RU95109575A - Способ гидроксикарбонилирования пентеновых кислот, бутадиена и его производных - Google Patents
Способ гидроксикарбонилирования пентеновых кислот, бутадиена и его производныхInfo
- Publication number
- RU95109575A RU95109575A RU95109575/04A RU95109575A RU95109575A RU 95109575 A RU95109575 A RU 95109575A RU 95109575/04 A RU95109575/04 A RU 95109575/04A RU 95109575 A RU95109575 A RU 95109575A RU 95109575 A RU95109575 A RU 95109575A
- Authority
- RU
- Russia
- Prior art keywords
- hydroxycarbonylation
- catalyst
- butadiene
- derivatives
- separated
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title claims 5
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical class CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 claims abstract 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract 2
- 229910052740 iodine Inorganic materials 0.000 claims abstract 2
- 239000011630 iodine Substances 0.000 claims abstract 2
- 229910052741 iridium Inorganic materials 0.000 claims abstract 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000011541 reaction mixture Substances 0.000 claims abstract 2
- 238000007670 refining Methods 0.000 claims abstract 2
- 229910052703 rhodium Inorganic materials 0.000 claims abstract 2
- 239000010948 rhodium Substances 0.000 claims abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 2
- YIYBQIKDCADOSF-UHFFFAOYSA-N pentenoic acid group Chemical class C(C=CCC)(=O)O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 claims 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
- C07C55/02—Dicarboxylic acids
- C07C55/14—Adipic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Предметом изобретения является способ гидроксикарбонилирования пентеновых кислот, заключающийся в том, что гидроксикарбонилируют одну или несколько пентеновых кислот до адипиновой кислоты с помощью монооксида углерода и воды в присутствии катализатора на основе иридия и/или родия и по крайней мере одного иодсодержащего промотора; полученную реакционную смесь подвергают процессу рафинирования, в случае необходимости после концентрирования, позволяющему отделять по крайней мере часть катализатора; таким образом отделенный катализатор рециркулируют в процесс гидроксикарбонилирования пентеновых кислот, бутадиена или производных бутадиена.
Claims (1)
- Предметом изобретения является способ гидроксикарбонилирования пентеновых кислот, заключающийся в том, что гидроксикарбонилируют одну или несколько пентеновых кислот до адипиновой кислоты с помощью монооксида углерода и воды в присутствии катализатора на основе иридия и/или родия и по крайней мере одного иодсодержащего промотора; полученную реакционную смесь подвергают процессу рафинирования, в случае необходимости после концентрирования, позволяющему отделять по крайней мере часть катализатора; таким образом отделенный катализатор рециркулируют в процесс гидроксикарбонилирования пентеновых кислот, бутадиена или производных бутадиена.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9212913 | 1992-10-22 | ||
| FR9212913A FR2697247B1 (fr) | 1992-10-22 | 1992-10-22 | Procédé d'hydroxycarbonylation d'acides penténoiques. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU95109575A true RU95109575A (ru) | 1996-12-27 |
| RU2119477C1 RU2119477C1 (ru) | 1998-09-27 |
Family
ID=9434963
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU95109575A RU2119477C1 (ru) | 1992-10-22 | 1993-10-19 | Способ гидроксикарбонилирования одной или нескольких пентеновых кислот до адипиновой кислоты |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6008408A (ru) |
| EP (1) | EP0665828B1 (ru) |
| JP (1) | JP2895233B2 (ru) |
| KR (1) | KR0185232B1 (ru) |
| CN (1) | CN1034660C (ru) |
| BR (1) | BR9307284A (ru) |
| CA (1) | CA2146975A1 (ru) |
| CZ (1) | CZ286694B6 (ru) |
| DE (1) | DE69310193T2 (ru) |
| ES (1) | ES2100575T3 (ru) |
| FR (1) | FR2697247B1 (ru) |
| PL (1) | PL175043B1 (ru) |
| RU (1) | RU2119477C1 (ru) |
| SG (1) | SG70989A1 (ru) |
| SK (1) | SK280442B6 (ru) |
| TW (1) | TW252102B (ru) |
| UA (1) | UA44228C2 (ru) |
| WO (1) | WO1994008939A1 (ru) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5292944A (en) * | 1993-06-29 | 1994-03-08 | E. I. Du Pont De Nemours And Company | Process for the preparation of adipic acid or pentenoic acid |
| FR2749299B1 (fr) * | 1996-06-04 | 1998-07-17 | Rhone Poulenc Fibres | Procede de purification de l'acide adipique dans l'eau |
| TW200633971A (en) * | 2005-02-11 | 2006-10-01 | Shell Int Research | Process for the carbonylation of a conjugated diene |
| US20090131630A1 (en) * | 2005-02-11 | 2009-05-21 | Van Broekhoven Johannes Adrian | Process For the Preparation of a Dicarboxylic Acid |
| CN101142162A (zh) * | 2005-02-11 | 2008-03-12 | 国际壳牌研究有限公司 | 二羧酸的制备方法 |
| US20080194870A1 (en) * | 2005-02-11 | 2008-08-14 | Eit Drent | Process for the Preparation of a Dicarboxylic Acid |
| TW200633972A (en) * | 2005-02-11 | 2006-10-01 | Shell Int Research | Process for the carbonylation of a conjugated diene |
| WO2006125801A1 (en) * | 2005-05-27 | 2006-11-30 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of adipic acid from n-pentenoic acid |
| CN115445662B (zh) * | 2022-08-31 | 2023-08-15 | 迈奇化学股份有限公司 | γ-丁内酯羰基化用催化剂及由γ-丁内酯合成戊二酸的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA512911A (en) * | 1955-05-17 | B. Clark William | Adipic acid crystallization | |
| US2910516A (en) * | 1953-08-20 | 1959-10-27 | Phillips Petroleum Co | Fractional crystallization process and apparatus |
| NL255708A (ru) * | 1959-09-08 | |||
| US4788333A (en) * | 1985-01-07 | 1988-11-29 | E. I. Du Pont De Nemours And Company | Hydrocarboxylation of unsaturated carboxylic acids to linear dicarboxylic acids |
| FR2666808B1 (fr) * | 1990-09-18 | 1994-04-01 | Rhone Poulenc Chimie | Procede de preparation de l'acide adipique par hydrocarboxylation d'acides penteniques. |
| US5166421A (en) * | 1991-03-18 | 1992-11-24 | E. I. Du Pont De Nemours And Company | Process for the manufacture of adipic acid |
-
1992
- 1992-10-22 FR FR9212913A patent/FR2697247B1/fr not_active Expired - Fee Related
-
1993
- 1993-10-04 TW TW082108170A patent/TW252102B/zh active
- 1993-10-19 RU RU95109575A patent/RU2119477C1/ru not_active IP Right Cessation
- 1993-10-19 KR KR1019950701488A patent/KR0185232B1/ko not_active IP Right Cessation
- 1993-10-19 SG SG1996008354A patent/SG70989A1/en unknown
- 1993-10-19 EP EP93924095A patent/EP0665828B1/fr not_active Expired - Lifetime
- 1993-10-19 CA CA002146975A patent/CA2146975A1/fr not_active Abandoned
- 1993-10-19 ES ES93924095T patent/ES2100575T3/es not_active Expired - Lifetime
- 1993-10-19 US US08/424,335 patent/US6008408A/en not_active Expired - Fee Related
- 1993-10-19 DE DE69310193T patent/DE69310193T2/de not_active Expired - Fee Related
- 1993-10-19 CZ CZ19951013A patent/CZ286694B6/cs not_active IP Right Cessation
- 1993-10-19 WO PCT/FR1993/001028 patent/WO1994008939A1/fr active IP Right Grant
- 1993-10-19 SK SK518-95A patent/SK280442B6/sk unknown
- 1993-10-19 PL PL93308300A patent/PL175043B1/pl not_active IP Right Cessation
- 1993-10-19 BR BR9307284A patent/BR9307284A/pt not_active IP Right Cessation
- 1993-10-19 JP JP6509714A patent/JP2895233B2/ja not_active Expired - Lifetime
- 1993-10-19 UA UA95038271A patent/UA44228C2/uk unknown
- 1993-10-21 CN CN93119171A patent/CN1034660C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| SG70989A1 (en) | 2000-03-21 |
| CN1034660C (zh) | 1997-04-23 |
| RU2119477C1 (ru) | 1998-09-27 |
| FR2697247B1 (fr) | 1994-12-02 |
| CZ286694B6 (en) | 2000-06-14 |
| SK51895A3 (en) | 1995-08-09 |
| DE69310193T2 (de) | 1997-10-30 |
| US6008408A (en) | 1999-12-28 |
| PL308300A1 (en) | 1995-07-24 |
| TW252102B (ru) | 1995-07-21 |
| WO1994008939A1 (fr) | 1994-04-28 |
| SK280442B6 (sk) | 2000-02-14 |
| CA2146975A1 (fr) | 1994-04-28 |
| CN1090840A (zh) | 1994-08-17 |
| BR9307284A (pt) | 1999-05-11 |
| JPH08501726A (ja) | 1996-02-27 |
| UA44228C2 (uk) | 2002-02-15 |
| KR0185232B1 (ko) | 1999-05-15 |
| DE69310193D1 (de) | 1997-05-28 |
| JP2895233B2 (ja) | 1999-05-24 |
| FR2697247A1 (fr) | 1994-04-29 |
| KR950703507A (ko) | 1995-09-20 |
| EP0665828B1 (fr) | 1997-04-23 |
| ES2100575T3 (es) | 1997-06-16 |
| EP0665828A1 (fr) | 1995-08-09 |
| CZ101395A3 (en) | 1995-10-18 |
| PL175043B1 (pl) | 1998-10-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20091020 |