SG11202000692VA - A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst - Google Patents

A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Info

Publication number
SG11202000692VA
SG11202000692VA SG11202000692VA SG11202000692VA SG11202000692VA SG 11202000692V A SG11202000692V A SG 11202000692VA SG 11202000692V A SG11202000692V A SG 11202000692VA SG 11202000692V A SG11202000692V A SG 11202000692VA SG 11202000692V A SG11202000692V A SG 11202000692VA
Authority
SG
Singapore
Prior art keywords
production
methyl methacrylate
heterogeneous catalyst
oxidative esterification
esterification
Prior art date
Application number
SG11202000692VA
Other languages
English (en)
Inventor
Justin Walker
Kirk W Limbach
Jeffrey Herron
Original Assignee
Rohm & Haas
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas, Dow Global Technologies Llc filed Critical Rohm & Haas
Publication of SG11202000692VA publication Critical patent/SG11202000692VA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/44Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/64Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644Arsenic, antimony or bismuth
    • B01J23/6447Bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51Spheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/0084Stationary elements inside the bed, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00858Moving elements
    • B01J2208/00867Moving elements inside the bed, e.g. rotary mixer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11202000692VA 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst SG11202000692VA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762538242P 2017-07-28 2017-07-28
PCT/US2018/039240 WO2019022891A1 (en) 2017-07-28 2018-06-25 PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDATIVE ESTERIZATION USING A HETEROGENEOUS CATALYST

Publications (1)

Publication Number Publication Date
SG11202000692VA true SG11202000692VA (en) 2020-02-27

Family

ID=62948353

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202000692VA SG11202000692VA (en) 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Country Status (9)

Country Link
US (1) US10800727B2 (ja)
EP (1) EP3658530A1 (ja)
JP (1) JP7212031B2 (ja)
KR (1) KR102639247B1 (ja)
CN (1) CN110997618B (ja)
BR (1) BR112020001595A2 (ja)
CA (1) CA3071243A1 (ja)
SG (1) SG11202000692VA (ja)
WO (1) WO2019022891A1 (ja)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981728B (zh) * 2019-12-06 2022-09-02 潍坊三力本诺化学工业有限公司 一种甲基丙烯酸甲酯的制备方法
CN118019726A (zh) * 2021-10-08 2024-05-10 罗门哈斯公司 用于氧化酯化反应器的方法
CN118076578A (zh) * 2021-10-08 2024-05-24 罗门哈斯公司 用于由氧化酯化反应器以副产物较低的方式形成甲基丙烯酸甲酯的方法
CN118043303A (zh) * 2021-10-08 2024-05-14 陶氏环球技术有限责任公司 用于降低添加碱的氧化酯化反应器中副产物形成的方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848369C3 (de) 1977-11-17 1981-08-06 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
DE3018071C2 (de) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
DE3306907A1 (de) 1983-02-26 1984-08-30 Basf Ag, 6700 Ludwigshafen Katalysator und seine verwendung zur herstellung von methylmethacrylat
JP3268022B2 (ja) * 1992-09-03 2002-03-25 旭化成株式会社 カルボン酸エステルの製造方法
DE69633753T2 (de) 1995-07-18 2005-12-22 Asahi Kasei Chemicals Corp. Verfahren zur Herstellung von Carbonsäureestern
JPH09216850A (ja) 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd カルボン酸エステルの製造方法
TW377306B (en) 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
JP3681285B2 (ja) * 1997-07-08 2005-08-10 旭化成ケミカルズ株式会社 メタクリル酸メチルの製造方法
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
TWI278346B (en) 2004-11-17 2007-04-11 Asahi Kasei Chemicals Corp Oxidation catalyst and oxidation method
CN1931824A (zh) 2006-09-18 2007-03-21 鲁东大学 一种由不饱和醛连续制备不饱和羧酸酯的方法及催化剂
US8461373B2 (en) 2007-08-13 2013-06-11 Asahi Kasei Chemicals Corporation Catalyst for producing carboxylic acid esters, process for producing same and process for producing carboxylic acid esters
GB201102502D0 (en) 2011-02-14 2011-03-30 Johnson Matthey Plc Catalysts for use in reforming processes
US9890105B2 (en) * 2013-04-19 2018-02-13 Evonik Roehm Gmbh Method for producing methylmethacrylate
EP2886529A1 (en) 2013-12-20 2015-06-24 Evonik Industries AG Process for producing methyl methacrylate
EP2886528A1 (de) 2013-12-20 2015-06-24 Evonik Industries AG Verfahren zur Herstellung von ungesättigten Estern ausgehend von Aldehyden durch Direkte Oxidative Veresterung
EP3170558A1 (de) 2015-11-19 2017-05-24 Evonik Röhm GmbH Gold-basierten katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
EP3235560A1 (de) * 2016-04-22 2017-10-25 Evonik Röhm GmbH Verfahren zur durchführung einer heterogen-katalysierten reaktion

Also Published As

Publication number Publication date
JP7212031B2 (ja) 2023-01-24
EP3658530A1 (en) 2020-06-03
US10800727B2 (en) 2020-10-13
JP2020528897A (ja) 2020-10-01
KR20200033277A (ko) 2020-03-27
KR102639247B1 (ko) 2024-02-21
CN110997618B (zh) 2023-04-04
CA3071243A1 (en) 2019-01-31
WO2019022891A1 (en) 2019-01-31
BR112020001595A2 (pt) 2020-07-21
CN110997618A (zh) 2020-04-10
US20200157037A1 (en) 2020-05-21

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