SG11202002227SA - Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst - Google Patents

Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Info

Publication number
SG11202002227SA
SG11202002227SA SG11202002227SA SG11202002227SA SG11202002227SA SG 11202002227S A SG11202002227S A SG 11202002227SA SG 11202002227S A SG11202002227S A SG 11202002227SA SG 11202002227S A SG11202002227S A SG 11202002227SA SG 11202002227S A SG11202002227S A SG 11202002227SA
Authority
SG
Singapore
Prior art keywords
production
methyl methacrylate
heterogeneous catalyst
oxidative esterification
esterification
Prior art date
Application number
SG11202002227SA
Inventor
Jeffrey Herron
Daniel J Arriola
D Wayne Blaylock
Wen-Sheng Lee
Victor J Sussman
Daniel A Hickman
Kirk W Limbach
Original Assignee
Dow Global Technologies Llc
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc, Rohm & Haas filed Critical Dow Global Technologies Llc
Publication of SG11202002227SA publication Critical patent/SG11202002227SA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C07C67/40Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of primary alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/58Platinum group metals with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/63Platinum group metals with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/64Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396Distribution of the active metal ingredient
    • B01J35/397Egg shell like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11202002227SA 2017-09-19 2018-09-12 Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst SG11202002227SA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762560319P 2017-09-19 2017-09-19
PCT/US2018/050598 WO2019060192A1 (en) 2017-09-19 2018-09-12 Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Publications (1)

Publication Number Publication Date
SG11202002227SA true SG11202002227SA (en) 2020-04-29

Family

ID=63686162

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202002227SA SG11202002227SA (en) 2017-09-19 2018-09-12 Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst

Country Status (9)

Country Link
US (1) US10865179B2 (en)
EP (1) EP3684752A1 (en)
JP (1) JP7268007B2 (en)
CN (1) CN111417617B (en)
BR (1) BR112020004818B1 (en)
CA (1) CA3075083A1 (en)
MX (1) MX2020002600A (en)
SG (1) SG11202002227SA (en)
WO (1) WO2019060192A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112020023925A2 (en) * 2018-06-28 2021-02-09 Dow Global Technologies Llc heterogeneous catalyst, catalyst bed, and method for preparing methyl methacrylate.
CN112165987B (en) * 2018-06-28 2024-05-17 陶氏环球技术有限责任公司 Heterogeneous catalyst
CA3233801A1 (en) * 2021-10-08 2023-04-13 Rohm And Haas Company Process for alkyl methacrylate production

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7713727A (en) * 1976-12-21 1978-06-23 Halcon International Inc PROCEDURE FOR PREPARING GLYCOLESTERS.
GB2008430B (en) 1977-11-17 1982-04-28 Asahi Chemical Ind Process for producing carboxylic esters
DE3018071C2 (en) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Process for the preparation of carboxylic acid esters
JPS58146515A (en) * 1982-02-05 1983-09-01 モビル・オイル・コ−ポレ−シヨン Conversion of methanol to olefin
DE3306907A1 (en) 1983-02-26 1984-08-30 Basf Ag, 6700 Ludwigshafen CATALYST AND ITS USE FOR PRODUCING METHYL METHACRYLATE
KR100259743B1 (en) 1995-07-18 2000-07-01 야마모토 카즈모토 Catalyst for producing carboxylic esters
JPH09216850A (en) 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd Production of carboxylic acid ester
TW385304B (en) * 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
JP3408700B2 (en) 1996-10-07 2003-05-19 旭化成株式会社 Method for continuous production of carboxylic acid ester
US5892101A (en) 1996-11-18 1999-04-06 E. I. Du Pont De Nemours And Company Cross-dimerization of olefins
TW377306B (en) 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
JP3297342B2 (en) 1997-03-24 2002-07-02 三菱レイヨン株式会社 Method for producing carboxylic acid ester
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
JP4193391B2 (en) * 2000-11-01 2008-12-10 三菱化学株式会社 Contact reaction method
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
JP4860064B2 (en) 2001-08-03 2012-01-25 旭化成ケミカルズ株式会社 PH control method in carboxylic acid ester synthesis reactor
JP2003267928A (en) 2002-03-14 2003-09-25 Asahi Kasei Corp Method for continuously producing carboxylic acid ester
JP4919808B2 (en) * 2004-11-17 2012-04-18 旭化成ケミカルズ株式会社 Hydrocarbon, alcohol, aldehyde oxidation method and carboxylic acid, carboxylic acid ester production method
US20090292144A1 (en) * 2006-07-21 2009-11-26 Basf Se Direct amination of hydrocarbons
CN1931824A (en) 2006-09-18 2007-03-21 鲁东大学 Process and catalyst for preparing unsaturated carboxylate continuously from unsaturated aldehyde
MY152280A (en) 2007-08-13 2014-09-15 Asahi Kasei Chemicals Corp Catalyst for producing carboxylic acid esters, process for producing same and process for producing carboxylic acid esters
RU2437715C1 (en) * 2007-10-26 2011-12-27 Асахи Касеи Кемикалз Корпорейшн Material with composite particles on substrate, method of producing said material and method of producing compounds using material with composite particles on substrate as chemical synthesis catalyst
GB201102502D0 (en) 2011-02-14 2011-03-30 Johnson Matthey Plc Catalysts for use in reforming processes
EP2925714B1 (en) * 2012-11-30 2016-11-16 Basf Se Method for the catalytic aldol condensation of aldehydes
US9890105B2 (en) 2013-04-19 2018-02-13 Evonik Roehm Gmbh Method for producing methylmethacrylate
EP2883864A1 (en) * 2013-12-11 2015-06-17 Basf Se Method for hydrogenating aromatic compounds
EP2886528A1 (en) 2013-12-20 2015-06-24 Evonik Industries AG Method for producing unsaturated esters from aldehydes by direct oxidative esterification
EP2886529A1 (en) * 2013-12-20 2015-06-24 Evonik Industries AG Process for producing methyl methacrylate
US10232353B2 (en) 2015-01-16 2019-03-19 Evonik Röhm Gmbh Gold-based catalyst for the oxidative esterification of aldehydes to obtain carboxylic esters
EP3170558A1 (en) * 2015-11-19 2017-05-24 Evonik Röhm GmbH Catalyst for oxidative esterification of aldehydes to carboxylic acid esters
EP3235560A1 (en) * 2016-04-22 2017-10-25 Evonik Röhm GmbH Method for performing a heterogeneously catalysed reaction

Also Published As

Publication number Publication date
MX2020002600A (en) 2020-07-20
JP7268007B2 (en) 2023-05-02
CN111417617A (en) 2020-07-14
US20200216381A1 (en) 2020-07-09
BR112020004818B1 (en) 2023-04-11
EP3684752A1 (en) 2020-07-29
WO2019060192A1 (en) 2019-03-28
BR112020004818A2 (en) 2020-09-24
JP2020534262A (en) 2020-11-26
CN111417617B (en) 2023-06-20
KR20200051692A (en) 2020-05-13
CA3075083A1 (en) 2019-03-28
US10865179B2 (en) 2020-12-15

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