TW200835736A - Polyurethane compositions and articles prepared therefrom, and methods for making the same - Google Patents

Info

Publication number

TW200835736A

TW200835736A TW96140976A TW96140976A TW200835736A TW 200835736 A TW200835736 A TW 200835736A TW 96140976 A TW96140976 A TW 96140976A TW 96140976 A TW96140976 A TW 96140976A TW 200835736 A TW200835736 A TW 200835736A

Authority

TW

Taiwan

Prior art keywords

composition

propylene

ethylene

component

polymer

Prior art date

2006-11-01

Links

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• Global Dossier
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• 239000000203 mixture Substances 0.000 title claims abstract description 407
• 239000004814 polyurethane Substances 0.000 title claims abstract description 145
• 229920002635 polyurethane Polymers 0.000 title claims abstract description 143
• 238000000034 method Methods 0.000 title claims description 101
• 229920000642 polymer Polymers 0.000 claims abstract description 242
• 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 100
• 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 88
• 239000006185 dispersion Substances 0.000 claims abstract description 47
• 239000000463 material Substances 0.000 claims abstract description 47
• 229920001971 elastomer Polymers 0.000 claims abstract description 41
• 150000001336 alkenes Chemical class 0.000 claims abstract description 36
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 33
• 239000005060 rubber Substances 0.000 claims abstract description 31
• 239000000853 adhesive Substances 0.000 claims abstract description 28
• 230000001070 adhesive effect Effects 0.000 claims abstract description 27
• 238000000576 coating method Methods 0.000 claims abstract description 26
• 229920000728 polyester Polymers 0.000 claims abstract description 23
• 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 19
• 239000006260 foam Substances 0.000 claims abstract description 17
• 239000004417 polycarbonate Substances 0.000 claims abstract description 17
• 229920000515 polycarbonate Polymers 0.000 claims abstract description 16
• 239000000835 fiber Substances 0.000 claims abstract description 15
• 238000004519 manufacturing process Methods 0.000 claims abstract description 10
• 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 7
• 239000004626 polylactic acid Substances 0.000 claims abstract description 7
• 230000001681 protective effect Effects 0.000 claims abstract description 6
• 239000005977 Ethylene Substances 0.000 claims description 212
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 212
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 208
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 204
• 229920001577 copolymer Polymers 0.000 claims description 180
• 229920000140 heteropolymer Polymers 0.000 claims description 154
• 150000002009 diols Chemical class 0.000 claims description 101
• -1 polyetherimine Polymers 0.000 claims description 101
• 239000004711 α-olefin Substances 0.000 claims description 95
• 239000000178 monomer Substances 0.000 claims description 69
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 52
• 229920000151 polyglycol Polymers 0.000 claims description 51
• 239000010695 polyglycol Substances 0.000 claims description 51
• 239000000155 melt Substances 0.000 claims description 47
• 239000000126 substance Substances 0.000 claims description 47
• 239000004970 Chain extender Substances 0.000 claims description 46
• KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 45
• 239000003054 catalyst Substances 0.000 claims description 43
• 239000000758 substrate Substances 0.000 claims description 43
• LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 40
• 125000005442 diisocyanate group Chemical group 0.000 claims description 38
• VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 33
• 229920001169 thermoplastic Polymers 0.000 claims description 33
• 239000004416 thermosoftening plastic Substances 0.000 claims description 32
• 239000003981 vehicle Substances 0.000 claims description 28
• 239000002253 acid Substances 0.000 claims description 26
• 229920000768 polyamine Polymers 0.000 claims description 26
• 125000001931 aliphatic group Chemical group 0.000 claims description 25
• TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 24
• 229920006112 polar polymer Polymers 0.000 claims description 23
• 239000000654 additive Substances 0.000 claims description 22
• 230000008569 process Effects 0.000 claims description 22
• 238000002844 melting Methods 0.000 claims description 21
• 230000008018 melting Effects 0.000 claims description 21
• 229920005989 resin Polymers 0.000 claims description 21
• 239000011347 resin Substances 0.000 claims description 21
• XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 18
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
• 239000003795 chemical substances by application Substances 0.000 claims description 17
• 239000011248 coating agent Substances 0.000 claims description 17
• 229920000570 polyether Polymers 0.000 claims description 16
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
• 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
• 150000002148 esters Chemical class 0.000 claims description 15
• 239000003973 paint Substances 0.000 claims description 15
• 229920005862 polyol Polymers 0.000 claims description 15
• 150000003077 polyols Chemical class 0.000 claims description 15
• IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 14
• 239000004744 fabric Substances 0.000 claims description 14
• 238000005481 NMR spectroscopy Methods 0.000 claims description 13
• 239000002649 leather substitute Substances 0.000 claims description 13
• 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 12
• KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 12
• 229910052707 ruthenium Inorganic materials 0.000 claims description 12
• 239000000779 smoke Substances 0.000 claims description 12
• 238000002156 mixing Methods 0.000 claims description 11
• 239000000843 powder Substances 0.000 claims description 11
• 239000001913 cellulose Substances 0.000 claims description 9
• 229920002678 cellulose Polymers 0.000 claims description 9
• 238000004132 cross linking Methods 0.000 claims description 9
• 238000001938 differential scanning calorimetry curve Methods 0.000 claims description 9
• XSCLFFBWRKTMTE-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCCC(CN=C=O)C1 XSCLFFBWRKTMTE-UHFFFAOYSA-N 0.000 claims description 8
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 8
• 230000000996 additive effect Effects 0.000 claims description 8
• 238000002347 injection Methods 0.000 claims description 8
• 239000007924 injection Substances 0.000 claims description 8
• 229920003023 plastic Polymers 0.000 claims description 8
• 239000004033 plastic Substances 0.000 claims description 8
• 229920000877 Melamine resin Polymers 0.000 claims description 7
• 229920000180 alkyd Polymers 0.000 claims description 7
• 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 7
• 239000013078 crystal Substances 0.000 claims description 7
• 230000001965 increasing effect Effects 0.000 claims description 7
• 238000000465 moulding Methods 0.000 claims description 7
• 239000010985 leather Substances 0.000 claims description 6
• 229920001225 polyester resin Polymers 0.000 claims description 6
• 239000004645 polyester resin Substances 0.000 claims description 6
• 238000002441 X-ray diffraction Methods 0.000 claims description 5
• 239000003431 cross linking reagent Substances 0.000 claims description 5
• 239000003960 organic solvent Substances 0.000 claims description 5
• 150000002978 peroxides Chemical class 0.000 claims description 5
• 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 5
• ROHUXHMNZLHBSF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCC(CN=C=O)CC1 ROHUXHMNZLHBSF-UHFFFAOYSA-N 0.000 claims description 4
• 239000004640 Melamine resin Substances 0.000 claims description 4
• 229920000954 Polyglycolide Polymers 0.000 claims description 4
• 238000013329 compounding Methods 0.000 claims description 4
• 229920000058 polyacrylate Polymers 0.000 claims description 4
• 239000004633 polyglycolic acid Substances 0.000 claims description 4
• 230000002829 reductive effect Effects 0.000 claims description 4
• PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 4
• QXRRAZIZHCWBQY-UHFFFAOYSA-N 1,1-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1(CN=C=O)CCCCC1 QXRRAZIZHCWBQY-UHFFFAOYSA-N 0.000 claims description 3
• CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 3
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
• WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 claims description 3
• 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
• 238000003723 Smelting Methods 0.000 claims description 3
• FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical group C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 3
• 238000005266 casting Methods 0.000 claims description 3
• 229920000909 polytetrahydrofuran Polymers 0.000 claims description 3
• 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
• 229920006132 styrene block copolymer Polymers 0.000 claims description 2
• 238000009941 weaving Methods 0.000 claims description 2
• RZTOWFMDBDPERY-UHFFFAOYSA-N Delta-Hexanolactone Chemical compound CC1CCCC(=O)O1 RZTOWFMDBDPERY-UHFFFAOYSA-N 0.000 claims 2
• 229920000271 Kevlar® Polymers 0.000 claims 2
• 150000002118 epoxides Chemical class 0.000 claims 2
• 239000004761 kevlar Substances 0.000 claims 2
• 239000004922 lacquer Substances 0.000 claims 2
• VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 claims 1
• WGLQHUKCXBXUDV-UHFFFAOYSA-N 3-aminophthalic acid Chemical compound NC1=CC=CC(C(O)=O)=C1C(O)=O WGLQHUKCXBXUDV-UHFFFAOYSA-N 0.000 claims 1
• AKJPUEOOQPBXIF-UHFFFAOYSA-N NN.N=C=O.N=C=O Chemical compound NN.N=C=O.N=C=O AKJPUEOOQPBXIF-UHFFFAOYSA-N 0.000 claims 1
• VLTICMVRVQWWIQ-UHFFFAOYSA-N ethyl carbamate;phthalic acid Chemical compound CCOC(N)=O.OC(=O)C1=CC=CC=C1C(O)=O VLTICMVRVQWWIQ-UHFFFAOYSA-N 0.000 claims 1
• 238000004299 exfoliation Methods 0.000 claims 1
• 229930003658 monoterpene Natural products 0.000 claims 1
• 150000002773 monoterpene derivatives Chemical class 0.000 claims 1
• 235000002577 monoterpenes Nutrition 0.000 claims 1
• 229920005990 polystyrene resin Polymers 0.000 claims 1
• 150000004060 quinone imines Chemical class 0.000 claims 1
• 238000003466 welding Methods 0.000 claims 1
• 239000000806 elastomer Substances 0.000 abstract description 10
• 230000001737 promoting effect Effects 0.000 abstract description 2
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 55
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 46
• 239000012948 isocyanate Substances 0.000 description 41
• 229920002857 polybutadiene Polymers 0.000 description 37
• 239000000523 sample Substances 0.000 description 37
• 239000005062 Polybutadiene Substances 0.000 description 36
• 150000002513 isocyanates Chemical class 0.000 description 33
• 238000006243 chemical reaction Methods 0.000 description 29
• 150000001993 dienes Chemical class 0.000 description 29
• 238000009826 distribution Methods 0.000 description 28
• RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 26
• 150000001875 compounds Chemical class 0.000 description 26
• 125000000524 functional group Chemical group 0.000 description 26
• 229920000573 polyethylene Polymers 0.000 description 25
• 229930195733 hydrocarbon Natural products 0.000 description 23
• 229920000098 polyolefin Polymers 0.000 description 23
• 238000012360 testing method Methods 0.000 description 23
• 150000002430 hydrocarbons Chemical class 0.000 description 22
• 229920001155 polypropylene Polymers 0.000 description 22
• 239000004215 Carbon black (E152) Substances 0.000 description 21
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 21
• 239000000047 product Substances 0.000 description 21
• OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 18
• 239000004743 Polypropylene Substances 0.000 description 17
• 239000003921 oil Substances 0.000 description 17
• 235000019198 oils Nutrition 0.000 description 17
• 229920001195 polyisoprene Polymers 0.000 description 17
• 239000000052 vinegar Substances 0.000 description 17
• 235000021419 vinegar Nutrition 0.000 description 17
• 239000004606 Fillers/Extenders Substances 0.000 description 16
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 16
• 150000001412 amines Chemical class 0.000 description 15
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 15
• 238000006116 polymerization reaction Methods 0.000 description 15
• 239000004698 Polyethylene Substances 0.000 description 14
• 238000002425 crystallisation Methods 0.000 description 14
• 230000008025 crystallization Effects 0.000 description 14
• IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 14
• 229920002397 thermoplastic olefin Polymers 0.000 description 14
• 229920002554 vinyl polymer Polymers 0.000 description 14
• 229910052799 carbon Inorganic materials 0.000 description 13
• 125000004122 cyclic group Chemical group 0.000 description 13
• HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical compound C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 13
• 238000001125 extrusion Methods 0.000 description 13
• 238000005259 measurement Methods 0.000 description 13
• 239000000243 solution Substances 0.000 description 13
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
• 125000003118 aryl group Chemical group 0.000 description 12
• WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical group OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 12
• 150000004985 diamines Chemical class 0.000 description 12
• 229920001684 low density polyethylene Polymers 0.000 description 12
• 239000004702 low-density polyethylene Substances 0.000 description 12
• BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 12
• YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 12
• 239000012071 phase Substances 0.000 description 12
• UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 11
• JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 11
• 229920001400 block copolymer Polymers 0.000 description 11
• 229920001038 ethylene copolymer Polymers 0.000 description 11
• 239000007789 gas Substances 0.000 description 11
• ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 11
• MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 10
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
• 125000004432 carbon atom Chemical group C* 0.000 description 10
• 238000001816 cooling Methods 0.000 description 10
• 239000000945 filler Substances 0.000 description 10
• 239000007788 liquid Substances 0.000 description 10
• 229910052757 nitrogen Inorganic materials 0.000 description 10
• 238000002360 preparation method Methods 0.000 description 10
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
• 230000008859 change Effects 0.000 description 9
• 238000010438 heat treatment Methods 0.000 description 9
• 229920001519 homopolymer Polymers 0.000 description 9
• 239000002904 solvent Substances 0.000 description 9
• WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 8
• ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 8
• LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 8
• WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 8
• QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 8
• 239000005642 Oleic acid Substances 0.000 description 8
• ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 8
• 230000032683 aging Effects 0.000 description 8
• 239000002585 base Substances 0.000 description 8
• QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 8
• 239000003446 ligand Substances 0.000 description 8
• 239000011572 manganese Substances 0.000 description 8
• 229910052751 metal Inorganic materials 0.000 description 8
• 239000002184 metal Substances 0.000 description 8
• 235000021313 oleic acid Nutrition 0.000 description 8
• XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 8
• 239000004800 polyvinyl chloride Substances 0.000 description 8
• 150000003254 radicals Chemical group 0.000 description 8
• 239000011541 reaction mixture Substances 0.000 description 8
• OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 7
• 235000021314 Palmitic acid Nutrition 0.000 description 7
• 235000021355 Stearic acid Nutrition 0.000 description 7
• 238000004458 analytical method Methods 0.000 description 7
• 238000009472 formulation Methods 0.000 description 7
• ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 7
• 229920001903 high density polyethylene Polymers 0.000 description 7
• 239000004700 high-density polyethylene Substances 0.000 description 7
• 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
• 235000020778 linoleic acid Nutrition 0.000 description 7
• OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 7
• WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 7
• QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 7
• OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 7
• 229920000915 polyvinyl chloride Polymers 0.000 description 7
• 239000008117 stearic acid Substances 0.000 description 7
• 235000015112 vegetable and seed oil Nutrition 0.000 description 7
• PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical group CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
• PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 6
• OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 6
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
• 241001441571 Hiodontidae Species 0.000 description 6
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
• AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 6
• YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 6
• 125000003277 amino group Chemical group 0.000 description 6
• 239000003963 antioxidant agent Substances 0.000 description 6
• 238000010828 elution Methods 0.000 description 6
• 235000019253 formic acid Nutrition 0.000 description 6
• AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 6
• ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 6
• 238000005984 hydrogenation reaction Methods 0.000 description 6
• AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 6
• 239000008188 pellet Substances 0.000 description 6
• 238000012545 processing Methods 0.000 description 6
• 238000000518 rheometry Methods 0.000 description 6
• 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 6
• OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 5
• 241000136406 Comones Species 0.000 description 5
• 239000004593 Epoxy Substances 0.000 description 5
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