SG11202000742QA - A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst - Google Patents

A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Info

Publication number
SG11202000742QA
SG11202000742QA SG11202000742QA SG11202000742QA SG11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA SG 11202000742Q A SG11202000742Q A SG 11202000742QA
Authority
SG
Singapore
Prior art keywords
production
methyl methacrylate
heterogeneous catalyst
oxidative esterification
esterification
Prior art date
Application number
SG11202000742QA
Inventor
Kirk W Limbach
Dmitri A Kraptchetov
Christopher D Frick
Daniel A Hickman
Original Assignee
Dow Global Technologies Llc
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc, Rohm & Haas filed Critical Dow Global Technologies Llc
Publication of SG11202000742QA publication Critical patent/SG11202000742QA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • B01J35/30
    • B01J35/394
    • B01J35/397
    • B01J35/399
    • B01J35/40
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44Palladium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48Silver or gold
    • C07C2523/52Gold
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials
SG11202000742QA 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst SG11202000742QA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762538237P 2017-07-28 2017-07-28
PCT/US2018/039238 WO2019022889A1 (en) 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Publications (1)

Publication Number Publication Date
SG11202000742QA true SG11202000742QA (en) 2020-02-27

Family

ID=63042096

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202000742QA SG11202000742QA (en) 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Country Status (10)

Country Link
US (1) US10829431B2 (en)
EP (1) EP3658533B1 (en)
JP (2) JP2020528442A (en)
KR (1) KR102639245B1 (en)
CN (1) CN111051274A (en)
BR (1) BR112020001805A2 (en)
CA (1) CA3071241A1 (en)
MX (1) MX2020001032A (en)
SG (1) SG11202000742QA (en)
WO (1) WO2019022889A1 (en)

Family Cites Families (26)

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GB2008430B (en) 1977-11-17 1982-04-28 Asahi Chemical Ind Process for producing carboxylic esters
DE3018071C2 (en) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Process for the preparation of carboxylic acid esters
DE3306907A1 (en) 1983-02-26 1984-08-30 Basf Ag, 6700 Ludwigshafen CATALYST AND ITS USE FOR PRODUCING METHYL METHACRYLATE
US5723041A (en) * 1994-10-10 1998-03-03 Amoco Corporation Process and apparatus for promoting annularly uniform flow
DE69632788T2 (en) 1995-07-18 2005-07-14 Asahi Kasei Chemicals Corp. CATALYST FOR THE PREPARATION OF CARBOXYLIC ACID ESTERS
US5856533A (en) * 1995-12-28 1999-01-05 Praxair Technology, Inc. High efficiency heat and mass transfer for vapor phase heterogeneous reactions
JPH09216850A (en) 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd Production of carboxylic acid ester
TW385304B (en) 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
TW377306B (en) * 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
JP3297342B2 (en) 1997-03-24 2002-07-02 三菱レイヨン株式会社 Method for producing carboxylic acid ester
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
JP4860064B2 (en) 2001-08-03 2012-01-25 旭化成ケミカルズ株式会社 PH control method in carboxylic acid ester synthesis reactor
JP4849387B2 (en) 2004-07-12 2012-01-11 アイシーエス株式会社 Process for producing fatty acid ester from fats and oils
WO2006054643A1 (en) 2004-11-17 2006-05-26 Asahi Kasei Chemicals Corporation Oxidation catalyst and oxidation method
JP4993437B2 (en) 2006-05-12 2012-08-08 旭化成ケミカルズ株式会社 Gold-supporting particles containing aluminum, silica and zirconia, and method for producing carboxylic acid ester using the particles
CN1931824A (en) 2006-09-18 2007-03-21 鲁东大学 Process and catalyst for preparing unsaturated carboxylate continuously from unsaturated aldehyde
CN101815579A (en) * 2007-08-13 2010-08-25 旭化成化学株式会社 Catalyst for carboxylic acid ester production, method for producing the same, and method for producing carboxylic acid ester
WO2009054462A1 (en) * 2007-10-26 2009-04-30 Asahi Kasei Chemicals Corporation Composite particle-loaded article, method for producing the composite particle-loaded article, and method for producing compound using the composite particle-loaded article as chemical synthesis catalyst
GB201102502D0 (en) 2011-02-14 2011-03-30 Johnson Matthey Plc Catalysts for use in reforming processes
EP2886529A1 (en) 2013-12-20 2015-06-24 Evonik Industries AG Process for producing methyl methacrylate
EP2886528A1 (en) * 2013-12-20 2015-06-24 Evonik Industries AG Method for producing unsaturated esters from aldehydes by direct oxidative esterification
CA2965481C (en) * 2014-10-31 2023-03-21 Rohm And Haas Company Oxidative esterification process for making methyl methacrylate
RU2017127194A (en) 2015-01-16 2019-02-20 Эвоник Рём ГмбХ GOLD-BASED CATALYST FOR THE OXIDATION ETHERIFICATION OF ALDEHYDES FOR THE PRODUCTION OF COMPLEX ETHERS OF CARBONIC ACIDS
EP3170558A1 (en) 2015-11-19 2017-05-24 Evonik Röhm GmbH Catalyst for oxidative esterification of aldehydes to carboxylic acid esters
EP3235560A1 (en) * 2016-04-22 2017-10-25 Evonik Röhm GmbH Method for performing a heterogeneously catalysed reaction

Also Published As

Publication number Publication date
EP3658533B1 (en) 2024-03-20
BR112020001805A2 (en) 2020-07-21
MX2020001032A (en) 2020-07-20
JP2023098982A (en) 2023-07-11
WO2019022889A1 (en) 2019-01-31
US10829431B2 (en) 2020-11-10
US20200148620A1 (en) 2020-05-14
EP3658533A1 (en) 2020-06-03
CN111051274A (en) 2020-04-21
KR20200033293A (en) 2020-03-27
KR102639245B1 (en) 2024-02-20
JP2020528442A (en) 2020-09-24
CA3071241A1 (en) 2019-01-31
JP7457859B2 (en) 2024-03-28

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