SK163695A3 - Polyolefinic wax and producing method thereof - Google Patents
Polyolefinic wax and producing method thereof Download PDFInfo
- Publication number
- SK163695A3 SK163695A3 SK1636-95A SK163695A SK163695A3 SK 163695 A3 SK163695 A3 SK 163695A3 SK 163695 A SK163695 A SK 163695A SK 163695 A3 SK163695 A3 SK 163695A3
- Authority
- SK
- Slovakia
- Prior art keywords
- bis
- methyl
- indenyl
- rac
- meso
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 28
- -1 Polypropylene Polymers 0.000 claims abstract description 40
- 229920000098 polyolefin Polymers 0.000 claims abstract description 17
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 8
- 238000009826 distribution Methods 0.000 claims abstract description 8
- 229920001155 polypropylene Polymers 0.000 claims abstract description 8
- 239000000155 melt Substances 0.000 claims abstract description 7
- 239000001993 wax Substances 0.000 claims description 24
- 238000002844 melting Methods 0.000 claims description 16
- 230000008018 melting Effects 0.000 claims description 16
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 claims description 11
- 229940126062 Compound A Drugs 0.000 claims description 8
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 abstract description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 5
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract description 2
- 125000004122 cyclic group Chemical group 0.000 abstract description 2
- 229910007928 ZrCl2 Inorganic materials 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 26
- 150000001875 compounds Chemical class 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 15
- 229910052739 hydrogen Inorganic materials 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- 125000000217 alkyl group Chemical group 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 229910007926 ZrCl Inorganic materials 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 9
- 150000001336 alkenes Chemical class 0.000 description 7
- 125000004429 atom Chemical group 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000012259 ether extract Substances 0.000 description 6
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 125000004104 aryloxy group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 125000003709 fluoroalkyl group Chemical group 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 125000005018 aryl alkenyl group Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical group 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 description 1
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 1
- UQRONKZLYKUEMO-UHFFFAOYSA-N 4-methyl-1-(2,4,6-trimethylphenyl)pent-4-en-2-one Chemical group CC(=C)CC(=O)Cc1c(C)cc(C)cc1C UQRONKZLYKUEMO-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 1
- PWDOQGLGEWYYAF-UHFFFAOYSA-N CC1=Cc2c(ccc3ccccc23)C1[Zr](C1C(C)=Cc2c1ccc1ccccc21)=[Si](C)C Chemical compound CC1=Cc2c(ccc3ccccc23)C1[Zr](C1C(C)=Cc2c1ccc1ccccc21)=[Si](C)C PWDOQGLGEWYYAF-UHFFFAOYSA-N 0.000 description 1
- VZMQJKDVAFVNJC-UHFFFAOYSA-N CCC1=CC2=C(C=CC=C2C1[Zr](C1C(CC)=CC2=C(C=CC=C12)C1=CC=CC=C1)=[Si](C)C)C1=CC=CC=C1 Chemical compound CCC1=CC2=C(C=CC=C2C1[Zr](C1C(CC)=CC2=C(C=CC=C12)C1=CC=CC=C1)=[Si](C)C)C1=CC=CC=C1 VZMQJKDVAFVNJC-UHFFFAOYSA-N 0.000 description 1
- BDTRKLCYYWDMHI-UHFFFAOYSA-J C[Si](=[Zr](C1C(=CC2=C(C=CC=C12)CC)CC)C1C(=CC2=C(C=CC=C12)CC)CC)C.[Cl-].[Cl-].C[Si](=[Zr](C1C(=CC2=CC=CC=C12)CC)C1C(=CC2=CC=CC=C12)CC)C.[Cl-].[Cl-].[Zr+4] Chemical compound C[Si](=[Zr](C1C(=CC2=C(C=CC=C12)CC)CC)C1C(=CC2=C(C=CC=C12)CC)CC)C.[Cl-].[Cl-].C[Si](=[Zr](C1C(=CC2=CC=CC=C12)CC)C1C(=CC2=CC=CC=C12)CC)C.[Cl-].[Cl-].[Zr+4] BDTRKLCYYWDMHI-UHFFFAOYSA-J 0.000 description 1
- LXFMFYMCYTZFGU-UHFFFAOYSA-N C[Si](=[Zr](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12)C Chemical compound C[Si](=[Zr](C1CCC2CC=CC=C12)C1CCC2CC=CC=C12)C LXFMFYMCYTZFGU-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical group [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 description 1
- LEOYKWIXWJXYQJ-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C Chemical compound [Cl-].[Cl-].CC1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1C LEOYKWIXWJXYQJ-UHFFFAOYSA-L 0.000 description 1
- BJIINASCOVLKCM-UHFFFAOYSA-L [Cl-].[Cl-].C[SiH](C)[Zr++]C1C(C)=Cc2c1cccc2-c1ccccc1 Chemical compound [Cl-].[Cl-].C[SiH](C)[Zr++]C1C(C)=Cc2c1cccc2-c1ccccc1 BJIINASCOVLKCM-UHFFFAOYSA-L 0.000 description 1
- MONGRUTXVWIVOQ-UHFFFAOYSA-J [Cl-].[Cl-].C[Si](=[Zr](C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)CC)C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)CC)C.[Cl-].[Cl-].[Zr+4] Chemical compound [Cl-].[Cl-].C[Si](=[Zr](C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)CC)C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)CC)C.[Cl-].[Cl-].[Zr+4] MONGRUTXVWIVOQ-UHFFFAOYSA-J 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000003106 haloaryl group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- OJNRQLXRJYAOGL-UHFFFAOYSA-L methyl(phenyl)silane zirconium(2+) dichloride Chemical compound [Cl-].[Cl-].[Zr+2].C[SiH2]C1=CC=CC=C1 OJNRQLXRJYAOGL-UHFFFAOYSA-L 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4446923A DE4446923A1 (de) | 1994-12-28 | 1994-12-28 | Polyolefinwachs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK163695A3 true SK163695A3 (en) | 1997-02-05 |
Family
ID=6537333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1636-95A SK163695A3 (en) | 1994-12-28 | 1995-12-22 | Polyolefinic wax and producing method thereof |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6407189B1 (enExample) |
| EP (1) | EP0719802B1 (enExample) |
| JP (1) | JP3844534B2 (enExample) |
| KR (1) | KR960022601A (enExample) |
| AU (1) | AU4061195A (enExample) |
| BR (1) | BR9506122A (enExample) |
| CZ (1) | CZ347395A3 (enExample) |
| DE (2) | DE4446923A1 (enExample) |
| ES (1) | ES2146704T3 (enExample) |
| SG (1) | SG76445A1 (enExample) |
| SK (1) | SK163695A3 (enExample) |
| TW (1) | TW372980B (enExample) |
| ZA (1) | ZA9510962B (enExample) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19632480A1 (de) * | 1996-08-12 | 1998-02-19 | Basf Ag | Toner für die Entwicklung elektrostatischer Bilder, enthaltend wenigstens ein zumindest teilweise taktisches Polyalkylenwachs |
| DE19729833A1 (de) * | 1997-07-11 | 1999-01-14 | Clariant Gmbh | Polypropylenwachs |
| DE19750663A1 (de) * | 1997-11-15 | 1999-05-20 | Clariant Gmbh | Verwendung von Polyolefinwachsen in Lösemittelpasten |
| AU1688199A (en) * | 1997-12-25 | 1999-07-19 | Denki Kagaku Kogyo Kabushiki Kaisha | Polymerization catalyst and process for producing olefin polymer or copolymer with the same |
| DE69941039D1 (de) | 1998-06-25 | 2009-08-06 | Idemitsu Kosan Co | Propylenpolymer und Zusammensetzung damit, Formobjekt und Laminat damit sowie Verfahren zur Herstellung von Propylenpolymer und einer Zusammensetzung damit |
| JP2000143733A (ja) * | 1998-09-07 | 2000-05-26 | Denki Kagaku Kogyo Kk | 芳香族ビニル化合物―エチレン共重合体及びその製造方法 |
| JP2001064322A (ja) * | 1999-06-24 | 2001-03-13 | Idemitsu Petrochem Co Ltd | プロピレン系重合体及びその成形体並びにプロピレン系重合体の製造方法 |
| WO2001044387A2 (de) * | 1999-12-13 | 2001-06-21 | Basf Aktiengesellschaft | Pigmentkonzentrate und verfahren zu ihrer herstellung |
| DE19960991C1 (de) * | 1999-12-17 | 2001-03-22 | Clariant Gmbh | Formmasse zur Herstellung pulvermetallischer oder keramischer Erzeugnisse |
| ES2282158T3 (es) | 1999-12-21 | 2007-10-16 | Exxonmobil Chemical Patents Inc. | Interpolimeros de alfa-olefina adhesivos. |
| EP1274773A1 (de) * | 2000-03-01 | 2003-01-15 | Clariant GmbH | Verbesserung der dispergierung von pigmenten in polypropylen |
| DE50107834D1 (de) | 2000-03-01 | 2005-12-01 | Clariant Gmbh | Dispergierung von pigmenten in polyolefinen |
| DE10015593A1 (de) * | 2000-03-29 | 2001-10-11 | Clariant Gmbh | Verwendung von Polyolefinwachsen in der Kunststoffverarbeitung |
| EP1294815B1 (de) * | 2000-06-20 | 2004-09-08 | Basf Aktiengesellschaft | Druckfarben und lacke, enthaltend polyolefinwachse |
| JP2004501248A (ja) * | 2000-06-20 | 2004-01-15 | ビーエーエスエフ アクチェンゲゼルシャフト | ポリエチレンワックス成分を含む溶剤含有ペースト |
| ATE276321T1 (de) * | 2000-06-20 | 2004-10-15 | Basf Ag | Pigmentkonzentrate und verfahren zu ihrer herstellung |
| US6706828B2 (en) * | 2002-06-04 | 2004-03-16 | Crompton Corporation | Process for the oligomerization of α-olefins having low unsaturation |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US20040132935A1 (en) * | 2002-10-24 | 2004-07-08 | Palanisamy Arjunan | Branched crystalline polypropylene |
| AU2003277350A1 (en) * | 2002-10-24 | 2004-05-13 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| EP1648946B1 (en) | 2003-07-04 | 2015-07-15 | Basell Polyolefine GmbH | Olefin polymerization process |
| DE10338344A1 (de) * | 2003-08-21 | 2005-03-24 | Clariant Gmbh | Modifizierte Polyolefinwachse |
| DE102004016790A1 (de) * | 2004-04-06 | 2005-11-17 | Clariant Gmbh | Verwendung von Wachsen als Modifizierungsmittel für gefüllte Kunststoffe |
| DE102004048536B4 (de) | 2004-10-06 | 2008-09-18 | Clariant Produkte (Deutschland) Gmbh | Verwendung von Heißschmelzmassen in Straßenmarkierungen |
| JP4583228B2 (ja) * | 2005-04-18 | 2010-11-17 | エヌイーシー ショット コンポーネンツ株式会社 | 感温ペレット型温度ヒューズ |
| US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
| US7951872B2 (en) | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
| US7928164B2 (en) | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
| US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
| US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
| US8022142B2 (en) | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
| US20070259012A1 (en) * | 2006-05-03 | 2007-11-08 | John Castro | Clear Cosmetic Compositions and Methods Of Use |
| US20100008880A1 (en) * | 2006-05-03 | 2010-01-14 | John Castro | Clear Cosmetic Compositions And Methods Of Using |
| DE102007028309A1 (de) * | 2007-06-20 | 2008-12-24 | Clariant International Limited | Licocene Performance Polymere als Phasenwechselmaterial (PCM) für den Gebrauch als Latentwärmespeicher |
| DE102007036792A1 (de) * | 2007-08-03 | 2009-02-05 | Clariant International Limited | Hochkristalline Polypropylenwachse |
| US7843307B2 (en) * | 2007-10-05 | 2010-11-30 | Nec Schott Components Corporation | Thermal fuse employing thermosensitive pellet |
| US8283428B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
| US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
| US8283419B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
| US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
| US8399725B2 (en) | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
| JP7155398B2 (ja) * | 2019-03-19 | 2022-10-18 | 三井化学株式会社 | プロピレン系樹脂組成物、成形体およびプロピレン重合体 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3148229A1 (de) * | 1981-12-05 | 1983-06-09 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinwachsen |
| DE3743321A1 (de) | 1987-12-21 | 1989-06-29 | Hoechst Ag | 1-olefinpolymerwachs und verfahren zu seiner herstellung |
| DE3743320A1 (de) | 1987-12-21 | 1989-06-29 | Hoechst Ag | 1-olefinstereoblockpolymerwachs und verfahren zu seiner herstellung |
| DE3904468A1 (de) * | 1989-02-15 | 1990-08-16 | Hoechst Ag | Polypropylenwachs und verfahren zu seiner herstellung |
| DE3929693A1 (de) | 1989-09-07 | 1991-03-14 | Hoechst Ag | Verfahren zur herstellung eines polyolefinwachses |
| DE69300609T2 (de) * | 1992-04-01 | 1996-06-13 | Mitsui Toatsu Chemicals | Syndiotaktischen Polypropylen, Wachs, Verfahren zur Herstellung derselbe und ihre Anwendung in eine Wärmefixiertonerzusammensetzung für geheizte Walze. |
| DE59305691D1 (de) | 1992-05-26 | 1997-04-17 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinwachsen |
-
1994
- 1994-12-28 DE DE4446923A patent/DE4446923A1/de not_active Withdrawn
-
1995
- 1995-12-11 TW TW084113203A patent/TW372980B/zh not_active IP Right Cessation
- 1995-12-20 ES ES95120125T patent/ES2146704T3/es not_active Expired - Lifetime
- 1995-12-20 EP EP95120125A patent/EP0719802B1/de not_active Expired - Lifetime
- 1995-12-20 DE DE59508314T patent/DE59508314D1/de not_active Expired - Fee Related
- 1995-12-21 AU AU40611/95A patent/AU4061195A/en not_active Abandoned
- 1995-12-22 US US08/577,413 patent/US6407189B1/en not_active Expired - Fee Related
- 1995-12-22 SK SK1636-95A patent/SK163695A3/sk unknown
- 1995-12-26 SG SG1995002413A patent/SG76445A1/en unknown
- 1995-12-27 CZ CZ953473A patent/CZ347395A3/cs unknown
- 1995-12-27 JP JP34101595A patent/JP3844534B2/ja not_active Expired - Fee Related
- 1995-12-27 KR KR1019950057908A patent/KR960022601A/ko not_active Withdrawn
- 1995-12-27 ZA ZA9510962A patent/ZA9510962B/xx unknown
- 1995-12-28 BR BR9506122A patent/BR9506122A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CZ347395A3 (en) | 1996-07-17 |
| DE4446923A1 (de) | 1996-07-04 |
| JP3844534B2 (ja) | 2006-11-15 |
| KR960022601A (ko) | 1996-07-18 |
| TW372980B (en) | 1999-11-01 |
| BR9506122A (pt) | 1997-12-23 |
| SG76445A1 (en) | 2000-11-21 |
| DE59508314D1 (de) | 2000-06-15 |
| ES2146704T3 (es) | 2000-08-16 |
| JPH08231640A (ja) | 1996-09-10 |
| US6407189B1 (en) | 2002-06-18 |
| EP0719802A3 (de) | 1998-11-25 |
| EP0719802B1 (de) | 2000-05-10 |
| ZA9510962B (en) | 1996-07-08 |
| AU4061195A (en) | 1996-07-04 |
| EP0719802A2 (de) | 1996-07-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SK163695A3 (en) | Polyolefinic wax and producing method thereof | |
| KR100301337B1 (ko) | 메탈로센 화합물 | |
| JP3234876B2 (ja) | ブリッジのあるキラルなメタロセン、その製造方法およびそれの触媒としての用途 | |
| US5304614A (en) | Process for the preparation of an olefin polymer using metallocenes having specifically substituted indenyl ligands | |
| USRE37208E1 (en) | Polyolefins prepared with metallocene catalysts having 2-substituted indenyl type ligands | |
| US5239022A (en) | Process for the preparation of a syndiotactic polyolefin | |
| US5243001A (en) | Process for the preparation of a high molecular weight olefin polymer | |
| US5693730A (en) | Metallocenes, process for their preparation and their use as catalysts | |
| USRE37384E1 (en) | 2-substituted disindenylmetallocenes, process for their preparation, and their use as catalysts in the polymerization of olefins | |
| KR100414759B1 (ko) | 메탈로센 화합물, 이것의 제조 방법, 및 이것의 올레핀중합용 촉매로서의 용도 | |
| US6096912A (en) | Soluble catalyst systems for the preparation of polyalk-1-enes having high molecular weights | |
| US6197902B1 (en) | Syndio-isoblock polymer and process for its preparation | |
| JP3946282B2 (ja) | プロピレンのエチレンとのアモルファスコポリマー | |
| KR100451680B1 (ko) | 유기금속화합물 | |
| US5786495A (en) | Bridged bis-fluorenyl metallocenes, process for the preparation thereof and use thereof in catalysts for the polymerization of olefins | |
| US6177376B1 (en) | Process for preparing a metallocene catalyst system | |
| US5990331A (en) | Metallocenes containing partially hydrogenated p-ligands | |
| US5457171A (en) | Catalyst systems for the polymerization of C2 -C10 -alkenes | |
| US6177526B1 (en) | Supported catalyst system, process for its preparation and its use for the polymerization of olefins | |
| US6063949A (en) | Stereorigid metallocene compound | |
| JP2001525801A (ja) | 立体剛性メタロセン化合物 | |
| US6486277B1 (en) | Zwitterionic transition metal compound which contains boron | |
| USRE39156E1 (en) | Process for the preparation of polyolefins | |
| JP2001519436A (ja) | オレフィン重合で使用される、フェロセニル置換されたブリッジを持つメタロセン |