TW200424251A

TW200424251A - Flame retardants

Flame retardants Download PDF

Info

Publication number: TW200424251A
Authority: TW; Taiwan
Prior art keywords: melamine; patent application; flame retardant; item; scope
Prior art date: 2002-11-21

Application number

TW092132403A

Other languages

English (en)

Chinese (zh)

Inventor

Rolf Drewes

Nicolaas Johanna Jozef Aelmans

Original Assignee

Ciba Sc Holding Ag

Priority date

2002-11-21

Filing date

2003-11-19

Publication date

2004-11-16

2003-11-19 Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag

2004-11-16 Publication of TW200424251A publication Critical patent/TW200424251A/zh

Links

239000003063 flame retardant Substances 0.000 title claims abstract description 58
-1 metalloid salt Chemical class 0.000 claims abstract description 182
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 41
229910052751 metal Inorganic materials 0.000 claims abstract description 23
239000002184 metal Substances 0.000 claims abstract description 23
239000001257 hydrogen Substances 0.000 claims abstract description 19
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 19
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 14
229920001059 synthetic polymer Polymers 0.000 claims abstract description 14
229910052752 metalloid Inorganic materials 0.000 claims abstract description 10
125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 7
125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 7
150000002738 metalloids Chemical class 0.000 claims abstract description 6
125000001424 substituent group Chemical group 0.000 claims abstract description 6
125000003282 alkyl amino group Chemical group 0.000 claims abstract description 5
229910052736 halogen Inorganic materials 0.000 claims abstract description 5
239000000203 mixture Substances 0.000 claims description 60
229920000877 Melamine resin Polymers 0.000 claims description 51
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 49
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 27
239000005977 Ethylene Substances 0.000 claims description 27
125000000217 alkyl group Chemical group 0.000 claims description 26
150000001875 compounds Chemical class 0.000 claims description 25
239000002253 acid Substances 0.000 claims description 24
150000001412 amines Chemical group 0.000 claims description 23
239000007859 condensation product Substances 0.000 claims description 23
150000003839 salts Chemical class 0.000 claims description 23
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 22
125000003118 aryl group Chemical group 0.000 claims description 16
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 14
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 13
239000004952 Polyamide Substances 0.000 claims description 12
229920002647 polyamide Polymers 0.000 claims description 12
239000004417 polycarbonate Substances 0.000 claims description 12
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 11
229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 11
239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 11
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 11
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 10
239000007795 chemical reaction product Substances 0.000 claims description 10
238000000034 method Methods 0.000 claims description 10
229920001169 thermoplastic Polymers 0.000 claims description 10
229910019142 PO4 Inorganic materials 0.000 claims description 9
229920000728 polyester Polymers 0.000 claims description 9
239000004114 Ammonium polyphosphate Substances 0.000 claims description 8
241000208340 Araliaceae Species 0.000 claims description 8
235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 claims description 8
235000003140 Panax quinquefolius Nutrition 0.000 claims description 8
239000004698 Polyethylene Substances 0.000 claims description 8
235000019826 ammonium polyphosphate Nutrition 0.000 claims description 8
229920001276 ammonium polyphosphate Polymers 0.000 claims description 8
235000008434 ginseng Nutrition 0.000 claims description 8
150000002431 hydrogen Chemical class 0.000 claims description 8
229910052500 inorganic mineral Inorganic materials 0.000 claims description 8
239000011707 mineral Substances 0.000 claims description 8
229920000573 polyethylene Polymers 0.000 claims description 8
239000002689 soil Substances 0.000 claims description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 7
229920000388 Polyphosphate Polymers 0.000 claims description 7
239000000654 additive Substances 0.000 claims description 7
229910052799 carbon Inorganic materials 0.000 claims description 7
239000001205 polyphosphate Substances 0.000 claims description 7
235000011176 polyphosphates Nutrition 0.000 claims description 7
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 6
125000003545 alkoxy group Chemical group 0.000 claims description 6
239000000945 filler Substances 0.000 claims description 6
239000000463 material Substances 0.000 claims description 6
239000000047 product Substances 0.000 claims description 6
239000004611 light stabiliser Substances 0.000 claims description 5
229910044991 metal oxide Inorganic materials 0.000 claims description 5
150000004706 metal oxides Chemical class 0.000 claims description 5
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
239000010452 phosphate Substances 0.000 claims description 5
229920000515 polycarbonate Polymers 0.000 claims description 5
229920001955 polyphenylene ether Polymers 0.000 claims description 5
239000004416 thermosoftening plastic Substances 0.000 claims description 5
229910052725 zinc Inorganic materials 0.000 claims description 5
239000011701 zinc Substances 0.000 claims description 5
YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 claims description 4
239000004793 Polystyrene Substances 0.000 claims description 4
125000002947 alkylene group Chemical group 0.000 claims description 4
POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 claims description 4
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 claims description 4
150000001463 antimony compounds Chemical class 0.000 claims description 4
239000003963 antioxidant agent Substances 0.000 claims description 4
239000002216 antistatic agent Substances 0.000 claims description 4
125000004429 atom Chemical group 0.000 claims description 4
COAPBYURHXLGMG-UHFFFAOYSA-N azane;1,3,5-triazine-2,4,6-triamine Chemical compound N.NC1=NC(N)=NC(N)=N1 COAPBYURHXLGMG-UHFFFAOYSA-N 0.000 claims description 4
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
150000003018 phosphorus compounds Chemical class 0.000 claims description 4
229920002223 polystyrene Polymers 0.000 claims description 4
238000012545 processing Methods 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
239000006096 absorbing agent Substances 0.000 claims description 3
125000005262 alkoxyamine group Chemical group 0.000 claims description 3
150000001450 anions Chemical class 0.000 claims description 3
125000000732 arylene group Chemical group 0.000 claims description 3
229910052791 calcium Inorganic materials 0.000 claims description 3
239000003795 chemical substances by application Substances 0.000 claims description 3
229910052749 magnesium Inorganic materials 0.000 claims description 3
239000002114 nanocomposite Substances 0.000 claims description 3
229910000073 phosphorus hydride Inorganic materials 0.000 claims description 3
229920002959 polymer blend Polymers 0.000 claims description 3
150000003254 radicals Chemical class 0.000 claims description 3
AVIZTSRRMBGYCJ-UHFFFAOYSA-N tetraazanium phosphonato phosphate 1,3,5-triazine-2,4,6-triamine Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].NC1=NC(N)=NC(N)=N1.[O-]P([O-])(=O)OP([O-])([O-])=O AVIZTSRRMBGYCJ-UHFFFAOYSA-N 0.000 claims description 3
ZZMPGNVAROSUSZ-UHFFFAOYSA-N triazanium;1,3,5-triazine-2,4,6-triamine;phosphate Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O.NC1=NC(N)=NC(N)=N1 ZZMPGNVAROSUSZ-UHFFFAOYSA-N 0.000 claims description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
244000241257 Cucumis melo Species 0.000 claims description 2
235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 2
SYNHCENRCUAUNM-UHFFFAOYSA-N Nitrogen mustard N-oxide hydrochloride Chemical class Cl.ClCC[N+]([O-])(C)CCCl SYNHCENRCUAUNM-UHFFFAOYSA-N 0.000 claims description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 2
229960000458 allantoin Drugs 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
229910052796 boron Inorganic materials 0.000 claims description 2
150000001642 boronic acid derivatives Chemical class 0.000 claims description 2
238000009833 condensation Methods 0.000 claims description 2
230000005494 condensation Effects 0.000 claims description 2
150000001879 copper Chemical class 0.000 claims description 2
210000004268 dentin Anatomy 0.000 claims description 2
229920006248 expandable polystyrene Polymers 0.000 claims description 2
239000004794 expanded polystyrene Substances 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
150000004679 hydroxides Chemical class 0.000 claims description 2
150000002443 hydroxylamines Chemical class 0.000 claims description 2
229910021331 inorganic silicon compound Inorganic materials 0.000 claims description 2
ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 2
YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 claims description 2
239000006078 metal deactivator Substances 0.000 claims description 2
239000000049 pigment Substances 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
239000012744 reinforcing agent Substances 0.000 claims description 2
229910052708 sodium Inorganic materials 0.000 claims description 2
239000003381 stabilizer Substances 0.000 claims description 2
238000005728 strengthening Methods 0.000 claims description 2
238000006467 substitution reaction Methods 0.000 claims description 2
239000011593 sulfur Substances 0.000 claims description 2
229910052717 sulfur Inorganic materials 0.000 claims description 2
230000002195 synergetic effect Effects 0.000 claims description 2
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims 3
OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical compound C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 claims 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
239000004254 Ammonium phosphate Substances 0.000 claims 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
239000004480 active ingredient Substances 0.000 claims 1
229910000148 ammonium phosphate Inorganic materials 0.000 claims 1
235000019289 ammonium phosphates Nutrition 0.000 claims 1
IUTYMBRQELGIRS-UHFFFAOYSA-N boric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OB(O)O.NC1=NC(N)=NC(N)=N1 IUTYMBRQELGIRS-UHFFFAOYSA-N 0.000 claims 1
239000004202 carbamide Substances 0.000 claims 1
239000003153 chemical reaction reagent Substances 0.000 claims 1
238000006482 condensation reaction Methods 0.000 claims 1
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims 1
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 claims 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 claims 1
230000006911 nucleation Effects 0.000 claims 1
238000010899 nucleation Methods 0.000 claims 1
150000002896 organic halogen compounds Chemical class 0.000 claims 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims 1
XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims 1
QVJYHZQHDMNONA-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1.NC1=NC(N)=NC(N)=N1 QVJYHZQHDMNONA-UHFFFAOYSA-N 0.000 claims 1
239000011541 reaction mixture Substances 0.000 claims 1
150000002367 halogens Chemical group 0.000 abstract description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 abstract description 4
125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract description 2
125000004453 alkoxycarbonyl group Chemical group 0.000 abstract description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract description 2
230000000737 periodic effect Effects 0.000 abstract description 2
125000000041 C6-C10 aryl group Chemical group 0.000 abstract 2
125000006702 (C1-C18) alkyl group Chemical group 0.000 abstract 1
125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
229910017464 nitrogen compound Inorganic materials 0.000 abstract 1
150000002830 nitrogen compounds Chemical class 0.000 abstract 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
229910052757 nitrogen Inorganic materials 0.000 description 48
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 44
229920000642 polymer Polymers 0.000 description 43
229920001577 copolymer Polymers 0.000 description 40
150000002148 esters Chemical class 0.000 description 26
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 23
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 17
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
235000019441 ethanol Nutrition 0.000 description 14
229920000768 polyamine Polymers 0.000 description 13
239000012964 benzotriazole Substances 0.000 description 12
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 12
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 11
OKKJLVBELUTLKV-UHFFFAOYSA-N methyl alcohol Substances OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 10
KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 8
239000005062 Polybutadiene Substances 0.000 description 8
239000004743 Polypropylene Substances 0.000 description 8
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 8
239000004615 ingredient Substances 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
229920002857 polybutadiene Polymers 0.000 description 8
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
239000003365 glass fiber Substances 0.000 description 7
229920001684 low density polyethylene Polymers 0.000 description 7
239000004702 low-density polyethylene Substances 0.000 description 7
235000021317 phosphate Nutrition 0.000 description 7
229920002554 vinyl polymer Polymers 0.000 description 7
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 6
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 6
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
150000004985 diamines Chemical class 0.000 description 6
229920001903 high density polyethylene Polymers 0.000 description 6
239000004700 high-density polyethylene Substances 0.000 description 6
239000000178 monomer Substances 0.000 description 6
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 6
229920006324 polyoxymethylene Polymers 0.000 description 6
239000004800 polyvinyl chloride Substances 0.000 description 6
229920000915 polyvinyl chloride Polymers 0.000 description 6
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
239000000052 vinegar Substances 0.000 description 6
235000021419 vinegar Nutrition 0.000 description 6
KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 5
229920002292 Nylon 6 Polymers 0.000 description 5
229920002302 Nylon 6,6 Polymers 0.000 description 5
239000004721 Polyphenylene oxide Substances 0.000 description 5
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
239000002585 base Substances 0.000 description 5
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
150000001993 dienes Chemical class 0.000 description 5
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 5
WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
239000002245 particle Substances 0.000 description 5
229920000962 poly(amidoamine) Polymers 0.000 description 5
229920001155 polypropylene Polymers 0.000 description 5
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
229920001897 terpolymer Polymers 0.000 description 5
238000012360 testing method Methods 0.000 description 5
239000011732 tocopherol Substances 0.000 description 5
229960001295 tocopherol Drugs 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 4
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