TW200528028A - Pest control composition and method of controlling pest - Google Patents
Pest control composition and method of controlling pest Download PDFInfo
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- TW200528028A TW200528028A TW094101881A TW94101881A TW200528028A TW 200528028 A TW200528028 A TW 200528028A TW 094101881 A TW094101881 A TW 094101881A TW 94101881 A TW94101881 A TW 94101881A TW 200528028 A TW200528028 A TW 200528028A
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- pest control
- ethyl
- patent application
- control method
- pest
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
Abstract
Description
200528028 (1) 九、發明說明 【發明所屬之技術領域】 本發明係關於有效地同時防除各種害蟲與各種植物病 害之有害生物防除組成物。 【先前技術】 硫代仲丁基氧-乙基2 -鑛基-1，3 -噻嗤D定-3 -基硫代膦 酸酯係專利文獻1所揭示之化合物。氧-乙基-硫代正丙基 (2-氰亞胺基-3-甲基-咪唑啶-1-基）硫磷酸酯係專利文獻 2所揭示之化合物。S，S-二仲丁基氧-乙基二硫代磷酸係 專利文獻3所揭示之化合物。此等係作爲殺蟲、殺蟎、殺 線蟲劑有效成份之已知有機磷系化合物。然而並未知組合 特定的有機磷系化合物與特定的殺菌劑時，關於防除棲息 於土壤及/或種子中的害蟲，及土壤及/或種子傳染性植物 病害雙方，發揮相乘的效果。 專利文獻1 :美國專利第45 90 1 82號 專利文獻2 :美國專利第5405 96 1號 專利文獻3 :美國專利第45 3 5 077號 【發明內容】 發明所欲解決的課題 要求可防除線蟲類、根蟎等之棲息於土壤及/或種子 中的害蟲，及土壤及/或種子傳染性植物病害雙方，而且 比單獨個別防除，更相乘地強化防除雙方效果之有害生物 -4- 200528028 (2) 防除劑。 課題之解決手段 本發明者等爲解決此等課題而努力檢討的結果，由組 合特定的有機磷系化合物與特定的殺菌劑時，發現可得到 預期以上的效果，而完成本發明。 本發明係由下述要點而成者。 1、 以含有至少1種選自硫代仲丁基氧-乙基 2_羰 基-1，3-噻唑啶-3-基硫代膦酸酯、氧-乙基-硫代正丙基（2-氰亞胺基-3-甲基-咪唑啶-卜基）硫磷酸酯及S，S -二仲丁基 氧-乙基二硫代磷酸所成群之有機磷系化合物，以及至少 1種選自扶吉胺（Fluazinam )、免賴得（Benomyl )、甲 基立枯憐（Tolclofos-methyl)、滅達樂（Metalaxyl)、 蓋普丹（Captan)、依普同（Iprodione)、四氯異苯（ Chlorothalonil )、邁隆（Dazomet )、殺紋寧（ Hymexazole)、福多寧（Flutolanil)及維利黴素 （ Validamycin )所成群之殺菌劑爲有效成份爲特徵之有害生 物防除組成物。 2、 上述1記載之有害生物防除組成物中，上述有機 磷系化合物與上述殺菌劑之含有比率係重量比爲1 ·· 1 0000 至 10000 ： 1 ° 3、 以含有至少1種選自硫代仲丁基氧-乙基 2-羰 基-1,3-噻唑啶-3-基硫代膦酸酯、氧-乙基-硫代正丙基（2-氰亞胺基-3-甲基-咪唑啶-卜基）硫磷酸酯及S，S-二仲丁基 -5- 200528028 (3) 氧-乙基二硫代磷酸所成群之有機磷系化合物，以及至少 1種選自扶吉胺（Fluazinam)、免賴得（Benomyl)、甲 基_11 枯憐（Tolclofos-methyl)、滅達樂（Metalaxyl)、 ’ 蓋普丹（Captan)、依普同（Iprodione)、四氯異苯（200528028 (1) IX. Description of the invention [Technical field to which the invention belongs] The present invention relates to a pest control composition for effectively controlling various pests and various plant diseases simultaneously. [Prior art] Thio-sec-butyloxy-ethyl 2-mine-l, 3-thizone-didine-3 -ylthiophosphonate is a compound disclosed in Patent Document 1. Oxy-ethyl-thio-n-propyl (2-cyanoimido-3-methyl-imidazol-1-yl) thiophosphate is a compound disclosed in Patent Document 2. S, S-di-sec-butyloxy-ethyl dithiophosphoric acid is a compound disclosed in Patent Document 3. These are known organophosphorus compounds as active ingredients of insecticides, acaricides, and nematicides. However, it is unknown to combine a specific organophosphorus compound with a specific fungicide to control the pests inhabiting the soil and / or seeds and the soil and / or seed infectious plant diseases to achieve a synergistic effect. Patent Document 1: U.S. Patent No. 45 90 1 82 Patent Document 2: U.S. Patent No. 5405 96 No. 1 Patent Document 3: U.S. Patent No. 45 3 5 077 [Summary of the Invention] The problem to be solved by the invention requires the prevention of nematodes , Root mites, and other pests inhabiting the soil and / or seeds, as well as soil and / or seed infectious plant diseases, and are more effective than the individual control, and strengthen the control of the pests on both sides -4- 200528028 ( 2) Control agents. Means for Solving the Problems As a result of efforts by the present inventors to solve these problems, the present inventors have found that the above-mentioned effects can be obtained when a specific organophosphorus compound and a specific fungicide are combined, and the present invention has been completed. The present invention is made up of the following points. 1. To contain at least one member selected from the group consisting of thio-sec-butyloxy-ethyl 2-carbonyl-1,3-thiazolidine-3-ylthiophosphonate, oxy-ethyl-thio-n-propyl (2 -Cyanoimido-3-methyl-imidazolidine-phenyl) thiophosphate and S, S-di-sec-butyloxy-ethyldithiophosphoric acid group of organic phosphorus compounds, and at least one Selected from Fluazinam, Benomyl, Tolclofos-methyl, Metalaxyl, Captan, Iprodione, Tetrachloro Chlorothalonil, Dazomet, Hymexazole, Flutolanil, and Validamycin are a group of fungicides, which are pest control compositions characterized by active ingredients . 2. In the pest control composition according to the above 1, the content ratio of the organic phosphorus-based compound to the fungicide is a weight ratio of 1 ·· 10,000 to 10000: 1 ° 3. It contains at least one selected from the group consisting of thio Sec-Butyloxy-ethyl 2-carbonyl-1,3-thiazolidine-3-ylthiophosphonate, oxy-ethyl-thio-n-propyl (2-cyanimido-3-methyl- Imidazolidine-phenyl) thiophosphate and S, S-di-sec-butyl-5-200528028 (3) An organic phosphorus-based compound grouped by oxy-ethyl dithiophosphoric acid, and at least one selected from Fu Ji Fluazinam, Benomyl, Tolclofos-methyl, Metalaxyl, Captan, Iprodione, Tetrachloroisobenzene (
Chlorothalonil ) 、邁隆（Dazomet ) 、殺紋寧（ Hymexazole )、福多寧（Flutolanil )及維利黴素（ Validamycin )所成群之殺菌劑爲有效成份而作用於有害生 B 物爲特徵之有害生物之防除方法。 4、 上述3記載之有害生物之防除方法，其中使上述 有機磷系化合物與上述殺菌劑同時作用，或使上述有機磷 系化合物與上述殺菌劑中之某一種作用，接著再使另一種 作用。 5、 上述3或4記載之有害生物之防除方法中，使上 述有機磷系化合物與上述殺菌劑之比率係重量比成1 ·· 10000 至 10000: 1 而作用。 # 6、上述3至5中任一項記載之有害生物之防除方法 係使上述有效成份之濃度成0.1至10〇〇〇ppm而作用。 7、 上述3至6中任一項記載之有害生物之防除方法 中，有害生物係棲息於土壤及/或種子中的有害生物。 8、 上述3至6中任一項記載之有害生物之防除方法 中’有害生物係棲息於土壤及/或種子中的害蟲。 9、 上述3至9中任一項記載之有害生物之防除方法 中’有害生物係植物寄生性線蟲類。 1 0、上述3至6中任一項記載之有害生物之防除方法 -6 - 200528028 (4) ，植物寄生性線蟲類係至少1種選自根瘤線蟲類、黃金線 蟲類、根腐線蟲類、稻心枯線蟲、莓芽線蟲（ Nothotylenchus acris，Strawberry bud nematodes )及松材 線蟲(Pine wood nemotode ) 〇 n、上述3至l o中任一項記載之有害生物之防除方 法中，處理上述有機磷系化合物與上述殺菌劑於土壤及/ 或種子。 發明之功效 依據本發明，提供同時提高防除棲息於土壤及/或種 子中的害蟲之效果，及防除土壤及/或種子傳染性病害之 效果之嶄新的有害生物防除組成物及防除方法。 用以實施發明之最佳型態 對於硫代仲丁基氧-乙基 2 -羰基-1，3 -噻唑啶-3 -基硫 φ 代膦酸酯’存在光學異構物，除了消旋體以外，包含（-)體及（+ )體。消旋體之（R，S)-硫代仲丁基氧-乙基 • 2-羰基-1，3-噻唑啶-3-基硫代膦酸酯係已知一般名爲福賽絕 • ( Fosthiazate)之化合物。 氧-乙基-硫代正丙基（2 -氰亞胺基-3-甲基-咪唑啶-1-基）硫磷酸酯亦存在光學異構物，除了消旋體以外，包含 (一）體及（+ )體。 S，S-二仲丁基氧-乙基二硫代磷酸酯係已知一般名 爲克線丹（cadusafos)之化合物。 200528028 (5) 扶吉胺（Fluazinam)、免賴得（Benomyl)、甲基立 枯憐（Tolclofos-methyl)、滅達樂（Metalaxyl)、蓋普 丹（Captan)、依普同（Iprodione)、四氯異苯（ Chlorothalonil ) 、邁隆（Dazomet )、殺紋寧（ Hymexazole )、福多寧（Flutolanil)、維利黴素 （ Validamycin)之任一種皆爲殺蟲劑，記載於The Pesticide Manual (第 13 版；BRITISH CROP PROTECTION p COUNCIL )之化合物。 上述有機磷系化合物及殺菌劑之混合比率，通常重量 比爲 1: 10000 至 10000: 1，以 1: 1000 至 1 000 ： 1 爲宜 〇 本發明組成物係含有效成份以外之補助劑。有效成份 之配合比率係〇.〇5至75重量％即可。作爲補助劑，可舉 例如載體、乳化劑、懸濁劑、分散劑、展開劑、滲透劑、 濕潤劑、增黏劑、安定劑等，因應需要而可適當地添加。 φ 作爲載體，可分爲固體載體及液體載體，作爲固體載體， 可舉例如澱粉、活性碳、大豆粉、小麥粉、木粉、魚粉及 乳粉等之動植物粉末、滑石、陶土、膨潤土、碳酸鈣、沸 石、矽藻土、碳白、黏土、氧化鋁及硫黃粉末等之礦物性 粉末等，作爲液體載體，可舉例如水、甲醇及乙醇等之醇 類、丙酮、甲基乙基甲酮等之酮類、二噚烷及四氫呋喃等 之醚類、煤油及燈油等之脂肪族烴類、及二甲苯、三甲苯 、四甲苯、環己烷及溶劑石腦油等之芳香族烴類、氯仿、 氯苯等之鹵素化烴類、二甲基甲醯胺等之酸醯胺類、乙酸 -8- 200528028 (6) 乙酯、脂肪酸之甘油酯等之酯類、乙腈等之腈類、二甲亞 硕等之含硫化合物類。可使用各種界面活性劑爲乳化劑、 ’ 懸濁劑、分散劑、展開劑、滲透劑及濕潤劑等。另外，因 •應需要，可混用、倂用其他農藥，例如殺蟲劑、殺蟎劑、 殺線蟲劑、殺菌劑、抗病毒劑、引誘劑、除草劑及植物成 長調整劑等，此時亦顯示更優異的效果。 本發明組成物係可製劑成乳劑、粉劑、微粒劑、粒劑 φ 、錠劑、水合劑、液劑、氣溶膠劑、糊劑、懸浮劑、乾懸 浮劑及微膠囊劑等之各種型態。其中係以乳劑、微粒劑、 水合劑、液劑粉劑、粒劑及錠劑等之型態爲宜，以乳劑、 微粒劑、水合劑及液劑等之型態最佳。乳劑中之適合配合 比率係有效成份爲5至75重量份，載體爲90至10重量 份及界面活性劑爲5至1 5重量份。另外，粉劑、粒劑及 錠劑中之適合配合比率係有效成份爲0.1至10重量份， 載體爲85至99重量份及界面活性劑爲0.5至5重量份。 • 實際上使用此等製劑時，可直接使用，或以水等之稀釋劑 稀釋成所定濃度而使用。 實施本發明組成物之有效濃度一般係以 〇· 1至 lOOOOppm爲宜，以1至lOOOppm尤佳。此等有效成份濃 度係依製劑的型態及使用方法、目的、時期、場所及害蟲 的發生狀況等而可適當地改變，每單位面積的使用量係每 10a，使用有效成份化合物約爲1至5000g，以10至 1 〇〇〇g爲宜。然而，特別情況下，亦可超出此等範圍。作 爲本發明組成物之使用方法，可舉例如土壤混合處理、植 -9- 200528028 (7) 穴處理、植溝處理或灌注處理，或對種子等之浸漬處理、 粉衣處理等。 本發明中，處理本發明組成物於有害生物之方法外， 包含同時處理上述有機磷系化合物及殺菌劑於有害生物之 方法、處理有機磷系化合物及殺菌劑中之某一種於有害生 物後，再處理另一種藥劑於有害生物之方法。 作爲可適用本發明之有害生物，可舉例如植物寄生性 線蟲類、等足類、鞘翅目害蟲、鱗翅目害蟲、腹足類、直 翅目害蟲、植物寄生性蟎類、薊馬目害蟲、雙翅目害蟲、 膜翅目害蟲、隱翅目害蟲、虱目害蟲及等翅目害蟲等之各 種害蟲或各種植物病害。尤其本發明係對於防除棲息於土 壤及/或種子中之有害生物有效。作爲棲息於土壤及/或種 子中之害蟲，可舉例如於土壤中加害農園藝作物及樹木等 之害蟲或加害農園藝作物或樹木的種子之害蟲等。可舉例 如上述之植物寄生性線蟲類、等足類、鞘翅目害蟲、鱗翅 目害蟲、腹足類、直翅目害蟲及植物寄生性蟎類等。其中 ’本發明係對於防除植物寄生性線蟲類最有效。 本發明可適用之各種害蟲之具體例如下所示。 作爲植物寄生性線蟲類，可舉例如蕃薯根瘤線蟲（ Meloidogyne incognita)等之根瘤線蟲類；馬鈴薯黃金線 蟲（Globoderarostochiensis)等之黃金線蟲類；北方根腐 線蟲（Pratylenchus penetrans )等之根腐線蟲類；稻心枯 線蟲；莓芽線蟲（Nothotylenchus acris，Strawberry bud nematodes )及松材線蟲（Pine wood nemotode)等。另外 -10- 200528028 (8) ，等足類係可舉例如土鱉、草鞋蟲等。 作爲鞘翅目害蟲，可舉例如西方玉米根蟲、南方玉米 ' 根蟲等之玉米根蟲類；金銅金龜、姬金龜等之金龜子類； •玉米象鼻蟲（maize weevil)、水稻水象鼻蟲、苜蓿葉象 鼻蟲、綠豆象鼻蟲等之象鼻蟲類；黃粉蟲、擬穀盜等之黑 粉蟲類、黃守瓜、黃條葉蚤、馬鈴薯甲蟲（Leptinotarsa decemlineata)等之金花蟲類；竊蠢類；節二十八星瓢蟲 φ 等之瓢蟲類；褐粉蠹類；大谷蠹類；長蠢類；褐毒隱翅蟲 等。 作爲鱗翅目害蟲，可舉例如斜紋夜蛾、黏蟲、大螟、 甜菜夜蛾、甘藍夜蛾等之夜蛾類；切根蟲、蕪菁夜蛾、擬 尺蠖屬、菸芽夜蛾屬及番茄夜蛾屬等之夜蛾類；二化螟蟲 、水稻縱捲葉蟲、歐洲玉米螟、ParaPediasia teterrella、 Notarcha derogata、Plodia interpunctella 等之螟蛾類；紋 白蝶等之粉蝶類；茶姬捲葉蛾屬、桃折心蟲及蘋果袁蛾等 φ 之捲葉蛾類；桃蛀果蛾等之蛀果蛾類；桃葉潛蛾屬等之潛 蛾類；舞毒蛾屬、黃毒蛾屬等之毒蛾類；小菜蛾等之巢蛾 類。 .作爲腹足類，可舉例如蝸牛、蛞蝓等。 作爲直翅目害蟲，可舉例如螻蛄、蚱蜢、德國姬蠊、 黑褐家蠊、美洲蜚蠊、棕色蜚蠊及東方蜚蠊等。 作爲植物寄生性蟎類，可舉例如二點葉蟎、赤葉瞞、 柑桔葉蟎及根蟎等。 作爲薊馬目害蟲，可舉例如南黃薊馬、蔥薊馬、花薊 -11 - 200528028 (9) 馬等。 作爲雙翅目害蟲，可舉例如淡色庫蚊、三帶喙庫蚊等 之庫蚊類、搖蚊類、家蠅、大家蠅等之家蠅類、麗蠅類、 肉蠅類、夏廁蠅類、種蠅類及洋蔥種蠅等之花蠅類、果寳 蠅類、果蠅類、蛾蚋類、蚋類、虻類、螫蠅類、潛蠅類等 〇 作爲膜翅目害蟲，可舉例如蟻類、胡蜂類、蟻形蜂類 、黃翅菜葉蜂等之蜂類等。 作爲隱翅目害蟲，可舉例如人蚤等。 作爲虱目害蟲，可舉例如人虱及恥陰蝨等。 作爲等翅目害蟲，可舉例如黃胸散白蟻、家白蟻等。 作爲本發明可適用之各種植物病害，可舉例如土壤及 /或種子傳染性之植物病害。具體上如下所述者。 由Rosellinia菌所引起之各種病害，例如草地之葉腐 病（Rhizoctonia solani);萵首之裾枯病（Rhizoctonia solani);鬱金香之葉腐病（Rhizoctonia solani);甜菜、蕃 茄、茄子、小黃瓜、青椒、鴨兒芹、薔麥、飛燕草、秋葵 之苗立枯病（Rhizoctonia solani);鴨兒拜：、高麗菜之立 枯病 （Rhizoctonia solani );紅蘿蔔之根腐病 （ Rhizoctonia solani);薛草之腰折病（Rhizoctonia solani) ;菠菜、高麗菜之株腐病（Rhizoctonia solani);牛蒡之黑 斑病（Rhizoctonia solani);蘿蔔之龜裂褐變症（根腐病 ) (Rhizoctonia solani );Chlorothalonil), Dazomet, Hymexazole, Flutolanil, and Validamycin are effective ingredients that act on harmful biological substances. Biological control methods. 4. The pest control method according to the above 3, wherein the organic phosphorus-based compound and the fungicide are allowed to act simultaneously, or one of the organic phosphorus-based compound and the fungicide is allowed to act, and then the other is allowed to act. 5. In the method for controlling pests according to 3 or 4, the ratio of the organic phosphorus-based compound to the fungicide is a weight ratio of 1 ·· 10000 to 10000: 1. # 6. The pest control method according to any one of 3 to 5 above, the action of the concentration of the above-mentioned effective ingredient is 0.1 to 100,000 ppm. 7. In the pest control method described in any one of 3 to 6, the pest is a pest that inhabits soil and / or seeds. 8. The pest control method described in any one of 3 to 6 above, the 'pest is a pest that inhabits soil and / or seeds. 9. The method for controlling pests according to any one of 3 to 9 above, 'The pest is a plant parasitic nematode. 10. The pest control method described in any one of 3 to 6 above-200528028 (4), at least one species of plant parasitic nematodes is selected from the group consisting of root nodules, gold nematodes, root rot nematodes, In the method of controlling pests according to any one of the above 3 to lo, the above-mentioned organophosphorus system is treated in a method for controlling P. oryzae, Nothotylenchus acris (Strawberry bud nematodes), and Pine wood nemotode. Compounds and fungicides described above in soil and / or seeds. EFFECT OF THE INVENTION According to the present invention, a novel pest control composition and method for improving the effect of controlling pests inhabiting the soil and / or seeds and the effect of controlling infectious diseases of soil and / or seeds are provided. The best form for carrying out the invention is an optical isomer of thiosec-butyloxy-ethyl 2-carbonyl-1,3-thiazolidine-3 -ylthioφ phosphonate, except for the racemate In addition, it includes (-) body and (+) body. The (R, S) -thio-sec-butyloxy-ethyl racemate • 2-carbonyl-1,3-thiazolidine-3-ylthiophosphonate is known by the general name Fauciol • ( Fosthiazate). Oxy-ethyl-thio-n-propyl (2-cyanoimido-3-methyl-imidazol-1-yl) thiophosphate is also an optical isomer. In addition to the racemate, it contains (a) Body and (+) body. S, S-di-sec-butyloxy-ethyl dithiophosphate is a compound known by the general name cadusafos. 200528028 (5) Fluazinam, Benomyl, Tolclofos-methyl, Metalaxyl, Captan, Iprodione, Chlorothalonil, Dazomet, Hymexazole, Flutolanil, and Validamycin are all insecticides and are described in The Pesticide Manual ( 13th Edition; BRITISH CROP PROTECTION p COUNCIL). The mixing ratio of the above-mentioned organic phosphorus-based compound and bactericide is usually 1: 10000 to 10000: 1, and preferably 1: 1000 to 1,000: 1. The composition of the present invention contains supplements other than effective ingredients. The blending ratio of the effective ingredients may be from 0.05 to 75% by weight. Examples of the auxiliary agent include a carrier, an emulsifier, a suspending agent, a dispersant, a developing agent, a penetrating agent, a wetting agent, a tackifier, and a stabilizer, and they may be appropriately added according to need. φ As the carrier, it can be divided into solid carrier and liquid carrier. As the solid carrier, for example, animal and plant powders such as starch, activated carbon, soybean flour, wheat flour, wood flour, fish meal and milk powder, talc, clay, bentonite, carbonic acid, etc. Mineral liquids such as calcium, zeolite, diatomaceous earth, carbon white, clay, alumina and sulphur powder, etc., as liquid carriers, for example, alcohols such as water, methanol and ethanol, acetone and methyl ethyl ketone Ketones, ethers such as dioxane and tetrahydrofuran, aliphatic hydrocarbons such as kerosene and kerosene, and aromatic hydrocarbons such as xylene, xylene, tetramethylbenzene, cyclohexane, and solvent naphtha, Halogenated hydrocarbons such as chloroform and chlorobenzene, acid amines such as dimethylformamide, acetic acid-8-200528028 (6) ethyl esters, esters of fatty acid glycerides, nitriles such as acetonitrile, Dimethyl Yashuo and other sulfur-containing compounds. Various surfactants can be used as emulsifiers, suspension agents, dispersants, developing agents, penetrants, wetting agents, and the like. In addition, other pesticides, such as insecticides, acaricides, nematicides, fungicides, antivirals, attractants, herbicides, and plant growth regulators, can be mixed and used as needed. Show more excellent effect. The composition of the present invention can be formulated into various forms such as emulsions, powders, granules, granules φ, lozenges, hydration agents, liquids, aerosols, pastes, suspensions, dry suspensions and microcapsules. . Among them, the types of emulsions, granules, hydrates, liquid powders, granules, and lozenges are suitable, and the types of emulsions, granules, hydrates, and liquids are the best. The suitable blending ratio in the emulsion is 5 to 75 parts by weight of the active ingredient, 90 to 10 parts by weight of the carrier, and 5 to 15 parts by weight of the surfactant. In addition, suitable mixing ratios in powders, granules, and lozenges are 0.1 to 10 parts by weight of the active ingredient, 85 to 99 parts by weight of the carrier, and 0.5 to 5 parts by weight of the surfactant. • When these preparations are actually used, they can be used directly or diluted with a diluent such as water to a predetermined concentration. The effective concentration for implementing the composition of the present invention is generally from 0.1 to 1,000 ppm, particularly preferably from 1 to 1,000 ppm. The concentration of these active ingredients can be appropriately changed depending on the type of preparation and the method of use, purpose, time, place, and occurrence of pests, etc. The amount used per unit area is every 10a, and the use of active ingredient compounds is about 1 to 5000g, preferably 10 to 1000g. However, in special cases, these ranges can also be exceeded. As a method for using the composition of the present invention, there can be mentioned, for example, soil mixing treatment, planting -9-200528028 (7) hole treatment, ditch treatment or perfusion treatment, or immersion treatment of seeds and the like, and powder coating treatment. In the present invention, in addition to the method for treating the composition of the present invention to a pest, it includes a method for simultaneously treating the above-mentioned organophosphorus compound and a bactericide to a pest, and after treating one of the organophosphorus compound and a bactericide to a pest, Then another method of treating the pesticides. Examples of pests to which the present invention is applicable include plant parasitic nematodes, isopoda, coleoptera pests, lepidopteran pests, gastropods, orthoptera pests, plant parasitic mites, thrips pests, and diptera Order pests, hymenoptera pests, cryptoptera pests, lice pests and other pests such as pests or plant diseases. In particular, the present invention is effective for controlling pests inhabiting soil and / or seeds. Examples of the pests inhabiting the soil and / or seeds include pests that damage agricultural or horticultural crops and trees in the soil or pests that damage agricultural or horticultural crops or tree seeds. Examples include the aforementioned plant parasitic nematodes, isopoda, coleoptera pests, lepidoptera pests, gastropods, orthoptera pests, and plant parasitic mites. Of these, the present invention is most effective for controlling plant parasitic nematodes. Specific examples of various pests to which the present invention is applicable are shown below. As plant parasitic nematodes, for example, Meloidogyne incognita and other rhizobial nematodes; potato golden nematodes (Globoderarostochiensis) and other root nematodes; Pratylenchus penetrans and other root rot nematodes ; Xanthomonas oryzae; Nothotylenchus acris (Strawberry bud nematodes) and Pine wood nemotode; etc .; In addition, -10- 200528028 (8), the isopods can be, for example, earthworms, grasshoppers, etc. Examples of coleoptera pests include corn rootworms such as western corn rootworms and southern corn 'rootworms; chafers such as gold and copper beetle and phoenix beetle; maize weevil and rice water weevil , Alfalfa leaf weevil, green bean weevil and other weevil worms; yellow mealworm, gluten worm and other black mealworms, yellow melons, yellow stripe flea, potato beetle (Leptinotarsa decemlineata) Flowers and insects; Stealing stupids; Ladybirds such as the 28th star ladybug φ; Brown mealybugs; Otani salamanders; Long stupids; Brown poisonous winged worms and so on. Examples of Lepidoptera pests include Spodoptera litura, slimeworms, large slugs, Spodoptera exigua, Spodoptera exigua, and other noctuid moths; root-cutting worms, turnip nocturnal moths, Pseudospodoptera, Spodoptera litura, and tomato Nocturnal moths such as Spodoptera spp .; Diploidia spp., Rice leaf rollers, European corn borer, ParaPediasia teterrella, Notarcha derogata, Plodia interpunctella, etc .; moths such as white butterfly; sylphidae, peach fold Heartworm, apple moth, etc. φ leaf curl moths; peach fruit moths, etc .; laminae moths, such as peach leaf miner, genus gypsy moth, yellow poison moth, etc .; diamondback moth, etc. Moths. Examples of gastropods include snails and tadpoles. Examples of orthoptera pests include crickets, grasshoppers, German flycatchers, black-brown flies, American flies, brown flies, and eastern flies. Examples of plant parasitic mites include Tetranychus urticae, Red leaf hide, Tetranychus citrus, and root mite. Examples of thrips pests include southern yellow thrips, onion thrips, flower thrips -11-200528028 (9) horses and the like. Examples of diptera pests include Culex pipiens, Culex pipiens pallens, Culex pipiens, house mosquitoes, house flies, house flies, house flies, maggots, meat flies, and summer toilet flies. Species, species of flies and onion species of flies, fruit flies, fruit flies, moth pupae, pupae, pupae, pupae, larvae, etc. as hymenoptera pests, can be Examples include bees such as ants, wasps, ant bees, yellow-winged leaf bees, and the like. Examples of cryptoptera pests include human fleas. Examples of lice insects include human lice and pubic lice. Examples of isoptera pests include yellow-breasted termites and house termites. Various plant diseases applicable to the present invention include, for example, soil and / or seed infectious plant diseases. Specifically, it is as follows. Various diseases caused by Rosellonia, such as Rhizoctonia solani on grass; Rhizoctonia solani on lettuce; Rhizoctonia solani on tulip; beet, tomato, eggplant, gherkin, Green pepper, duck celery, rose wheat, delphinium, okra seedling blight (Rhizoctonia solani); Duck worship :, Rhizoctonia solani; Rhizoctonia solani ; Rhizoctonia solani; Rhizoctonia solani of spinach and cabbage; Rhizoctonia solani of burdock; Rhizoctonia solani (root rot) of radish );
Uromyces菌所引起之百合之鱗莖銹症（Uromyces -12- (10) 200528028 ho 1wayi) ;Lily bulbous rust caused by Uromyces (Uromyces -12- (10) 200528028 ho 1wayi);
Pythium菌所引起之各種病害，例如甜菜之苗立枯病 (Pythium debaryanum );蘇草之舞病（Pythium debaryanum);蕃前、小黃瓜、節子、青椒、哈密瓜、甜 瓜、西瓜、白瓜、南瓜之苗立枯病（Pythium vexans);草 地之紅燒病（Pythium aphanidermatum);蔬藺之根腐病（ Pythium aristosporum);薑、茗荷之根莖腐敗病（Pythium ulitimum ); F us arium菌所引起之各種病害，例如鬱金香之球根腐 敗病（Fusarium oxysporum);萄藭之乾腐病（Fusarium oxy sporum );草莓之萎黃病（Fusarium oxysporum);馬鈴 薯、蕃節之萎调病（Fusarium oxysporum);小黃瓜、蕃薯 之蔓割病 （Fusarium oxysporum);巴西利之立枯病 （Various diseases caused by Pythium, such as Pythium debaryanum; Pythium debaryanum; Fanqian, gherkin, knot, green pepper, cantaloupe, melon, watermelon, white melon, pumpkin Pythium vexans; Pythium aphanidermatum; Pythium aristosporum; Pythium ulitimum; Fus arium For example, Fusarium oxysporum of tulip; Fusarium oxy sporum; Fusarium oxysporum of strawberry; Fusarium oxysporum of potato and fan festival; Gherkin, Fusarium oxysporum; Basil's disease
Fusarium solani );洋蔥、辣韭之乾腐病（Fusarium oxysporum );Fusarium solani); Fusarium oxysporum;
Phytophthora菌所引起之各種病害，例如鳳梨之心腐 病（Phytophthora cinnamomi );刺嫩芽之立枯疫病（ Phytophthora cactorum);青椒、巴西利、非洲菊、宿根 滿天星、海芋、非洲堇、菸草之疫病（Phytophthora capsici);草莓之根腐病（Phytophthora fragariae);Various diseases caused by Phytophthora, such as Phytophthora cinnamomi; Phytophthora cactorum; Green pepper, Basili, Gerbera, Perennial star, Alocasia, Saintpaulia, Tobacco blight (Phytophthora capsici); Strawberry root rot (Phytophthora fragariae);
Verticillium菌所引起之各種病害，例如白菜之黃化 病 （Verticillium dahliae ); 茄子之半身萎调病 （ Verticillium dahliae ) ；Various diseases caused by Verticillium, such as Verticillium dahliae; Verticillium dahliae;
Thanatephorus菌所引起之甜菜之根腐病（ -13- 200528028 (11)Sugar beet root rot caused by Thanatephorus fungi (-13- 200528028 (11)
Thanatephorus cucumeris ) ;Thanatephorus cucumeris);
Rhizopu菌所引起之百合之莖腐病（Rhizopunecans)Lichen stem rot caused by Rhizopu fungus (Rhizopunecans)
Penicillium菌所引起之鬱金香之青黴病（peniciliium cyclopium ) ;Penicillium cyclopium caused by Penicillium;
Plasmodiophora菌所引起之高麗菜、白菜等之油菜科 蔬菜等之根瘤病（Plasmodiophora brassicae);Plasmodiophora caused by nodule disease of cabbage, cabbage and other vegetables of the rape family (Plasmodiophora brassicae);
Spongospora菌所引起之馬鈴薯之粉狀層化病（ Spongospora subterranea ) ;Spongospora subspnea caused by potato (Spongospora subterranea);
Rosellinia菌所引起之果樹、花木、茶之白紋羽病（ Rosellinia necatrix ) ；Rosellinia necatrix caused by Rosellinia fungus;
Sclerotium菌所引起之蔥、韭菜、款冬、菊篛、大豆 、菊、青椒之白絹病（Sclerotiumrolfsii)；Sclerotiumrolfsii caused by Sclerotium fungus, leeks, butterbur, chrysanthemum, chrysanthemum, soybean, chrysanthemum, green pepper
Colletotrichum 菌所引起之草莓之炭疽病 （Colletotrichum anthracnose caused by strawberry (
Colletotrichum acutaum ) ；Colletotrichum acutaum);
Polymyxa菌所引起之甜菜之叢根病（Polymyxa betae 媒介）；Beet bush root disease caused by Polymyxa bacteria (Polymyxa betae vector);
Botritis菌所引起之蔥之小菌核腐敗病（Botritis squamosa );Botritis squamosa caused by Botritis;
Helicobasidium菌所引起之果樹、花木、茶之紫紋羽 病(Helicobasidium mompa);Helicobasidium mompa caused by Helicobasidium bacteria in fruit trees, flowers and tea;
Ceratocystis菌所引起之蕃薯之黑斑病（Ceratocystis imbriata ) ；Ceratocystis imbriata caused by Ceratocystis;
Monosporascus菌所引起之哈密瓜之黑點根腐病（ -14-Monosporascus black spot root rot caused by cantaloupe (-14-
200528028 (12)200528028 (12)
Mono sporascus cannonballus ) ；Mono sporascus cannonballus);
Thielaviopsis 菌所引起之蔽草 Thielaviopsis basicola) ；Thielaviopsis basicola caused by Thielaviopsis;
Thantatporus 菌所引起之馬鈴薯 Thantatporus cucumeris ) ；Potato Thantatporus cucumeris caused by Thantatporus);
Thanatephorus 菌所引起之豌豆Peas caused by Thanatephorus
Thanatephorus cucumeris ) ；Thanatephorus cucumeris);
Gibberella菌所引起之水稻之徒長： fuj ikuro i) ;Gibberella fungus caused by rice: fuj ikuro i);
Sterpomyces 菌所引起之馬鈴薯 Sterpomyces scabies ) ;及 Pyricularia 菌戸 稻熱病（Pyricularia oryzae);等。 另外，本發明係適用於如例示以外之f 或種子傳染性之病害。 本發明組成物及方法係關於防除有害5 的作用。此作用係由各藥劑所具有防除各 無法預測的效果。可說本發明之有效性係W 劑，明顯地增強防除有害生物的效果，尤美 有害生物能力，並且具有賦予即效性的效果 【實施方式】 實施例 其次係記載本發明之實施例 之黑根病（ 之黑斑病（ 之莖腐病 （ n ( Gibberella 之層化病（ i引起之水稻之 多土壤傳染性 物’具有協问 病害蟲特性所 單獨使用各藥 防除土壤中之 -15- 200528028Sterpomyces scabies caused by Sterpomyces); and Pyricularia oryzae; etc. In addition, the present invention is applicable to f or seed infectious diseases other than those exemplified. The composition and method of the present invention are related to the action of preventing harmful 5. This effect is due to the unpredictable effects of each agent. It can be said that the effectiveness of the present invention is the W agent, which obviously enhances the pest control effect, especially the ability of pest control, and has the effect of imparting immediate effect. [Embodiment] The embodiment is followed by the black recording of the embodiment of the present invention. Root disease (black spot disease) (stem rot (Gibberella stratified disease) (multiple soil infectious agents caused by rice) have the characteristics of disease and insect pests, and each drug is used alone to prevent -15- 200528028
(13) 〔表1〕 一般名或化學名 化合物 No. [I]有機磷系化合物 福賽絕 I - a 氧-乙基-硫代正丙基（2-氰亞胺基-3-甲基-咪唑啶-1- I-b 基）硫磷酸酯：美國專利第5405 96 1號所記載之化合物 克綠丹 I-c [Π]殺菌劑 扶吉胺 II-a 免懶得 Il-b 甲基立枯磷 II-c 滅達樂 Il-d 蓋普丹 Il-e 依普同 II-f 四氯異苯 II-g 邁隆 Il-h 殺紋寧 Il-i 福多寧 n-j 維利黴素 Il-k -16- 200528028 (14) 試驗例1 調整所定濃度之藥液中，浸漬處理2 0 0至2 5 0隻蕃薯 根瘤線蟲2期幼蟲，於25 °C的恆溫室保存24小時。調查 顯微鏡下，藥液中之蕃薯根瘤線蟲總數（A )及藥液中j 5 秒鐘未活動的個數（B )。另外，調查使用蒸I留水以取代 藥液之對照區，調查總數（A’ ）及1 5秒鐘未活動的個數 (B ’ )。由此等値，依下式求取運動阻礙率。結果如第 1表至第1 2表所示。 運動阻礙率（％ )= [1 — {(1 — B/A)/(B’ /A’ ）}]X100 另外，由Corby式計算運動阻礙率之理論値（％ )。 運動阻礙率（％ )若比理論値（％ )高時，本發明之有害 生物防除組成物係具有關於防除線蟲之相乘效果。此時之 理論値（％ ) —倂表示於第1表至第12表之（）內。 〔表2〕(13) [Table 1] General name or chemical name Compound No. [I] Organophosphorus compound Fosazone I-a Oxy-ethyl-thio-n-propyl (2-cyanimido-3-methyl) -Imidazolidine-1-Ib) phosphorothioate: the compound described in US Patent No. 5405 96 1 glutan Ic [Π] bactericide Fugillamine II-a not too lazy to get Il-b methyllitrazine II -c Methalene Il-d Gaiptan Il-e Iptomide II-f Tetrachloroisobenzene II-g Myron Il-h Fenneline Il-i Fodoinine nj Verimycin Il-k- 16- 200528028 (14) Test Example 1 In the medicinal solution adjusted to a predetermined concentration, 200 to 250 second stage larvae of the potato root nodule nematode were immersed and stored in a constant temperature room at 25 ° C for 24 hours. Under the microscope, the total number of A. nematodes in the medicinal solution (A) and the number of inactivity in the medicinal solution for 5 seconds (B). In addition, the investigation used distilled water to replace the control area of the medicinal solution, and the total number (A ') and the number of inactive 15 seconds (B') were investigated. From this, the motion obstruction rate is obtained by the following formula. The results are shown in Tables 1 to 12. Movement obstruction rate (%) = [1 — {(1 — B / A) / (B ’/ A’)}] X100 In addition, the theoretical 値 (%) of the movement obstruction rate is calculated by the Corby formula. When the motion obstruction rate (%) is higher than the theoretical value (%), the harmful biological control composition of the present invention has a synergistic effect on the control of nematodes. The theoretical 値 (%)-at this time is shown in () of Tables 1 to 12. 〔Table 2〕
第1表蕃薯根瘤線蟲運動阻礙率(%) [I-a] 1 0 p p m 5.0 p p m 2.5 p p m 1.2 5 p p m 0.6 3 p p m Oppm [Π-e] 1 0 0 0 p p m 100.0 (98.0) 93.6 (92.5) 93.5 (84.3) 56.4 (37.9) 54.8 (37.9) 10.3 Oppm 97.8 9 1.6 82.5 30.8 30.8 0 17- (15) (15)200528028 〔表3〕 第2表蕃薯根瘤線蟲運動阻礙率（％) [I-a] 1 Oppm 5 . Oppm 2.5 p p m 1.2 5 p p m 0.6 3 ppm Oppm [II-a] 5 0 Oppm 100.0 (97.8) 100.0 (91.6) 100.0 (82.5) 100.0 (30.8) 5 1.7 (30.8) 2.8 Oppm 97.8 91.6 82.5 30.8 30.8 0Table 1 Movement inhibition rate of sweet potato root nodule nematodes (%) [Ia] 10 ppm 5.0 ppm 2.5 ppm 1.2 5 ppm 0.6 3 ppm Oppm [Π-e] 1 0 0 0 ppm 100.0 (98.0) 93.6 (92.5) 93.5 ( 84.3) 56.4 (37.9) 54.8 (37.9) 10.3 Oppm 97.8 9 1.6 82.5 30.8 30.8 0 17- (15) (15) 200528028 [Table 3] Table 2 Sweet potato rhizobium nematode movement inhibition rate (%) [Ia] 1 Oppm 5. Oppm 2.5 ppm 1.2 5 ppm 0.6 3 ppm Oppm [II-a] 5 0 Oppm 100.0 (97.8) 100.0 (91.6) 100.0 (82.5) 100.0 (30.8) 5 1.7 (30.8) 2.8 Oppm 97.8 91.6 82.5 30.8 30.8 0
〔表4〕 第3表蕃薯根瘤線蟲運動阻礙率（％) [I-a] 1 0 p p m 5 . Oppm 2.5 p p m 1.2 5 p p m 0.6 3 ppm Oppm [II-c] 1 OOOppm 100.0 (97.9) 100.0 (91.9) 100.0 (83.1) 100.0 (33.2) 77.1 (33.2) 3.4 Oppm 97.8 91.6 82.5 30.8 30.8 0[Table 4] Table 3 Sweet potato rhizobium nematode movement obstruction rate (%) [Ia] 10 ppm 5. Oppm 2.5 ppm 1.2 5 ppm 0.6 3 ppm Oppm [II-c] 1 OOOppm 100.0 (97.9) 100.0 (91.9) 100.0 (83.1) 100.0 (33.2) 77.1 (33.2) 3.4 Oppm 97.8 91.6 82.5 30.8 30.8 0
〔表5〕 第4表蕃薯根瘤線蟲運動阻礙率（％) [I-a] 1 0 p p m 5.0 p p m 2.5 p p m 1.2 5 p p m 0.6 3 ppm Oppm [II-b] 2 5 Oppm 100.0 (92.7) 100.0 (88.5) 89.7 (78.8) 67.1 (52.4) 48.2 (449) 12.1 Oppm 91.7 86.9 75.9 45.8 37.3 0 -18- 200528028 (16) 〔表6〕 第5表蕃薯根瘤線蟲運動阻礙率（％) [I-b] 1 Oppm 5 . Oppm 2.5 ppm Oppm [II-c] 1 OOOppm 97.8 94.0 (93.5) 91.4 (70.9) 3.4 Oppm 100.0 93.3 69.9 0[Table 5] Table 4 Sweet potato rhizobial nematode movement inhibition rate (%) [Ia] 10 ppm 5.0 ppm 2.5 ppm 1.2 5 ppm 0.6 3 ppm Oppm [II-b] 2 5 Oppm 100.0 (92.7) 100.0 (88.5) 89.7 (78.8) 67.1 (52.4) 48.2 (449) 12.1 Oppm 91.7 86.9 75.9 45.8 37.3 0 -18- 200528028 (16) [Table 6] Table 5 Potato rhizobium nematode movement inhibition rate (%) [Ib] 1 Oppm 5 Oppm 2.5 ppm Oppm [II-c] 1 OOOppm 97.8 94.0 (93.5) 91.4 (70.9) 3.4 Oppm 100.0 93.3 69.9 0
〔表7〕 第6表蕃薯根瘤線蟲運動阻礙率（％) [I-b] 1 Oppm 5 . Oppm 2.5 ppm Oppm [II-c] 5 0 Oppm 100.0 (100.0) 100.0 (93.3) 92.1 (69.9) 0 Oppm 100.0 93.3 69.9 0[Table 7] Table 6 Sweet potato rhizobial nematode movement inhibition rate (%) [Ib] 1 Oppm 5. Oppm 2.5 ppm Oppm [II-c] 5 0 Oppm 100.0 (100.0) 100.0 (93.3) 92.1 (69.9) 0 Oppm 100.0 93.3 69.9 0
〔表8〕 第7表蕃薯根瘤線蟲運動阻礙率（％) [I-b] 1 Oppm 5.0 p p m 2.5 p p m 1.2 5 p p m 0.6 3 ppm Oppm [H-b] 2 5 Oppm 100.0 (85.5) 94.3 (84.5) 7 1.1 (49.3) 53.1 (43.4) 37.1 (28.5) 12.1 Oppm 83.5 82.4 42.3 35.6 18.7 0 -19- (17) (17)200528028 〔表9〕 第8表蕃薯根瘤線蟲運動阻礙率（％) [I-c] 1 0 p p m 5.0 p p m 2.5 p p m 1.2 5 ppm Oppm [II-b] 2 5 Oppm 100.0 (96.2) 97.0 (87.4) 70.6 73.5 (48.8) 12.1 Oppm 95.7 85.7 70.3 41.8 0[Table 8] Table 7 Sweet potato rhizobium nematode movement inhibition rate (%) [Ib] 1 Oppm 5.0 ppm 2.5 ppm 1.2 5 ppm 0.6 3 ppm Oppm [Hb] 2 5 Oppm 100.0 (85.5) 94.3 (84.5) 7 1.1 ( 49.3) 53.1 (43.4) 37.1 (28.5) 12.1 Oppm 83.5 82.4 42.3 35.6 18.7 0 -19- (17) (17) 200528028 [Table 9] Table 8 Sweet potato rhizobium nematode movement obstruction rate (%) [Ic] 1 0 ppm 5.0 ppm 2.5 ppm 1.2 5 ppm Oppm [II-b] 2 5 Oppm 100.0 (96.2) 97.0 (87.4) 70.6 73.5 (48.8) 12.1 Oppm 95.7 85.7 70.3 41.8 0
〔表 10〕 第9表蕃薯根瘤線蟲運動阻礙率（％) [I-c] 1 0 p p m 5 . Oppm 2.5 p p m 1 . 2 5 ppm Oppm [H-e] 1 0 0 Oppm 100.0 (96.2) 90.1 (87.2) 72.9 49.4 (48.0) 10.6 Oppm 95.7 85.7 70.3 41.8 0[Table 10] Table 9 Sweet potato rhizobial nematode movement obstruction rate (%) [Ic] 10 ppm 5. Oppm 2.5 ppm 1. 2.5 ppm Oppm [He] 1 0 0 Oppm 100.0 (96.2) 90.1 (87.2) 72.9 49.4 (48.0) 10.6 Oppm 95.7 85.7 70.3 41.8 0
〔表1" 第1 0表蕃薯根瘤線蟲運動阻礙率（％) [I-c] 1 Oppm 5 . Oppm 2.5 p p m 1.2 5 ppm Oppm [II-c] 1 OOOppm 100.0 (96.4) 92.1 (88.1) 79.7 (75.3) 37.6 16.7 Oppm 95.7 85.7 70.3 41.8 0 -20- (18)200528028 [I - c 1 1 0 p p m 5.0 p p m 2.5 p p m 1.2 5 ppm Oppm [Π-a] 5 OOppm 100.0 (95.9) 100.0 (86.4) 75.9 (71.7) 60.1 (44.5) 4.7 Oppm 95.7 85.7 70.3 4 1.8 0[Table 1 " Table 10 Sweet potato rhizobia nematode movement obstruction rate (%) [Ic] 1 Oppm 5. Oppm 2.5 ppm 1.2 5 ppm Oppm [II-c] 1 OOOppm 100.0 (96.4) 92.1 (88.1) 79.7 (75.3 ) 37.6 16.7 Oppm 95.7 85.7 70.3 41.8 0 -20- (18) 200528028 (I-c 1 1 0 ppm 5.0 ppm 2.5 ppm 1.2 5 ppm Oppm [Π-a] 5 OOppm 100.0 (95.9) 100.0 (86.4) 75.9 (71.7 ) 60.1 (44.5) 4.7 Oppm 95.7 85.7 70.3 4 1.8 0
〔表 12〕 第1 1表蕃薯根瘤線蟲運動阻礙率（％) [I-cl 2 Oppm 1 Oppm 5.0 p p m 1.2 5 ppm Oppm [Π-d] 2 5 Oppm 100.0 100.0 99.2 58.9 4.1 (100.0) (96.5) (90.5) (48.3) Oppm 100.0 96.3 90.1 46.1 0〔Table 12〕 Table 11 Sweet potato rhizobial nematode movement obstruction rate (%) [I-cl 2 Oppm 1 Oppm 5.0 ppm 1.2 5 ppm Oppm [Π-d] 2 5 Oppm 100.0 100.0 99.2 58.9 4.1 (100.0) (96.5 ) (90.5) (48.3) Oppm 100.0 96.3 90.1 46.1 0
〔表 1 3〕 第1 2表蕃薯根瘤線蟲運動阻礙率（％) 試驗例2 於洋蔥粉末中，以1 : 1 〇的比率加入水，充份地攪拌 。將8 cm的濾紙浸漬於粉末懸濁液而風乾後，重疊3張放 入8cni培養皿’加入2nil之所疋濃度之有機鱗系化合物及 /或殺菌劑之藥劑。每個培養皿中接種50隻之根滿雌成蟲 後加蓋，靜置25 °C之恆溫室。於48至72小時後，於實體 顯微鏡下觀察’進行生死判定’而求出死蟲率。 死蟲率（％)=丨1—(生存數/放入蟲數）} χ100 -21 - 200528028 (19) 另外’可由Corby式計算死蟲率之理論値（％ )。死 蟲率之實驗値（％ )若比理論値（％ )高時，本發明之有 害生物防除組成物係具有關於防除根蟎有害生物之相乘效 果。 有機磷系化合物：殺菌劑=1 : 1 0 0至1 〇 0 : 1之範圍 內’顯示死蟲率之實驗値爲比理論値高之値。 g 試驗例3 作成混合壤土 3 :砂土 1 :腐植土 1之試驗土壤，各 放入200g之土壤於3 00ml之塑膠製容器，以所定濃度添 加混合有機磷系化合物及/或殺菌劑。各放入丨〇隻剛孵化 後之金龜子幼蟲，於黑暗下之25 °C的恆溫室中靜置5至 1〇天後’解體土壤，計數生存之幼蟲數，而求出死蟲率。 死蟲率（％) = { 1—(生存數/放入蟲數）} χΙΟΟ 另外’可由Corby式計算死蟲率之理論値（％ )。死 φ 蟲率（％ )若比理論値（％ )高時，本發明之有害生物防 除組成物係具有關於防除金龜子之有害生物之相乘效果。 有機磷系化合物：殺菌劑=1 : 1 〇 〇 〇至1 : 6之範圍內 ’顯示死蟲率之實驗値爲比理論値高之値。 試驗例4 倒入調整含有機磷系化合物及/或殺菌劑至所定濃度 之PAS培養基於8cm培養皿，將於其他培養基上所增殖 之 Rhizoctonia 菌、Pythium 菌及 Fusarium 菌，以 6mm 之 -22- 200528028 (20) 打孔器切取含有菌絲之培養基，移植於含藥劑之培養基。 於25 °C之恆溫室中，培養4至7天後，測定伸長之菌絲長 度，求出菌絲伸長阻礙率。 菌絲伸長阻礙率（％ ) = { 1 — （藥物處理區之菌絲 伸長量/無處理之菌絲伸長量）} xl 〇〇 另外，可由C 〇 r b y式計算菌絲伸長阻礙率之理論値（ % )。菌絲伸長阻礙率（％ )若比理論値（％ )高時，本 B 發明之有害生物防除組成物係具有關於防除病害菌之相乘 效果。 有機磷系化合物：殺菌劑=1 : 100至1 0000 : 1之範 圍內，顯示菌絲伸長阻礙率之實驗値爲比理論値高之値。 試驗例5 將3公升之混合水田土 4 :砂1之砂壤土，放入 1 /5 000a缽中，以所定濃度添加混合有機磷系化合物及/或 φ 殺菌劑。剛添加藥劑後，20天後及40天後，接種500cc 之線蟲蕃薯根瘤線蟲（Meloidogyne incognita)污染土壤 於各個缽中，充份地混合後，移植蕃茄（品種：強力米壽 )苗。移植51天後，調查線蟲之根瘤著生程度（〇至100 %著生）。結果如第1 3表所示。另外，爲統一移植曰， 混和砂壤土及藥劑係於由移植日反算之日預先進行。另外 ’由Corby式計算根瘤著生程度之理論値（％ )。根瘤著 生程度（％ )若比理論値（％ )低時，本發明之有害生物 防除組成物係具有關於防除線蟲之相乘效果。此時之理論 -23- (21) 200528028 値（％ ) —倂表示於第13表之（）內。 〔表 14〕[Table 1 3] Table 12 Table 2 Sweet potato rhizobium nematode movement obstruction rate (%) Test Example 2 Water was added to the onion powder at a ratio of 1: 1 and stirred well. 8 cm filter paper was immersed in the powder suspension and air-dried, and 3 sheets were stacked and placed in an 8cni Petri Dish 'to add 2nil of organic scale compounds and / or fungicides. Each petri dish was inoculated with 50 adult roots filled with females, covered, and left in a constant temperature room at 25 ° C. After 48 to 72 hours, the 'determined life and death' was observed under a stereo microscope to determine the dead insect rate. Dead insect rate (%) = 丨 1— (survival number / inserted insect number)} χ100 -21-200528028 (19) In addition, the theoretical death rate (%) can be calculated by Corby's formula. If the experimental pupa (%) of the dead insect rate is higher than the theoretical pupa (%), the pest control composition of the present invention has a multiplicative effect on controlling root mite pests. Organophosphorus compounds: fungicides = 1: 100 to 1: 00: 1 The experimental test showing the rate of dead insects is higher than the theoretical test. g Test Example 3 A mixed loam soil 3: sandy soil 1: humus soil 1 was put into the test soil. 200 g of soil was placed in a plastic container of 300 ml each, and an organic phosphorus-based compound and / or a fungicide was added at a predetermined concentration. Each of the larvae of the beetle just after hatching was placed in a constant temperature room at 25 ° C in the dark for 5 to 10 days, after which the soil was disintegrated and the number of surviving larvae was counted to determine the dead insect rate. Dead insect rate (%) = {1— (survival number / inserted insect number)} χΙΟΟ In addition, the theoretical death rate (%) can be calculated by Corby's formula. If the dead worm rate (%) is higher than the theoretical maggot (%), the pest control composition of the present invention has a multiplicative effect on controlling the pests of chafers. Organophosphorus compounds: fungicides = 1: 1 to 1: 6 ′ The experimental result showing the rate of dead insects is higher than the theoretical value. Test Example 4 Pour a PAS medium containing an organic phosphorus-based compound and / or a bactericide to a predetermined concentration on an 8 cm petri dish, and grow Rhizoctonia, Pythium, and Fusarium bacteria on other culture media, at -22- 6mm 200528028 (20) Cut out the medium containing mycelium with a punch and transplant it into the medium containing the medicine. After incubating in a constant temperature room at 25 ° C for 4 to 7 days, the elongation of the mycelium was measured to determine the rate of hindrance to elongation. Mycelium elongation hindrance rate (%) = {1 — (mycelium elongation in the drug-treated area / untreated mycelial elongation)} xl 〇〇 In addition, the theory of mycelial elongation hindrance can be calculated by the C 〇rby formula (%). When the mycelium elongation hindrance rate (%) is higher than the theoretical value (%), the pest control composition of the present invention B has a synergistic effect on the control of disease bacteria. In the range of organophosphorus compounds: bactericides = 1: 100 to 10,000: 1, the experimental results showing the resistance of mycelium elongation are higher than the theoretical ones. Test Example 5 3 liters of mixed paddy soil 4: sandy loam of sand 1 was placed in a 1/5 000a bowl, and an organic phosphorus-based compound and / or φ fungicide were added at a predetermined concentration. Immediately after the addition of the agent, 20 days and 40 days later, 500cc of the nematode Meloidogyne incognita was used to contaminate the soil in each bowl, and after mixing thoroughly, the tomato (variety: powerful rice sap) seedlings were transplanted. 51 days after transplantation, the degree of nodule infestation (0 to 100% invasion) was investigated. The results are shown in Table 13. In addition, for unified transplantation, the mixed sandy loam and chemicals are preliminarily calculated on the day of reclamation from the transplantation date. In addition, the theoretical calculation of the degree of nodule invasion by Corby's formula (%). If the nodule invasion degree (%) is lower than the theoretical 値 (%), the pest control composition of the present invention has a synergistic effect on the control of nematodes. The theory at this time -23- (21) 200528028 値 (%) — 倂 is shown in () in Table 13. (Table 14)
第1 3表 根瘤著生程度（％ ) 供試藥劑 移植後之曰數 (Kg a. i. /ha) 0 20 40 I-a(3) 30 17 57 II-a(l .5) 100 100 100 I_a(3)+II-a(l.5) 20(30) 10(17) 50(57) II-c(l .5) 100 100 100 I-a(3)+II-c(1.5) 25(30) 10(17) 60 II-d(l .5) 100 100 100 I-a(3)+II-d(l.5) 30 7(17) 53(57) II-f(l.5) 100 100 100 I-a(3) + II-f(l .5) 20(30) 13(17) 40(57) H-g(1.5) 100 100 100 I-a(3) + II-g(1.5) 20(30) 10(17) 50(57) II-i(l.5) 100 100 100 I-a(3) + II-i(l .5) 17(30) 17 50(57) II-j(1.5) 100 100 100 I-a(3) + II-j(1.5) 20(30) 10(17) 47(57) II-k(l .5) 100 100 100 I-a(3)+II-k(l.5) 33 10(17) 50(57) 無處理 100 100 100 24- 200528028 (22) 試驗例6 將蕃薯根瘤線蟲（Meloidogye incognita)及鐮胞菌（ Fusarium oxy soprum )所污染之土壤及所定量的藥劑混合 於1 / 1 000a塑膠缽中，播種7粒小黃瓜（品種：北進）種 子。播種66天後，調查小黃瓜蔓割病發病株率，並且切 斷小黃瓜的第2至第3節間的莖，導管的褐變程度係依下 述基準5階段評估，基於評估結果，算出受害指數。此等 p 結果如第14表所示。另外，試驗係以3連制進行。另外 ’由Corby式計算發病株率及受害指數之理論値。發病株 率及受害指數若比理論値低時，本發明之有害生物防除組 成物係具有關於防除小黃瓜蔓割病之相乘效果。此時之理 論値（％ ) —倂表示於第14表之（）內。 A :株全體枯死 B :導管之2/3以上褐變 C :導管之1/2程度褐變 φ D :導管之I/3以下褐變 E :導管無褐變 N :調查株數（本試驗中爲7)Table 13 Degree of root nodule initiation (%) Number after test agent transplantation (Kg ai / ha) 0 20 40 Ia (3) 30 17 57 II-a (1.5) 100 100 100 I_a (3) + II-a (l.5) 20 (30) 10 (17) 50 (57) II-c (l.5) 100 100 100 Ia (3) + II-c (1.5) 25 (30) 10 (17 ) 60 II-d (l.5) 100 100 100 Ia (3) + II-d (l.5) 30 7 (17) 53 (57) II-f (l.5) 100 100 100 Ia (3) + II-f (1.5) 20 (30) 13 (17) 40 (57) Hg (1.5) 100 100 100 Ia (3) + II-g (1.5) 20 (30) 10 (17) 50 (57 ) II-i (l.5) 100 100 100 Ia (3) + II-i (l.5) 17 (30) 17 50 (57) II-j (1.5) 100 100 100 Ia (3) + II- j (1.5) 20 (30) 10 (17) 47 (57) II-k (l.5) 100 100 100 Ia (3) + II-k (l.5) 33 10 (17) 50 (57) None Treatment of 100 100 100 24- 200528028 (22) Test Example 6 The soil contaminated by Meloidogye incognita and Fusarium oxy soprum and the amount of medicine were mixed in a 1/1 000a plastic bowl. Sowing 7 gherkins (variety: Beijin) seeds. After 66 days of sowing, the incidence of gherkin disease was investigated, and the stems between the 2nd and 3rd nodes of the gherkin were cut. The degree of browning of the duct was evaluated in accordance with the following benchmark 5 stages, and calculated based on the results of the evaluation. Victim Index. These p results are shown in Table 14. In addition, the test was performed in a three-line system. In addition, the theory of the incidence rate and damage index calculated by Corby's formula. When the diseased plant rate and the damage index are lower than the theoretical value, the pest control component system of the present invention has a multiplicative effect on the prevention and control of gherkin disease. The theory at this time 値 (%)-倂 is shown in () in Table 14. A: The entire plant is dead B: Browning of more than 2/3 of the duct C: Browning of 1/2 degree of the duct φ D: Browning of I / 3 of the duct E: No browning of the duct N: Number of investigated plants (this test (Medium is 7)
受害指數={ (4A+3B+2C+1D/4N) } xlOO -25- 200528028 (23) 〔表 1 5〕 第14表 小黃瓜蔓割病發病株率 供試藥劑 發病株率（％) 受害指數 (Kg a. i. /ha) I-a(3) 100 82 II-a(3) 100 100 I-a(3) + II-a(3) 81(100) 61(82) 無處理 100 100Damage index = {(4A + 3B + 2C + 1D / 4N)} xlOO -25- 200528028 (23) 〔Table 1 5〕 Table 14 Gherkin disease incidence rate Test agent disease incidence rate (%) Victim Index (Kg ai / ha) Ia (3) 100 82 II-a (3) 100 100 Ia (3) + II-a (3) 81 (100) 61 (82) No treatment 100 100
試驗例7 (1)將蕃薯根瘤線蟲（Meloidogye incognita)及鐮 胞菌（Fusarium oxysoprum)所污染之土壤及所定量的 Basamid微粒劑（有效成份Π — h )混合於l/l〇〇〇a塑膠缽 中，7天後及10天後進行土壤中氣體移除。 (2 ) ( 1 )之操作後，混合所定量之NematorinS粒 φ 劑（有效成份I — a )於土壤中，再經4天後，播種7粒 小黃瓜（品種：北進）種子。 (3 )播種6 1天後，調查小黃瓜蔓割病發病株率，並 且以與試驗例6同樣的方法，算出受害指數。並且調查線 蟲之根瘤著生程度（〇至1 〇〇%著生）。此等結果如第1 5 表所示。試驗係以3連制進行。 爲進行比較，對於不進行（1 )之操作’以（2 )中之 所定量NematorinS粒劑（有效成份I — a)處理受污染之 土壤情況時，以及（1 )之操作後，（2 )之操作中，不混 -26- 200528028 (24) 合所定量之N e m a t o r i n S粒劑（有效成份I — a )於土壌情 況時，進行相同的試驗。 〔表 1 6〕 第1 5表 複數病害 供試藥劑 小黃瓜蔓割__ 根瘤 (Kg a. i. /ha) 發病株率（％) 受害指數 著生程度（％) I-ai3 ) 71 40 5 II-h(294) 79 53 2 I-a(3)+II-h(294) 4 1 23 0 無處理 89 60 25Test Example 7 (1) The soil contaminated by Meloidogye incognita and Fusarium oxysoprum and the Basamimid microparticles (active ingredient Π-h) were mixed in 1 / l00〇a After 7 days and 10 days, the soil gas was removed from the plastic bowl. (2) After the operation of (1), mix the specified amount of NematorinS grain φ agent (active ingredient I — a) in the soil, and after 4 days, sow 7 gherkin (variety: Beijin) seeds. (3) Sixty-one days after sowing, the incidence rate of gherkin disease was investigated, and the damage index was calculated in the same manner as in Test Example 6. In addition, the degree of nodule infestation of nematodes (from 0 to 100%) was investigated. These results are shown in Table 15. The test was carried out in a three-line system. For comparison, when the operation of (1) is not performed, the NematorinS granules (active ingredient I — a) in the amount of (2) are used to treat the contaminated soil, and after the operation of (1), (2) In the operation, do not mix -26- 200528028 (24) The same test is performed when the amount of N ematorin S granules (active ingredient I — a) is in the case of soil. 〔Table 1 6〕 Table 15 Multiple disease test agents Gherkin Cultivation __ Root nodule (Kg ai / ha) Incidence rate (%) Damage index growth (%) I-ai3) 71 40 5 II- h (294) 79 53 2 Ia (3) + II-h (294) 4 1 23 0 No treatment 89 60 25
製劑例1 9 8.3重量份 0. 2重量份 1. 〇重量份 0.5重量份 作爲對於（1 )之 (1 )矽石細粒（東海工業製） (2) 扶吉胺（Fluazinam) (3) 福賽絕（Fosthiazate) (4 )環氧化亞麻籽油 將上述（2 )至（4 )加熱混合者 吹付粒劑。 製劑例2 (1 )矽石細粒（東海工業製） 9 7 · 7重量份 (2 )扶吉胺（Fluazinam ) 1·〇重量份 (3 )福賽絕（Fosthiazate ) 1.〇 重量份 -27- 200528028 (25) (4 )環氧化亞麻籽油 〇 · 3重量份 將上述（2 )至（4 )加熱混合者’作爲對於（1 )之 吹付粒劑。 製劑例3 (1 )矽石細粒（東海工業製）9 8 · 3重量份 (2)扶吉胺（Fluazinam) 〇·2重量份 g (3)福賽絕（Fosthiazate) 1·〇 重量份 (4 )環氧化亞麻好油 〇 · 5重量份 將上述（2 )至（4 )加熱混合者’作爲對於（1 )之 吹付粒劑。 製劑例2 (1) 扶吉胺（Fluazinam) 20重量份 (2) 福賽絕（Fosthiazate) 10重量份 φ ( 3 ) Solpol3 66 1 S (東邦化學製） 1〇重量份 (4) Ipuzoll50 (出光石油化學製）60重量份 將上述（1 )至（4 )混合溶解成乳劑。 另外，在此引用成爲本申請書之優先權主張基礎之曰 本特許願2004-015667號（2004年1月23日對日本特許 廳提出申請）之總說明書內容，作爲本發明之說明書之揭 示所採用者。 -28-Formulation Example 1 9 8.3 parts by weight 0.2 parts by weight 1.0 parts by weight 0.5 parts by weight As (1) of (1) silica fine particles (manufactured by Tokai Industries) (2) Fuzinam (3) Fosthiazate (4) epoxidized linseed oil blows granules by heating and mixing the above (2) to (4). Formulation Example 2 (1) Silica fine particles (manufactured by Tokai Industries) 9 7 · 7 parts by weight (2) Fuzinam (1.0) parts by weight (3) Fosthiazate 1.〇 parts by weight- 27- 200528028 (25) (4) Epoxidized linseed oil 0.3 parts by weight The above-mentioned (2) to (4) are heated and mixed as a blow granule for (1). Formulation Example 3 (1) Silica fine particles (manufactured by Tokai Industries) 9 8 · 3 parts by weight (2) Fluazinam 2 parts by weight g (3) Fosthiazate 1 · 0 parts by weight (4) 0.5 parts by weight of epoxidized linseed oil. The above-mentioned (2) to (4) are heated and mixed as the blowing granule for (1). Formulation Example 2 (1) 20 parts by weight of Fluazinam (2) 10 parts by weight of Fosthiazate φ (3) Solpol3 66 1 S (manufactured by Toho Chemical) 10 parts by weight (4) Ipuzoll50 (Idemitsu (Production of petrochemical) 60 parts by weight of the above (1) to (4) are mixed and dissolved to form an emulsion. In addition, the contents of the general specification of Japanese Patent Application No. 2004-015667 (filed with the Japan Patent Office on January 23, 2004), which is the basis for claiming priority in this application, is incorporated herein by reference as the disclosure of the specification of the present invention. Adopter. -28-
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| CN101953341A (en) * | 2010-06-03 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Sterilizing composition |
| CN102258051B (en) * | 2011-05-25 | 2013-08-14 | 江苏龙灯化学有限公司 | Composition and method for preventing and removing pests |
| KR102015382B1 (en) * | 2012-07-03 | 2019-08-28 | 이시하라 산교 가부시끼가이샤 | Pesticidal composition and pest control method |
| JP2014097975A (en) * | 2012-10-16 | 2014-05-29 | Sumitomo Chemical Co Ltd | Method of controlling sweet potato fusarium wilt |
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| CN103734176B (en) * | 2013-12-26 | 2015-06-10 | 山东康乔生物科技有限公司 | Insecticidal composition containing fipronil |
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| CN105918346A (en) * | 2016-06-24 | 2016-09-07 | 江苏省绿盾植保农药实验有限公司 | Rice seed treating agent containing fluazinam and fosthiazate and application thereof |
| JP7280803B2 (en) | 2019-10-23 | 2023-05-24 | 日鉄神鋼建材株式会社 | Spill prevention device |
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| JPS6052146B2 (en) * | 1979-12-25 | 1985-11-18 | 石原産業株式会社 | N-pyridylaniline compounds, their production methods, and pest control agents containing them |
| JPS60136590A (en) * | 1983-12-23 | 1985-07-20 | Ishihara Sangyo Kaisha Ltd | Organic phosphorous compound, insecticide, acaricide, and nematocide containing same |
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| JPH01238505A (en) * | 1988-03-18 | 1989-09-22 | Ishihara Sangyo Kaisha Ltd | Control agent of harmful animal |
| JPH0739430B2 (en) * | 1990-07-06 | 1995-05-01 | アグロカネショウ株式会社 | Organophosphorus compound, method for producing the same and insecticide, acaricide, nematicide containing the compound |
| EP0713485B1 (en) * | 1993-08-11 | 1998-04-15 | Bayer Ag | Thiocarbamoyl compounds as microbicides |
| JP4217991B2 (en) * | 1998-04-20 | 2009-02-04 | 富士工業株式会社 | Range hood with cleaning device |
| CN1298877A (en) * | 1999-12-03 | 2001-06-13 | 拜尔公司 | Tacca chantrieri andre ketonic internal ester and its use |
| JP2003081987A (en) * | 2001-09-06 | 2003-03-19 | Agro Kanesho Co Ltd | Imidazolidine derivative containing optically active organophosphorus group, method for producing the same and noxious animal controller containing the same as active ingredient |
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2005
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- 2005-01-20 KR KR1020127010237A patent/KR101290948B1/en active IP Right Grant
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- 2005-01-20 WO PCT/JP2005/000709 patent/WO2005070206A1/en active Application Filing
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|---|---|
| TWI373310B (en) | 2012-10-01 |
| KR101290948B1 (en) | 2013-07-29 |
| CN101810194B (en) | 2012-04-18 |
| CN1909781A (en) | 2007-02-07 |
| TW201138636A (en) | 2011-11-16 |
| TWI366439B (en) | 2012-06-21 |
| KR20060135717A (en) | 2006-12-29 |
| JP2011140514A (en) | 2011-07-21 |
| WO2005070206A1 (en) | 2005-08-04 |
| JP5301603B2 (en) | 2013-09-25 |
| CN1909781B (en) | 2010-06-16 |
| JP2011140515A (en) | 2011-07-21 |
| TWI418301B (en) | 2013-12-11 |
| JP5369134B2 (en) | 2013-12-18 |
| CN102265898B (en) | 2013-11-06 |
| KR20120061986A (en) | 2012-06-13 |
| TW201124084A (en) | 2011-07-16 |
| CN102265898A (en) | 2011-12-07 |
| CN101810194A (en) | 2010-08-25 |
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