SE7703986L - Forfarande for separering och regenerering av katalysatorer - Google Patents

Forfarande for separering och regenerering av katalysatorer

Info

Publication number
SE7703986L
SE7703986L SE7703986A SE7703986A SE7703986L SE 7703986 L SE7703986 L SE 7703986L SE 7703986 A SE7703986 A SE 7703986A SE 7703986 A SE7703986 A SE 7703986A SE 7703986 L SE7703986 L SE 7703986L
Authority
SE
Sweden
Prior art keywords
catalysts
regeneration
hydrochloric acid
carbon monoxide
separated
Prior art date
Application number
SE7703986A
Other languages
Unknown language ( )
English (en)
Other versions
SE440609B (sv
Inventor
R Kummer
H-W Schneider
K Schwirten
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of SE7703986L publication Critical patent/SE7703986L/sv
Publication of SE440609B publication Critical patent/SE440609B/sv

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SE7703986A 1976-04-06 1977-04-05 Forfarande for separering och regenerering av rodium-fosfin-katalysatorer SE440609B (sv)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2614799A DE2614799C2 (de) 1976-04-06 1976-04-06 Verfahren zur Regenerierung von Rhodium enthaltenden Katalysatoren durch Behandeln von rhodiumhaltigen Destillationsrückständen von Hydroformylierungsgemischen

Publications (2)

Publication Number Publication Date
SE7703986L true SE7703986L (sv) 1977-10-07
SE440609B SE440609B (sv) 1985-08-12

Family

ID=5974560

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7703986A SE440609B (sv) 1976-04-06 1977-04-05 Forfarande for separering och regenerering av rodium-fosfin-katalysatorer

Country Status (13)

Country Link
US (1) US4113754A (sv)
JP (1) JPS52123397A (sv)
AT (1) AT347909B (sv)
BE (1) BE853246A (sv)
CA (1) CA1093057A (sv)
DE (1) DE2614799C2 (sv)
ES (1) ES457530A1 (sv)
FR (1) FR2347099A1 (sv)
GB (1) GB1576514A (sv)
IT (1) IT1085517B (sv)
NL (1) NL180482C (sv)
SE (1) SE440609B (sv)
SU (1) SU898951A3 (sv)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0007768A3 (en) * 1978-07-27 1980-02-20 DAVY McKEE (LONDON) LIMITED Hydroformylation of alpha-olefinic compounds
US4297239A (en) * 1979-07-16 1981-10-27 Union Carbide Corporation Hydroformylation catalyst reactivation
US4710587A (en) * 1980-04-16 1987-12-01 Union Carbide Corp. Process for removing triorganophosphine from an organic liquid
US4363764A (en) * 1980-12-30 1982-12-14 Union Carbide Corporation Preparation of rhodium complex compounds
US4388476A (en) * 1981-05-01 1983-06-14 Eastman Kodak Company Hydroformylation process with rhodium catalyst and oxygen stabilization thereof
GB2097795B (en) * 1981-05-01 1984-08-01 Johnson Matthey Plc Recovering triaryl phosphine from poisoned thodium catalyst systems
US4409149A (en) * 1981-06-29 1983-10-11 Union Carbide Corporation Process for producing catalyst precursors
DE3126265A1 (de) * 1981-07-03 1983-01-20 Basf Ag, 6700 Ludwigshafen Verfahren zur hydroformylierung olefinisch ungesaettigter verbindungen
US4446074A (en) * 1981-12-24 1984-05-01 Union Carbide Corporation Preparation of rhodium complex compounds
US4547595A (en) * 1982-09-02 1985-10-15 Ashland Oil, Inc. Method of reactivating Group VIII anionic hydroformylation catalysts
US4894477A (en) * 1986-10-14 1990-01-16 Hoechst Celanese Corporation Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid
DE3744213A1 (de) * 1987-12-24 1989-07-06 Ruhrchemie Ag Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen
DE4034501A1 (de) * 1990-10-30 1992-05-07 Hoechst Ag Verfahren zur entfernung metallischer korrosionsprodukte aus wasserfrei betriebenen carbonylierungsreaktionen
DE4316180A1 (de) * 1992-09-16 1994-11-17 Basf Ag Verfahren zur Herstellung von Aldehyden
GB9305902D0 (en) * 1993-03-22 1993-05-12 Bp Chem Int Ltd Process
US5773665A (en) * 1996-07-01 1998-06-30 Elf Atochem North America, Inc. Hydroformylation process with separation and recycle of active rhodium catalyst
PL184401B1 (pl) * 1995-07-18 2002-10-31 Atofina Chemicals Sposób oczyszczania i separacji aktywnego katalizatora rodowego od nieaktywnego katalizatora rodowego zawartego w strumieniu procesu hydroformylowania, kwasowa żywica jonowymienna i sposób hydroformylowania olefin
GB0113079D0 (en) 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
GB0113080D0 (en) * 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
RU2628609C2 (ru) * 2015-12-30 2017-08-21 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Способ получения альдегидов гидроформилированием с модификацией лигандов ацетализацией
CN106187721B (zh) * 2016-08-25 2019-04-02 浙江巴陵恒逸己内酰胺有限责任公司 利用蒸汽加热导热油进行环己醇脱氢反应的工艺系统
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3515757A (en) * 1966-04-01 1970-06-02 Ethyl Corp Organic compounds and processes
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
US3560539A (en) * 1968-08-21 1971-02-02 Union Oil Co Selective catalyst recovery
DE1954315C3 (de) * 1969-10-29 1975-08-14 Basf Ag, 6700 Ludwigshafen Verfahren zur Abtrennung von Metallcarbonylkatalysatoren aus Oxoreaktionsge mischen
DE2045416C3 (de) * 1970-09-15 1979-10-25 Basf Ag, 6700 Ludwigshafen Verfahren zur Elution von Rhodium, das als Rhodiumcarbonylat auf einem basischen Ionenaustauscher gebunden ist
AT312559B (de) * 1972-01-07 1974-01-10 Basf Ag Verfahren zur Abscheidung von Rhodium aus Rhodiumcarbonylkomplexe enthaltenden Lösungen und Überführung des abgescheidenen Rhodiums in lösliche Rhodiumcarbonylkomplexe
IT1007026B (it) * 1974-01-23 1976-10-30 Montedison Spa Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione
DE2448005C2 (de) * 1974-10-09 1983-10-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium oder Iridium enthaltenden Katalysatoren aus Destillationsrückständen von Hydroformylierungsgemischen

Also Published As

Publication number Publication date
BE853246A (fr) 1977-10-05
AT347909B (de) 1979-01-25
ES457530A1 (es) 1978-03-16
FR2347099B1 (sv) 1980-05-09
SU898951A3 (ru) 1982-01-15
JPS616703B2 (sv) 1986-02-28
ATA236477A (de) 1978-06-15
GB1576514A (en) 1980-10-08
CA1093057A (en) 1981-01-06
SE440609B (sv) 1985-08-12
IT1085517B (it) 1985-05-28
DE2614799C2 (de) 1986-02-27
DE2614799A1 (de) 1977-10-27
FR2347099A1 (fr) 1977-11-04
JPS52123397A (en) 1977-10-17
NL7703723A (nl) 1977-10-10
NL180482C (nl) 1987-03-02
US4113754A (en) 1978-09-12

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