RU2654696C2 - Гетерофазный сополимер пропилена с высокой температурой плавления - Google Patents

Гетерофазный сополимер пропилена с высокой температурой плавления Download PDF

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Publication number
RU2654696C2
RU2654696C2 RU2016139260A RU2016139260A RU2654696C2 RU 2654696 C2 RU2654696 C2 RU 2654696C2 RU 2016139260 A RU2016139260 A RU 2016139260A RU 2016139260 A RU2016139260 A RU 2016139260A RU 2654696 C2 RU2654696 C2 RU 2654696C2
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Prior art keywords
propylene copolymer
raheco
fraction
heterophasic propylene
mol
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RU2016139260A
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English (en)
Russian (ru)
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RU2016139260A (ru
Inventor
Джингбо Ванг
Петар Дошев
Маркус ГАХЛЕИТНЕР
Йоханна Лильхья
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Бореалис Аг
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethylene-propylene or ethylene-propylene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/02Heterophasic composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
RU2016139260A 2014-03-21 2015-02-03 Гетерофазный сополимер пропилена с высокой температурой плавления RU2654696C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14161005 2014-03-21
EP14161005.5 2014-03-21
PCT/EP2015/052198 WO2015139875A1 (en) 2014-03-21 2015-02-03 Heterophasic propylene copolymer with high melting point

Publications (2)

Publication Number Publication Date
RU2016139260A RU2016139260A (ru) 2018-04-23
RU2654696C2 true RU2654696C2 (ru) 2018-05-22

Family

ID=50336181

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2016139260A RU2654696C2 (ru) 2014-03-21 2015-02-03 Гетерофазный сополимер пропилена с высокой температурой плавления

Country Status (10)

Country Link
US (1) US10053568B2 (https=)
EP (1) EP3119816B2 (https=)
JP (2) JP2017514926A (https=)
KR (1) KR101742453B1 (https=)
CN (1) CN106062014B (https=)
BR (1) BR112016019583B1 (https=)
ES (1) ES2699641T5 (https=)
PL (1) PL3119816T5 (https=)
RU (1) RU2654696C2 (https=)
WO (1) WO2015139875A1 (https=)

Cited By (1)

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RU2746595C1 (ru) * 2017-12-28 2021-04-16 Бореалис Аг Оболочка кабеля

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BR112016017227B1 (pt) * 2014-02-06 2021-06-29 Borealis Ag Copolímero de propileno heterofásico, película não orientada, recipiente, e uso de um copolímero de propileno heterofásico
JP2017508032A (ja) 2014-02-06 2017-03-23 ボレアリス エージー 高衝撃強さを有する軟質コポリマー
US10723870B2 (en) 2015-02-20 2020-07-28 Borealis Ag Process for producing heterophasic copolymers of propylene
EP3263640B1 (en) * 2016-06-28 2025-08-13 Borealis GmbH Soft and transparent polypropylene composition
US11453767B2 (en) 2017-03-27 2022-09-27 Basell Poliolefine Italia S.R.L. Propylene ethylene random copolymer
CN110770264B (zh) * 2017-07-07 2022-10-14 博里利斯股份公司 制备多相丙烯共聚物的方法
EP3740533B1 (en) * 2018-01-18 2022-08-17 Borealis AG Heterophasic polypropylene composition with high flexibility and softness
EP3856800A1 (en) * 2018-09-28 2021-08-04 Borealis AG Process for producing a prepolymerized solid ziegler-natta catalyst
ES2945963T3 (es) 2018-12-14 2023-07-11 Borealis Ag Composición de polipropileno con combinación favorable de óptica, suavidad y bajo sellado
EP3670547B1 (en) * 2018-12-21 2023-06-07 Borealis AG Polypropylene composition for film sealing layer
EP3980473B1 (en) 2019-06-05 2024-08-07 Borealis AG Multilayer polyproplyene film
EP3750927A1 (en) 2019-06-12 2020-12-16 Borealis AG Heterophasic propylene copolymer with improved mechanical properties
CN114929800B (zh) * 2020-02-14 2024-09-03 Sabic环球技术有限责任公司 包含多相丙烯共聚物组合物的膜
WO2022157231A1 (en) * 2021-01-22 2022-07-28 Borealis Ag Fiber reinforced polypropylene composition
JP2024510836A (ja) * 2021-03-24 2024-03-11 ボレアリス エージー コポリマー
US20240174774A1 (en) * 2021-03-24 2024-05-30 Borealis Ag Process for producing heterophasic propylene resin
WO2025117354A1 (en) * 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Methods for producing impact copolymers using c1 symmetric metallocene catalysts

Citations (6)

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WO2005023891A1 (en) * 2003-09-11 2005-03-17 Basell Polyolefine Gmbh Multistep process for preparing heterophasic propylene copolymers
WO2012016965A1 (en) * 2010-08-06 2012-02-09 Borealis Ag Heterophasic propylene copolymer with excellent impact/stiffness balance
WO2012028252A1 (en) * 2010-08-30 2012-03-08 Borealis Ag Heterophasic polypropylene with high flowability and enhanced mechanical properties
RU2446181C1 (ru) * 2007-12-18 2012-03-27 Бореалис Текнолоджи Ой Гетерофазный полипропилен с характеристиками высокой ударной вязкости
WO2012159927A1 (en) * 2011-05-23 2012-11-29 Borealis Ag Random propylene copolymer with high stiffness and low haze
EP2557118A1 (en) * 2011-08-09 2013-02-13 Borealis AG Preparation of a soft heterophasic propylene copolymer

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Publication number Priority date Publication date Assignee Title
WO2005023891A1 (en) * 2003-09-11 2005-03-17 Basell Polyolefine Gmbh Multistep process for preparing heterophasic propylene copolymers
RU2446181C1 (ru) * 2007-12-18 2012-03-27 Бореалис Текнолоджи Ой Гетерофазный полипропилен с характеристиками высокой ударной вязкости
WO2012016965A1 (en) * 2010-08-06 2012-02-09 Borealis Ag Heterophasic propylene copolymer with excellent impact/stiffness balance
WO2012028252A1 (en) * 2010-08-30 2012-03-08 Borealis Ag Heterophasic polypropylene with high flowability and enhanced mechanical properties
WO2012159927A1 (en) * 2011-05-23 2012-11-29 Borealis Ag Random propylene copolymer with high stiffness and low haze
EP2557118A1 (en) * 2011-08-09 2013-02-13 Borealis AG Preparation of a soft heterophasic propylene copolymer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2746595C1 (ru) * 2017-12-28 2021-04-16 Бореалис Аг Оболочка кабеля
RU2746595C9 (ru) * 2017-12-28 2021-06-08 Бореалис Аг Оболочка кабеля

Also Published As

Publication number Publication date
ES2699641T3 (es) 2019-02-12
EP3119816B2 (en) 2023-02-22
BR112016019583B1 (pt) 2022-03-29
JP2018059116A (ja) 2018-04-12
CN106062014A (zh) 2016-10-26
US20170066912A1 (en) 2017-03-09
EP3119816B1 (en) 2018-09-12
CN106062014B (zh) 2018-03-30
RU2016139260A (ru) 2018-04-23
WO2015139875A1 (en) 2015-09-24
JP2017514926A (ja) 2017-06-08
US10053568B2 (en) 2018-08-21
KR20160120354A (ko) 2016-10-17
EP3119816A1 (en) 2017-01-25
KR101742453B1 (ko) 2017-05-31
PL3119816T5 (pl) 2023-05-15
ES2699641T5 (es) 2023-06-07
BR112016019583A2 (https=) 2017-08-15
PL3119816T3 (pl) 2019-02-28

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