SI0643065T1 - Novel bisphosphines for asymetric hydrogenation catalysts - Google Patents

Novel bisphosphines for asymetric hydrogenation catalysts

Info

Publication number
SI0643065T1
SI0643065T1 SI9430296T SI9430296T SI0643065T1 SI 0643065 T1 SI0643065 T1 SI 0643065T1 SI 9430296 T SI9430296 T SI 9430296T SI 9430296 T SI9430296 T SI 9430296T SI 0643065 T1 SI0643065 T1 SI 0643065T1
Authority
SI
Slovenia
Prior art keywords
hydrogenation catalysts
bisphosphines
novel
asymetric
novel bisphosphines
Prior art date
Application number
SI9430296T
Other languages
English (en)
Slovenian (sl)
Inventor
Dr. Christian Laue
Dr. Georg Schr�der
Prof. Dr. Dieter Arlt
Dr. Rolf Grosser
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of SI0643065T1 publication Critical patent/SI0643065T1/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/313—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of doubly bound oxygen containing functional groups, e.g. carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5325—Aromatic phosphine oxides or thioxides (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5329—Polyphosphine oxides or thioxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
    • C07F9/65517—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring condensed with carbocyclic rings or carbocyclic ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B01J2231/482—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
SI9430296T 1993-09-10 1994-08-29 Novel bisphosphines for asymetric hydrogenation catalysts SI0643065T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4330730A DE4330730A1 (de) 1993-09-10 1993-09-10 Neue Bisphosphine für asymmetrische Hydrierkatalysatoren
EP94113441A EP0643065B1 (de) 1993-09-10 1994-08-29 Neue Bisphosphine für asymmetrische Hydrierkatalysatoren

Publications (1)

Publication Number Publication Date
SI0643065T1 true SI0643065T1 (en) 2000-02-29

Family

ID=6497384

Family Applications (1)

Application Number Title Priority Date Filing Date
SI9430296T SI0643065T1 (en) 1993-09-10 1994-08-29 Novel bisphosphines for asymetric hydrogenation catalysts

Country Status (12)

Country Link
US (1) US5510503A (da)
EP (1) EP0643065B1 (da)
JP (1) JP3681418B2 (da)
KR (1) KR100341258B1 (da)
AT (1) ATE186539T1 (da)
CA (1) CA2131571C (da)
DE (2) DE4330730A1 (da)
DK (1) DK0643065T3 (da)
ES (1) ES2139695T3 (da)
GR (1) GR3032397T3 (da)
SI (1) SI0643065T1 (da)
TW (1) TW370521B (da)

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US5935892A (en) 1994-02-22 1999-08-10 California Institute Of Technology Supported phase catalyst
US5736480A (en) * 1994-02-22 1998-04-07 California Institute Of Technology Supported phase chiral sulfonated BINAP catalyst solubilized in alcohol and method of asymmetric hydrogenation
DE4422672A1 (de) * 1994-06-30 1996-01-04 Hoechst Ag Halogenierte Biphenyl-2,2'-diyl-bis-diphenylphosphine, ihre Herstellung und ihre Verwendung
IT1270082B (it) 1994-07-12 1997-04-28 Univ Degli Studi Milano Difosfine eteroaromatiche come leganti chirali, complessi tra dette difosfine e metalli di transizione ed impiego di detti complessi come catalizzatori chirali
JP3789508B2 (ja) * 1995-03-14 2006-06-28 高砂香料工業株式会社 光学活性非対称ジホスフィン及び該化合物の存在下にて光学活性体を得る方法
DE19522293A1 (de) * 1995-06-20 1997-01-02 Bayer Ag Neue Bisphospine als Katalysatoren für asymmetrische Reaktionen
DE19530205A1 (de) * 1995-08-17 1997-02-20 Bayer Ag Verfahren zur Herstellung von optisch aktiven l-Aryl-alkylaminen
DE19535243A1 (de) * 1995-09-22 1997-03-27 Bayer Ag Neue Zwischenprodukte für die Synthese von Bisphosphinverbindungen
JP3431749B2 (ja) * 1996-03-07 2003-07-28 高砂香料工業株式会社 新規な１−置換−２−ジフェニルホスフィノナフタレンおよびこれを配位子とする遷移金属錯体
US5874629A (en) * 1996-06-12 1999-02-23 Merck & Co., Inc. Chiral bisphosphines
JPH1059992A (ja) * 1996-08-15 1998-03-03 Takasago Internatl Corp 新規ルテニウム錯体
JP3493266B2 (ja) * 1996-08-27 2004-02-03 高砂香料工業株式会社 新規な光学活性ジホスフィン化合物、該化合物を製造す る方法、該化合物を配位子とする遷移金属錯体並びに該 錯体を用いた光学活性体の製造方法
IT1286497B1 (it) * 1996-11-20 1998-07-15 Italfarmaco Sud Spa Difosfine di tipo misto eteroariliche-ariliche come leganti chirali, relativi complessi con metalli di transizione e impiego di detti
JP3148136B2 (ja) * 1996-12-26 2001-03-19 高砂香料工業株式会社 新規なキラルジホスフィン化合物、その製造中間体、該ジホス フィン化合物を配位子とする遷移金属錯体並びに該錯体を含む 不斉水素化触媒
US6207868B1 (en) * 1997-06-13 2001-03-27 The Penn State Research Foundation Asymmetric synthesis catalyzed by transition metal complexes with chiral ligands
US6162929A (en) * 1997-12-23 2000-12-19 Hoffmann-La Roche Inc. Process for the manufacture of bisphosphine oxide and bisphosphonate compounds
JP3549390B2 (ja) * 1998-03-23 2004-08-04 高砂香料工業株式会社 ルテニウム−ホスフィン錯体及びその製造方法
EP0949241B1 (fr) * 1998-04-07 2003-12-10 Firmenich Sa Isomérisation stéréospécifique d'amines allyliques à l'aide de ligands phosphorés chiraux
US7223879B2 (en) * 1998-07-10 2007-05-29 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
US6307087B1 (en) 1998-07-10 2001-10-23 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
IT1303757B1 (it) * 1998-11-16 2001-02-23 Sigma Tau Ind Farmaceuti Processo industriale per la produzione di l-carnitina.
US6563005B1 (en) 1998-12-03 2003-05-13 Cytec Technology Corp. Preparation of mono- and di-arylphosphines
ATE297807T1 (de) 1999-06-17 2005-07-15 Firmenich & Cie Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden
DE10027154A1 (de) * 2000-05-31 2001-12-13 Bayer Ag Verfahren zur Herstellung optisch aktiver Trimethylmilchsäure und ihrer Ester
DE10036516A1 (de) 2000-07-27 2002-02-07 Asta Medica Ag Verfahren zur Herstellung von enantiomerenreinen 6,8-Dihydroxyoctansäureestern durch assymetrische katalytische Hydrierung
DE10056310A1 (de) 2000-11-14 2002-05-16 Bayer Ag Verbessertes Verfahren zur Herstellung von enantiomerenreinen(5,5`-Dichlor-6,6`-dimethoxybiphenyl-2,2`-diyl)-bis-(diphenylphosphinoxiden)
DE10212301A1 (de) 2002-03-20 2003-10-02 Bayer Ag Verfahren zur Herstellung von Aryl-aminopropanolen
CA2496883C (en) 2002-08-27 2011-03-08 Merck Patent Gesellschaft Mit Beschraenkter Haftung Process for the enantioselective hydrogenation of amino alcohols
WO2008141077A1 (en) * 2007-05-10 2008-11-20 Janssen Pharmaceutica N.V. Process for the preparation of tetrahydroquinolinyl, benzoxazine and benzothiazine derivatives
FR2952638A1 (fr) * 2009-11-17 2011-05-20 Univ Strasbourg Procede de phosphination catalytique double ou triple de composes di, tri ou tetrahalobiaryles, intermediaires employes, composes obtenus et leurs utilisations
JP5810847B2 (ja) * 2011-11-08 2015-11-11 コニカミノルタ株式会社 有機エレクトロルミネッセンス素子用材料、有機エレクトロルミネッセンス素子、表示装置及び照明装置
TWI617352B (zh) * 2012-12-25 2018-03-11 南帝化學工業股份有限公司 催化劑組成物及使用該組成物之不飽合共聚物之氫化方法

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DK350383A (da) * 1982-08-27 1984-02-28 Hoffmann La Roche Phosphorforbindelser
JPS6163690A (ja) * 1984-09-04 1986-04-01 Takasago Corp ルテニウム−ホスフイン錯体
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JP2850068B2 (ja) * 1991-10-22 1999-01-27 高砂香料工業株式会社 ルテニウム−ホスフィン錯体及びこれを触媒とする光学活性１−置換−１，３−プロパンジオールの製造方法

Also Published As

Publication number Publication date
CA2131571A1 (en) 1995-03-11
ATE186539T1 (de) 1999-11-15
EP0643065B1 (de) 1999-11-10
KR950008525A (ko) 1995-04-19
JP3681418B2 (ja) 2005-08-10
EP0643065A1 (de) 1995-03-15
KR100341258B1 (ko) 2002-11-04
ES2139695T3 (es) 2000-02-16
TW370521B (en) 1999-09-21
US5510503A (en) 1996-04-23
GR3032397T3 (en) 2000-05-31
CA2131571C (en) 2005-07-26
JPH0782282A (ja) 1995-03-28
DE59408907D1 (de) 1999-12-16
DE4330730A1 (de) 1995-03-16
DK0643065T3 (da) 2000-05-08

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Legal Events

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Owner name: LANXESS DEUTSCHLAND GMBH; DE

Effective date: 20060831

KO00 Lapse of patent

Effective date: 20120403