SK279348B6 - Spôsob čistenia adsorpčného prostriedku obsahujúce - Google Patents
Spôsob čistenia adsorpčného prostriedku obsahujúce Download PDFInfo
- Publication number
- SK279348B6 SK279348B6 SK2515-91A SK251591A SK279348B6 SK 279348 B6 SK279348 B6 SK 279348B6 SK 251591 A SK251591 A SK 251591A SK 279348 B6 SK279348 B6 SK 279348B6
- Authority
- SK
- Slovakia
- Prior art keywords
- desorption
- gas
- adsorption
- adsorbent
- flue gas
- Prior art date
Links
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000004140 cleaning Methods 0.000 title claims abstract description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 11
- 238000003795 desorption Methods 0.000 claims abstract description 49
- 239000003546 flue gas Substances 0.000 claims abstract description 38
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000007789 gas Substances 0.000 claims abstract description 29
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 16
- 231100000719 pollutant Toxicity 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 11
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 239000003463 adsorbent Substances 0.000 claims description 42
- 239000000126 substance Substances 0.000 claims description 12
- 238000000746 purification Methods 0.000 claims description 7
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 238000011084 recovery Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 2
- 239000002737 fuel gas Substances 0.000 abstract description 5
- 238000000926 separation method Methods 0.000 abstract description 5
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 230000008929 regeneration Effects 0.000 abstract description 2
- 238000011069 regeneration method Methods 0.000 abstract description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 150000002013 dioxins Chemical class 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/08—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds according to the "moving bed" method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2045—Hydrochloric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2047—Hydrofluoric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/206—Organic halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/206—Organic halogen compounds
- B01D2257/2064—Chlorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40043—Purging
- B01D2259/4005—Nature of purge gas
- B01D2259/40052—Recycled product or process gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40086—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/515—Specific contaminant removal
- Y10S502/516—Metal contaminant removal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/515—Specific contaminant removal
- Y10S502/517—Sulfur or sulfur compound removal
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Treating Waste Gases (AREA)
- Carbon And Carbon Compounds (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4026071A DE4026071C2 (de) | 1990-08-17 | 1990-08-17 | Verfahren und Vorrichtung zum Regenerieren von kohlenstoffhaltigem Adsorptionsmittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK279348B6 true SK279348B6 (sk) | 1998-10-07 |
Family
ID=6412425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK2515-91A SK279348B6 (sk) | 1990-08-17 | 1991-08-14 | Spôsob čistenia adsorpčného prostriedku obsahujúce |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5405812A (cs) |
| EP (1) | EP0543834B1 (cs) |
| AT (1) | ATE110983T1 (cs) |
| CZ (1) | CZ282146B6 (cs) |
| DE (2) | DE4026071C2 (cs) |
| SK (1) | SK279348B6 (cs) |
| WO (1) | WO1992003224A1 (cs) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0787889B2 (ja) * | 1992-02-08 | 1995-09-27 | 大同ほくさん株式会社 | 混合ガスの分離方法およびそれに用いる装置 |
| JP3438786B2 (ja) * | 1992-02-28 | 2003-08-18 | 住友重機械工業株式会社 | ダイオキシン類の低温熱分解方法 |
| US5597545A (en) * | 1994-11-14 | 1997-01-28 | Alliedsignal Inc. | Recovery of HF from aqueous streams |
| DE19518447A1 (de) * | 1994-11-18 | 1996-05-23 | Steag Ag | Verfahren und Anordnung zum Behandeln von kohlenstoffhaltigem Adsorptionsmittel |
| US6121179A (en) * | 1998-01-08 | 2000-09-19 | Chematur Engineering Ab | Supercritical treatment of adsorbent materials |
| US6439138B1 (en) | 1998-05-29 | 2002-08-27 | Hamon Research-Cottrell, Inc. | Char for contaminant removal in resource recovery unit |
| CN1102418C (zh) * | 1999-06-11 | 2003-03-05 | 华懋科技股份有限公司 | 废气吸附处理系统的再生方法 |
| SE518803C2 (sv) | 1999-09-03 | 2002-11-26 | Chematur Eng Ab | Metod och reaktionssystem med högt tryck och hög temperatur som är lämpat för superkritisk vattenoxidation |
| US6521021B1 (en) * | 2002-01-09 | 2003-02-18 | The United States Of America As Represented By The United States Department Of Energy | Thief process for the removal of mercury from flue gas |
| AU2005225449A1 (en) * | 2004-03-22 | 2005-10-06 | The Babcock & Wilcox Company | Dynamic halogenation of sorbents for the removal of mercury from flue gases |
| ITMI20101470A1 (it) * | 2010-08-03 | 2012-02-04 | Ecospray Technologies S R L | Apparato e metodo per la rigenerazione del carbone attivo all'interno di un impianto industriale |
| NZ630439A (en) | 2012-03-14 | 2016-03-31 | Mercutek Llc | Activated carbon and coal combustion residue treatment system and method |
| JP6066191B2 (ja) * | 2013-03-11 | 2017-01-25 | 太平洋セメント株式会社 | 排ガス中の水銀回収方法 |
| DE102013106677A1 (de) * | 2013-06-26 | 2014-12-31 | Karlsruher Institut für Technologie | Kleinfeuerungsanlage, Verfahren zu deren Betrieb und Brennstoff hierzu |
| US10675854B2 (en) | 2015-01-16 | 2020-06-09 | Raytheon Technologies Corporation | Additive processing apparatus and method |
| DE102015211326A1 (de) * | 2015-06-19 | 2016-12-22 | Rwe Power Aktiengesellschaft | Verfahren zur Abscheidung von Quecksilber aus Rauchgasen von Verbrennungsanlagen |
| CN108246043B (zh) * | 2018-01-29 | 2019-01-29 | 中冶长天国际工程有限责任公司 | 用于多工序烟气净化的接口装置、活性炭运输系统及方法 |
| CN109011991B (zh) * | 2018-08-31 | 2021-08-27 | 佛山市锐拓环境工程设备有限公司 | 一种有机废气吸附回收利用设备 |
| CN111135665B (zh) * | 2019-11-06 | 2022-04-12 | 中国神华能源股份有限公司国华电力分公司 | 吸附剂脱汞工艺和设备 |
| NL2024499B1 (en) * | 2019-12-18 | 2021-09-08 | Wim En Wim B V | Gas treatment device, combination of the gas treatment and a non-gas-fired incinerator, and method for treating gas contaminated with at least one contaminant |
| CN111257083B (zh) * | 2020-03-25 | 2023-03-17 | 江苏安捷鹿检测科技有限公司 | 一种土壤和底泥的重金属含量检测方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2992065A (en) * | 1958-07-31 | 1961-07-11 | Reinluft G M B H | Process for removing sulfur oxides from gases |
| DE1262233C2 (de) * | 1958-07-31 | 1973-02-01 | Reinluft Ges Mit Beschraenkter | Verfahren zur Entfernung von Schwefeltroxyd und gegebenenfalls von Schwefeldioxyd aus heissen Gasen, insbesondere aus Feuerungsabgasen |
| GB1459871A (en) * | 1974-03-05 | 1976-12-31 | Kureha Chemical Ind Co Ltd | Method for the regeneration of spent activated carbon |
| JPS5843222A (ja) * | 1981-09-10 | 1983-03-12 | Mitsui Mining Co Ltd | 廃ガスより硫黄酸化物および窒素酸化物を除去する方法 |
| US4708853A (en) * | 1983-11-03 | 1987-11-24 | Calgon Carbon Corporation | Mercury adsorbent carbon molecular sieves and process for removing mercury vapor from gas streams |
| JPS60172330A (ja) * | 1984-02-16 | 1985-09-05 | Mitsui Miike Kakoki Kk | 乾式移動層式吸着塔におけるプレ脱塵方法 |
| DE3426059A1 (de) * | 1984-07-14 | 1986-01-16 | Hugo Petersen Gesellschaft für verfahrenstechnischen Anlagenbau mbH & Co KG, 6200 Wiesbaden | Verfahren zur abscheidung und beseitigung von organischen schadstoffen, insbesondere von polychlorierten dibenzodioxinen (pcdd) aus rauchgasen |
| EP0169997B1 (de) * | 1984-07-28 | 1991-09-18 | Kernforschungszentrum Karlsruhe Gmbh | Verfahren zur Reinigung von Rauchgas |
| DE3602710A1 (de) * | 1986-01-30 | 1987-08-06 | Petersen Hugo Verfahrenstech | Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel |
| US4857285A (en) * | 1987-06-04 | 1989-08-15 | General Electric Environmental Services, Inc. | Method and system for removal of sulfur compounds from gases and for regenerating spent sorbents |
| DE3844422A1 (de) * | 1988-12-30 | 1990-07-05 | Steag Ag | Verfahren und vorrichtung zum abtrennen unerwuenschter bestandteile aus einem abgas |
| US5260047A (en) * | 1990-10-05 | 1993-11-09 | Linde Aktiengesellschaft | Process for purifying waste gases containing polyhalogenated compounds |
-
1990
- 1990-08-17 DE DE4026071A patent/DE4026071C2/de not_active Expired - Fee Related
-
1991
- 1991-07-20 DE DE59102865T patent/DE59102865D1/de not_active Expired - Lifetime
- 1991-07-20 WO PCT/EP1991/001367 patent/WO1992003224A1/de active IP Right Grant
- 1991-07-20 EP EP91913018A patent/EP0543834B1/de not_active Expired - Lifetime
- 1991-07-20 US US07/977,417 patent/US5405812A/en not_active Expired - Lifetime
- 1991-07-20 AT AT91913018T patent/ATE110983T1/de not_active IP Right Cessation
- 1991-08-14 SK SK2515-91A patent/SK279348B6/sk not_active IP Right Cessation
- 1991-08-14 CZ CS912515A patent/CZ282146B6/cs not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO1992003224A1 (de) | 1992-03-05 |
| US5405812A (en) | 1995-04-11 |
| CS251591A3 (en) | 1992-03-18 |
| ATE110983T1 (de) | 1994-09-15 |
| CZ282146B6 (cs) | 1997-05-14 |
| DE4026071C2 (de) | 1994-04-14 |
| DE59102865D1 (de) | 1994-10-13 |
| EP0543834B1 (de) | 1994-09-07 |
| DE4026071A1 (de) | 1992-02-20 |
| EP0543834A1 (de) | 1993-06-02 |
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