SK4152001A3 - Process for making microcellular polyurethane elastomers - Google Patents
Process for making microcellular polyurethane elastomers Download PDFInfo
- Publication number
- SK4152001A3 SK4152001A3 SK415-2001A SK4152001A SK4152001A3 SK 4152001 A3 SK4152001 A3 SK 4152001A3 SK 4152001 A SK4152001 A SK 4152001A SK 4152001 A3 SK4152001 A3 SK 4152001A3
- Authority
- SK
- Slovakia
- Prior art keywords
- chain extender
- polyol
- equivalent percent
- prepolymer
- elastomer
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 229920003225 polyurethane elastomer Polymers 0.000 title claims description 14
- 229920005862 polyol Polymers 0.000 claims abstract description 92
- 150000003077 polyols Chemical class 0.000 claims abstract description 90
- 239000004970 Chain extender Substances 0.000 claims abstract description 54
- 229920001971 elastomer Polymers 0.000 claims abstract description 43
- 239000000806 elastomer Substances 0.000 claims abstract description 43
- 229920000642 polymer Polymers 0.000 claims description 35
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical group C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 21
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- 229920001228 polyisocyanate Polymers 0.000 claims description 17
- 239000005056 polyisocyanate Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 239000004604 Blowing Agent Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 5
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 claims description 4
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 abstract description 6
- 239000004814 polyurethane Substances 0.000 abstract description 6
- 230000000704 physical effect Effects 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000000047 product Substances 0.000 description 17
- 238000004519 manufacturing process Methods 0.000 description 11
- 150000002009 diols Chemical class 0.000 description 8
- 125000006353 oxyethylene group Chemical group 0.000 description 8
- -1 polyoxypropylene Polymers 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 229920001451 polypropylene glycol Polymers 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 238000010923 batch production Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 241001425800 Pipa Species 0.000 description 1
- DUFKCOQISQKSAV-UHFFFAOYSA-N Polypropylene glycol (m w 1,200-3,000) Chemical group CC(O)COC(C)CO DUFKCOQISQKSAV-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000004662 dithiols Chemical class 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- UKZMMGLXYHSVFS-UHFFFAOYSA-N ethane-1,1-diol ethene Chemical compound OC(C)O.C=C UKZMMGLXYHSVFS-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical class O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical class CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical class CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6552—Compounds of group C08G18/63
- C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6564—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/160,968 US6100310A (en) | 1998-09-25 | 1998-09-25 | Process for making microcellular polyurethane elastomers |
| PCT/EP1999/005375 WO2000018817A1 (en) | 1998-09-25 | 1999-07-27 | Process for making microcellular polyurethane elastomers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK4152001A3 true SK4152001A3 (en) | 2001-10-08 |
Family
ID=22579243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK415-2001A SK4152001A3 (en) | 1998-09-25 | 1999-07-27 | Process for making microcellular polyurethane elastomers |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US6100310A (de) |
| EP (1) | EP1124875B1 (de) |
| JP (1) | JP2002525403A (de) |
| KR (1) | KR20010079916A (de) |
| CN (1) | CN1157431C (de) |
| AT (1) | ATE290032T1 (de) |
| AU (1) | AU738330B2 (de) |
| BR (1) | BR9913917A (de) |
| CA (1) | CA2345120A1 (de) |
| CZ (1) | CZ20011059A3 (de) |
| DE (1) | DE69923991T2 (de) |
| HK (1) | HK1041276A1 (de) |
| HU (1) | HUP0103932A3 (de) |
| PL (1) | PL346967A1 (de) |
| RU (1) | RU2001111329A (de) |
| SK (1) | SK4152001A3 (de) |
| TR (1) | TR200100849T2 (de) |
| TW (1) | TW517065B (de) |
| WO (1) | WO2000018817A1 (de) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6437013B2 (en) * | 2000-02-17 | 2002-08-20 | Mitsui Chemicals, Inc. | Microcellular polyurethane elastomer, and method of producing the same |
| WO2001083107A2 (en) | 2000-04-28 | 2001-11-08 | Synuthane International, Inc. | Double metal cyanide catalysts containing polyglycol ether complexing agents |
| DE10032957A1 (de) * | 2000-07-06 | 2002-01-17 | Basf Ag | Polyisocyanat-Polyadditionsprodukte auf Basis von niedrig ungesättigten Polyolen |
| US6458861B1 (en) * | 2001-01-18 | 2002-10-01 | Bayer Antwerp N.V. | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
| JP5496457B2 (ja) * | 2004-03-24 | 2014-05-21 | ポリィノボ バイオマテリアルズ ピーティワイ リミテッド | 生分解性ポリウレタン及びポリウレタン尿素 |
| US20090318251A1 (en) * | 2006-06-30 | 2009-12-24 | Huntsman International Llc | Novel tennis ball |
| US20090035350A1 (en) * | 2007-08-03 | 2009-02-05 | John Stankus | Polymers for implantable devices exhibiting shape-memory effects |
| JP2010540737A (ja) * | 2007-10-02 | 2010-12-24 | ビーエーエスエフ ソシエタス・ヨーロピア | 低密度ポリウレタンフォーム及びこれを靴底に使用する方法 |
| EP2209827B1 (de) * | 2007-11-14 | 2016-05-25 | Basf Se | Geschäumte polyurethane mit verbesserten dauerbiegeeigenschaften |
| WO2009068421A1 (en) * | 2007-11-26 | 2009-06-04 | Huntsman International Llc | Novel tennis ball |
| KR100969016B1 (ko) | 2007-12-13 | 2010-07-09 | 현대자동차주식회사 | 내 가수분해성이 향상된 스티어링휠용 폴리우레탄 발포체 |
| CN101565495A (zh) * | 2008-04-23 | 2009-10-28 | 拜耳材料科技贸易(上海)有限公司 | 聚氨酯弹性体及其制备方法和用途 |
| CN101486788B (zh) * | 2008-12-30 | 2011-09-14 | 浙江华峰新材料股份有限公司 | 一种低密度高硬度聚氨酯微孔弹性体及其制备方法 |
| US20100234483A1 (en) * | 2009-03-10 | 2010-09-16 | Tyco Healthcare Group Lp | Foam seal formulation |
| EP2408841B1 (de) | 2009-03-17 | 2014-11-19 | Basf Se | POLYURETHANFORMKÖRPER MIT VERBESSERTER WEITERREIßFESTIGKEIT UND VERBESSERTEM DAUERBIEGEVERHALTEN |
| CN102250313B (zh) * | 2011-06-03 | 2012-09-26 | 山东东大一诺威聚氨酯有限公司 | 一种用于聚氨酯发泡轮胎的自结皮微孔弹性体组合物 |
| US20140094534A1 (en) * | 2011-06-22 | 2014-04-03 | Dow Global Technologies Llc | Polyurethane Foam Elastomers for High Temperature Applications |
| DE102012109024A1 (de) * | 2012-09-25 | 2014-05-28 | Krones Ag | Blasformmaschine mit Dämpfung für deren Steuerung |
| JP6253942B2 (ja) * | 2013-10-10 | 2017-12-27 | ヤマハ株式会社 | 発泡ウレタンゴム及び発泡ウレタンゴム形成用組成物 |
| EP3083271B1 (de) * | 2013-12-20 | 2019-11-20 | Huntsman International LLC | Reifen, gefüllt mit polyurethan |
| CN106632982A (zh) * | 2016-12-31 | 2017-05-10 | 山东诺威聚氨酯股份有限公司 | 软式排球用聚氨酯组合料及其制备方法 |
| WO2019224235A1 (de) * | 2018-05-22 | 2019-11-28 | Basf Polyurethanes Gmbh | Polyurethanelastomer |
| JP7183685B2 (ja) * | 2018-10-18 | 2022-12-06 | 東ソー株式会社 | ポリウレタンインテグラルスキンフォーム用組成物、ポリウレタンインテグラルスキンフォーム、及びその製造方法 |
| CN111518259B (zh) * | 2020-05-06 | 2022-08-19 | 长华化学科技股份有限公司 | 高回弹性的聚氨酯微孔弹性体及其制备方法和应用 |
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| US4559366A (en) * | 1984-03-29 | 1985-12-17 | Jaquelyn P. Pirri | Preparation of microcellular polyurethane elastomers |
| US4687851A (en) * | 1985-08-15 | 1987-08-18 | The Dow Chemical Company | Polyurethane elastomers prepared from high equivalent weight polyahls |
| US5106874A (en) * | 1989-06-16 | 1992-04-21 | The Dow Chemical Company | Process for preparing elastomeric polyurethane or polyurethane-urea polymers, and polyurethanes so prepared |
| US5250582A (en) * | 1990-05-03 | 1993-10-05 | Olin Corporation | Process for making cellular and microcellular polyurethane foams |
| US5284880A (en) * | 1993-04-15 | 1994-02-08 | Basf Corporation | Water-blown polyurethane integral skin foam |
| US5470813A (en) * | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| JP2928088B2 (ja) * | 1994-03-31 | 1999-07-28 | 株式会社イノアックコーポレーション | 発泡ポリウレタンエラストマー製鉄道用パッド |
| US5482908A (en) * | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5670601A (en) * | 1995-06-15 | 1997-09-23 | Arco Chemical Technology, L.P. | Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation |
| US5677413A (en) * | 1995-06-15 | 1997-10-14 | Arco Chemical Technology, L.P. | Polyurethane elastomers exhibiting improved demold green strength and water absorption and haze-free polyols suitable for their preparation |
| US5658959A (en) * | 1995-10-30 | 1997-08-19 | Basf Corporation | Water blown integral skin polyurethane composition |
| US5618967A (en) * | 1995-10-30 | 1997-04-08 | Basf Corporation | Isocyanate composition |
| US5856372A (en) * | 1996-05-23 | 1999-01-05 | Arco Chemical Technology, L.P. | Microcellular elastomers with improved processability and properties |
| US5696221A (en) * | 1996-07-15 | 1997-12-09 | Arco Chemical Technology, L.P. | Polyurethane/urea heat-cured and moisture-cured elastomers with improved physical properties |
-
1998
- 1998-09-25 US US09/160,968 patent/US6100310A/en not_active Expired - Fee Related
-
1999
- 1999-07-27 WO PCT/EP1999/005375 patent/WO2000018817A1/en active IP Right Grant
- 1999-07-27 JP JP2000572274A patent/JP2002525403A/ja active Pending
- 1999-07-27 EP EP99938355A patent/EP1124875B1/de not_active Expired - Lifetime
- 1999-07-27 DE DE69923991T patent/DE69923991T2/de not_active Expired - Fee Related
- 1999-07-27 AT AT99938355T patent/ATE290032T1/de not_active IP Right Cessation
- 1999-07-27 RU RU2001111329/04A patent/RU2001111329A/ru unknown
- 1999-07-27 PL PL99346967A patent/PL346967A1/xx unknown
- 1999-07-27 KR KR1020017003788A patent/KR20010079916A/ko not_active Application Discontinuation
- 1999-07-27 SK SK415-2001A patent/SK4152001A3/sk unknown
- 1999-07-27 TR TR2001/00849T patent/TR200100849T2/xx unknown
- 1999-07-27 CA CA002345120A patent/CA2345120A1/en not_active Abandoned
- 1999-07-27 AU AU52886/99A patent/AU738330B2/en not_active Ceased
- 1999-07-27 CZ CZ20011059A patent/CZ20011059A3/cs unknown
- 1999-07-27 BR BR9913917-0A patent/BR9913917A/pt not_active IP Right Cessation
- 1999-07-27 HU HU0103932A patent/HUP0103932A3/hu unknown
- 1999-07-27 CN CNB998114103A patent/CN1157431C/zh not_active Expired - Fee Related
- 1999-08-30 TW TW088114854A patent/TW517065B/zh active
-
2002
- 2002-04-24 HK HK02103102.7A patent/HK1041276A1/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010079916A (ko) | 2001-08-22 |
| DE69923991T2 (de) | 2006-04-13 |
| CN1320131A (zh) | 2001-10-31 |
| CZ20011059A3 (cs) | 2001-12-12 |
| AU738330B2 (en) | 2001-09-13 |
| CN1157431C (zh) | 2004-07-14 |
| CA2345120A1 (en) | 2000-04-06 |
| HUP0103932A3 (en) | 2003-05-28 |
| AU5288699A (en) | 2000-04-17 |
| PL346967A1 (en) | 2002-03-11 |
| EP1124875B1 (de) | 2005-03-02 |
| BR9913917A (pt) | 2001-06-19 |
| US6100310A (en) | 2000-08-08 |
| HK1041276A1 (zh) | 2002-07-05 |
| ATE290032T1 (de) | 2005-03-15 |
| TW517065B (en) | 2003-01-11 |
| EP1124875A1 (de) | 2001-08-22 |
| HUP0103932A2 (hu) | 2002-02-28 |
| JP2002525403A (ja) | 2002-08-13 |
| TR200100849T2 (tr) | 2001-08-21 |
| WO2000018817A1 (en) | 2000-04-06 |
| RU2001111329A (ru) | 2004-02-20 |
| DE69923991D1 (de) | 2005-04-07 |
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