TW201008995A - Creep resistant fluoropolymer - Google Patents
Creep resistant fluoropolymer Download PDFInfo
- Publication number
- TW201008995A TW201008995A TW098121429A TW98121429A TW201008995A TW 201008995 A TW201008995 A TW 201008995A TW 098121429 A TW098121429 A TW 098121429A TW 98121429 A TW98121429 A TW 98121429A TW 201008995 A TW201008995 A TW 201008995A
- Authority
- TW
- Taiwan
- Prior art keywords
- fluoropolymer
- melt
- composition
- carbon fibers
- carbon
- Prior art date
Links
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 58
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 57
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 72
- 239000004917 carbon fiber Substances 0.000 claims abstract description 72
- 239000000203 mixture Substances 0.000 claims abstract description 40
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 239000000155 melt Substances 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims description 22
- 239000000835 fiber Substances 0.000 claims description 20
- 229920001577 copolymer Polymers 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000011159 matrix material Substances 0.000 claims description 9
- 229920005548 perfluoropolymer Polymers 0.000 claims description 9
- -1 alkyl vinyl ether Chemical compound 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims 1
- 239000008188 pellet Substances 0.000 description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 9
- 229910052731 fluorine Inorganic materials 0.000 description 9
- 239000011737 fluorine Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- 238000000748 compression moulding Methods 0.000 description 5
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000004381 surface treatment Methods 0.000 description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 238000003682 fluorination reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- GWTYBAOENKSFAY-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-2-(1,2,2-trifluoroethenoxy)ethane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)F GWTYBAOENKSFAY-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical group FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012667 polymer degradation Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 1
- WFLOTYSKFUPZQB-UHFFFAOYSA-N 1,2-difluoroethene Chemical group FC=CF WFLOTYSKFUPZQB-UHFFFAOYSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical group NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- FXPHNQAHHHWMAV-UHFFFAOYSA-N 1-ethenoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)OC=C FXPHNQAHHHWMAV-UHFFFAOYSA-N 0.000 description 1
- IHWDSEPNZDYMNF-UHFFFAOYSA-N 1H-indol-2-amine Chemical compound C1=CC=C2NC(N)=CC2=C1 IHWDSEPNZDYMNF-UHFFFAOYSA-N 0.000 description 1
- GVEUEBXMTMZVSD-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C GVEUEBXMTMZVSD-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052805 deuterium Inorganic materials 0.000 description 1
- 125000004431 deuterium atom Chemical group 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7728608P | 2008-07-01 | 2008-07-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201008995A true TW201008995A (en) | 2010-03-01 |
Family
ID=40999824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW098121429A TW201008995A (en) | 2008-07-01 | 2009-06-25 | Creep resistant fluoropolymer |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8247486B2 (enExample) |
| EP (1) | EP2294124A1 (enExample) |
| JP (1) | JP2011526948A (enExample) |
| CN (1) | CN102083901B (enExample) |
| TW (1) | TW201008995A (enExample) |
| WO (1) | WO2010002592A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8247486B2 (en) * | 2008-07-01 | 2012-08-21 | E.I. Du Pont De Nemours And Company | Creep resistant fluoropolymer |
| JP5735109B2 (ja) * | 2010-08-13 | 2015-06-17 | グリーン， ツイード オブ デラウェア， インコーポレイテッド | 高体積繊維負荷を有する熱可塑性繊維複合材ならびにそれを作製するための方法および装置 |
| US20140210129A1 (en) * | 2013-01-25 | 2014-07-31 | Corning Incorporated | Method for manufacturing carbon electrode material |
| TW201627584A (zh) * | 2015-01-17 | 2016-08-01 | 伊格爾工業股份有限公司 | 水潤滑式軸承材料 |
| CN105017697B (zh) * | 2015-07-08 | 2017-07-11 | 广州机械科学研究院有限公司 | 耐高温蠕变、低磨损可注塑的含氟热塑性密封材料及低泄漏密封环的制备方法 |
| DE102015217138A1 (de) * | 2015-09-08 | 2017-03-09 | Robert Bosch Gmbh | Verfahren zum Ermitteln einer Ursache eines Fehlers in einem Einspritzsystem einer Brennkraftmaschine |
| EP3798269B1 (en) | 2018-05-22 | 2023-08-23 | Daikin Industries, Ltd. | Resin composition |
| JP6750645B2 (ja) | 2018-05-22 | 2020-09-02 | ダイキン工業株式会社 | ポリテトラフルオロエチレン組成物 |
| WO2025170649A1 (en) * | 2023-10-31 | 2025-08-14 | Dowaksa Usa, Llc | Chopped fiber polymer composites and method to make them |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3624250A (en) | 1970-01-20 | 1971-11-30 | Du Pont | Copolymers of ethylene/tetrafluoroethylene and of ethylene/chlorotrifluoroethylene |
| US4123602A (en) | 1976-05-24 | 1978-10-31 | Asahi Glass Company, Ltd. | Terpolymers of tetrafluoroethylene, ethylene and perfluoroalkyl vinyl monomer and process for producing the same |
| US4163742A (en) | 1978-02-09 | 1979-08-07 | E. I. Du Pont De Nemours And Company | Process and product prepared from tetrafluoroethylene resin and graphite fibers |
| US4380618A (en) | 1981-08-21 | 1983-04-19 | E. I. Du Pont De Nemours And Company | Batch polymerization process |
| US4414356A (en) | 1981-10-09 | 1983-11-08 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymer |
| US4422992A (en) * | 1982-02-12 | 1983-12-27 | E. I. Du Pont De Nemours & Company | Extruder process for preparation of carbon fiber reinforced fluoropolymer compositions |
| JPS59197411A (ja) | 1983-04-25 | 1984-11-09 | Daikin Ind Ltd | エチレン−テトラフルオロエチレンまたはクロロトリフルオロエチレン系共重合体 |
| JPS60168742A (ja) * | 1984-02-10 | 1985-09-02 | Mitsubishi Petrochem Co Ltd | 溶融成形体 |
| JPS60248710A (ja) | 1984-05-22 | 1985-12-09 | Daikin Ind Ltd | 新規エチレン／テトラフルオロエチレン系共重合体 |
| US4743658A (en) | 1985-10-21 | 1988-05-10 | E. I. Du Pont De Nemours And Company | Stable tetrafluoroethylene copolymers |
| AU648048B2 (en) * | 1989-10-06 | 1994-04-14 | E.I. Du Pont De Nemours And Company | Fluoropolymer process aids containing functional groups |
| JP3410487B2 (ja) | 1992-05-21 | 2003-05-26 | ダイキン工業株式会社 | 摺動部品用樹脂組成物 |
| JP2792359B2 (ja) * | 1992-10-01 | 1998-09-03 | 三菱化学株式会社 | シームレスベルト |
| US5902755A (en) * | 1993-05-03 | 1999-05-11 | Tox-Wastech, Inc. | High Strength composite materials |
| US5705120A (en) | 1994-02-08 | 1998-01-06 | Osaka Gas Company, Limited | Method of producing graphite fiber-reinforced fluororesin composites |
| JPH10158456A (ja) * | 1996-11-27 | 1998-06-16 | Ntn Corp | 潤滑性樹脂組成物 |
| US6559238B1 (en) * | 1998-06-29 | 2003-05-06 | E. I. Du Pont De Nemours And Company | Thermally cross-linked fluoropolymer |
| US6288372B1 (en) * | 1999-11-03 | 2001-09-11 | Tyco Electronics Corporation | Electric cable having braidless polymeric ground plane providing fault detection |
| JP3578070B2 (ja) * | 2000-09-13 | 2004-10-20 | ダイキン工業株式会社 | 摺動部品用樹脂組成物 |
| JP2003041083A (ja) * | 2001-07-25 | 2003-02-13 | Du Pont Mitsui Fluorochem Co Ltd | 変性ポリテトラフルオロエチレン組成物 |
| CN100381488C (zh) * | 2002-03-18 | 2008-04-16 | 旭化成化学株式会社 | 阻燃性芳族聚碳酸酯树脂组合物 |
| CN1662566B (zh) * | 2002-06-21 | 2010-06-16 | 3M创新有限公司 | 极性端基量减少的含氟聚合物的制备方法 |
| EP1561784B1 (en) | 2002-10-29 | 2012-11-28 | Daikin Industries, Ltd. | Fluororesin composition, molded fluororesin articles, fluororesin laminates and use of the laminates |
| US20070276080A1 (en) * | 2006-05-25 | 2007-11-29 | Jacob Lahijani | Melt fabrication of fiber-filled fluoropolymer |
| JP5436219B2 (ja) * | 2007-11-08 | 2014-03-05 | 帝人株式会社 | 樹脂組成物 |
| US8247486B2 (en) * | 2008-07-01 | 2012-08-21 | E.I. Du Pont De Nemours And Company | Creep resistant fluoropolymer |
-
2009
- 2009-06-11 US US12/482,511 patent/US8247486B2/en active Active
- 2009-06-17 CN CN2009801256830A patent/CN102083901B/zh active Active
- 2009-06-17 EP EP09774044A patent/EP2294124A1/en not_active Withdrawn
- 2009-06-17 WO PCT/US2009/047646 patent/WO2010002592A1/en not_active Ceased
- 2009-06-17 JP JP2011516454A patent/JP2011526948A/ja active Pending
- 2009-06-25 TW TW098121429A patent/TW201008995A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN102083901A (zh) | 2011-06-01 |
| US8247486B2 (en) | 2012-08-21 |
| JP2011526948A (ja) | 2011-10-20 |
| CN102083901B (zh) | 2013-08-14 |
| EP2294124A1 (en) | 2011-03-16 |
| WO2010002592A1 (en) | 2010-01-07 |
| US20100004374A1 (en) | 2010-01-07 |
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