SU1715187A3 - Способ борьбы с сорн ками в посевах сорго - Google Patents

Способ борьбы с сорн ками в посевах сорго Download PDF

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Publication number
SU1715187A3
SU1715187A3 SU792807710A SU2807710A SU1715187A3 SU 1715187 A3 SU1715187 A3 SU 1715187A3 SU 792807710 A SU792807710 A SU 792807710A SU 2807710 A SU2807710 A SU 2807710A SU 1715187 A3 SU1715187 A3 SU 1715187A3
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SU
USSR - Soviet Union
Prior art keywords
sorghum
herbicide
compound
controlling weeds
antidote
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SU792807710A
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English (en)
Inventor
Щепански Хенри
Мартин Хенри
Фери Вернер
Пассиотас Георг
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Циба-Гейги Аг (Фирма)
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Publication of SU1715187A3 publication Critical patent/SU1715187A3/ru
Priority to LV930416A priority Critical patent/LV5650A3/xx
Priority to LTRP1284A priority patent/LT2613B/xx

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/185—Radicals derived from carboxylic acids from aliphatic carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
    • C07C275/48—Y being a hydrogen or a carbon atom
    • C07C275/50—Y being a hydrogen or an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/10—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D263/14—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
    • C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings

Abstract

Изобретение относитс  к химическим способам защиты растений. Цель изобретени  - уменьшение фитотоксичности способа по отношению к растени м сорго, предварительную обработку сем н антидотом - производным бенз/ацетонитрила формулы СбНбС (=Ы-0-СН2-[СзН502]) (CN) в количестве 0,75-4 г/кг сем н и довсходовую обработку почвы в посевах сорго гербицидом -N-

Description

Изобретение относитс  к химическим способам защиты растений, конкретно к способу борьбы с сорн ками в посевах сорго путем обработки растений или их биотона гербицидом N-(1-мeтил-2-мeтoкcи-зтил)-N (хлорацетил)-2-этил-6-метиланилином (метолахлор ), и обработки сем н антидотом производным метоксииминобензилцианида .
Цель изобретени  - уменьшение фитотоксичности способа по отношению к растени м сорго.
П р и м е р 1. Синтез N-(1,3-диоксолан2-ил-метокси )-иминобензацетонитрила (соединение I).
К суспензии 33,6 г (0,2 моль) натриевой солиа-фенилацетонитрилоксима в 140мл диметилсульфоксида прикапывают при перемешивании и охлаждении на бане с лед ной водой 33,8 г (0,2 моль) 2-бром-метил-1,3-диоксолан . Затем реакционную смесь перемешивают 4 ч при 60-70°С, экстрагируют 600
мл зфира и трижды промывают 2%-ным раствором NaOH. Эфирную выт жку сушат сульфатом натри , фильтруют и упаривают. Остаток перекристаллизовываютиз гексана и получают 44,1 г (95% от теории) соединени  I в виде бесцветных кристаллов с т.пл. 67°С.
П р и м е р 2. Антидотна  активность соединени  I.
В стекл нный сосуд помещали семена сорго (100 г) и антидот. Сосуд встр хивают и вращают дл  обеспечени  хорошего смещени .
Через 5-10 дн. после протравливани  сем н их засевают в теплице в пластмассовые горшки диаметром 11 см или контейнеры высотой 5 см (25x17 см), которые наполнены песчаным суглинком. Доза сем н 10-20 кг/га. Затем поверхность земли обрабатывают гербицидом путем разбрызгивани .
Антидотную активность определ ют через 21 день после нанесени  гербицида. Данные представлены в таблице.
Таким образом предлагаемый способ обладает высокой эффективностью при малых нормах расхода.

Claims (1)

  1. Формула изобретени 
    Способ борьбы с сорн ками в посевах сорго путем предварительной обработки сем н антидотом - производным бензацетонитрила и довсходовой обработки почвы гербицидом М-{1-метил-2-метоксизтил)-Ыхлорацетил-2-этил-6-метиланилином в дозе
    1,5-2,5кг/га. отличающийс  темгчто. с целью уменьшени  фитотоксического воздействи  гербицида на сорго, в качестве производного бензацетонитрила используют соединение формулы
    Л С-СИ.
    у II/о
    Н-0-СНа-
    0
    в количестве 0,75-4 г/кг сем н.
    Соединение А - ангидрид ,8-нафталевой кислоты. Соединение Б - цизнометаксииминобензолиетпиитрилл
SU792807710A 1978-09-01 1979-08-31 Способ борьбы с сорн ками в посевах сорго SU1715187A3 (ru)

Priority Applications (2)

Application Number Priority Date Filing Date Title
LV930416A LV5650A3 (lv) 1978-09-01 1993-05-25 Panemiens nezalu apkarosanai sorgo sejumos
LTRP1284A LT2613B (lt) 1978-09-01 1993-09-29 Kovos su piktzolemis budas sorgo paseliuose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH925278 1978-09-01

Publications (1)

Publication Number Publication Date
SU1715187A3 true SU1715187A3 (ru) 1992-02-23

Family

ID=4349982

Family Applications (1)

Application Number Title Priority Date Filing Date
SU792807710A SU1715187A3 (ru) 1978-09-01 1979-08-31 Способ борьбы с сорн ками в посевах сорго

Country Status (13)

Country Link
US (1) US4269775A (ru)
EP (1) EP0011047B1 (ru)
JP (2) JPS599546B2 (ru)
AU (1) AU531302B2 (ru)
CS (1) CS212243B2 (ru)
DD (1) DD147904A5 (ru)
DE (1) DE2966641D1 (ru)
HU (2) HU193495B (ru)
IE (1) IE48817B1 (ru)
IL (1) IL58150A (ru)
SU (1) SU1715187A3 (ru)
UA (1) UA5584A1 (ru)
ZA (1) ZA794622B (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013130392A1 (en) * 2012-03-01 2013-09-06 Fmc Corporation Safening fluthiacet-methyl on sorghum with 2,4-d amine

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013130392A1 (en) * 2012-03-01 2013-09-06 Fmc Corporation Safening fluthiacet-methyl on sorghum with 2,4-d amine
US20150051073A1 (en) * 2012-03-01 2015-02-19 Fmc Corporation Safening Fluthiacet-Methyl on Sorghum with 2,4-D Amine
US9084427B2 (en) 2012-03-01 2015-07-21 Fmc Corporation Safening fluthiacet-methyl on sorghum with 2,4-D amine

Also Published As

Publication number Publication date
EP0011047A2 (de) 1980-05-14
AU5047379A (en) 1980-03-06
IE48817B1 (en) 1985-05-29
DE2966641D1 (en) 1984-03-15
IL58150A (en) 1985-07-31
AU531302B2 (en) 1983-08-18
CS212243B2 (en) 1982-03-26
HU182942B (en) 1984-03-28
US4269775A (en) 1981-05-26
ZA794622B (en) 1981-04-29
UA5584A1 (ru) 1994-12-28
IE791662L (en) 1980-03-01
JPS5535093A (en) 1980-03-11
HU193495B (en) 1987-10-28
EP0011047A3 (en) 1980-09-03
JPS599546B2 (ja) 1984-03-03
DD147904A5 (de) 1981-04-29
JPS58140003A (ja) 1983-08-19
IL58150A0 (en) 1979-12-30
EP0011047B1 (de) 1984-02-08

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