SU676167A3 - Способ получени производных тиофосфорной кислоты - Google Patents
Способ получени производных тиофосфорной кислотыInfo
- Publication number
- SU676167A3 SU676167A3 SU772522352A SU2522352A SU676167A3 SU 676167 A3 SU676167 A3 SU 676167A3 SU 772522352 A SU772522352 A SU 772522352A SU 2522352 A SU2522352 A SU 2522352A SU 676167 A3 SU676167 A3 SU 676167A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- mol
- solution
- thiophosphoric acid
- cis
- acid
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 3
- 150000003582 thiophosphoric acids Chemical class 0.000 title 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000243 solution Substances 0.000 description 9
- HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000012071 phase Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 3
- -1 isopropyl acetoacetic acid ester Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- WDJHALXBUFZDSR-UHFFFAOYSA-N Acetoacetic acid Natural products CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000004809 thin layer chromatography Methods 0.000 description 2
- WQYSXVGEZYESBR-UHFFFAOYSA-N thiophosphoryl chloride Chemical compound ClP(Cl)(Cl)=S WQYSXVGEZYESBR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- UDYGXWPMSJPFDG-UHFFFAOYSA-M benzyl(tributyl)azanium;bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CC1=CC=CC=C1 UDYGXWPMSJPFDG-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical group C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- KDCIHNCMPUBDKT-UHFFFAOYSA-N hexane;propan-2-one Chemical compound CC(C)=O.CCCCCC KDCIHNCMPUBDKT-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- GVIIRWAJDFKJMJ-UHFFFAOYSA-N propan-2-yl 3-oxobutanoate Chemical compound CC(C)OC(=O)CC(C)=O GVIIRWAJDFKJMJ-UHFFFAOYSA-N 0.000 description 1
- DHGFMVMDBNLMKT-UHFFFAOYSA-N propyl 3-oxobutanoate Chemical compound CCCOC(=O)CC(C)=O DHGFMVMDBNLMKT-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/20—Esters of thiophosphoric acids containing P-halide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/173—Esters of thiophosphoric acids with unsaturated acyclic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1138776A CH623593A5 (en) | 1976-09-08 | 1976-09-08 | Process for the preparation of vinylthionophosphoryl halides |
| CH1138976A CH636360A5 (en) | 1976-09-08 | 1976-09-08 | Process for the preparation of vinylthionophosphoric acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU676167A3 true SU676167A3 (ru) | 1979-07-25 |
Family
ID=25708233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU772522352A SU676167A3 (ru) | 1976-09-08 | 1977-09-08 | Способ получени производных тиофосфорной кислоты |
Country Status (12)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112645977A (zh) * | 2020-12-23 | 2021-04-13 | 天津阿尔塔科技有限公司 | 一种脱异丙基巴胺磷的合成方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE737270C (de) * | 1941-02-18 | 1943-07-09 | Hauhinco Maschf | Schlagwerkzeug |
| GB1262760A (en) * | 1968-07-15 | 1972-02-09 | Sandoz Ltd | Halogen containing phosphorus derivatives |
| NL7010111A (enrdf_load_stackoverflow) * | 1969-07-18 | 1971-01-20 |
-
1977
- 1977-08-31 GB GB3633777A patent/GB1587913A/en not_active Expired
- 1977-09-01 IT IT5085777A patent/IT1091117B/it active
- 1977-09-01 DK DK390577A patent/DK144190C/da active
- 1977-09-01 DE DE19772739310 patent/DE2739310A1/de active Granted
- 1977-09-02 NL NL7709690A patent/NL7709690A/xx not_active Application Discontinuation
- 1977-09-05 FR FR7726892A patent/FR2364222A1/fr active Granted
- 1977-09-06 BR BR7705950A patent/BR7705950A/pt unknown
- 1977-09-06 IE IE184777A patent/IE45582B1/en not_active IP Right Cessation
- 1977-09-07 ES ES462188A patent/ES462188A1/es not_active Expired
- 1977-09-07 PL PL20071177A patent/PL109053B1/pl not_active IP Right Cessation
- 1977-09-07 JP JP10831377A patent/JPS5334728A/ja active Granted
- 1977-09-08 SU SU772522352A patent/SU676167A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| FR2364222B1 (enrdf_load_stackoverflow) | 1984-05-11 |
| BR7705950A (pt) | 1978-06-27 |
| IE45582L (en) | 1978-03-08 |
| DE2739310C2 (enrdf_load_stackoverflow) | 1988-08-25 |
| DE2739310A1 (de) | 1978-03-09 |
| GB1587913A (en) | 1981-04-15 |
| JPS5334728A (en) | 1978-03-31 |
| IT1091117B (it) | 1985-06-26 |
| DK144190B (da) | 1982-01-11 |
| JPS6143359B2 (enrdf_load_stackoverflow) | 1986-09-26 |
| ES462188A1 (es) | 1980-12-16 |
| PL200711A1 (pl) | 1978-10-23 |
| NL7709690A (nl) | 1978-03-10 |
| PL109053B1 (en) | 1980-05-31 |
| FR2364222A1 (fr) | 1978-04-07 |
| DK390577A (da) | 1978-03-09 |
| DK144190C (da) | 1982-06-14 |
| IE45582B1 (en) | 1982-10-06 |
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