SG11202000678WA - A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst - Google Patents

A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Info

Publication number
SG11202000678WA
SG11202000678WA SG11202000678WA SG11202000678WA SG11202000678WA SG 11202000678W A SG11202000678W A SG 11202000678WA SG 11202000678W A SG11202000678W A SG 11202000678WA SG 11202000678W A SG11202000678W A SG 11202000678WA SG 11202000678W A SG11202000678W A SG 11202000678WA
Authority
SG
Singapore
Prior art keywords
production
methyl methacrylate
heterogeneous catalyst
oxidative esterification
esterification
Prior art date
Application number
SG11202000678WA
Inventor
Kirk W Limbach
Dmitri A Kraptchetov
Daniel A Hickman
Jeffrey Herron
Original Assignee
Rohm & Haas
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas, Dow Global Technologies Llc filed Critical Rohm & Haas
Publication of SG11202000678WA publication Critical patent/SG11202000678WA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C07C67/40Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of primary alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/394Metal dispersion value, e.g. percentage or fraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/399Distribution of the active metal ingredient homogeneously throughout the support particle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Dispersion Chemistry (AREA)
SG11202000678WA 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst SG11202000678WA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762538262P 2017-07-28 2017-07-28
PCT/US2018/039227 WO2019022882A1 (en) 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Publications (1)

Publication Number Publication Date
SG11202000678WA true SG11202000678WA (en) 2020-02-27

Family

ID=63047423

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202000678WA SG11202000678WA (en) 2017-07-28 2018-06-25 A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Country Status (10)

Country Link
US (1) US11691942B2 (en)
EP (1) EP3658534A1 (en)
JP (1) JP7150816B2 (en)
KR (1) KR102644577B1 (en)
CN (1) CN110997616A (en)
BR (1) BR112020001710A2 (en)
CA (1) CA3071184A1 (en)
SA (1) SA520411163B1 (en)
SG (1) SG11202000678WA (en)
WO (1) WO2019022882A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11691924B2 (en) * 2020-02-21 2023-07-04 Raytheon Technologies Corporation CVI matrix densification process
CA3184726A1 (en) * 2020-07-14 2022-01-20 Dow Global Technologies Llc Process and catalyst for oxidative esterication with mechanically strong and chemically resistant catalyst

Family Cites Families (26)

* Cited by examiner, † Cited by third party
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JPS55151533A (en) * 1979-05-17 1980-11-26 Asahi Chem Ind Co Ltd Preparation of carboxylic acid ester
DE3018071C2 (en) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Process for the preparation of carboxylic acid esters
IN151805B (en) 1979-05-17 1983-08-06 Asahi Chemical Ind
JPS58198442A (en) * 1982-05-14 1983-11-18 Asahi Chem Ind Co Ltd Improved method for preparation of methyl methacrylate or methyl acrylate
DE3306907A1 (en) 1983-02-26 1984-08-30 Basf Ag, 6700 Ludwigshafen CATALYST AND ITS USE FOR PRODUCING METHYL METHACRYLATE
JP2598466B2 (en) 1988-06-27 1997-04-09 松下電工株式会社 Nose hair cutter
EP1361206B1 (en) 1995-07-18 2004-10-27 Asahi Kasei Chemicals Corporation Method for producing carboxylic esters
JP3408700B2 (en) * 1996-10-07 2003-05-19 旭化成株式会社 Method for continuous production of carboxylic acid ester
TW377306B (en) 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
JP4001454B2 (en) * 2000-07-21 2007-10-31 株式会社日本触媒 How to stop the purification tower
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
JP2003267928A (en) 2002-03-14 2003-09-25 Asahi Kasei Corp Method for continuously producing carboxylic acid ester
JP4919808B2 (en) 2004-11-17 2012-04-18 旭化成ケミカルズ株式会社 Hydrocarbon, alcohol, aldehyde oxidation method and carboxylic acid, carboxylic acid ester production method
JP2007275854A (en) * 2006-04-12 2007-10-25 Asahi Kasei Chemicals Corp Carboxylate production catalyst excellent in reaction stability and method for producing carboxylate
CN1931824A (en) 2006-09-18 2007-03-21 鲁东大学 Process and catalyst for preparing unsaturated carboxylate continuously from unsaturated aldehyde
EP2177267B1 (en) * 2007-08-13 2013-07-31 Asahi Kasei Chemicals Corporation Catalyst for carboxylic acid ester production, method for producing the same, and method for producing carboxylic acid ester
EP2500093B1 (en) * 2007-10-26 2020-06-10 Asahi Kasei Kabushiki Kaisha Use of a supported composite particle material, production process of said material and process for producing compounds using supported composite particle material as catalyst for chemical synthesis
GB201102502D0 (en) 2011-02-14 2011-03-30 Johnson Matthey Plc Catalysts for use in reforming processes
CN102736757A (en) 2011-03-31 2012-10-17 比亚迪股份有限公司 Method and apparatus for touch control identification
GB201111819D0 (en) * 2011-07-11 2011-08-24 Johnson Matthey Plc Catalyst and method for its preparation
ES2673104T3 (en) * 2013-04-19 2018-06-19 Evonik Röhm Gmbh Procedure for the preparation of methyl methacrylate
EP2886529A1 (en) * 2013-12-20 2015-06-24 Evonik Industries AG Process for producing methyl methacrylate
EP2886528A1 (en) * 2013-12-20 2015-06-24 Evonik Industries AG Method for producing unsaturated esters from aldehydes by direct oxidative esterification
EP3170558A1 (en) 2015-11-19 2017-05-24 Evonik Röhm GmbH Catalyst for oxidative esterification of aldehydes to carboxylic acid esters
EP3235560A1 (en) * 2016-04-22 2017-10-25 Evonik Röhm GmbH Method for performing a heterogeneously catalysed reaction

Also Published As

Publication number Publication date
KR20200032139A (en) 2020-03-25
EP3658534A1 (en) 2020-06-03
JP7150816B2 (en) 2022-10-11
CN110997616A (en) 2020-04-10
CA3071184A1 (en) 2019-01-31
BR112020001710A2 (en) 2020-07-21
US11691942B2 (en) 2023-07-04
KR102644577B1 (en) 2024-03-07
US20210363094A1 (en) 2021-11-25
SA520411163B1 (en) 2024-08-19
JP2020528422A (en) 2020-09-24
WO2019022882A1 (en) 2019-01-31

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