/or seed transmission plant disease.
Patent documentation 1: No. the 4590182nd, United States Patent (USP)
Patent documentation 2: No. the 5405961st, United States Patent (USP)
Patent documentation 3: No. the 4535077th, United States Patent (USP)
Summary of the invention
People wish to obtain a kind of noxious organism control agent, its can prevent and kill off nematoda, thorn sufficient root mite etc. live in insect in soil and/or the seed and soil and/or seed transmission venereal disease evil the two, and compare with preventing and kill off each side separately, both are had the synergy preventive effect of reinforcement.
The inventor finds can obtain above expected effect, thereby finish the present invention by making up specific organophosphorus compound and specific bactericide for solving the result that such problem is studied repeatedly.
The present invention is made of following main points.
1, a kind of Pesticidal composition, it is characterized in that, it contains and is selected from S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidine-3-base thiophosphate, O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate and S, at least a kind of organophosphorus compound in the group that S-two sec-butyl O-diethyldithioposphoric acid esters are formed, with be selected from fluazinam, benomyl, tolelofos-methyl, metalaxyl, captan, iprodione, tpn, dazomet, hydroxyisoxazole, at least a kind of bactericide in the group that flutolanil and valida are formed is as active ingredient.
2, as above-mentioned 1 described Pesticidal composition, above-mentioned organophosphorus compound and above-mentioned bactericide to contain proportional be 1: 10000～10000: 1 by weight.
3, the method of control of a kind of pest, it is characterized in that, to be selected from S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidine-3-base thiophosphate, O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate and S, at least a kind of organophosphorus compound in the group that S-two sec-butyl O-diethyldithioposphoric acid esters are formed, with be selected from fluazinam, benomyl, tolelofos-methyl, metalaxyl, captan, iprodione, tpn, dazomet, hydroxyisoxazole, at least a kind of bactericide in the group that flutolanil and valida are formed acts on pest as active ingredient.
4, as the method for control of above-mentioned 3 described pests, above-mentioned organic phosphorus compound and above-mentioned bactericide are acted on simultaneously, or made any effect of above-mentioned organophosphorus compound and above-mentioned bactericide, then make another kind of effect again.
5,, make the ratio of above-mentioned organophosphorus compound and above-mentioned bactericide count 1: 10000～10000: 1 by weight and act on as above-mentioned 3 or the method for control of 4 described pests.
6, as the method for control of wantonly 1 described pest of above-mentioned 3～5, the concentration that makes above-mentioned active ingredient is 0.1～10000ppm effect.
7, as the method for control of wantonly 1 described pest of above-mentioned 3～6, pest is the pest that lives in soil and/or the seed.
8, as the method for control of wantonly 1 described pest of above-mentioned 3～6, pest is the insect that lives in soil and/or the seed.
9, as the method for control of wantonly 1 described pest of above-mentioned 3～9, pest is the plant parasitic nematodes class.
10, as the method for control of wantonly 1 described pest of above-mentioned 3～6, the plant parasitic nematodes class is at least a kind that is selected from root-knot nematode, packing nematode, pratylenchus, the white sharp nematode of paddy rice, strawberry bud nematode and the pine wood nematodes.
11, as the method for control of wantonly 1 described pest of above-mentioned 3～10, it handles soil and/or seed with above-mentioned organic phosphorus compound and bactericide.
By the present invention, can provide to improve simultaneously and prevent and kill off the effect of living in the insect in soil and/or the seed and prevent and kill off soil and/or the new Pesticidal composition and the method for control of the effect of seed transmission venereal disease evil.
Embodiment
There is optical isomer in S-sec-butyl O-ethyl 2-oxo-1,3-thiazoles alkane-3-base thiophosphate, except racemic modification, also comprises (-) body and (+) body.As racemic modification (R S)-S-sec-butyl O-ethyl-2-oxo-1,3-thiazoles alkane-3-base thiophosphate, is general colophonate by name and compound known.
There is optical isomer in O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate, except racemic modification, also comprises (-) body and (+) body.
S, S-two sec-butyl O-diethyldithioposphoric acid esters are the known compounds as general gram line pellet by name.
Fluazinam (Fluazinam), benomyl (Benomyl), tolelofos-methyl (Tolclofos-methyl), metalaxyl (Metalaxyl), captan (Captan), iprodione (Iprodione), tpn (Chlorothalonil), dazomet (Dazomet), hydroxyisoxazole (Hymexzole), flutolanil (Flutolanil) and valida (Validamycin) all are to be recorded in The Pesticide Manual (the 13rd edition as bactericide; BRITISH CROPPROTECHTION COUNCIL) compound in.
The ratio of Phosphorus compound of above-mentioned machine and bactericide is counted 1: 10000～10000: 1 usually by weight, is preferably 1: 1000～1000: 1.
Composition of the present invention also contains adjuvant except active ingredient.The cooperation ratio of active ingredient can be 0.05～75 weight %.Can list carrier, emulsifier, suspending agent, dispersant, solvent, bleeding agent, wetting agent, tackifier, stabilizing agent etc. as adjuvant, can suitably add as required.As carrier, be divided into solid carrier and liquid-carrier, can list starch as solid carrier, active carbon, soybean meal, wheat flour, wood powder, fish meal, the animals and plants powder of milk powder etc., talcum, kaolin, bentonite, calcium carbonate, zeolite, diatomite, white carbon, clay, alumina, the mineral powder of sulphur powder etc. etc., as liquid-carrier, can enumerate water outlet, methyl alcohol, the alcohols of ethanol etc., acetone, the ketone diox of MEK etc., the ethers of oxolane etc., kerosene, the aliphatic hydrocarbon of lam-oil etc., dimethylbenzene, trimethylbenzene, durene, cyclohexane, solvent naphtha etc. aromatic hydrocarbon based, chloroform, the halogenated hydrocarbon of chlorobenzene etc., the amide-type of dimethyl formamide etc., ethyl acetate, the ester class of fatty glyceride etc., the nitrile of acetonitrile etc., the sulfur-containing compound class of dimethyl sulfoxide (DMSO) etc. etc.As emulsifier, suspending agent, dispersant, solvent, bleeding agent, wetting agent etc., can use various surfactants.In addition, can use with and usefulness with other agricultural chemicals, for example insecticide, miticide, nematocide, bactericide, antivirotic, attractant, weed killer herbicide, plant growth regulator etc. as required, can demonstrate more excellent effect sometimes in this case.
The present composition can preparation be the various forms of emulsion, pulvis, fine granule, granule, tablet, wetting powder, liquor, aerosol, paste, colloidal suspending agent, dried colloidal suspending agent, microcapsule formulations etc.The wherein more preferably form of emulsion, fine granule, wetting powder, liquor, pulvis, granule, tablet etc., the most preferably form of emulsion, fine granule, wetting powder, liquor etc.The preferred cooperation ratio of emulsion is active ingredient 5～75 weight portions, carrier 90～10 weight portions and surfactant 5～15 weight portions.The preferred cooperation ratio of pulvis, granule and tablet is active ingredient 0.1～10 weight portion, carrier 85～99 weight portions and surfactant 0.5～5 weight portion in addition.These preparations can directly use when reality is used, and perhaps the thinner of water etc. is diluted to normal concentration and uses.
The present composition is generally with 0.1～10000ppm, preferably use with the active ingredient concentration of 1～1000ppm.Above-mentioned active ingredient concentration can be according to suitably change such as the form of preparation and the situation occurred of application process, purpose, period, place and insect, the amount of application of per unit area is that every 10a uses about 1～5000g active ingredient compound, preferably uses 10～1000g.But, under special situation, also may exceed above-mentioned scope.As the application process of the present composition, can list that earth mixture is handled, point is executed processings, row replacement is handled or the perfusion processing, or to the impregnation process of seed etc., Cotton seeds etc.
Except handle the method for pest with the present composition, the present invention also comprises simultaneously with above-mentioned organophosphorus compound and bactericide and handles the method for pest, behind any chemicals treatment pest with Phosphorus compound of machine and bactericide, use the method for another kind of chemicals treatment pest again.
As the pest that the present invention is suitable for, can list the plant parasitic nematodes class, etc. various insects or the various plant disease of sufficient class, coleopteran pest, lepidoptera pest, gastropod, orthoptera pest, phytotrophy mite class, thrips insect, Diptera pest, Hymenoptera insect, latent wing order insect, Anoplura insect, Isoptera insect etc.The present invention is effective for preventing and kill off the pest that lives in soil and/or the seed especially.As the insect that lives in soil and/or the seed, the insect of the seed that the insect of destroying horticultural crop and trees etc. is arranged in soil, destroys horticultural crop or trees etc.For example, can list above-mentioned plant parasitic nematodes class, etc. sufficient class, coleopteran pest, lepidoptera pest, gastropod, orthoptera, phytotrophy mite class etc.Wherein, the present invention is the most effective for preventing and kill off the plant parasitic nematodes class.
The present invention various insects applicatory are as follows.
As the plant parasitic nematodes class, can list the root-knot nematode class of Meloidogyne incognita (Meloidogyneincognita) etc.; The packing nematoda of globodera rostochiensis (Globodera rostochiensis) etc.; The pratylenchus class of Cobb root (Pratylenchus penetrans) etc.; The white sharp nematode of paddy rice; Strawberry bud nematode; Pine wood nematodes etc.In addition, as etc. sufficient class, can list pillworm, damp worm etc.
As coleopteran pest, can list the corn root eating insect class of west corn root eating insect, southern corn root eating insect etc.; The cockchafer subclass of the different cockchafer of bronze etc.; Corn weevil, rice weevil, alfalfa leaf resemble, the curculionid class of adzuki bean weevil etc.; The plan walking worms of yellow mealworm, red flour beetle etc.; Huang is kept the class Diabrotica of pawl, cabbage flea beetle, Colorado beetle etc.; Deathwatch's class; The Siphonophora of potato ladybug (Epilachnavigintioctopunctata) etc.; The stupid class of powder; Long stupid class; It bovine; Paederus fuscipes Curtis etc.
As lepidoptera pest, can list the nocturnal moth class of Autographa spp, mythimna separata, rice pink borer, beet armyworm, tomato moth etc.; The nocturnal moth class of black cutworm, white line dart moth of turnip, three tooth bean weevil genus, Heliothis, Hericoverpa genus etc.; The snout moth class of striped rice borer, light red assorted leafhopper, corn borer, lawn bud moth, the wild snout moth's larva of lap leaf, the ancient phycitid of India etc.; The white butterfly class of imported cabbageworm etc.; The moth fruit moth class of the leaf roller of Adoxophyes spp genus, oriental fruit moth, apple skin steinernema etc., peach fruit borer etc.; The lyonetid section that lyonetid belongs to; The pornography and drug moth class of Euproctis, Euproctis etc.; The apple ermine moth class of Oeobia undalis etc. etc.
Can list strong snail, slug etc. as gastropod.
As orthoptera pest, can list mole cricket, locust, Groton bug, the big Lian of grey, big Lian, brown blattaria, oriental cockroach etc.
As phytotrophy mite class, can list Tetranychus urticae, tetranychus telarius, purple joint tick, the sufficient root mite of thorn etc.
As the thrips insect, can list southern golden thistle horse, golden thistle horse, yellow chest thrips etc.
As Diptera pest, can list the little flowerfly class, trypetid class, fruit bat class, hair fly class, buffalo gnat class, horsefly class, tatukira class, the fly class of diving of the fly class, bluebottle, big sarcophagid class, latrine fly class, delia platura, onion fly etc. of the culex class, midge class, housefly, nonbiting stable fly etc. of culex, mosquito etc. etc.
As the Hymenoptera insect, can list the sawfly class of ant class, wasp class, swollen leg honeybee class, cabbage sawfly etc. etc.
As latent wing order insect, can list flea etc.
As the Anoplura insect, can list humanlice, crab louse etc.
As the Isoptera insect, can list Japanese termite, coptotermes formosanus etc.
As the present invention's various plant diseases applicatory, can list the plant disease of soil for example and/or seed transmission.But the concrete following disease of illustration.
The hard shell of seat belongs to microbial various disease, for example the leaf rot of cotton grass (Rhizoctonia solani Kuhn Rhizoctonia solani); The foot rot of lettuce (Rhizoctonia solani Kuhn Rhizoctonia solani); The leaf rot of tulip (Rhizoctonia solani Kuhn Rhizoctonia solani); The seedling blight of beet, tomato, eggplant, cucumber, green pepper, Japanese honewort, buckwheat, tealeaves damping off, gumbo (Rhizoctonia solani Kuhn Rhizoctonia solani); The damping off (Rhizoctonia solani Kuhn Rhizoctonia solani) of Japan honewort, brussels-sprouts; The root rot of carrot (Rhizoctonia solani Kuhn Rhizoctonia solani); The waist folding sick (Rhizoctonia solani Kuhn Rhizoctonia solani) of tobacco; The root neck of spinach, wild cabbage (Rhizoctonia solani Kuhn Rhizoctonia solani); The tar spot of burdock (Rhizoctonia solani Kuhn Rhizoctoniasolani); The be full of cracks brown stain disease of radish (Rhizoctonia solani Kuhn Rhizoctonia solani);
The microbial bulb rust of Uromyces (Uromyces holwayi);
The microbial various diseases of pythium, for example seedling blight of beet (pythium debaryanum bacterium Pythium debaryanum); Tobacco damping off (pythium debaryanum bacterium Pythiumdebaryanum); The seedling blight of tomato, cucumber, eggplant, green pepper, muskmelon, muskmelon, watermelon, snake melon, pumpkin (Pythium Vexans); The red burning sick (melon and fruit pythium spp Pythium aphanidermatum) of cotton grass; The root rot of konjaku (awns spore pythium spp Pythiumaristosporum); The rhizome rot of ginger, ginger (ultimate pythium spp Pythium ultimum);
The microbial various diseases of Fusarium, for example the napiform root rot of tulip (sharp sickle spore bacterium Fusarium oxysporum); The dry rot of konjaku (sharp sickle spore bacterium Fusarium oxysporum); The chlorosis of strawberry (sharp sickle spore bacterium Fusarium oxysporum); The fusarium wilt of potato, tomato (sharp sickle spore bacterium Fusarium oxysporum); The fusarium wilt of cucumber, sweet potato (sharp sickle spore bacterium Fusarium oxysporum); The damping off of caraway (fusarium solani Fusarium solani); The dry rot of onion, Chinese onion (sharp sickle spore bacterium Fusarium oxysporum);
The microbial various diseases of the swollen mould genus of stalk, for example mashed worry of pineapple (camphor tree phytophthora Phytophthora cinnamomi); The upright withered eqpidemic disease of green onion wood (Phytophthora cactorum bacterium Phytophthoracactorum); The eqpidemic disease (phytophthora blight of pepper Phytophthora capsici) of green pepper, caraway, gerbera, perennial root rosy clouds grass, common calla, African purple lettuce dish, tobacco; The root rot of strawberry (strawberry phytophthora Phytophthora fragariae);
The microbial various diseases of Verticillium, for example yellows of Chinese cabbage (dahlia verticillium sp Verticillium dahliae); The verticillium wilt of eggplant (dahlia verticillium sp Verticilliumdahliae);
The lead fungi of dying belongs to the root rot (thanatephorus cucumeris(frank) donk Thanatephoruscucumeris) of microbial beet;
The stem rot of the microbial lily of rhizopus (melanomyces Rhizopus necans);
The black heart of the microbial tulip of Penicillium (penicillium cyclopium Penicillium cyclopium);
The root knot (plasmodiophora brassica bacteria Plasmodiophora brassicae) of the brassicaceous vegetable of the microbial wild cabbage of knee Pseudomonas, Chinese cabbage etc.;
The microbial powdery scab of potato of powder scab Pseudomonas (spongospora subterranea Spongosporasubterranea);
The hard shell of seat belongs to the white root rot (brown Ascomycetes bacterium Rosellinianecatrix) of microbial fruit tree, flowers and trees, tea;
The southern blight of the microbial green onion of sclerotium, leek, Petasites officinalis Moench, konjaku, soybean, chrysanthemum, green pepper (Sclerotium rolfsii Sclerotium rolfsii);
The anthracnose of the microbial strawberry of Colletotrichum (anthrax-bacilus colletotrichum acutaum);
Many Acarasiales belong to the clump root disease (Polymyxa betae media) of microbial beet;
The bulbil rot of the microbial green onion of gray mold (green onion squama botrytis Botritissquamosa);
The violet root rot of the microbial fruit tree of volume load Pseudomonas, flowers and trees, tea (mulberry volume load bacterium Helicobasidium mompa);
Long beak shell belongs to the black class sick (Ceratocystis fimbriata bacterium Ceratocystisimbriata) of microbial sweet potato;
The stain root rot of the microbial muskmelon of root rot Pseudomonas (stain pine root fungus Monosporascus cannonballus);
The microbial black root of tobacco of Thiclaviopsis (thielaviopsis sp bacterium Thielaviopsisbasicola);
The lead fungi of dying belongs to the black spot (thanatephorus cucumeris(frank) donk Thanatephoruscucumeris) of microbial potato;
The lead fungi of dying belongs to the stem rot (thanatephorus cucumeris(frank) donk Thanatephoruscucumeris) of microbial pea shell;
The bakanae disease of the microbial paddy rice of Gibberella (gibberella fujikuroi bacterium Gibberella fujikuroi);
Sterpomyces belongs to microbial powdery scab of potato (Sterpomyces scabies); And
The rice blast of the microbial paddy rice of Pyricularia Sacc. (Pyricularia oryzae Pyricularia oryzae); Deng.
In addition, the present invention also is suitable for a variety of soil infection beyond the illustration or the disease of seed transmission.
Composition of the present invention and method have the effect of synergy for Pesticidal.This effect have the various disease and insects that have from each medicament prevent and kill off the characteristic unpredictable to effect.Compare with each medicament of independent use, serviceability of the present invention in the Pesticidal power that obviously strengthens in Pesticidal effect, the particularly soil, also has the characteristics of quick-acting effect.
Embodiment
Following notebook inventive embodiment.
[table 1]
Test example 1
With 200～250 Meloidogyne incognita 2 instar larvaes impregnation process in being formulated as the soup of normal concentration, preserved 24 hours at 25 ℃ thermostatic chambers.Meloidogyne incognita total individual number (A) in microscopically investigation soup and in soup 15 seconds motionless individual number (B).In addition, for the check plot that replaces soup with distilled water, investigation total individual number (A ') and 15 seconds motionless individual number (B ').Obtain motionless rate by such numerical value according to following formula.The results are shown in the 1st table～the 12 table.
Motionless rate (%)=[1-{ (1-B/A)/(1-B '/A ')] * 100
In addition, by calculating the theoretical value (%) of motionless rate by the cobly formula.
Motionless rate (%) is than under the high situation of theoretical value (%), and Pesticidal composition of the present invention has synergistic effect for preventing and kill off nematode.(%) is shown in () of table 2～table 13 simultaneously with the theoretical value under the same case.
The motionless rate of [table 2] Meloidogyne incognita (%)
The motionless rate of [table 3] Meloidogyne incognita (%)
The motionless rate of [table 4] Meloidogyne incognita (%)
The motionless rate of [table 5] Meloidogyne incognita (%)
The motionless rate of [table 6] Meloidogyne incognita (%)
The motionless rate of [table 7] Meloidogyne incognita (%)
The motionless rate of [table 8] Meloidogyne incognita (%)
The motionless rate of [table 9] Meloidogyne incognita (%)
The motionless rate of [table 10] Meloidogyne incognita (%)
[table 11] the 10th table motionless rate of Meloidogyne incognita (%)
The motionless rate of Meloidogyne incognita (%)
The motionless rate of [table 13] Meloidogyne incognita (%)
Test example 2
With 1: 10 ratio water is joined fully stirring in the onion powder.With 8cm filter paper be dipped in the powder suspension air-dry after, with 3 overlapping 8cm culture dishes of putting into, add the organophosphorus compound of 2ml normal concentration and/or the soup of bactericide.Close the lid behind 50 sufficient root mites of thorn of each culture dish inoculation, leave standstill at 25 ℃ of thermostatic chambers.Examine under a microscope live body after 48～72 hours, carry out asking lethality after life and death is judged.
Lethality (%)={ 1-(existence a number/put a worm number) } * 100
In addition, can calculate the theoretical value (%) of lethality by the cobly formula.The experimental value of lethality (%) is than under the high situation of theoretical value (%), and Pesticidal composition of the present invention has synergistic effect for preventing and kill off the such pest of the sufficient root mite of thorn.
At organophosphorus compound: in the scope of bactericide=1: 100～100: 1, the experimental value of lethality has shown the value higher than theoretical value
Test example 3
Mixed soil 3: sand 1: saprophage soil 1 preparation test soil, the 200g soil of packing in each 300ml plastic container mixes organophosphorus compound and/or bactericide with the concentration interpolation of stipulating.Put 10 chafers larva of hatching just in each container, after 25 ℃ of thermostatic chambers left standstill, the soil that scatter was asked lethality behind the larva number of counting existence to dark down.
Lethality (%)={ 1-(existence a number/put a worm number) } * 100
In addition, can calculate the theoretical value (%) of lethality by the cobly formula.Lethality (%) is than under the high situation of theoretical value (%), and Pesticidal composition of the present invention has synergistic effect for preventing and kill off the such pest of chafer.
At organophosphorus compound: in the scope of bactericide=1: 1000～1: 6, the experimental value of lethality (%) has shown the value higher than theoretical value.
Test example 4
The organophosphorus compound that contains normal concentration of preparation and/or the PSA medium of bactericide are poured in the 8cm culture dish, rhizoctonia (Rhizoctonia), pythium bacterium (Pythium) and the sickle spore bacterium (Fusarium) that to cultivate on other medium with the 6mm cork borer cut the medium that becomes to contain mycelia, are transplanted on the medium that contains medicament.After 25 ℃ of thermostatic chambers were cultivated 4～7 days, the mycelia of measuring growth was long, asks mycelial growth inhibition rate.
Mycelial growth inhibition rate (%)={ 1-(the mycelial growth amount of the mycelial growth amount/non-processor in chemicals treatment district) } * 100
In addition, can calculate the theoretical value (%) of mycelial growth inhibition rate by the cobly formula.Mycelial growth inhibition rate (%) is than under the high situation of theoretical value (%), and Pesticidal composition of the present invention has synergistic effect for preventing and kill off the disease bacterium.
At organophosphorus compound: in the scope of bactericide=1: 100～10000: 1, the experimental value of mycelial growth inhibition rate has shown the value higher than theoretical value
Test example 5
Mixed paddy field soil 4 with 3 liters: the sandy loam of sand 1 is packed in the 1/5000a basin, adds organophosphorus compound and/or the bactericide that mixes with the concentration of regulation.Behind 20 days of firm interpolation medicament and after 40 days,, fully mix back transplanting tomato (kind: seedling powerful Mi Shou) with being inoculated in each basin of 500cc by Meloidogyne incognita (Meloidogyne incognita) contaminated soil.The root nodule of transplanting 51 days " Invest, Then Investigate " nematodes the degree of giving birth to (0～100% give birth to).The results are shown in table 14.In addition, should unify to transplant day, according to carrying out the mixing of sandy loam and medicament in advance from transplanting the date that day begins to retrodict.In addition, can calculate the theoretical value (%) that root nodule the degree of giving birth to by the cobly formula.Root nodule the degree of giving birth to (%) than under the low situation of theoretical value (%), and Pesticidal composition of the present invention has synergistic effect for preventing and kill off nematode.(%) is illustrated in () of table 14 simultaneously with the theoretical value under the above-mentioned situation.
[table 14] root nodule the degree (%) of giving birth to
Test example 6
In the 1/1000a plastic basin, mix, sow 7 cucumber (kinds: seed northing) by behind the medicament of Meloidogyne incognita (Meloidogyne incognita) and sickle spore bacterium (Fusarium) contaminated soil and ormal weight.The sowing beginning in investigation cucumber fusarium axysporum diseased plant rate, was cut off the stem of the 2nd～the 3rd internode of cucumber after 66 days, according to following standard the browning degree of conduit was carried out for 5 stages and estimated, and calculated killed index according to evaluation result.The results are shown in the table 15 like this.In addition, test repeats with 3 times.In addition, can calculate the theoretical value of diseased plant rate and killed index by the cobly formula.Diseased plant rate and killed index are than under the low situation of theoretical value, and Pesticidal composition of the present invention has synergistic effect for preventing and kill off cucumber class fusarium wilt.Theoretical value under the above-mentioned situation (%) is merged in () that is shown in Table 15.
A: whole strain is withered
B: 2/3 above brown stain of conduit
C: 1/2 left and right sides brown stain of conduit
D: 1/3 following brown stain of conduit
E: conduit does not have brown stain
N: investigation strain number (being 7 under the situation of this test)
Killed index=(4A+3B+2C+1D)/4N} * 100
[table 15] cucumber fusarium axysporum morbidity diseased plant rate
| Reagent agent (Kg a.i./ha) | Diseased plant rate (%) | Killed index |
| ??I-a(3) | ??100 | ??82 |
| ??II-a(3) | ??100 | ??100 |
| ??I-a(3)+II-a(3) | ?81(100) | ??61(82) |
| Non-processor | ?100 | ??100 |
Test example 7
(1) in the 1/1000a plastic basin, mixes by the dazomet fine granule (active ingredient II-h) of Meloidogyne incognita (Meloidogyne incognita) and sickle spore bacterium (Fusarium) contaminated soil and ormal weight, after 7 days and carry out exhaust in the soil after 10 days.
(2) after the operation of (1), the quantitative colophonate granule (active ingredient I-a) of hybrid regulatory and then 7 cucumber (kinds: seed northing) of sowing after 4 days in soil.
(3) sowing beginning is after 61 days, in investigation cucumber fusarium axysporum morbidity diseased plant rate, according to calculating killed index with the same method of test example 6.In addition, the root nodule of investigation nematode the degree of giving birth to (0～100% give birth to).The above results is shown in table 16.Test repeats with 3 times.
In order to compare, for the operation of not carrying out (1), in (2), handle the situation of soil and, carry out same test in the situation of the quantitative colophonate granule (active ingredient I-a) of hybrid regulatory in soil not after the operation of (1), in the operation of (2) with the colophonate granule (active ingredient I-a) of ormal weight.
[table 16] compound disease preventing iron test
Formulation example 1
(1) silica particulate (East Sea industry system) 98.3 weight portions
(2) fluazinam 0.2 weight portion
(3) colophonate 1.0 weight portions
(4) epoxy linseed oil 0.5 weight portion
Heating blends with above-mentioned (2)～(4) is sprayed on (1) and makes granule.
Formulation example 2
(1) silica particulate (East Sea industry system) 97.7 weight portions
(2) fluazinam 1.0 weight portions
(3) colophonate 1.0 weight portions
(4) epoxy linseed oil 0.3 weight portion
Heating blends with above-mentioned (2)～(4) is sprayed on (1) and makes granule.
Formulation example 3
(1) silica particulate (East Sea industry system) 98.3 weight portions
(2) fluazinam 0.2 weight portion
(3) colophonate 1.0 weight portions
(4) epoxy linseed oil 0.5 weight portion
Heating blends with above-mentioned (2)～(4) is sprayed on (1) and makes granule
Formulation example 4
(1) fluazinam 20 weight portions
(2) colophonate 10 weight portions
(3) ソ Le Port one ト 3661S (eastern nation chemistry system) 10 weight portions
(4) イ プ ゾ one Le 150 (bright dipping petrochemistry system) 60 weight portions
Mixed dissolution above-mentioned (1)～(4) is made emulsion.
In addition, as the disclosed content of specification of the present invention, be incorporated herein the specification full content of advocating Japanese patent application 2004-015667 number (on January 23rd, 2004 is to the application of Japan Patent office) of basis for priority as the application.
Claims (11)
1. a Pesticidal composition is characterized in that, it contains O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate, and fluazinam and/or benomyl are as active ingredient.
2. Pesticidal composition as claimed in claim 1, O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate and fluazinam and/or benomyl to contain proportional be 1: 10000～10000: 1 by weight.
3. the method for control of a pest is characterized in that, with O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate, and fluazinam and/or benomyl act on pest as active ingredient.
4. the method for control of pest as claimed in claim 3, made O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate, and fluazinam and/or benomyl act on simultaneously, or make any effect of O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate and fluazinam and/or benomyl, then make another kind of effect again.
5. as the method for control of claim 3 or 4 described pests, make the ratio of O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate and fluazinam and/or benomyl count 1: 10000～10000: 1 by weight and act on.
6. as the method for control of wantonly 1 described pest of claim 3～5, the concentration that makes above-mentioned active ingredient is 0.1～10000ppm effect.
7. as the method for control of wantonly 1 described pest of claim 3～6, pest is the pest that lives in soil and/or the seed.
8. as the method for control of wantonly 1 described pest of claim 3～6, pest is the insect that lives in soil and/or the seed.
9. as the method for control of wantonly 1 described pest of claim 3～6, pest is the plant parasitic nematodes class.
10. as the method for control of wantonly 1 described pest of claim 3～9, the plant parasitic nematodes class is at least a kind that is selected from root-knot nematode, packing nematode, pratylenchus, the white sharp nematode of paddy rice, strawberry bud nematode and the pine wood nematodes.
11. as the method for control of wantonly 1 described pest of claim 3～10, it is with O-ethyl-S-n-pro-pyl (2-cyanogen imido grpup-3-ethyl-imidazoline-1-yl) thiophosphate, and fluazinam and/or benomyl are handled soil and/or seed.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP015667/2004 | 2004-01-23 | ||
| JP2004015667 | 2004-01-23 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800030665A Division CN1909781B (en) | 2004-01-23 | 2005-01-20 | Noxious organism controlling composition and method for controlling the noxious organism |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101810194A true CN101810194A (en) | 2010-08-25 |
| CN101810194B CN101810194B (en) | 2012-04-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101619627A Expired - Fee Related CN101810194B (en) | 2004-01-23 | 2005-01-20 | Pest control composition and method of controlling pest |
| CN2005800030665A Expired - Fee Related CN1909781B (en) | 2004-01-23 | 2005-01-20 | Noxious organism controlling composition and method for controlling the noxious organism |
| CN2011101449527A Expired - Fee Related CN102265898B (en) | 2004-01-23 | 2005-01-20 | Pest control composition and method of controlling pest |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800030665A Expired - Fee Related CN1909781B (en) | 2004-01-23 | 2005-01-20 | Noxious organism controlling composition and method for controlling the noxious organism |
| CN2011101449527A Expired - Fee Related CN102265898B (en) | 2004-01-23 | 2005-01-20 | Pest control composition and method of controlling pest |
Country Status (5)
| Country | Link |
|---|---|
| JP (2) | JP5301603B2 (en) |
| KR (2) | KR20060135717A (en) |
| CN (3) | CN101810194B (en) |
| TW (3) | TWI418301B (en) |
| WO (1) | WO2005070206A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105851054A (en) * | 2016-04-16 | 2016-08-17 | 广东中迅农科股份有限公司 | Pesticide composition containing fluazinam and fosthiazate |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101953341A (en) * | 2010-06-03 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Sterilizing composition |
| CN102258051B (en) * | 2011-05-25 | 2013-08-14 | 江苏龙灯化学有限公司 | Composition and method for preventing and removing pests |
| KR102015382B1 (en) * | 2012-07-03 | 2019-08-28 | 이시하라 산교 가부시끼가이샤 | Pesticidal composition and pest control method |
| JP2014097975A (en) * | 2012-10-16 | 2014-05-29 | Sumitomo Chemical Co Ltd | Method of controlling sweet potato fusarium wilt |
| CN103210955A (en) * | 2013-03-24 | 2013-07-24 | 广东中迅农科股份有限公司 | Thiazole phosphine and metalaxyl granule and preparation method thereof |
| CN103734176B (en) * | 2013-12-26 | 2015-06-10 | 山东康乔生物科技有限公司 | Insecticidal composition containing fipronil |
| CN103749529B (en) * | 2013-12-26 | 2016-04-13 | 山东康乔生物科技有限公司 | A kind of insecticidal and bactericidal composition |
| CN103734180B (en) * | 2013-12-30 | 2015-12-30 | 刘一平 | A kind of Fungicidal insecticidal composition containing sufluoxime |
| CN103704256A (en) * | 2013-12-30 | 2014-04-09 | 孙蒙蒙 | Sterilization insecticidal combination containing iprodione |
| CN103814947B (en) * | 2013-12-30 | 2016-08-17 | 青岛青知企业管理咨询有限公司 | A kind of Pesticidal combination containing chlorfenapyr |
| CN103749530B (en) * | 2013-12-30 | 2015-10-14 | 顾祥茂 | A kind of Pesticidal combination containing Avermectin |
| CN105918346A (en) * | 2016-06-24 | 2016-09-07 | 江苏省绿盾植保农药实验有限公司 | Rice seed treating agent containing fluazinam and fosthiazate and application thereof |
| JP7280803B2 (en) | 2019-10-23 | 2023-05-24 | 日鉄神鋼建材株式会社 | Spill prevention device |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS6052146B2 (en) * | 1979-12-25 | 1985-11-18 | 石原産業株式会社 | N-pyridylaniline compounds, their production methods, and pest control agents containing them |
| JPS60136590A (en) * | 1983-12-23 | 1985-07-20 | Ishihara Sangyo Kaisha Ltd | Organic phosphorous compound, insecticide, acaricide, and nematocide containing same |
| JPS60136500A (en) * | 1983-12-26 | 1985-07-19 | Hitachi Ltd | Control transmitter of remote supervisory and controlling device |
| JPH01238505A (en) * | 1988-03-18 | 1989-09-22 | Ishihara Sangyo Kaisha Ltd | Control agent of harmful animal |
| JPH0739430B2 (en) * | 1990-07-06 | 1995-05-01 | アグロカネショウ株式会社 | Organophosphorus compound, method for producing the same and insecticide, acaricide, nematicide containing the compound |
| EP0713485B1 (en) * | 1993-08-11 | 1998-04-15 | Bayer Ag | Thiocarbamoyl compounds as microbicides |
| JP4217991B2 (en) * | 1998-04-20 | 2009-02-04 | 富士工業株式会社 | Range hood with cleaning device |
| CN1298877A (en) * | 1999-12-03 | 2001-06-13 | 拜尔公司 | Tacca chantrieri andre ketonic internal ester and its use |
| JP2003081987A (en) * | 2001-09-06 | 2003-03-19 | Agro Kanesho Co Ltd | Imidazolidine derivative containing optically active organophosphorus group, method for producing the same and noxious animal controller containing the same as active ingredient |
-
2005
- 2005-01-20 CN CN2010101619627A patent/CN101810194B/en not_active Expired - Fee Related
- 2005-01-20 CN CN2005800030665A patent/CN1909781B/en not_active Expired - Fee Related
- 2005-01-20 KR KR1020067014810A patent/KR20060135717A/en not_active Application Discontinuation
- 2005-01-20 KR KR1020127010237A patent/KR101290948B1/en active IP Right Grant
- 2005-01-20 CN CN2011101449527A patent/CN102265898B/en not_active Expired - Fee Related
- 2005-01-20 WO PCT/JP2005/000709 patent/WO2005070206A1/en active Application Filing
- 2005-01-21 TW TW100110106A patent/TWI418301B/en not_active IP Right Cessation
- 2005-01-21 TW TW100125129A patent/TW201138636A/en not_active IP Right Cessation
- 2005-01-21 TW TW094101881A patent/TW200528028A/en not_active IP Right Cessation
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- 2011-04-05 JP JP2011083457A patent/JP5301603B2/en not_active Expired - Fee Related
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105851054A (en) * | 2016-04-16 | 2016-08-17 | 广东中迅农科股份有限公司 | Pesticide composition containing fluazinam and fosthiazate |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI373310B (en) | 2012-10-01 |
| KR101290948B1 (en) | 2013-07-29 |
| CN101810194B (en) | 2012-04-18 |
| CN1909781A (en) | 2007-02-07 |
| TW201138636A (en) | 2011-11-16 |
| TWI366439B (en) | 2012-06-21 |
| KR20060135717A (en) | 2006-12-29 |
| TW200528028A (en) | 2005-09-01 |
| JP2011140514A (en) | 2011-07-21 |
| WO2005070206A1 (en) | 2005-08-04 |
| JP5301603B2 (en) | 2013-09-25 |
| CN1909781B (en) | 2010-06-16 |
| JP2011140515A (en) | 2011-07-21 |
| TWI418301B (en) | 2013-12-11 |
| JP5369134B2 (en) | 2013-12-18 |
| CN102265898B (en) | 2013-11-06 |
| KR20120061986A (en) | 2012-06-13 |
| TW201124084A (en) | 2011-07-16 |
| CN102265898A (en) | 2011-12-07 |
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