SE444003B - Komposition till anvendning som korrosions- och pannstensinbibitorer for metallytor i vattenhaltiga system - Google Patents
Komposition till anvendning som korrosions- och pannstensinbibitorer for metallytor i vattenhaltiga systemInfo
- Publication number
- SE444003B SE444003B SE7801154A SE7801154A SE444003B SE 444003 B SE444003 B SE 444003B SE 7801154 A SE7801154 A SE 7801154A SE 7801154 A SE7801154 A SE 7801154A SE 444003 B SE444003 B SE 444003B
- Authority
- SE
- Sweden
- Prior art keywords
- water
- acid
- soluble polymer
- dimethylaminomethylene
- composition according
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 61
- 238000005260 corrosion Methods 0.000 title claims description 26
- 230000007797 corrosion Effects 0.000 title claims description 19
- 239000003112 inhibitor Substances 0.000 title description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 40
- BFDMEODWJJUORJ-UHFFFAOYSA-N [dimethylamino(phosphono)methyl]phosphonic acid Chemical compound CN(C)C(P(O)(O)=O)P(O)(O)=O BFDMEODWJJUORJ-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 229920002125 Sokalan® Polymers 0.000 claims description 21
- 239000004584 polyacrylic acid Substances 0.000 claims description 21
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 15
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 14
- 229920003169 water-soluble polymer Polymers 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- -1 alkali metal salts Chemical class 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000011592 zinc chloride Substances 0.000 claims description 7
- 235000005074 zinc chloride Nutrition 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000003751 zinc Chemical class 0.000 claims description 5
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 239000002455 scale inhibitor Substances 0.000 claims description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims 1
- UTRWIBWHXZRMIB-UHFFFAOYSA-N [methylamino(phosphono)methyl]phosphonic acid Chemical compound CNC(P(O)(O)=O)P(O)(O)=O UTRWIBWHXZRMIB-UHFFFAOYSA-N 0.000 claims 1
- 125000000271 carboxylic acid salt group Chemical group 0.000 claims 1
- 229920000141 poly(maleic anhydride) Polymers 0.000 claims 1
- 239000000243 solution Substances 0.000 description 46
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 30
- 238000001556 precipitation Methods 0.000 description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 16
- 229910000019 calcium carbonate Inorganic materials 0.000 description 15
- 235000010216 calcium carbonate Nutrition 0.000 description 15
- 230000005764 inhibitory process Effects 0.000 description 14
- 239000004575 stone Substances 0.000 description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 12
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 10
- 229910052791 calcium Inorganic materials 0.000 description 10
- 239000011575 calcium Substances 0.000 description 10
- 235000011132 calcium sulphate Nutrition 0.000 description 10
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 239000001175 calcium sulphate Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- 239000000498 cooling water Substances 0.000 description 6
- MSNWSDPPULHLDL-UHFFFAOYSA-K ferric hydroxide Chemical compound [OH-].[OH-].[OH-].[Fe+3] MSNWSDPPULHLDL-UHFFFAOYSA-K 0.000 description 6
- 230000002401 inhibitory effect Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 235000019700 dicalcium phosphate Nutrition 0.000 description 5
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001348 alkyl chlorides Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229960004887 ferric hydroxide Drugs 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001350 alkyl halides Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical group 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- HFWUFTDXLCGTRE-UHFFFAOYSA-L P(OC(N(C)C)OP([O-])=O)([O-])=O.[Na+].[Na+].[Na+] Chemical compound P(OC(N(C)C)OP([O-])=O)([O-])=O.[Na+].[Na+].[Na+] HFWUFTDXLCGTRE-UHFFFAOYSA-L 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 238000003321 atomic absorption spectrophotometry Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000007773 growth pattern Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
- C02F5/145—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus combined with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3839—Polyphosphonic acids
- C07F9/3873—Polyphosphonic acids containing nitrogen substituent, e.g. N.....H or N-hydrocarbon group which can be substituted by halogen or nitro(so), N.....O, N.....S, N.....C(=X)- (X =O, S), N.....N, N...C(=X)...N (X =O, S)
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Metallurgy (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/845,011 US4163733A (en) | 1977-10-25 | 1977-10-25 | Synergistic compositions for corrosion and scale control |
Publications (2)
Publication Number | Publication Date |
---|---|
SE7801154L SE7801154L (sv) | 1979-04-26 |
SE444003B true SE444003B (sv) | 1986-03-17 |
Family
ID=25294194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE7801154A SE444003B (sv) | 1977-10-25 | 1978-01-31 | Komposition till anvendning som korrosions- och pannstensinbibitorer for metallytor i vattenhaltiga system |
Country Status (18)
Country | Link |
---|---|
US (2) | US4163733A (bg) |
JP (2) | JPS5495648A (bg) |
AR (1) | AR217676A1 (bg) |
AU (1) | AU518434B2 (bg) |
BE (1) | BE863904A (bg) |
BR (1) | BR7806956A (bg) |
CA (1) | CA1089315A (bg) |
DE (1) | DE2807222B2 (bg) |
ES (1) | ES467263A1 (bg) |
FR (2) | FR2407253A1 (bg) |
GB (1) | GB1590510A (bg) |
IT (1) | IT1102471B (bg) |
MX (1) | MX149051A (bg) |
NL (1) | NL175440C (bg) |
NO (1) | NO780906L (bg) |
NZ (1) | NZ186474A (bg) |
SE (1) | SE444003B (bg) |
ZA (1) | ZA781847B (bg) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2838437A1 (de) * | 1978-09-02 | 1980-03-20 | Benckiser Gmbh Joh A | N,n'-dialkyl-ureidomethan-diphosphonsaeure, deren herstellung und verwendung |
US4411865A (en) * | 1979-04-05 | 1983-10-25 | Betz Laboratories, Inc. | Method of corrosion inhibition in aqueous mediums |
US4279758A (en) * | 1979-07-19 | 1981-07-21 | Joh. A. Benckiser Gmbh | Process for inhibiting the formation of mineral deposits from a water using N-N-dialkylureidomethane diphosphonic acids |
US4303568A (en) * | 1979-12-10 | 1981-12-01 | Betz Laboratories, Inc. | Corrosion inhibition treatments and method |
DE3047107A1 (de) * | 1980-12-13 | 1982-07-29 | Hoechst Ag, 6000 Frankfurt | Verfahren zur hertellung von 1-amino-alkan-1,1-diphosphonsaeuren |
US4414126A (en) * | 1981-10-22 | 1983-11-08 | Basf Wyandotte Corporation | Aqueous compositions containing corrosion inhibitors for high lead solder |
US4457847B2 (en) * | 1981-11-05 | 1996-12-31 | Nalco Chemical Co | Carboxylate polymers for internal scale control agents in boiler systems |
EP0089189B1 (en) * | 1982-03-11 | 1986-06-11 | Calgon Corporation | A calcium carbonate, magnesium hydroxide and calcium sulfate hemihydrate scale inhibitor |
US4714564A (en) * | 1982-04-21 | 1987-12-22 | The United States Of America As Represented By The Secretary Of The Air Force | High performance multifunctional corrosion inhibitors especially for combining at 20 to 50 weight percent with soap or paint |
GB8309573D0 (en) * | 1983-04-08 | 1983-05-11 | Ciba Geigy Ag | Water treatment composition |
US4642194A (en) * | 1985-09-16 | 1987-02-10 | Nalco Chemical Company | Method for prevention of phosphonate decomposition by chlorine |
US4711724A (en) * | 1985-09-16 | 1987-12-08 | Nalco Chemical Company | Method for prevention of phosphonate decomposition by chlorine |
US4959075A (en) * | 1985-12-23 | 1990-09-25 | Henkel Kommanditgesellschaft Auf Aktien | Silicate- and magnesium-free stabilizer hydrogen peroxide mixtures for bleaching processes |
DE3545909A1 (de) * | 1985-12-23 | 1987-06-25 | Henkel Kgaa | Silikat- und magnesiumfreie wirkstoffgemische |
US4904413A (en) * | 1986-03-26 | 1990-02-27 | Nalco Chemical Company | Cooling water corrosion control method and composition |
US4717542A (en) * | 1987-01-23 | 1988-01-05 | W. R. Grace & Co. | Inhibiting corrosion of iron base metals |
US5068059A (en) * | 1990-01-16 | 1991-11-26 | Drew Chemical Corporation | Corrosion inhibitor |
DE4006849C2 (de) * | 1990-03-05 | 1999-01-28 | Brigitte Mendel Fa | Verfahren zum Markieren von in einem Stapel enthaltenen Teilstapeln aus einer bestimmten Anzahl von ausgestanzten Folienzuschnitten und Vorrichtung zur Durchführung des Verfahrens |
US5089150A (en) * | 1990-05-29 | 1992-02-18 | Mobil Oil Corporation | Method of increasing retention of scale inhibitors in subterranean formations |
US5019651A (en) * | 1990-06-20 | 1991-05-28 | Merck & Co., Inc. | Process for preparing 4-amino-1-hydroxybutylidene-1,1-bisphosphonic acid (ABP) or salts thereof |
US5292449A (en) * | 1992-11-24 | 1994-03-08 | Akzo Nv | Scale inhibiting composition |
CA2197267C (en) * | 1997-02-11 | 2000-02-08 | Yong Tao | Process for the production of 4-amino-1-hydroxybutylidene-1,1-bisphosphonic acid or salts thereof |
US6585933B1 (en) | 1999-05-03 | 2003-07-01 | Betzdearborn, Inc. | Method and composition for inhibiting corrosion in aqueous systems |
AU2003211022A1 (en) * | 2002-02-19 | 2003-09-09 | Ilex Products, Inc. | Aminodiphosphonate apolipoprotein e modulators |
CN103819506A (zh) * | 2014-03-12 | 2014-05-28 | 山东省泰和水处理有限公司 | 一种用于炼油厂循环冷却水的阻垢缓蚀剂制备方法 |
CN104086007A (zh) * | 2014-07-31 | 2014-10-08 | 威海翔宇环保科技有限公司 | 一种供热管网用缓蚀阻垢剂 |
DE102018119835A1 (de) | 2018-08-15 | 2020-02-20 | Chemische Fabrik Budenheim Kg | Polymerzusammensetzung mit Phosphonatflammschutzmittel |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2763200A (en) * | 1953-08-21 | 1956-09-18 | Charles R Kittler | Charcoal barbecue |
DE1302557B (bg) * | 1963-04-09 | 1971-08-26 | ||
US3505238A (en) * | 1965-03-29 | 1970-04-07 | Calgon C0Rp | Methods and compositions for inhibiting scale in saline water evaporators |
IL30533A (en) * | 1967-09-01 | 1972-01-27 | Bayer Ag | Thiol-or thionothiol-phosphoric or-phosphonic acid esters |
GB1208827A (en) * | 1968-02-23 | 1970-10-14 | Grace W R & Co | Composition and process for inhibiting scaling and/or corrosion in cooling water systems and for stabilizing phosphate solutions |
DE1806594C3 (de) * | 1968-11-02 | 1979-05-03 | Joh. A. Benckiser Gmbh, 6700 Ludwigshafen | Verwendung eines Gemisches aus Aminoalkylenphosphonsäure und polymerer Verbindungen zur Verhinderung von Steinbildenden Ablagerungen in wässrigen Systemen |
DE1958123C3 (de) * | 1969-11-19 | 1978-09-28 | Henkel Kgaa, 4000 Duesseldorf | Verfahren zur Herstellung von 1 -Aminoalkan-1,1 -diphosphonsäuren oder deren Salzen |
DE2022777A1 (de) * | 1970-05-09 | 1971-11-25 | Henkel & Cie Gmbh | Inhibitor fuer Aluminium in alkalischen Loesungen |
US3669673A (en) * | 1970-10-23 | 1972-06-13 | Rca Corp | Recording of a continuous tone focused image on a diffraction grating |
DE2104476C2 (de) * | 1971-02-01 | 1983-12-01 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur Verhinderung von Ausfällungen in Wasser oder wäßrigen Lösungen |
US3821335A (en) * | 1971-02-04 | 1974-06-28 | Swift & Co | Aminomethylphosphonates |
GB1374270A (en) * | 1971-12-10 | 1974-11-20 | Ciba Geigy Ag | Polymaleic anhydride compositions and their use |
US3963636A (en) * | 1972-12-04 | 1976-06-15 | Ciba-Geigy Corporation | Treatment of water or aqueous systems |
DE2306069A1 (de) * | 1973-02-08 | 1974-08-22 | Henkel & Cie Gmbh | Waschmittel |
US3890228A (en) * | 1973-04-13 | 1975-06-17 | Chemed Corp | Polyacrylate-polyphosphonic acid treatment in aqueous systems |
US3885914A (en) * | 1973-06-04 | 1975-05-27 | Calgon Corp | Polymer-zinc corrosion inhibiting method |
US3975160A (en) * | 1974-07-29 | 1976-08-17 | Milton Roy Company | Colorimetric analyzer |
US4018701A (en) * | 1975-07-31 | 1977-04-19 | Calgon Corporation | Phosphorous acid and zinc corrosion inhibiting compositions and methods for using same |
US4029696A (en) * | 1976-04-09 | 1977-06-14 | Benckiser-Knapsack Gmbh | N-hydroxy alkane amino alkane diphosphonic acids, process of producing same, and compositions for and method of using same |
-
1977
- 1977-10-25 US US05/845,011 patent/US4163733A/en not_active Expired - Lifetime
-
1978
- 1978-01-31 SE SE7801154A patent/SE444003B/sv not_active IP Right Cessation
- 1978-02-06 CA CA296,315A patent/CA1089315A/en not_active Expired
- 1978-02-08 US US05/875,964 patent/US4157364A/en not_active Expired - Lifetime
- 1978-02-13 AR AR271093A patent/AR217676A1/es active
- 1978-02-13 BE BE185118A patent/BE863904A/xx not_active IP Right Cessation
- 1978-02-14 NZ NZ186474A patent/NZ186474A/xx unknown
- 1978-02-14 AU AU33284/78A patent/AU518434B2/en not_active Expired
- 1978-02-20 DE DE2807222A patent/DE2807222B2/de not_active Ceased
- 1978-02-23 ES ES467263A patent/ES467263A1/es not_active Expired
- 1978-02-28 FR FR7805776A patent/FR2407253A1/fr active Granted
- 1978-03-01 MX MX172612A patent/MX149051A/es unknown
- 1978-03-14 NO NO780906A patent/NO780906L/no unknown
- 1978-03-29 NL NLAANVRAGE7803311,A patent/NL175440C/xx not_active IP Right Cessation
- 1978-03-31 ZA ZA00781847A patent/ZA781847B/xx unknown
- 1978-04-06 IT IT48768/78A patent/IT1102471B/it active
- 1978-05-22 GB GB21014/78A patent/GB1590510A/en not_active Expired
- 1978-10-20 BR BR7806956A patent/BR7806956A/pt unknown
- 1978-10-25 JP JP13146778A patent/JPS5495648A/ja active Granted
- 1978-11-23 FR FR7833054A patent/FR2407217B3/fr not_active Expired
-
1979
- 1979-01-24 JP JP698879A patent/JPS54160317A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
IT1102471B (it) | 1985-10-07 |
CA1089315A (en) | 1980-11-11 |
NL7803311A (nl) | 1979-04-27 |
NZ186474A (en) | 1979-08-31 |
DE2807222B2 (de) | 1980-05-22 |
JPS5444694B2 (bg) | 1979-12-27 |
AU3328478A (en) | 1979-08-23 |
DE2807222A1 (de) | 1979-04-26 |
FR2407253B1 (bg) | 1983-02-25 |
FR2407217B3 (bg) | 1980-06-20 |
JPS54160317A (en) | 1979-12-19 |
BR7806956A (pt) | 1979-07-10 |
FR2407217A1 (bg) | 1979-05-25 |
SE7801154L (sv) | 1979-04-26 |
US4157364A (en) | 1979-06-05 |
JPS5495648A (en) | 1979-07-28 |
NL175440B (nl) | 1984-06-01 |
ZA781847B (en) | 1979-03-28 |
AR217676A1 (es) | 1980-04-15 |
NO780906L (no) | 1979-04-26 |
GB1590510A (en) | 1981-06-03 |
AU518434B2 (en) | 1981-10-01 |
BE863904A (fr) | 1978-05-29 |
ES467263A1 (es) | 1978-10-16 |
FR2407253A1 (fr) | 1979-05-25 |
MX149051A (es) | 1983-08-15 |
IT7848766A0 (it) | 1978-04-06 |
NL175440C (nl) | 1984-11-01 |
JPS5726675B2 (bg) | 1982-06-05 |
US4163733A (en) | 1979-08-07 |
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