SG11202005802VA - A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst - Google Patents

A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Info

Publication number
SG11202005802VA
SG11202005802VA SG11202005802VA SG11202005802VA SG11202005802VA SG 11202005802V A SG11202005802V A SG 11202005802VA SG 11202005802V A SG11202005802V A SG 11202005802VA SG 11202005802V A SG11202005802V A SG 11202005802VA SG 11202005802V A SG11202005802V A SG 11202005802VA
Authority
SG
Singapore
Prior art keywords
production
methyl methacrylate
heterogeneous catalyst
oxidative esterification
esterification
Prior art date
Application number
SG11202005802VA
Inventor
Christopher D Frick
Jeffrey Herron
Kirk W Limbach
Wen Sheng Lee
Victor J Sussman
Original Assignee
Dow Global Technologies Llc
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc, Rohm & Haas filed Critical Dow Global Technologies Llc
Publication of SG11202005802VA publication Critical patent/SG11202005802VA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/088Decomposition of a metal salt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1812Tubular reactors
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11202005802VA 2018-01-10 2018-12-13 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst SG11202005802VA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862615504P 2018-01-10 2018-01-10
PCT/US2018/065374 WO2019139720A1 (en) 2018-01-10 2018-12-13 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Publications (1)

Publication Number Publication Date
SG11202005802VA true SG11202005802VA (en) 2020-07-29

Family

ID=65041908

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202005802VA SG11202005802VA (en) 2018-01-10 2018-12-13 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Country Status (11)

Country Link
US (1) US11111204B2 (en)
EP (1) EP3737661A1 (en)
JP (1) JP7305650B2 (en)
KR (1) KR102666711B1 (en)
CN (1) CN111465591A (en)
BR (1) BR112020011719A2 (en)
CA (1) CA3086012A1 (en)
MX (1) MX2020006522A (en)
SA (1) SA520412332B1 (en)
SG (1) SG11202005802VA (en)
WO (1) WO2019139720A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11577225B2 (en) * 2018-01-10 2023-02-14 Dow Global Technologies Llc Heterogeneous catalyst
MX2020012675A (en) 2018-06-28 2021-02-09 Dow Global Technologies Llc Heterogeneous catalyst.
MX2020012682A (en) 2018-06-28 2021-02-09 Dow Global Technologies Llc Heterogeneous catalyst.
WO2024123526A1 (en) * 2022-12-08 2024-06-13 Dow Global Technologies Llc Process for preparing alkyl methacrylates

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4069242B2 (en) * 2001-06-04 2008-04-02 株式会社日本触媒 Metal particle carrier and method for producing carboxylic acid ester
JP2002361086A (en) * 2001-06-04 2002-12-17 Nippon Shokubai Co Ltd Carboxylic acid ester synthesis catalyst and method for producing carboxylic acid ester
US7326806B2 (en) * 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
JP2004181359A (en) * 2002-12-03 2004-07-02 Nippon Shokubai Co Ltd Catalyst for producing carboxylic acid ester and method for producing carboxylic acid ester
JP2004181357A (en) 2002-12-03 2004-07-02 Nippon Shokubai Co Ltd Method for suppressing stripping of gold fine particle
BRPI0815166A8 (en) 2007-08-13 2016-12-20 Asahi Kasei Chemicals Corp CATALYST FOR USE IN THE PRODUCTION OF CARBOXYL ACID ESTER, PROCESSES FOR PRODUCING THE SAME, AND, FOR PRODUCING CARBOXYL ACID ESTER
CN201294443Y (en) 2008-12-01 2009-08-19 东元总合科技(杭州)有限公司 Permanent magnet self-startup synchronous motor rotor
CN105189444B (en) * 2013-04-19 2017-12-12 赢创罗姆有限公司 The method for preparing methyl methacrylate
US10232353B2 (en) 2015-01-16 2019-03-19 Evonik Röhm Gmbh Gold-based catalyst for the oxidative esterification of aldehydes to obtain carboxylic esters

Also Published As

Publication number Publication date
JP7305650B2 (en) 2023-07-10
EP3737661A1 (en) 2020-11-18
CA3086012A1 (en) 2019-07-18
MX2020006522A (en) 2020-10-14
BR112020011719A2 (en) 2020-11-17
US20200331840A1 (en) 2020-10-22
SA520412332B1 (en) 2023-11-30
CN111465591A (en) 2020-07-28
JP2021510679A (en) 2021-04-30
US11111204B2 (en) 2021-09-07
WO2019139720A1 (en) 2019-07-18
KR20200107985A (en) 2020-09-16
KR102666711B1 (en) 2024-05-17

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