KR20060135717A - Pest control composition and method of controlling pest - Google Patents

Abstract

A pest control composition and a pest control method which have the heightened effect of controlling harmful insects living in soils and/or seeds and simultaneously have the heightened effect of controlling diseases infectious through soils and/or seeds. The pest control composition contains as active ingredients at least one organophosphorus compound selected from the group consisting of S-sec-butyl O-ethyl 2-oxo- 1,3-thiazolidin-3-ylphosphonothioate, O-ethyl-S-n-propyl(2-cyanoimino-3- ethylimidazolidin-1-yl)-phosphonothiolates, and S,S-di-sec-butyl O-ethyl phosphorodithioate and at least one bactericide selected from the group consisting of fluazinam, benomyl, tolclophos-methyl, metalaxyl, captan, iprodione, chlorothalonil, dazomet, hymexazol, flutolanil, and validamycin. The method comprises using the composition.

Description

Hazardous Biocontrol Compositions and Hazardous Biocontrol Methods {PEST CONTROL COMPOSITION AND METHOD OF CONTROLLING PEST}

The present invention relates to a harmful biological control composition effective for the simultaneous control of various pests and various plant diseases.

S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate is a compound disclosed in Patent Document 1. O-ethyl-S-n-propyl (2-cyanoimino-3-ethyl-imidazolidin-1-yl) phosphonothiolate is a compound disclosed in Patent Document 2. S, S-di-sec-butyl O-ethyl phosphorodithioate is a compound disclosed in Patent Document 3. These are organophosphorus compounds known as active ingredients of insecticides, mites and nematicides. However, in combination with certain organophosphorus compounds and certain fungicides, it relates to the control of both pests that live in soil and / or seeds, and soil and / or seed infectious plant diseases, and has a synergistic effect. It is not known to exercise.

Patent Document 1: US Patent No. 4,590,182

Patent Document 2: U.S. Patent No.

Patent Document 3: US Patent 4535077

<Start of invention>

<Technical problem to be achieved>

It is possible to control both pests inhabiting soil and / or seeds, such as nematodes, root mites and the like, and soil and / or seed infectious diseases, and further, the two control effects are synergistically enhanced than controlling each alone. Noxious biological control agents are required.

Means for Solving the Invention

MEANS TO SOLVE THE PROBLEM As a result of earnestly examining in order to solve these problems, the present inventors discovered that by combining a specific organophosphorus compound and a specific fungicide, an abnormal effect expected was obtained and completed the present invention.

This invention consists of the following summary.

1.S-sec-Butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imida At least one organophosphorous compound selected from the group consisting of zolidin-1-yl) phosphonothiolate and S, S-di-sec-butyl O-ethyl phosphorodithioate, fluazinam, benoyl and tall Control of harmful organisms comprising as an active ingredient at least one fungicide selected from the group consisting of clofosmethyl, metallacyl, captan, iprodione, chlorotalonyl, dazomet, himexazole, plutoranyl and validamycin Composition.

2. The harmful biological control composition according to item 1, wherein a content ratio of the organophosphorus compound and the fungicide is 1: 10000 to 10000: 1 in weight ratio.

3. S-sec-Butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imida At least one organophosphorous compound selected from the group consisting of zolidin-1-yl) phosphonothiolate and S, S-di-sec-butyl O-ethyl phosphorodithioate, fluazinam, benoyl and tall At least one fungicide selected from the group consisting of clophosmethyl, metallaxyl, captan, iprodione, chlorotalonyl, dazomet, himexazole, plutonanyl and validamycin, as an active ingredient, acting on harmful organisms How to control harmful organisms.

4. A method for controlling harmful organisms according to 3 above, wherein the organophosphorus compound and the fungicide are acted on simultaneously, or any one of the organophosphorus compound and the fungicide is acted on and then the other.

5. The method for controlling harmful organisms according to 3 or 4 above, wherein the ratio of the organophosphorus compound to the fungicide is controlled to be 1: 10000 to 10000: 1 in weight ratio.

6. The method for controlling harmful organisms according to any one of items 3 to 5, wherein the concentration of the active ingredient is 0.1 to 10,000 ppm.

7. The method for controlling harmful organisms according to any one of 3 to 6, wherein the harmful creatures are harmful organisms that reproduce in soil and / or seeds.

8. The method for controlling harmful organisms according to any one of 3 to 6, wherein the harmful creatures are pests that reproduce in soil and / or seeds.

9. The method for controlling harmful organisms according to any one of 3 to 9, wherein the harmful organisms are plant parasitic nematodes.

10. A method for controlling harmful organisms according to any one of 3 to 6, wherein the plant parasitic nematodes are at least one selected from root-knot nematodes, cyst nematodes, grassland nematodes, inesingar nematodes, ichigome nematodes and pine ash nematodes.

11. The method for controlling harmful organisms according to any one of 3 to 10 above, wherein the organophosphorus compound and bactericide are treated to soil and / or seeds.

Effect of the Invention

According to the present invention, there is provided a novel harmful biological control composition and a method for controlling pests that reproduce in soil and / or seeds, and simultaneously controlling the effects of soil and / or seed infectious diseases.

Best Mode for Carrying Out the Invention

S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate contains optical isomers and includes (-) and (+) bodies in addition to racemates. . Racemic Chain (R, S) -S-sec-Butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate is a compound known as Fosthiazate to be.

O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidin-1-yl) phosphonothiolate also has optical isomers, and in addition to racemates, (-) and (+ ) Is included.

S, S-di-sec-butyl O-ethyl phosphorodithioate is a compound known as the common name cadusafos.

Fluazinam, Benomyl, Tolclofos-methyl, Metalaxyl, Captan, Iprodione, Chlorothalonil, Dazomet ), Hymexazole, Flutoranil and Validamycin are all compounds described in The Pesticide Manual (13th edition; BRITISH CROP PROTECTLON COUNCIL) as fungicides.

The mixing ratio of the organophosphorus compound and the fungicide is usually 1: 10000 to 10000: 1 by weight, preferably 1: 1000 to 1000: 1.

The composition of the present invention contains an adjuvant in addition to the active ingredient. The blending ratio of the active ingredient may be 0.05 to 75% by weight. As an adjuvant, a carrier, an emulsifier, a suspension agent, a dispersing agent, an electrodeposition agent, a penetrant, a humectant, a thickener, a stabilizer, etc. are mentioned, It can add suitably as needed. As a carrier, it is divided into a solid carrier and a liquid carrier, and solid carriers include starch, activated carbon, soybean powder, wheat flour, wood flour, fish meal, powdered animal and vegetable powders such as talc, kaolin, bentonite, calcium carbonate, zeolite, diatomaceous earth, Mineral powders such as white carbon, clay, alumina, sulfur powder, and the like. Examples of the liquid carrier include water, alcohols such as methyl alcohol and ethylene glycol, ketones such as acetone and methyl ethyl ketone, dioxane and tetrahydrofuran. Aliphatic hydrocarbons such as ethers, kerosine, kerosene, aromatic hydrocarbons such as xylene, trimethylbenzene, tetramethylbenzene, cyclohexane, solvent naphtha, halogenated hydrocarbons such as chloroform and chlorobenzene, dimethylformamide, and the like. Acid amides, esters such as ethyl acetate, glycerin esters of fatty acids, nitriles such as acetonitrile, dimethyl Sulfur-containing compounds, such as sulfoxide, etc. are mentioned. Various surfactants are used as emulsifiers, suspending agents, dispersing agents, electrodeposition agents, penetrants, wetting agents and the like. If necessary, other pesticides such as insecticides, acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides, plant growth regulators and the like can be used and used together. In some cases.

The composition of the present invention can be formulated in various forms such as emulsions, powders, granules, granules, tablets, hydrates, liquids, aerosols, pastes, fluid formulations, dry fluid formulations, microcapsules and the like. Especially, the form of an emulsion, a granule, a hydrating agent, a liquid, a powder, granules, a tablet, etc. is more preferable, The form of an emulsion, a granule, a hydrating agent, a liquid, etc. is the most preferable. Preferred blending ratios in the oil agent are 5 to 75 parts by weight of the active ingredient, 90 to 10 parts by weight of the carrier and 5 to 15 parts by weight of the surfactant. Moreover, the preferable compounding ratio in powder, granules, and tablets is 0.1-10 weight part of active ingredients, 85-99 weight part of carriers, and 0.5-5 weight part of surfactant. In actual use of these preparations, they may be used as they are or diluted with a predetermined concentration with a diluent such as water.

The composition of the present invention is generally applied at an active ingredient concentration of 0.1 to 10000 ppm, preferably 1 to 1000 ppm. These active ingredient concentrations can be appropriately changed depending on the form of the preparation, the method used, the purpose, the timing, the location, the situation of occurrence of pests, and the dosage per unit area is about 1 to 5000 g, preferably 10 g as the active ingredient compound. Preferably from 10 to 1000 g. However, in special cases, it is possible to deviate from these ranges. Examples of the method for applying the composition of the present invention include soil mixing treatment, blood donation treatment, family treatment, irrigation treatment, further immersion treatment for seeds, and the like.

According to the present invention, in addition to the method for treating the composition of the present invention to the harmful organism, the method for treating the organophosphorus compound and the fungicide at the same time to the harmful organism, after treating any one of the agents of the organophosphorus compound and the fungicide to the harmful organism, the other It includes a method of treating the drug of a harmful organism.

Examples of harmful organisms to which the present invention can be applied include plant parasitic nematodes, isometric trees, vermicelli pests, spp. Pests, gastropods, direct pests, plant parasitic mites, coleopteran pests, dioptera pests and maximus Various pests, such as a pest, a flea pest, a binocular pest, and a pest of every age, and various plant diseases are mentioned. In particular, the present invention is effective for controlling harmful organisms that reproduce in soil and / or seeds. Pests that reproduce in soil and / or seeds include pests that add agricultural horticultural crops and trees in the soil, and pests that add seeds of agrohorticultural crops and trees. For example, the said plant parasitic nematodes, a conformal tree, a grasshopper pest, an evergreen tree pest, a gastropod, a direct-view pest, a plant parasitic tick, etc. are mentioned. Among them, the present invention is most effective for controlling plant parasitic nematodes.

Specific examples of various pests to which the present invention can be applied are shown below.

Examples of plant parasitic nematodes include root-knot nematodes such as sweet potato root nematodes (Meloidogyne incognita); Cyst nematodes, such as potato cyst nematodes (Globodera rostochiensis); Grasshopper nematodes, such as strawberry grasshopper nematodes (Pratylenchus penetrans); Inesingar nematodes; Ichigome nematodes; Pine tree nematodes, and the like. Examples of the conformal species include soybean beetles, rat scabers, and the like.

Examples of the vermin insects include corn root worms such as western cornworm and southern cornworm; Scarabs such as copper beetle and scarab; Weevils such as rice weevil, rice weevil, alfalfa weevil and red bean weevil; Brown mealworm; Mealworms such as false rice stealers; Leaf beetles such as cucumber leaf beetle, flea leaf beetle and Colorado leaf beetle; Comb beetle; Ladybugs such as twenty eight spotted ladybugs; Thigh wood fungus; Dog bark; Sky flow; Wood ant half wing, etc. are mentioned.

Examples of insect pests include moths such as tobacco spiderworm, moth moth, rice chestnut moth, green chestnut moth and thief moth; Chestnut moths, such as an arranging seminar moth, a macropodate, Trichoplusia genus, Heliotis genus, and Helicobpa genus; Bright moths such as Ewha moth, Persimmon moth, European lighting moth, Grasshopper moth, Cotton moth, Hwagok moth; White butterflies, such as cabbage white butterflies; Leaf horses and stalks such as genus Adoki Sophie, peach pure moth, cordrin moth; Deep moths such as peach deep moths; Oyster moths such as Lyonetia genus; White venom moths such as genus Lymantria and genus Euproctis; Home moths, such as a Chinese cabbage moth, etc. are mentioned.

Examples of the gastropods include bottlenecks, snails, and the like.

Direct pests include ground dogs, grasshoppers, wheels, black wheels, alien wheels, brown wheels and king wheels.

Examples of plant-parasitic mites include spotted mites, nisenamihini, tangerine mites and root mites.

Examples of the locust pests include cucumber larvae, locust worms, flower shovels, and the like.

As a double-pest insect, home mosquitoes such as red mosquitoes and small red mosquitoes, houseworms such as midgets, house flies, and king flies, black flies, fly flies, queen house flies, cypress flies, and constellation flies And the like, fruit flies, fruit flies, fruit flies, moth flies, backs, flies, chimneys, and oysters.

Examples of the maximal pests include leaf bees, such as ants, wasps, horned bees, and leafless bees.

Fleas etc. are mentioned as a flea pest.

As a big-headed pest, a tooth, a slope, etc. are mentioned.

As pests of isotropic species, termites, house termites, and the like can be given.

Examples of various plant diseases to which the present invention can be applied include soil and / or seed infectious plant diseases. Specifically, the following is illustrated.

Various diseases caused by Rosellinia bacteria, for example, Rhizoctonia solani in turfgrass; Leaf rot of lettuce (Rhizoctonia solani); Foliar disease (Rhizoctonia solani); Rhizoctonia solani of beets, tomatoes, eggplants, cucumbers, bell peppers, parsley, oats, delfinium and okra; Rhozoctonia solani (Prunus vulgaris), Rhozoctonia solani; Root disease of carrot (Rhizoctonia solani); Tobacco rash (Rhizoctonia solani); Spinach, cabbage housewife (Rhizoctonia solani); Burdock disease (Rhizoctonia solani); Crack browning (root disease) of radishes (Rhizoctonia solani);

Uromyces holwayi of lilies caused by the bacterium Urromyces;

Various diseases caused by Pythium bacteria, for example, Pythium debaryanum; Disease free of tobacco (Pythium debaryanum); Pythium vexans of tomatoes, cucumbers, eggplants, bell peppers, melons, melons, watermelons, white cucumbers, and pumpkins; Turf disease (Pythium aphanidermatum); Konjac root disease (Pythium aristosporum); Ginger, Pythium ultimum;

Various diseases caused by Fusarium bacteria, for example, Fusarium oxysporum of tulips: Fusarium oxysporum of konjac; Fusarium oxysporum of strawberry; Fusarium oxysporum of potatoes and tomatoes; Cucumber, Fusarium oxysporum; Fusarium solani; Dry onion, Fusarium oxysporum;

Various diseases caused by Phytophthora bacteria, for example, the disease of pineapple (Phytophthora cinnamomi); Phytophthora cactorum of the elm; Bell peppers, parsley, cottonseeds, root sprouts, flower taro, st. Polya, tobacco plague (Phytophthora capsici); Root diseases of strawberries (Phytophthora fragariae);

Various diseases caused by Verticillium bacteria, for example, Verticillium dahliae of Chinese cabbage; Eggplant counterfeit (Verticillium dahliae);

Thanatephorus cucumeris caused by the bacteria Thanatephorus;

Rhizopus necans caused by Rhizopu bacteria;

Blue fungal disease of tulip caused by Penicillium bacteria (Penicillium cyclopium);

Plasmodiophora brassicae caused by Plasmodiophora bacteria, such as cabbage and Chinese cabbage:

Spongospora subterranea of potatoes caused by Spongospora bacteria;

Rosellinia necatrix of fruit trees, tree flowers, and tea caused by Rosellinia bacteria;

Leek, leek, butterbur, konjac, soybean, chrysanthemum, bell pepper caused by Sclerotium bacteria (Sclerotium rolfsii);

Strawberry's carbon bottle (Colletotrichum acutaum) caused by Coletotrichum bacteria;

Total myopathy (Polymyxa betae mediated) caused by Polymyxa bacteria;

Botritis squamosa of leeks caused by Botritis bacteria;

Helicobasidium mompa of fruit, tree, and tea caused by the bacterium Helicobasidium;

Ceratocystis imbriata caused by Sera bacteria (Ceratocystis);

Melanoma of the melon caused by the monosporascus (Monosporascus) (Monosporascus cannonballus);

Black myopathy (Thielaviopsis basicola) caused by the bacteria Thiielaviopsis;

Thantatporus cucumeris of potato caused by the Thantatporus bacterium;

Thanatephorus cucumeris caused by Thanatephorus bacteria;

Gibberella fujihikuroi of wetland rice caused by Gibberella;

Sterpomyces scabies caused by the bacterium Sterpomyces; And

Pyricularia oryzae caused by Pyricularia bacteria; Etc.

In addition, the present invention has application to many soil infectious or seed infectious diseases in addition to those illustrated.

The compositions and methods of the present invention have aerodynamic action against harmful biological control. This action is an effect unpredictable from the various pest control properties which each drug has. The usefulness of the present invention can be said to be that the harmful biological control effect, in particular, the harmful biological control power in the soil is reliably enhanced and an immediate effect is provided rather than using each agent alone.

Examples of the present invention are described below.

Experimental Example 1

200-250 larvae of sweet potato root nematode stage 2 larvae were immersed in a drug adjusted to a predetermined concentration, and kept in a constant temperature room at 25 ° C. for 24 hours. Under the microscope, the total number of sweet potato root nematodes (A) in the drug, and the number (B) which did not move for 15 seconds in the drug were examined. In addition, the control population using distilled water instead of the chemical liquid was also examined for the total population A 'and the population B' that did not move for 15 seconds. From these values, the inhibition rate of motion was determined by the following equation. The results are shown in Tables 1-12.

% Of motion inhibition = [1-{(1-B / A) / (1-B '/ A')}] × 100

In addition, the theoretical value (%) of the exercise inhibition rate was calculated by Colby's formula. When the exercise inhibition rate (%) is higher than the theoretical value (%), the harmful biological control composition of the present invention has a synergistic effect on the control of nematodes. The theoretical value (%) in such a case was shown together in () of Table 1-12.

Test Example 2

Water was added to the onion powder in a ratio of 1:10 and sufficiently stirred. After 8 cm filter paper was immersed in a powder suspension and air-dried, 3 sheets of 8 cm shaale were overlaid and 2 ml of drug of organophosphorus compound and / or fungicide of predetermined concentration was added. Fifty adult females of Shaledan root mite were inoculated and capped, and allowed to stand in a constant temperature room at 25 ° C. After 48 to 72 hours, observation was carried out under a stereoscopic microscope, and death and death were determined to determine mortality.

Insect mortality (%) = {1- number of surviving birds / insects)} × 100

In addition, the theoretical value (%) of a mortality rate can be calculated by Colby's formula. When the experimental value (%) of the mortality rate is higher than the theoretical value (%), the harmful biological control composition of this invention has a synergistic effect with respect to the control of the harmful organism of a root mite.

Organophosphorus compound: Sterilizer = 1: 100 to 100: 1, the experimental value of the mortality rate is higher than the theoretical value.

Test Example 3

Loam 3: Sand 1: Test soil mixed with humus 1 was prepared, 200 g of soil was put in a 300 ml plastic container, and the organophosphorus compound and / or fungicide were added and mixed at a predetermined concentration. Ten larvae were released immediately after the scarab was hatched, and left in the dark at 25 ° C. for 5 to 10 days in the dark. After dismantling the soil, the number of surviving larvae was counted.

Insect mortality (%) = {1- (number of survival / insect insects)} × 100

In addition, the theoretical value (%) of a mortality rate can be calculated by Colby's formula. When the mortality rate (%) is higher than the theoretical value (%), the pest control composition of the present invention has a synergistic effect on the control of pests of scarabs.

Organophosphorus compound: In the range of fungicide = 1: 1000-1: 6, the experimental value of a mortality rate shows a value higher than a theoretical value.

Test Example 4

PSA medium adjusted to contain a predetermined concentration of organophosphorus compound and / or fungicide is introduced into 8 cm saale, and the bacteria of Rizochtonia, Pitium and Fusarium grown on separate medium are hyphaeed to 6 mm cork holes. The medium containing the was cut out and implanted in the medium containing a drug. After 4 to 7 days incubation in a 25 ℃ constant temperature room, the mycelial elongation inhibition rate was determined by measuring the elongated mycelial length.

Mycelial elongation inhibition rate (%) = {1- (mycelial elongation of the pharmaceutical treatment / no mycelial elongation)} × 100

In addition, the theoretical value (%) of the mycelial elongation inhibition rate can be calculated by Colby's formula. When the mycelial elongation inhibition rate (%) is higher than the theoretical value (%), the harmful biological control composition of the present invention has a synergistic effect with respect to the control of pests.

Organophosphorus compound: Sterilizer = 1: 10000-10000: 1 The experimental value of the mycelium elongation inhibition rate shows a value higher than a theoretical value.

Test Example 5

Aqueous soil 4: 3 liters of sandy loam mixed with sand 1 was put into a 1 / 5000a pot, and the organophosphorus compound and / or the fungicide were added and mixed at predetermined concentration. Immediately after addition of the drug, 20 days and 40 days later, 500 cc of sweet potato rootworm nematode (Meloidogyne incognita) contaminated soil was inoculated into each pot, and after being sufficiently mixed, tomato seedlings (cultivar: strong rice seedlings) were transplanted. The degree of root gall engraftment (0 to 100% engraftment) of the nematodes was examined 51 days after transplantation, and the results are shown in Table 13. In addition, in order to unify the transplantation day, the mixture of sandy loam and the drug reversed from the transplantation day. In addition, the theoretical value (%) of root nodule engraftment was calculated by Colby's formula When the root nodule engraftment percentage (%) was lower than the theoretical value (%), the harmful biological control composition of the present invention was prepared by The theoretical value (%) in such a case was also shown in () of Table 13 together.

Test Example 6

Soils contaminated with sweet potato root nematode (Meloidogyne incognita) and Fusarium oxysoprum mixed with a predetermined amount in 1/1000 a polypot, and then the seeds of cucumber (breed; Hokushin) Egg seeded. After 66 days from sowing, the incidence of gall bladder disease was examined, and the stem between the second and third sections of cucumbers was cut, and the degree of browning of the catheter was evaluated by five steps based on the following criteria. The index was calculated. These results are shown in Table 14. In addition, the test was performed by the triple flame retardant. Also, the theoretical values of the incidence rate and the damage index were calculated by Colby's formula. When the incidence rate and the damage index are lower than the theoretical value, the harmful biological control composition of the present invention has a synergistic effect on the control of cucumber manure disease. The theoretical value (%) in such a case was shown together in () of Table 14.

A: All state

B: at least two-thirds of the conduit turns brown

C: about half of the conduit is browned

D: Less than 1/3 of the conduit browns

E: no browning of conduit

N: number of weeks surveyed (7 for this test)

Damage Index = {(4A + 3B + 2C + 1D) / 4N} × 100

Test Example 7

(1) Soil contaminated with sweet potato root nematode (Meloidogyne incognita) and Fusarium oxysoprum, and a predetermined amount of basamide fine particles (active ingredient II-h) in a 1 / 100O a polypot, 7 After days and after 10 days, the gas was discharged in the soil.

(2) After the operation of (1), a predetermined amount of nematorin ace granules (active ingredient I-a) was mixed in the soil, and after 4 days, seven seeds of cucumber (variety: Hokusin) were sown.

(3) After 61 days from the sowing, the incidence of cucumber gall disease was investigated, and the damage index was calculated in the same manner as in Test Example 6. In addition, the degree of root gall engraftment (0-100% engraftment) of nematodes was examined. These results are shown in Table 15. The test was carried out with triple fire.

For comparison, when (2) is treated in soil contaminated with a predetermined amount of nematorin ace granules (active ingredient Ia) without performing the operation of (1), and (2) after the operation. The same test was done about the case where the predetermined amount of the nematorin acetate granules (active component Ia) is not mixed with soil.

Preparation Example 1

(1) 98.3 parts by weight of silica fine grains

(2) 0.2 parts by weight of fluazin

(3) 1.0 part by weight of phosphthiazate

(4) 0.5 parts by weight of epoxidized linseed oil

What heat-mixed said (2)-(4) is sprayed on (1), and it is set as a granule.

Formulation Example 2

(1) 97.7 parts by weight of silica granules (Toka Kogyo Co., Ltd.)

(2) 1.0 parts by weight of fluazin

(3) 1.0 part by weight of phosphthiazate

(4) 0.3 parts by weight of epoxidized flax oil

What heat-mixed said (2)-(4) is sprayed on (1), and it is set as a granule.

Formulation Example 3

(1) 98.3 parts by weight of silica fine grains

(2) 0.2 parts by weight of fluazin

(3) 1.0 part by weight of phosphthiazate

(4) 0.5 parts by weight of epoxidized linseed oil

What heat-mixed said (2)-(4) is sprayed on (1), and it is set as a granule.

Formulation Example 4

(1) 20 parts by weight of fluazin

(2) 10 parts by weight of phosphthiazate

(3) 10 parts by weight of sorbol 3661 S (Toho Chemical)

(4) ifsol 150 (made by Idemitsu Sekiyu Kagaku) 60 parts by weight

The above (1) to (4) are mixed and dissolved to form an oil agent.

In addition, the content of the entire specification of Japanese Patent Application 2004-015667 (filed with the Japan Patent Office on January 23, 2004), which is the basis for claiming priority of the present application, is cited herein, and is incorporated as a disclosure of the specification of the present invention. do.

Claims (11)

S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidine -1-yl) phosphonothiolate and at least one organophosphorous compound selected from the group consisting of S, S-di-sec-butyl O-ethyl phosphorodithioate, Fluazinam and Benomil ( Benomyl, Tolclofos-methyl, Metalaxyl, Captan, Iprodione, Chlorothalonil, Dazomet, Himexazole, Pluto A pest control composition comprising at least one fungicide selected from the group consisting of Ranil (Flutolanil) and validamycin (Validamycin) as an active ingredient. The harmful biological control composition according to claim 1, wherein a content ratio of the organophosphorus compound and the fungicide is 1: 10000 to 10000: 1 by weight. S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidine -1-yl) phosphonothiolate and at least one organophosphorous compound selected from the group consisting of S, S-di-sec-butyl O-ethyl phosphorodithioate, fluazin, benoyl and tollclofos At least one fungicide selected from the group consisting of methyl, metallaxyl, captan, iprodione, chlorothalonil, dazomet, himexazole, plutoranyl and validamycin as an active ingredient, characterized in that it acts on a noxious organism as an active ingredient How to control harmful organisms. The method for controlling harmful organisms according to claim 3, wherein the organophosphorus compound and the fungicide are acted simultaneously or any one of the organophosphorus compound and the fungicide is acted on and then the other. The method of controlling harmful organisms according to claim 3 or 4, wherein the ratio of the organophosphorus compound and the fungicide is 1: 1 to 10000: 1 in weight ratio. The method for controlling harmful organisms according to any one of claims 3 to 5, wherein the concentration of the active ingredient is 0.1 to 10000 ppm. The method for controlling harmful organisms according to any one of claims 3 to 6, wherein the harmful organisms are harmful organisms that reproduce in soil and / or seeds. The pest control method according to any one of claims 3 to 6, wherein the pest is a pest that reproduces in soil and / or seeds. The method for controlling harmful organisms according to any one of claims 3 to 6, wherein the harmful organisms are plant parasitic nematodes. The method for controlling harmful organisms according to any one of claims 3 to 9, wherein the plant parasitic nematodes are at least one species selected from root-knot nematodes, cyst nematodes, grassland nematodes, inesincare nematodes, Ichigome nematodes and pine re-nematodes. . The method for controlling harmful organisms according to any one of claims 3 to 10, wherein the organophosphorus compound and the fungicide are treated to soil and / or seeds.