SU1336938A3 - Фунгицидное средство в виде эмульсионного концентрата - Google Patents

Фунгицидное средство в виде эмульсионного концентрата Download PDF

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SU1336938A3
SU1336938A3 SU853903101A SU3903101A SU1336938A3 SU 1336938 A3 SU1336938 A3 SU 1336938A3 SU 853903101 A SU853903101 A SU 853903101A SU 3903101 A SU3903101 A SU 3903101A SU 1336938 A3 SU1336938 A3 SU 1336938A3
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hydrogen
methyl
methoxy
chlorine
alkyl
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Никкель Йозеф
Пипер Гельмут
Куртце Юрген
Драндаревски Кристо
Луст Зигмунд
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Целамерк Гмбх Унд Ко,Кг (Фирма)
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Priority claimed from DE19833308045 external-priority patent/DE3308045A1/de
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Abstract

Изобретение относитс  к химическим средствам защиты .растений и поз-- вол ет использовать его в качестве фунгицидного средства дл  борьбы с заболевани ми растений томатов и винограда . Повьшение фунгицидной активности до 100% при С 100 ч/млно по g,b достигаетс  за счет использовани  средства в виде эмульсионного концентрата, содержащего активное вещество (в мас.%) формулы (А)(В)С CR.,-CX-e, где А - , B-Y- (CR CRf), в которых R - водород, алкил Сц, , циано, а также хлор или бром, если k означает 0; Rj -водород , амино, нитро, метил, метокси, хлор, бром; RJ - водород, алкил , амино, ацетамино, галоген, метокси, трифторметил, гидрокси, дифторметокси RI и Rj совместно - ОСН,0 или R - водород, гидрокси, амино, метил, зтил, бутил, метокси, пропокси, хлор, бром, нитро, аллилок- си, диметиламино, N-метил, N-бутил- амино, метилтио, трифторметил, дифторметокси; R и R, - одинаковые или различные и означают водород, метил; R и Y совместно означают - (W ,) f Y - циклогексил, пиридил, фуранил, нафтил, 4-метоксинафталин- 1-ил, бензил, циклопентил, циклогек- сенил, алкил С ,-С , гексил, а также метил, если k означает 1 или группу , где R, - водород, гидрокси , хлор, нитро, метил, метокси; водород, хлор, бром, метил, нитро, метокси, трифторметил; Rg водород, фтор, хлор, бром, амино, нитро, диме- Тиламино, алкил , метокси, эток- си, фенил, циклогексил или Rg и Rg OCHjO; k - 0,1 или 2; X - кислород, сера; Q - группа NR,o R,oN(CH) R,3 OR,2 (СН.) , (СН ОСНСН; N (CHg) СИ,; N(CH.). осн(снз); tUcHTTTocH ; -S(CH2)40, f5(CH)o, N(CH2),j(C,Hj)2 , где R и R одинаковые или различные означают водород алкил С,-С, бензил, аллил или н-додецил; R водород , метил, этил, бутил; R,j - водород , метил, причем оба радикала А и В одновременно не обозначают фенил, моногалогенфенил, мононитрофенил имо- ноаминофенил (0,5), растворитель - ацетон (98,5), поверхностно-активное вещество - три-н-пропиламинова  соль н-додецилбензолсульфокислоты (1,0). 7 табл. g U) со со Oi со со

Description

1П369382
Изобретение относитс  к химичес- вещества средства используют соедине
КИМ средствам защиты растений, а имен- ни , указанные в табл,1. Активные
но к фунгицидному средству в виде вещества средства получают ацилирова
эмульсионного концентрата.
Цель изобретени  - повьшение фунгицидной активности.
нием соответствующим образом замещен ных производных акриловой кислоты с производными карбоновойкислоты в при сутствии средства активирующего кислоту или его обезвоживающего,
Изобретение иллюстрируетс  примерами , в которых в качестве активного
Производные насыщенной карбоновой кислоты А.
C CI -CO-Q 6
нием соответствующим образом замещенных производных акриловой кислоты с производными карбоновойкислоты в присутствии средства активирующего кислоту или его обезвоживающего,
Т а б л и ц а 1
Изомеры цис/транс 3:2
цис/транс 3:2 транс-Изомер
С1
С1
С1
1JH С1
,С1
С1
OQ
Qo
:Г.
140-144
150-155 168-171
256-258 165-180
Таблица 2 карбоновой кислоты
соа
97 S-CHjA-CH O
NtCH,)
0,56
Анализ масл нистых продуктов указан в табл.3.
Анализ масл нистых продуктов приведен в табл.4.
70,87 59,72 62,99 79,05 65,03 58,34 75,59 74,75 59,72 74,30 70,98 75,62 65,97 72,42
70,71 59,87 63,20 78,96 64,74 58,67 75,89 74,55 59,91 74,61 71,06 75,61 65,73 72,54
Анализ продуктов приведен в табл,5,
Таблица 3
Таблица 4
6,10 5,21 4,67 7,78 5,77 5,25 7,69 7,01 5,12 6,73 6,68 7,35 5,91 7,26
3,94
3,32
3,87
4,01
3,61
3,24
3,83
4,15 3 ,32
4,33
8,28
3,84
7,33
3,67
4,05 3,17 3,70 3,86 3,60 3,22 3,69 4,17 3,18 4,01 8,16 4,03 7,19 3,50
Таблица 5
11
Продолжение табл.6
1336938
12 Продолжение табл.6
mopara vlticola.
21133693822
Продолжение таблс.7
Фунгицидное средство в виде эмуль-где R - водород, гидрокси, хлор,
сионного концентрата, содержащее ак-нитро, метил, метокси;
тивное вещество, производное ненасы-R водород, хлор, бром, метил,
щенной карбоновой кислоты, раствори-нитро, метокси или трифтортель и поверхностно-активное вещест-метил
2313369382Д
Rg - водород, фтор, хлор, бром, фтор, хлор, бром, метил, амино, ннтро , диметиламино, метокси, этоксн.
амиио, нитро, диметиламино, .,-алкил, метокси, эток- си, фенил или циклогексил, или Rg и Р, вместе означают OCHjO,
k 0,1 или 2;
X - кислород или сера;
О. - группа формул
5 (У)0 -NH-Nr)oi
10
15
Vb/ RiZ
О
V-0
СНз
-0,Х- кислород, (i - группа форьп,пы
liQo или Qo
RIIСНз
R,2 - водород, метил, этил, бутил, R - водород, метил;
07,03,83 при Rj и Rj вместе означают 0-СН2-0, R4 аллилокси, R j- и R j - одинаковые или различные метил, Ry и Y вместе означают группу -(СН)-, Y - пиридил, фуранил, наф- тил, С2-С4 -алкил, гексил, группа общей формулы
где и R - одинаковые или различ- ные, водород, алкил, бензил, аллил, или н-додецил;
водород, метил, этил, бутил R, - водород, метил; А и В одновременио не обозначают фенил, моногалогенфенил, мононитрофенил и моноамино- фенил,
в качестве растворител  - ацетон, а в качестве поверхностно-активного не щества - три-н-пропиламиновую соль н-додецилбензолсульфокислоты при следующем количественном соотношении компонентов, (мас,%):
Соединение общей формулы (1)0,5
Ацетон98,5
Три-н-пропил- аминова  соль н-додецилбензолсульфокислоты 1,0 Приоритет по признакам:
28,,83 при R, - водород или С -С алкил, Я - водород, алкил, хлор, бром, нитро, метил, метоксил, амино, RJ - водород, C,-Cj -апкил, амино, галоген, метокси, R - водород, гидроксил, амино, метил, этил, бутил метокси, пропокси, хлор, бром, нитро диметиламино, М-метил, N-бутиламино, R и R, - водород, Y - радикал общей формулы
«8.
R - водород, хлор,нитро, метил, метокси, Rj - водород, хлор, бром, метил, нитро, метокси, Rg водород.
ро, диметиламино, метокси, этоксн.
-0,Х- кислород, (i - группа форьп,пы
liQo или Qo
RIIСНз
R,2 - водород, метил, этил, бутил, R - водород, метил;
07,03,83 при Rj и Rj вместе означают 0-СН2-0, R4 аллилокси, R j- и R j - одинаковые или различные метил, Ry и Y вместе означают группу -(СН)-, Y - пиридил, фуранил, наф- тил, С2-С4 -алкил, гексил, группа общей формулы
R-7
9
k 1, R - гидрокси, Q - группа формул
NR-ic H
HN-T4(0
RIO и «11
- одинаковые или различные, водород, -алкил, бензил;
27.,02,84 при R, - циано, а также хлор и бром, если , R - ацета;мино, трифторметил, гидроксил, дифторметок- сй, R4 метилтио, трифторметил, дифторметокси, вместе означают , Y - циклогексил, 4-меток- инафтапин-1-ил, бензил, циклопен- тил, циклогексенил, а также метил, сли , группа общей формулы RT
go
9
где Rg трифторметил, Нд - 45 алкил, фенил, циклогексил, Rg и Rg вместе означают , , , 0. - группа формулы
NR,o 11 .
О
MO
и R, - аплил, н-додецил.

Claims (1)

  1. Формула изобретения
    Фунгицидное средство в виде эмульсионного концентрата, содержащее активное вещество, производное ненасыщенной карбоновой кислоты, растворитель и поверхностно-активное вещест- где R? - водород, гидрокси, хлор, нитро, метил, метокси;
    Rg “ водород, хлор, бром, метил, нитро, метокси или трифторметил ;
    фтор, хлор, бром, метил, амино, нит> ро, диметиламино, метокси, этокси, к=О,Х- кислород, Q - группа формчлы или
    R12
    R, - водород, фтор, хлор, бром, амино, нитро, диметиламино, С1-С,-алкил, метокси, этокси, фенил или циклогексил, или Rg и R, вместе означают ОСНгО, к = 0,1 или 2;
    X - кислород или сера;
    Q, - группа формул
    Ж3
    NR10Ru-nQ)o> -NH-nQ/0,
    RiZ
    Ή
    У-о сн3 Rn R 13 А и
    R - одинаковые или различные, водород, С1-С4алкил, бензил, аллил, или н-додецил;
    водород, метил, этил, бутил; водород, метил;
    одновременно не обозначают фенил, моногалогенфенил, мононитрофенил и моноаминофенил, в качестве растворителя - ацетон, а в качестве поверхностно-активного вещества - три-н-пропиламиновую соль н-додецилбензолсульфокислоты при следующем количественном компонентов, (мас.%):
    Соединение общей формулы (1) Ацетон Три-н-пропиламиновая соль н-додеципбензолсульфокислоты Приоритет н а к а м:
    28.02,83 при R, - водород или С 1~С4 алкил, Rj “ водород, алкил, хлор, бром, нитро, метил, метоксил, амино, Rj - водород, С,-С3 -алкил, амино, галоген, метокси, R4 - водород, гидроксил, амино, метил, этил, бутил, метокси, пропокси, хлор, бром, нитро, диметиламино, N-метил, N-бутиламино, Rj и - водород, Y - радикал общей формулы соотношении ·
    0,5
    98,5
    1,0 о при
    R? - водород, хлор,нитро, метил, метокси, R? - водород, хлор, бром, метил, нитро, метокси, Rg - водород, сн3 метил, этил, бутил, метил;
    и R
    R(Z %
    - водород,
    - водород,
    07.03.83 при R2 и R3 вместе означают О-СН2-О, R4 - аллилокси, Rf и R fc - одинаковые или различные f метил, R? и Y вместе означают группу -(CH2)S“, Y - пиридил, фуранил, нафтил, С2-С4 -алкил, гексил, группа общей формулы к = мул
    1, R-,
    NR R*>
    гидрокси, Q - группа фор30 HN_NC/° и R„ Rio
    27..02,84 одинаковые или различные, водород, Сл-С4 -алкил, бензил;
    при R, - циано, а также хлор и бром, если k=0, R5 - ацетамино, трифторметил, гидроксил, дифторметоксй, R4 - метилтио, трифторметил, дифторметокси, R^JLR.i вместе означают 0СН2СН,0, Y - циклогексил, 4-метоксинафталин-1-ил, бензил, циклопентил, циклогексенил, а также метил, если к=1, группа общей формулы «Л в9 где Rg - трифторметил, Rg - С?-С4алкил, фенил, циклогексил, Rg и Rg вместе означают ОСН^О, к=2, Х=сера, Q. - группа формулы
    NR(0 Rtt >
    N
    -О
    -N
    -nQo и R„ аллил, н-додецил.
SU853903101A 1983-02-28 1985-06-07 Фунгицидное средство в виде эмульсионного концентрата SU1336938A3 (ru)

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DE19833306996 DE3306996A1 (de) 1983-02-28 1983-02-28 Acrylsaeuremorpholide, ihre herstellung und verwendung
DE19833308045 DE3308045A1 (de) 1983-03-07 1983-03-07 Acrylsaeureamide, ihre herstellung und verwendung

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Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3702769A1 (de) * 1987-01-30 1988-08-11 Shell Agrar Gmbh & Co Kg Fungizide mittel
USRE35985E (en) * 1983-02-28 1998-12-08 American Cyanamid Company Fungicidal compositions
US5952496A (en) * 1984-02-27 1999-09-14 American Cyanamid Company Fungicidal compositions
US5262414A (en) * 1987-01-30 1993-11-16 Shell Research Limited Fungicidal compositions
US4781750A (en) 1985-08-27 1988-11-01 Rohm And Haas Company Herbicidally active enols
ES2061432T3 (es) * 1985-10-09 1994-12-16 Shell Int Research Nuevas amidas de acido acrilico.
FI92189C (fi) * 1986-03-17 1994-10-10 Eisai Co Ltd Menetelmä lääkeaineina käyttökelpoisen difenyylimetaanijohdannaisen valmistamiseksi
US5182301A (en) * 1986-03-17 1993-01-26 Eisai Co., Ltd. Diphenylethylene derivatives pharmaceutical compositions containing same and treatment methods
DE3643403A1 (de) * 1986-12-19 1988-06-30 Shell Agrar Gmbh & Co Kg Benzophenone und verfahren zu ihrer herstellung
US5157028A (en) * 1987-01-30 1992-10-20 Shell Research Limited Fungicidal compositions
DE3719488A1 (de) * 1987-06-11 1988-12-29 Shell Agrar Gmbh & Co Kg Verfahren zur herstellung von 3,3-diarylacrylsaeureamiden
GB8728236D0 (en) * 1987-12-02 1988-01-06 Sandoz Ltd Improvements in/relating to fungicides
DE3805235A1 (de) * 1988-02-19 1989-08-31 Shell Int Research Verfahren zur herstellung von 3,3-diarylacrylsaeureamiden
AU2992089A (en) * 1988-02-22 1989-08-24 Takeda Chemical Industries Ltd. Acrylic acid morpholides, their production and use
DE3817711A1 (de) * 1988-05-25 1989-11-30 Shell Int Research Verfahren zur herstellung von 3,3-diphenylacrylsaeureamiden
DE3903247A1 (de) * 1989-02-03 1990-08-09 Shell Int Research Fungizid wirkende zusammensetzung, verfahren zu ihrer herstellung und ihre verwendung, insbesondere zur heilenden behandlung von an pilzerkrankungen leidenden pflanzen
PT93909B (pt) * 1989-04-28 1996-10-31 Sankyo Co Processo para a preparacao de novos derivados n-acriloil-piperazina com actividade antagonista de paf
US5189035A (en) * 1991-04-16 1993-02-23 Shell Research Limited Fungicidal furanone derivatives
GB9114004D0 (en) * 1991-06-28 1991-08-14 Shell Int Research Fungicidal compositions
DE4124989A1 (de) * 1991-07-27 1993-02-04 Basf Ag (beta)-substituierte zimtsaeurederivate
TW419461B (en) * 1993-06-16 2001-01-21 Bristol Myers Squibb Co Alicyclic phospholipase A2 inhibitors
DK0653160T3 (da) 1993-11-15 1997-06-02 Shell Int Research Fremgangsmåde til bekæmpelse af svampe
CN1043720C (zh) * 1995-08-28 1999-06-23 化学工业部沈阳化工研究院 含氟二苯基丙烯酰胺类杀菌剂
US5633254A (en) 1996-01-11 1997-05-27 Agrogene Ltd. Synergistic fungicidal mixtures for the control of plant diseases
WO1997042821A1 (de) 1996-05-09 1997-11-20 Basf Aktiengesellschaft Fungizide mischungen
US5677303A (en) * 1996-06-20 1997-10-14 American Cyanamid Company Enolethers and their use as a fungicide
US6020332A (en) * 1997-02-20 2000-02-01 Shenyang Research Institute Of Chemical Industry Fluorine-containing diphenyl acrylamide antimicrobial agents
US6316446B1 (en) 1998-05-18 2001-11-13 Basf Aktiengesellschaft Fungicidal mixture
US6090806A (en) * 1998-08-31 2000-07-18 American Cyanamid Company Fungicidal mixtures
US7314953B2 (en) * 2001-03-27 2008-01-01 Errant Gene Therapeutics, Llc Treatment of lung cells with histone deacetylase inhibitors
US7842727B2 (en) * 2001-03-27 2010-11-30 Errant Gene Therapeutics, Llc Histone deacetylase inhibitors
US6495719B2 (en) * 2001-03-27 2002-12-17 Circagen Pharmaceutical Histone deacetylase inhibitors
US8026280B2 (en) 2001-03-27 2011-09-27 Errant Gene Therapeutics, Llc Histone deacetylase inhibitors
US7312247B2 (en) 2001-03-27 2007-12-25 Errant Gene Therapeutics, Llc Histone deacetylase inhibitors
MXPA04005427A (es) * 2001-12-10 2005-04-19 Amgen Inc Ligandos de receptor vainilloide y su uso en tratamientos.
CA2486303C (en) * 2002-05-22 2013-04-30 Errant Gene Therapeutics, Llc Histone deacetylase inhibitors based on alpha-ketoepoxide compounds
WO2005104847A1 (de) 2004-04-30 2005-11-10 Basf Aktiengesellschaft Fungizide mischungen
CA2587013A1 (en) * 2004-11-08 2006-05-18 Errant Gene Therapeutics, Llc Histone deacetylase inhibitors
PE20060796A1 (es) 2004-11-25 2006-09-29 Basf Ag Procedimiento para intensificar la eficiencia de etaboxam
BRPI0519230A2 (pt) * 2004-12-23 2009-01-06 Basf Ag misturas fungicidas, agente, processo para combater fungos nocivos fitopatogÊnicos, semente, e, uso dos compostos
AP2008004381A0 (en) 2005-08-05 2008-04-30 Basf Se Fungicidal mixtures comprising substituted 1-methlpyrazol-4-ylcarboxanillides
JP5424881B2 (ja) 2006-09-18 2014-02-26 ビーエーエスエフ ソシエタス・ヨーロピア 殺有害生物混合物
EP2258177A3 (en) 2006-12-15 2011-11-09 Rohm and Haas Company Mixtures comprising 1-methylcyclopropene
BR122019020347B1 (pt) 2007-02-06 2020-08-11 Basf Se Misturas, composição pesticida e métodos para controlar fungos nocivos fitopatogênicos, para proteger plantas do ataque ou infestação pelos insetos, acarídeos ou nematódeos e para proteger semente
EP2392662A3 (en) 2007-04-23 2012-03-14 Basf Se Plant productivity enhancement by combining chemical agents with transgenic modifications
EA201000429A1 (ru) 2007-09-26 2010-10-29 Басф Се Трехкомпонентные фунгицидные композиции, включающие боскалид и хлороталонил
CN102422837B (zh) * 2007-10-09 2013-04-03 中国中化股份有限公司 杀真菌组合物
WO2011026796A1 (en) 2009-09-01 2011-03-10 Basf Se Synergistic fungicidal mixtures comprising lactylates and method for combating phytopathogenic fungi
PT105407B (pt) 2010-11-26 2016-09-30 Sapec Agro S A Mistura fungicida
WO2012084670A1 (en) 2010-12-20 2012-06-28 Basf Se Pesticidal active mixtures comprising pyrazole compounds
EP2481284A3 (en) 2011-01-27 2012-10-17 Basf Se Pesticidal mixtures
JP6049684B2 (ja) 2011-03-23 2016-12-21 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ イミダゾリウム基を含むポリマーのイオン性化合物を含有する組成物
CN102715172B (zh) * 2011-03-30 2014-06-18 中国中化股份有限公司 一种二苯基丙烯酰胺类化合物作为农用杀菌剂的用途
BR112014004568A2 (pt) 2011-09-02 2017-04-04 Basf Se misturas agrícolas, método para proteger plantas de ataque, método para controlar insetos, método para a proteção de material de propagação de planta, semente, método para controlar fungos nocivos fitopagênicos, uso de uma mistura e composição agrícola
PT106351B (pt) 2012-06-01 2014-05-21 Sapec Agro S A Mistura fungicida sinérgica contendo dimetomorfe e propamocarbe-hidrocloreto
BR122019015125B1 (pt) 2012-06-20 2020-04-07 Basf Se mistura pesticida, composição, composição agrícola, métodos para o combate ou controle das pragas de invertebrados, para a proteção dos vegetais em crescimento ou dos materias de propagação vegetal, para a proteção de material de propagação vegetal, uso de uma mistura pesticida e métodos para o combate dos fungos fitopatogênicos nocivos e para proteger vegetais de fungos fitopatogênicos nocivos
US20150257383A1 (en) 2012-10-12 2015-09-17 Basf Se Method for combating phytopathogenic harmful microbes on cultivated plants or plant propagation material
PL2934147T3 (pl) 2012-12-20 2020-06-29 BASF Agro B.V. Kompozycje zawierające związki triazolowe
EP2783569A1 (en) 2013-03-28 2014-10-01 Basf Se Compositions comprising a triazole compound
EP2835052A1 (en) 2013-08-07 2015-02-11 Basf Se Fungicidal mixtures comprising pyrimidine fungicides
WO2015036058A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
WO2015036059A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
EP2979549A1 (en) 2014-07-31 2016-02-03 Basf Se Method for improving the health of a plant
CN104222110B (zh) * 2014-09-12 2016-03-23 江苏七洲绿色化工股份有限公司 一种含有苯噻菌酯和烯酰吗啉的杀菌组合物及其应用
JP2017538860A (ja) 2014-10-24 2017-12-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 固体粒子の表面荷電を改変するための、非両性の四級化可能な水溶性ポリマー
AU2016287098A1 (en) 2015-07-02 2018-01-25 BASF Agro B.V. Pesticidal compositions comprising a triazole compound
CN109152675A (zh) 2016-04-29 2019-01-04 博优国际集团股份有限公司 三叶形双组分短纤维或短切纤维及其用途
USD965031S1 (en) 2018-07-12 2022-09-27 Kennametal Inc. Stump cutter tooth
US10856474B2 (en) 2018-07-12 2020-12-08 Kennametal Inc. Stump cutter tooth assembly

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1222926C2 (de) * 1960-03-09 1976-07-15 General Aniline & Filme Corporation, New York, N.Y. (V.St.A.) Schuetzen organischer stoffe gegen uv-strahlung
FR1259830A (fr) * 1960-05-19 1961-04-28 Bayer Ag Filtre protecteur contre les rayons ultraviolets constitué par un produit aryl-éthyle substitué
NL295240A (ru) * 1963-02-05
ES311043A1 (es) * 1964-04-06 1965-08-16 Lilly Co Eli Un procedimiento para preparar derivados del acido cinamico.
US4342781A (en) * 1981-05-29 1982-08-03 Pfizer Inc. Diphenylpropenamides as SRS-A antagonists

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Colwe11 W. and etc.5,5-Diarylpen- te 2,4-dicnoic Acid Anides as Potential Antimalarial Agents - J.Med, Chem., № 11, p. 749-752, *

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